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    Volumetric Analysis-2

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    Chithrakumar
    1. The document describes a procedure to prepare a Mohr's salt (FAS) solution with a concentration of M/30 and use it to estimate the concentration of a KMnO4 solution through titration. 2. FAS solution is prepared by weighing the appropriate amount of Mohr's salt to make a 0.033 M solution. This is then titrated against the KMnO4 solution until a pale pink color persists. 3. The molarity of KMnO4 is calculated based on the moles of FAS and volume of KMnO4 solution used in the titration. This is then used to calculate the strength of KMnO4 in g/L.

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    Volumetric Analysis-2

    Uploaded by

    Chithrakumar
    120 views4 pages
    1. The document describes a procedure to prepare a Mohr's salt (FAS) solution with a concentration of M/30 and use it to estimate the concentration of a KMnO4 solution through titration. 2. FAS solution is prepared by weighing the appropriate amount of Mohr's salt to make a 0.033 M solution. This is then titrated against the KMnO4 solution until a pale pink color persists. 3. The molarity of KMnO4 is calculated based on the moles of FAS and volume of KMnO4 solution used in the titration. This is then used to calculate the strength of KMnO4 in g/L.

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    VOLUMETRIC ANALYSIS-2

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    1. The document describes a procedure to prepare a Mohr's salt (FAS) solution with a concentration of M/30 and use it to estimate the concentration of a KMnO4 solution through titration. 2. FAS solution is prepared by weighing the appropriate amount of Mohr's salt to make a 0.033 M solution. This is then titrated against the KMnO4 solution until a pale pink color persists. 3. The molarity of KMnO4 is calculated based on the moles of FAS and volume of KMnO4 solution used in the titration. This is then used to calculate the strength of KMnO4 in g/L.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    120 views4 pages

    Volumetric Analysis-2

    Uploaded by

    Chithrakumar
    1. The document describes a procedure to prepare a Mohr's salt (FAS) solution with a concentration of M/30 and use it to estimate the concentration of a KMnO4 solution through titration. 2. FAS solution is prepared by weighing the appropriate amount of Mohr's salt to make a 0.033 M solution. This is then titrated against the KMnO4 solution until a pale pink color persists. 3. The molarity of KMnO4 is calculated based on the moles of FAS and volume of KMnO4 solution used in the titration. This is then used to calculate the strength of KMnO4 in g/L.

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    ESTIMATION OF KMnO4 using MOHR SALT (FAS) solution (M/10)

    AIM:[R1] To prepare a Mohr Salt (Ferrous Ammonium Sulphate-FAS) Solution M/10


    concentration and estimate the strength of KMnO 4 using Mohr salt solution.
    APPARATUS REQUIRED: [R2]
     Burette
     Conical flask
     Funnel
     Pipette.
     Standard Mohr salt solution.
     KMnO4 solution.
    PRINCIPLE: [R3] KMnO4 solution acts an Oxidising agent in acid medium and reacts with
    FAS solution which acts as reducing agent.
    PROCEDURE: [R4]
    1) The Mohr’s salt solution of required concentration is prepared by weighing the salt
    accurately and making the solution up to 250 mL in standard flask.
    2) The burette is rinsed and filled with KMnO 4 solution 20 mL of ferrous ammonium
    sulphate solution is pipette out into a conical flask.
    3) One test tube of Dilute 2N H2SO4 is added (approximately 20mL).
    4) The initial reading of the burette is noted and the content in the conical flask is titrated
    against KMnO4until the appearance of pale permanent pink colour.
    5) Final reading of the burette is recorded.
    6) The difference gives the value of KMnO 4 to oxidise ferrous ions present in 20 mL of
    Mohr salt.
    7) The titration is repeated and the concordant value is recorded.
    SHORT PROCEDURE:[L1]
    Burette solution : KMnO4 solution
    Pipette solution : Standard Mohr’s salt (FAS) Solution
    Conical flask : 20 mL of FAS +20 mL of 2N H 2SO4
    Temperature : Room temperature
    Indicator : Self Indicator
    End Point : Appearance of pale permanent pink colour.
    REACTIONS: [L2] MnO4- +8H+ +5Fe2+  Mn2+ +5Fe3+ +4H2O
    Oxidation: [Fe2+ Fe3++e-] x 5
    Reduction: MnO4- +8H+ +5e- Mn2++4H2O
    OBSERVATIONS AND CALCULATIONS: [L3]
    Preparation of Standard solution of Mohr salt:
    Calculation of weight to be weighed to prepare 250 mL M/10 solution of Mohr salt
    THEORETICAL VALUE: [L4] [MM of FAS- FeSO4. (NH4)2SO4.6H2O=392 g/mol]
    Wt/Lt = Molecular mass x Molarity = 392 g/mol × 0.1 mol/L (M/10 = 0.1 M) = 39.2 g/L
    Wt for 250 mL = 39.2/4 = 9.8 g
    MOLARITY OF FAS:[L5] Wt/Lt/GMm = 39.2 g/L /392 g/mol = 0.1 M
    PREPARATION OF STANDARD FAS:[L6]
    Weight of FAS = 9.8 g
    Weight of paper = __ g
    Weight of FAS+Paper = 9.8 g+__ g
    STANDARDISATION OF FAS vs KMnO4:[L7]
    S No Volume of Burette Reading Volume of Concordant
    FAS (mL) Initial Final KMnO4(mL) Value
    1 20 0
    2 20 0
    3 20 0

    (VxMxN)KMnO4 = (VxMxN) FAS


    MKMnO4 = (VxMxN) FAS = 20x0.1x1 = M
    (VxN)KMnO4 __ x 5
    Strength of KMnO4= Molecular Mass x M KMnO4 = 158 x = gL-1.
    RESULT:[R5]
    1. Molarity of FAS = 0.1 M
    2. Molarity of KMnO 4 = __ M
    3. Strength of KMnO 4 = __ g/L
    ESTIMATION OF KMnO4 using MOHR SALT (FAS) solution (M/30).
    AIM:[R1] To prepare a Mohr’s Salt (Ferrous Ammonium Sulphate-FAS) Solution M/30
    concentration and estimate the strength of KMnO 4 using Mohr salt solution.
    APPARATUS REQUIRED: [R2]
     Burette
     Conical flask
     Funnel
     Pipette.
     Standard Mohr salt solution.
     KMnO4solution.
    PRINCIPLE: [R3] KMnO4solution acts an Oxidising agent in acid medium and react
    with FAS solution which acts as a reducing agent.
    PROCEDURE: [R4]
    1. The Mohr’s salt solution of required concentration is prepared by weighing the salt
    accurately and making the solution up to 250 mL in standard flask.
    2. The burette is rinsed and filled with KMnO 4solution 20 mL of ferrous ammonium
    sulphate solution is pipetted out into a conical flask.
    3. One test tube of Dilute 2N H2SO4 is added (approximately 20mL).
    4. The initial reading of the burette is noted and the content in the conical flask is titrated
    against KMnO4until the appearance of pale permanent pink colour.
    5. Final reading of the burette is recorded.
    6. The difference gives the value of KMnO 4to oxidise ferrous ions present in 20 mL of
    Mohr salt.
    7. The titration is repeated and the concordant value is recorded.
    SHORT PROCEDURE:[L1]
    Burette solution : KMnO4solution
    Pipette solution : Standard Mohr’s salt (FAS) Solution
    Conical flask : 20 mL of FAS +20 mL of 2N H 2SO4
    Temperature : Room temperature
    Indicator : Self Indicator
    End Point : Appearance of pale permanent pink colour.
    REACTIONS: [L2] MnO4- +8H+ +5Fe2+  Mn2+ +5Fe3+ +4H2O
    Oxidation: [Fe2+  Fe3++e-] x5
    Reduction: MnO4- +8H+ +5e-  Mn2+ +4H2O
    OBSERVATIONS AND CALCULATIONS: [L3]
    Preparation of Standard solution of Mohr salt:
    Calculation of weight to be weighed to prepare 250 mL M/30 solution of Mohr salt
    THEORETICAL VALUE: [L4] [MM of FAS- FeSO4. (NH4)2SO4.6H2O=392 g/mol]
    Wt/Lt = Molecular Mass x Molarity = 392 g/mol × 0.033 mol/L (M/30 = 0.033 M) = 13.06 g/L
    Wt for 250 mL = 13.06/4 = 3.268 g
    MOLARITY OF FAS: [L5] Wt/Lt/ MM = 13.06 g/L /392 g/mol = 0.033 M
    PREPARATION OF STANDARD FAS:[L6]
    Weight of FAS = 3.268 g
    Weight of paper = __ g
    Weight of FAS+ Paper = 3.268 g + __ g
    STANDARDISATION OF FAS vs KMnO4:[L7]
    S No Volume of Burette Reading Volume of Concordant
    FAS (mL) Initial Final KMnO4(mL) Value
    1 20 0
    2 20 0
    3 20 0

    (VxMxN)KMnO4 = (VxMxN)FAS
    M KMnO4 = (VxMxN) FAS = 20x0.033x1 = __ M
    (VxN)KMnO4 __ x 5
    Strength of KMnO4= Molecular Mass x M KMnO4 = 158 x __ = gL-1.
    RESULT:[R5]
    1. Molarity of FAS = 0.033 M
    2. Molarity of KMnO 4= __ M
    3. Strength of KMnO 4=__ g/L

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