ANNEXURE II

The Maharaja Sayajirao University of Baroda

Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Chemistry
YEAR III Core CREDIT 3
Semester I Paper-1
HOURS 45
Inorganic Chemistry-I

OBJECTIVES:
COURSE CONTENT / SYLLABUS
Main Group Elements-1
Chemistry of Boron family : Electron deficiency and acceptor behavior, Oxides, hydroxides
and halides, boronnitride and borazole. Structure, bonding and important applications.
UNIT-I
Boranes, borohydrides and carboranes. 15 hrs.
Chemistry of Carbon family: Allotropy, trends in metallic properties and conduction,
structure, bonding and properties of oxides. Carbides, graphitic compounds, silicates,
zeolites, feldspars, ultramarines and clay minerals. Synthetic zeolites and clays.

Main Group Elements-2

Nitrogen family: hydrazine, hydroxylamine and hydrazoic acid, hydrides of other elements,
oxides and halides, oxyacids of nitrogen and phosphorous.
Chemistry of Oxygen family : Ozone, oxides, peroxides and superoxides. Oxyacids and
UNIT-II
halides of sulphur, peracids and persalts of sulphur, Chemistry and applications of lead 15 hrs.
compounds, toxicity and biological role of selenium and tellurium. Chemistry of Halogens:
Oxides and oxyacids of halogens, peracids and persalts, interhalogen compounds,
pseudohalogens and polyhalides, basic properties of Iodine, Chemistry of Astatine.
Chemistry of Noble Gases: Oxides, fluorides and oxyfluorides of xenon.

Novel Inorganic Solids

Synthesis and modification of inorganic solids: Conventional heat and beatmethods, Co-
precipitation method, Sol-gel methods, Hydrothermal method, Ion-exchange and
Intercalation methods. Inorganic solids of technological importance: Solid electrolytes –
UNIT-III Cationic, anionic, mixed Molecular material and fullerides, molecular materials & 15 hrs.
chemistry – one-dimensional metals, molecular magnets, inorganic liquid crystals.
Introduction to inorganic polymers, comparison with organic polymers, synthesis,
structural aspects and applications of silicones.
Inorganic Pigments: Types of pigment, physical and chemical properties, choice of
pigment, synthetic iron oxide, titania, colloidal gold, zircon, glaze stains.
REFERENCES
1. Lee J.D., (1991) Concise Inorganic Chemistry, 4th Edition, Chapman and Hall
2. Cotton F.A. and Wilkinson G., (1988) Basic Inorganic Chemistry, Wiley Eastern.
3. Huheey J.E., (1983), Inorganic Chemistry: Principles of Inorganic Chemistry, 4th Edition, Harper-Collins
4.
Rodgers Glen E., Introduction to Coordination, Solid State & Descriptive Inorganic Chemistry, McGraw Hill
Inc. (1994).

1
5 Cotton F.A. & Wilkinson G, Advanced Inorganic Chemistry, 6th Ed., Wiley Interscience (1999).
6 Sanderson R.T., Inorganic Chemistry, East-West Press (1971).
7 Purcell K.F. & Kotz J.C., Inorganic Chemistry, Holt-Saunders (1980).
8
Rodgers Glen E., Introduction to Coordination, Solid State & Descriptive Inorganic Chemistry, McGraw Hill
Inc. (1994).

2
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Chemistry
YEAR III Core CREDIT 3
Semester I Paper-2
HOURS 45
Organic Chemistry-I

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Stereochemistry of Organic Compounds
Stereochemistry of Organic Compounds: Conformation, energy of conformers,
conformation of cyclohexane, Conformation of mono- and di-substituted cyclohexanes,
1,2-, 1,3- and 1,4- disubstituted cyclohexanes and their relative energies, chair form of 
and  D- glucose.
UNIT-I Chirality in organic compounds: Concept of chirality, generation of chiral centre, reactions 15 hrs.
remote from chiral centre, correlating stereochemistry of chiral compounds, generation of
another chiral centre, reaction of chiral compounds with chiral compounds, resolution,
stereochemical outcome of addition of halogens to alkenes. Chirality in absence
ofstereogenic centre, chiral biphenyls, atropisomerism, chiral allenes and spiro
compounds.
Carbohydrates
Carbohydrates: Classification and nomenclature, open chain and cyclic structure of
glucose, determination of ring size, mutarotation and its mechanism, epimers, chain
shortening and chain lengthening of aldose, conversion of glucose to fructose and
UNIT-II Mannose, conversion of fructose to glucose, formation of glycosides, ethers and esters, 15 hrs.
erythro and threo diastereoisomers. Disaccharides and polysaccharides: Introduction to
maltose, sucrose and lactose, starch and cellulose.
Energy production in biological systems, biological oxidation of alcohols and
carbohydrates.
Heterocyclic compounds
Heterocyclic compounds: Introduction, structure, molecular orbitals and aromaticity in
pyrrole, furan and thiophene, methods of preparation, electrophilic and nucleophilic
substitution reactions with mechanism; relative basicity of pyridine, piperidine and pyrrole.
UNIT-III Condensed five and six member heterocycles: Introduction and nomenclature, preparation 15 hrs.
and reactions of indole, quinoline and isoquinoline, Fischer indole synthesis, Skraup
synthesis, Bischler-Napieralski synthesis, electrophilic and nucleophilic substitution
reactions of indole, quinoline and isoquinoline.

REFERENCES
1. Morrison R.T., Boyd R.N.; Organic Chemistry, Prentice Hall of India, NewDelhi (VI Ed).
2. Pine S.H; (1993) Organic Chemistry, McGraw Hill, New Delhi.
3. Loudon G M; (2002) Organic Chemistry, Oxford, New York.
4.
Roberts J.D. and Caserio M.C., (1992) Basic Principles of Organic Chemistry, 2nd
Edition, W.A. Benjamin Inc., California, USA.

3
5. Graham Solomons T.W. and Fryhle C., (2002) Organic Chemistry, John Wiley
6. Singh S.P. and Mukherjee S.M; (1984) Organic Chemistry, McMillan India.
7. Finar I.L; (2013 print) Organic Chemistry, Vol 1 & 2, Pearson Edu. Ltd
8. Arora M. G.; (1997) Stereochemistry in Organic Compounds, Anmol Publ. New Delhi

4
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Chemistry
YEAR III Core CREDIT 3
Semester I Paper-3
HOURS 45
Physical Chemistry-II
OBJECTIVES:

COURSE CONTENT / SYLLABUS

Phase equilibria I
Phases, components, degrees of freedom, equilibrium between phases, phase boundaries,
phase stability and phase transitions, Ehrenfest classification of phase transitions, phase 15 hrs.
UNIT-I
diagrams. Derivation of phase rule and Experimental procedures for phase studies. One
component systems (Water, sulphur, carbon dioxide, carbon, helium), supercritical fluid.
Two component systems involving eutectics, congruent and incongruent melting points.
Electrochemistry I
Electrolytic and galvanic cells, reversible and irreversible cells. EMF of a Cell and its
measurement. Nernst’s equation. Determination of E0 and equilibrium constant of cell
reaction. Standard electrodes (including reference electrodes). Electrochemical series of 15 hrs.
UNIT-II
electrode potentials. Convention for half-cell potential. Applications of EMF
measurements: Determination of solubility product, pH, mean activity coefficient,
transport number. Potentiometric titrations: Acid-base, Precipitation and Redox. Weston-
Cadmium cell
Thermodynamics
Second law of thermodynamics: Need for the II law, statements of the second law.
Spontaneous process, Carnot’s cycle and efficiency of heat engine. Concept of entropy,
definition, entropy of an ideal gas, entropy changes in cyclic, reversible and irreversible
processes and physical transformations. Calculation of entropy changes with changes in T,
UNIT-III 15 hrs.
V and P, entropy of mixing. Gibbs free energy, Helmholtz work functions, their variations
with temperature, pressure and volume. Criteria for spontaneity, Gibbs-Helmholtz
equations- derivation and its applications. Third law of Thermodynamics: Nernst heat
theorem, statement of third law of thermodynamics. Evaluation and absolute entropy from
heat capacity measurements. Exception to third law.
REFERENCES

1.
Atkins P. and Paula J. D. (2006), Physical Chemistry, 8th Edition (International Student
Edition) Oxford Univ. Press, New Delhi.
2.
Glasstone, S. (1990), Text Book of Physical Chemistry, 2nd Edition Reprint, Macmillan and Co. Ltd., New
York
3.
Puri, B. R., Sharma, L.R. and Pathania, M. S. (2009), 44st Edition, Principles of Physical Chemistry, Vishal
Publ. Co., Jalandhar
4.
Bahl, B.S., Bahl A. and Tuli, G.D. (2007), Essentials of Physical Chemistry, 25th Edition,
S. Chand, New Delhi.
5. Engel T. and Reid P. (2007), Physical Chemistry, Pearson Prentice Hall, Noida.
6. Mahan B. H. (2009), University Chemistry,3rd Edition, Narosa Publishing House, New Delhi.

5
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Chemistry
YEAR III Core CREDIT 3
Semester I Paper-4
HOURS 45
Chemistry- IX

OBJECTIVES:

COURSE CONTENT / SYLLABUS

QUANTUM MECHANICS
Schrodinger wave equation, Laplacian operator, Energy associated with particle in one
dimensional box (qualitative treatment). Polar coordinates r, and . Separation of the
wave equation in translational and rotational parts, , and R equations and the (),
UNIT-I () and R(r) functions. Quantum numbers derived from the wave equation, relation 15 hrs.
between quantum numbers and radial and angular nodes, spherical harmonics and shapes
of orbitals. Radial probability, Screening effect and order of suborbital energies in
multielectronic atoms, Ground spectral states of atoms and ions (up to Z=30).
Elementary concept of symmetry elements and symmetry operations, Point symmetries,
CnV, D4h, D6h, Td and Oh.
Absorption Spectroscopy of Organic Compounds
Electromagnetic spectrum, interaction of electromagnetic radiation with matter, atomic
and molecular spectroscopy, absorption and emission spectroscopy.
Ultraviolet-Visible (UV-Vis) Spectroscopy: Absorption laws, instrumentation, UV-Vis
spectrum, types of electronic transitions, concept of chromophore and auxochrome, UV
UNIT-II spectra of alkenes, conjugated enes, enones and aromatic compounds. 15 hrs.
Infrared (IR) Spectroscopy: Molecular vibrations, Hooke’s law, selection rules,
instrumentation and measurement of IR spectrum, Fundamental, overtone, combination
and coupled bands, fingerprint region, characteristic absorptions of various organic
compounds such as hydrocarbons, ethers, halides, alcohols, phenols, carbonyl compounds
including acid derivatives, amines and nitro compounds.
Chemical Equilibrium
Equilibrium constant and free energy, Thermodynamic derivation of law of mass action, Le
Chatelier’s principle. Reaction isotherm and isochore-Clapeyron equation and Clausius-
Clapeyron equation, applications.
UNIT-III 15 hrs.
Partial Molar Properties: Chemical potential, Gibbs-Duhem equation- effect of
temperature and pressure on chemical potential, chemical potential in system of ideal
gases, Duhem-Margules equation. Concept of Fugacity, activity and activity coefficient,
Methods for determination of fugacity of gas.
REFERENCES
1 Day M. C. and Selbin J., (1985) Theoretical Inorganic Chemistry, East-West Press
Cartmell E. and Fowles G.W.A., (1977)Valency and Molecular Structure, 4th Edition.
2
ELBS, Butterworths,
3 Kettle S. F. A., Murrell J. N. and Teddler S., (1985) The Chemical Bond, ELBS. Butterworths

6
4 Lee J.D., (1991) Concise Inorganic Chemistry, 4th Edition, Chapman and Hall

5 Emeleus H.J. and Sharpe A.G., (1994) Modern Aspects of Inorganic Chemistry, 4th Edition, UBS.

6 Banerjea D., Coordination Chemistry, Tata McGraw Hill (1993).

7 Cotton. F.A. & Wilkinson G., Basic Inorganic Chemistry, Wiley Eastern (1988).

8 Huheey J.E. & Harper-Collins, Inorganic Chemistry: Principles of Inorganic Chemistry, 4th Edition (1983).

9 Cotton F.A. & Wilkinson G, Advanced Inorganic Chemistry, 6th Ed., Wiley Interscience (1999).

10 Purcell K.F. & Kotz J.C., Inorganic Chemistry, Holt-Saunders (1980).

Atkins P., Overton T., Rourke J., Weller M. & Armstrong F., “Shriver and Atkins – Inorganic Chemistry"
11
4th edition. Oxford University Press, Oxford (2006).

7
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Chemistry
YEAR III Discipline Specific Elective--1 CREDIT 2
Semester I
HOURS 30
Green Chemistry

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Introduction to Green Chemistry
What is Green Chemistry? Need for Green Chemistry. Goals of Green Chemistry.
Limitations/Obstacles in the pursuit of the goals of Green Chemistry. Principles of Green
Chemistry and Designing a Chemical synthesis. Twelve principles of Green Chemistry
with their explanations and special emphasis on the following examples: Designing a
Green Synthesis using these principles; Prevention of Waste/by products; maximum
incorporation of the materials used in the process into the final products, Atom Economy,
UNIT-I 15 hrs.
calculation of atom economy of the rearrangement, addition, substitution and
elimination reactions; Prevention/minimization of hazardous/toxic products reducing
toxicity risk = (function) hazard x exposure; waste or pollution prevention hierarchy;
Green solvents- super critical fluids, water as a solvent for organic reactions, ionic liquids,
fluorous biphasic solvent, PEG, solvent less processes, immobilized solvents and how to
compare greenness of solvents; Microwave assisted reactions in water and organic
solvents. Microwave assisted solid state reactions; Ultrasound assisted reactions.
Green Synthesis of the following compounds
adipic acid, catechol, methyl methacrylate, urethane, aromatic amines (4-
aminodiphenylamine), benzyl bromide, acetaldehyde, disodium iminodiacetate
UNIT-II (alternative to strecker synthesis), citral, ibuprofen, paracetamol, furfural. 15 hrs.
Biomass conversion: Introduction and importance of biomass, Composition, Pre-
treatment, Biorefinery; Catalytic pyrolysis of lignocellulosic biomass; Biomass to liquid
Bio fuels via heterogeneous catalysis
REFERENCES
1. Green chemistry, Theory and Practice, P.T. Anatase and J.C. Warner, Oxford University press, 2000
V.K. Ahluwalia & M.R. Kidwai: New Trends in Green Chemistry,2nd edition, Anamalaya Publishers
2.
(2005).
Real-World cases in Green Chemistry, M.C. Cann & M.E. Connely, American Chemical Society,
3.
Washington (2000).
Introduction to Green Chemistry, American Chemical Society, M.A. Ryan & M. Tinnesand, Washington
4.
(2002).
5. Green Chemistry: Introductory Text. M. Lancaster Royal Society of Chemistry (London) 2002
6. Green Chemistry, 2nd Ed: Environmentally benign reactions. V.K. Ahluwalia. Ane Books Pvt. Ltd., 2012
7. Fuel production with heterogeneous catalysis, edited by Jacinto Sa, CRC press.

8
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Chemistry
YEAR III Discipline Specific Elective--2 CREDIT 2
Semester I Medicinal Chemistry and Natural Products HOURS 30

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Medicinal Chemistry
Introduction, Characteristic of drugs, Terminology, Classification of drugs. Anti-
malarial agents: Malaria cycle. Structure and synthesis of chloroquine and
primaquine. Antipyretics & Analgesics: Classification, Synthesis and action of
Paracetamol, Phenacetin, Ibuprofen. Antibiotics: Introduction, classification, broad
UNIT-I 15 hrs.
spectrum antibiotics- Penicillin and amoxycilin. Anticancer agents: Causes &
treatment of cancer, Limitations of cancer therapy, classification, Synthesis,
uses and mode of action of mechlorethamine, melphalan, chlorambucil.
Antitubercular agents: Characteristic and classification, synthesis and uses of
Isoniazide & Ethambutol.
Vitamins
Introduction to Vitamins and Classification, Vitamin A1 (retinoI): structure
elucidation and synthesis, its role in vision. Vitamin K1 (phylloquinone):
Structure elucidation and synthesis. Vitamin C (ascorbic acid): Structure
elucidation and different methods of synthesis including biosynthesis (Gorlich
and Bakke).
UNIT-II Natural pigments: Introduction, pigments in apple. rose, carrot and 15 hrs.
tomato. General methods of extraction and purification of natural
pigments, Structure elucidation and synthesis of flavone. flavylium chloride
and quercetin. Structure elucidation and synthesis of cyanidin chloride and
cyanin. Carotenes: Structure elucidation and synthesis (one) of β-carotene.
Structure relation between α- β-, γ-carotenes and lycopene. Structure and
function of porphyrin pigments- haemin and chlorophyll.
REFERENCES
1. Kar A.: Medicinal Chemistry. New Age International Publishers.
2. Chatwal G. R,. Synthetic Drugs.-Himalaya Publication Home
3. Finar I.L; (2013 print) Organic Chemistry, Vol 1 & 2, Pearson Edu. Ltd
Chatwal G R: Organic Chemistry of Natural Products Vol. 1&2. Himalaya
4.
Publication Home

9
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-‘22

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Elective-1 CREDIT 8
Semester I Inorganic Chemistry Practical-1 HOURS 180

OBJECTIVES:
Practical Training

COURSE CONTENT / SYLLABUS

Quantitative Inorganic Analysis:

(1) Introduction to Gravimetric method of analysis and estimation of iron/

aluminium as oxide.

(2) Separation of Binary mixtures of metal ions and their estimation by suitable
combination of the following methods: 60
a. Gravimetric analysis
b. Alkalimetry
c. Redox titrations
d. Complexometric titrations
e. Argentimetry

REFERENCES

1.
Mendham J., Denney R C, Barnes J B, MJK Thomas, (2003) Vogel’s Textbook of Quantitative Chemical
Analysis, 6th Edition, Pearson Education, New Delhi.
2. Suehla G, (!989)Vogel’s Qualitative Inorganic Analysis, 6th Edition, Orient Longman,
3. Shah R C, (1996)Inorganic Analysis Part-I, 5th Edition Baroda Book Depot, Vadodara
4. Shah R C, (1996)Inorganic Analysis Part-II R C Shah, 5th Edition, Baroda Book Depot, Vadodara
5
John Bassett (Editor) Vogel's Textbook of Quantitative Inorganic Analysis, Including Elementary
Instrumental Analysis, 4th edition, Longman Science and Tech
6 Shah R C, (2001) Organic Analysis Part I Qualitative Analysis Baroda Book Depot,
7 Shoemaker, D. P., Garland, C.W. and Nibler, J.W. (1996), Experiments in Physical Chemistry, McGraw Hill
8 Findlay, A. (1972), Practical Physical Chemistry, 9th Edition, B.P. Levitt, Longman, London.
9
Athawale,V. D. and Mathur, P. (2001), Experimental Physical Chemistry, 1st Edition, New Age
International Publication, New Delhi.
10 Yadav, J.B. (2003), Advanced Practical Physical Chemistry, Goel Pub., Meerut.

10
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-‘22

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Elective-2 CREDIT 8
Semester I Organic Chemistry Practical-1 HOURS 180

OBJECTIVES:
Practical Training

COURSE CONTENT / SYLLABUS

Separation of binary mixtures of Organic Compounds and identification
i) Solid + Solid (6-7 mixtures).
ii) Liquid + Liquid (6-7 mixtures). 60
iii) Solid + Liquid (2-3 mixtures).

REFERENCES

1.
Mendham J., Denney R C, Barnes J B, MJK Thomas, (2003) Vogel’s Textbook of Quantitative Chemical
Analysis, 6th Edition, Pearson Education, New Delhi.
2. Suehla G, (!989)Vogel’s Qualitative Inorganic Analysis, 6th Edition, Orient Longman,
3. Shah R C, (1996)Inorganic Analysis Part-I, 5th Edition Baroda Book Depot, Vadodara
4. Shah R C, (1996)Inorganic Analysis Part-II R C Shah, 5th Edition, Baroda Book Depot, Vadodara
John Bassett (Editor) Vogel's Textbook of Quantitative Inorganic Analysis, Including Elementary
5
Instrumental Analysis, 4th edition, Longman Science and Tech
6 Shah R C, (2001) Organic Analysis Part I Qualitative Analysis Baroda Book Depot,
7 Shoemaker, D. P., Garland, C.W. and Nibler, J.W. (1996), Experiments in Physical Chemistry, McGraw Hill
8 Findlay, A. (1972), Practical Physical Chemistry, 9th Edition, B.P. Levitt, Longman, London.
9
Athawale,V. D. and Mathur, P. (2001), Experimental Physical Chemistry, 1st Edition, New Age
International Publication, New Delhi.
10 Yadav, J.B. (2003), Advanced Practical Physical Chemistry, Goel Pub., Meerut.

11
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-‘22

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Elective-3 CREDIT 8
Semester I Physical Chemistry Practical-1 HOURS 180

OBJECTIVES:
Practical Training

COURSE CONTENT / SYLLABUS

Physical Chemistry Experiments:
1. Potentiometeric titration : strong acid – strong base
weak acid -- strong base
2. Conductomertic titration: strong acid – strong base
weak acid -- strong base
weak acid -- weak base
3. Determination of Surface tension and Parachor of liquid. 60
4. Determination of composition of mixture of liquids by Viscometry.
5. Determination of composition of mixture of liquids by Refractometry.
6. Molecular weight by Victor Meyer’s method.
7. Adsorption of oxalic acid on charcoal.
8. Determination of percentage of glucose/sucrose by polarimetry.
9. Dissociation constant of weak acid/base by pH metry.

REFERENCES

1.
Mendham J., Denney R C, Barnes J B, MJK Thomas, (2003) Vogel’s Textbook of Quantitative Chemical
Analysis, 6th Edition, Pearson Education, New Delhi.
2. Suehla G, (!989)Vogel’s Qualitative Inorganic Analysis, 6th Edition, Orient Longman,
3. Shah R C, (1996)Inorganic Analysis Part-I, 5th Edition Baroda Book Depot, Vadodara
4. Shah R C, (1996)Inorganic Analysis Part-II R C Shah, 5th Edition, Baroda Book Depot, Vadodara
5
John Bassett (Editor) Vogel's Textbook of Quantitative Inorganic Analysis, Including Elementary
Instrumental Analysis, 4th edition, Longman Science and Tech
6 Shah R C, (2001) Organic Analysis Part I Qualitative Analysis Baroda Book Depot,
7 Shoemaker, D. P., Garland, C.W. and Nibler, J.W. (1996), Experiments in Physical Chemistry, McGraw Hill
8 Findlay, A. (1972), Practical Physical Chemistry, 9th Edition, B.P. Levitt, Longman, London.
9
Athawale,V. D. and Mathur, P. (2001), Experimental Physical Chemistry, 1st Edition, New Age
International Publication, New Delhi.
10 Yadav, J.B. (2003), Advanced Practical Physical Chemistry, Goel Pub., Meerut.

12
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Chemistry
YEAR III Foundation Course CREDIT 2
Semester I Chromatography and Optical methods HOURS 30

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Chromatography
Separation methods, Introduction, classification, principle of separation, terminology
(stationary and mobile phases, retention time, retention volume, resolution, number of
theoretical plates (N and HETP), Paper and thin layer chromatography – choice of
UNIT-I 15 hrs.
adsorbent and solvents, factors affecting Rf values, development techniques, important
applications. Ion exchange chromatography: principle, choice of resins and applications.
Liquid chromatography and HPLC: principle, instrumentation and applications. Gas
Chromatography: principle, instrumentation and applications.
Optical Methods
interaction of radiation with matter, fundamental laws of spectroscopy and selection
rules. UV-visible Spectrometry: Basic principles of instrumentation (Choice of source,
monochromator and detector), single and double beam instrument; basic principles of
quantitative analysis: validity of Beer-Lambert’s law, estimation of metal ions in aqueous
solution,
UNIT-II 15 hrs.
Infrared spectroscopy: Basic principle of instrumentation (choice of source,
monochromator and detector) for single and double beam instrument; sampling
techniques. Flame atomic absorption and emission spectrometry: Basic principles of
instrumentation (choice of source, monochromator, detector, choice of flame and
burner designs, techniques of atomization and sample introduction, techniques for the
quantitative estimation of trace level of metal ions from metal samples.
REFERENCES
Instrumental methods of analysis H.H. Willard, L.L. Merritt, J.N. Dean and F.A. Settle,
1.
I.B.H. Publishing House, New Delhi. 7th Ed. 1988
2. Analytical Chemistry, G.D. Christian, John Willey & Sons. 6th Edition,2004
Principles of Instrumental analysis, D.A. Skoog, F.J. Holler and T.A.Nieman., Saunders College
3.
Publishing. 5th Edition, 1998.
4. Instrumental Analysis , H. H. Bauer, G.D. Christian, J. E. O’ Reilly, Ed. Allyn and Bacon, Inc. USA, 1978
5. Introduction to Instrumental Analysis, (1987) R. D. Braun, McGraw-Hill Book Company.
6. Principles and Practice of Analytical Chemistry, F.W. Fifield, 5th Ed. (2000) Blackwell science.
O. Mikes, R.A. Chalmers: Laboratory Handbook of Chromatographic Methods. Van Nostrand Company,
7.
1966.

13
 The Maharaja Sayajirao University of Baroda
Faculty of Science, ACADEMIC YEAR

Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III CORE CREDIT 3
Semester II Paper-1
HOURS 45
Inorganic Chemistry-II

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Comparative study of Group 3 to 12, occurrence and extraction of elements, Ionic salts,
Stoichiometric and non-stoichiometric oxides, trends in the acidic/basic characteristic of
oxides and hydroxides. Horizontal comparison in iron, cobalt and nickel groups. Iso and
heteropoly acids and their salts. Tungsten bronzes. Complex formation by transition metal
ions in different oxidation states, colour, magnetic properties and catalytic properties.
structure and uses of representative compounds of various transition elements. Chemistry
of platinum group elements, application of platinum group metals and their compounds
UNIT-I 15 hrs.
in catalysis.
Redox potentials and electrochemical series, analysis of redox cycle, redox stability in
water, Disproportionation, oxidation by atmospheric oxygen, presentation and use of
redox potential data- Frost, Latimer and Pourbaix diagrams, pH dependence of redox and
conditional Latimer diagrams, trends in stabilities of the oxidation states of metals. Effect
of complex formation on redox potentials and stabilization of oxidation states of transition
metal ions in various complexes.
Water Oxidation with special reference to electrochemical processes.
Chemistry of lanthanide and actinide compounds
higher coordination number and complex formation, colour and absorption spectra,
magnetic properties and their important applications.
Genesis of elements and extension of periodic table. Szilard-Chalmers’ separation process,
UNIT-III 15 hrs.
separation of Neptunium and Plutonium from 92U238, processing of spent fuel, extraction
of U233 and Pu239.
Application of radioactive elements and radioisotopes in agriculture, industries and clinical
diagnosis. Preliminary concept of damage to DNA from nuclear radiations.
REFERENCES
1. Lee J.D., (1991) Concise Inorganic Chemistry, 4th Edition, Chapman and Hall.
2.
Emeleus H.J. and Sharpe A.G., (1994) Modern Aspects of Inorganic Chemistry, 4th Edition
UBS
3. Banerjea D., (1993) Coordination Chemistry, Tata McGraw Hill
4. Cotton F.A. and Wilkinson G., (1988) Basic Inorganic Chemistry, Wiley Eastern.
5. Huheey J.E. , (1983) Inorganic Chemistry: Principles of Inorganic Chemistry, 4th Edition, Harper-Collins
6 Cotton F.A. & Wilkinson G, Advanced Inorganic Chemistry, 6th Ed., Wiley Interscience (1999).
7 Sanderson R.T., Inorganic Chemistry, East-West Press (1971).
8 Purcell K.F. & Kotz J.C., Inorganic Chemistry, Holt-Saunders (1980).
9
Rodgers Glen E., Introduction to Coordination, Solid State & Descriptive Inorganic Chemistry, McGraw Hill
Inc. (1994).

14
 The Maharaja Sayajirao University of Baroda
Faculty of Science, ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III CORE CREDIT 3
Semester II Paper-2
HOURS 45
Organic Chemistry-II (3 Credits)

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Chemistry of Natural Products
Terpenes: Classification and isolation, structure and synthesis of citral, geraniol and -
terpeniol, essential oils.
UNIT-I
Alkaloids: Classification, isolation, physiological activity, and general characteristics, 15 hrs.
structure elucidation and synthesis of nicotine, coniine and papaverine.
Fats: Occurrence and composition of fats, saponification, general chemical properties of
fats, hydrolysis, hardening of oil, rancidity, phosphoglycerides.

Drugs
Classification, methods of preparation and uses of Aspirin, mode of action, salol principle,
true and partial salol, sulphanilamide, sulphathiazole, succinoyl sulphathiazole,
UNIT-II mechanism of action of sulpha drugs. 15 hrs.
Synthetic Dyes: Introduction, classification of dyes, colour and constitution, methods of
preparation and uses of methyl orange, congo red, malachite green, crystal violet,
phenolphthalein and fluorescein.
Pericyclic Reactions
Molecular orbitals of ethyle ne and 1,3-butadiene, and 1,3,5- hexatriene, Photochemical
and thermal reactions, [2+2] and [4+2] cycloaddition reactions, the Diels-Alder reaction,
electrocyclic reactions, Claisen rearrangement as a sigmatropic reaction, Photochemical
UNIT-III 15 hrs.
reactions: Norrish type-I and type II reactions of carbonyl compounds.
Enolates in organic synthesis: Acidity of a-hydrogen, halogenation of ketones, aldol
condensation, Claisen condensation, Wittig reaction, alkylation of diethyl malonate and
ethyl acetoacetate and its application in organic synthesis.
REFERENCES
1. Morrison R.T., Boyd R.N.; Organic Chemistry, Prentice Hall of India, NewDelhi (VI Ed).
2. Pine S.H; (1993) Organic Chemistry, McGraw Hill, New Delhi.
3. Loudon G M; (2002) Organic Chemistry, Oxford, New York.
4.
Roberts J.D. and Caserio M.C., (1992) Basic Principles of Organic Chemistry, 2nd
Edition, W.A. Benjamin Inc., California, USA.
5. Graham Solomons T.W. and Fryhle C., (2002) Organic Chemistry, John Wiley
6. Singh S.P. and Mukherjee S.M; (1984) Organic Chemistry, McMillan India.
7. Finar I.L; (2013 print) Organic Chemistry, Vol 1 & 2, Pearson Edu. Ltd
8. Chatwal G; (1985) Synthetic Dyes, Himalaya Publication Home

15
 The Maharaja Sayajirao University of Baroda
Faculty of Science, ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III CORE CREDIT 3
Semester II Paper-3
Physical Chemistry-III (3 Credits) HOURS 45

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Macromolecules
Importance of polymers. Basic concepts: Monomers, repeat units, degree of
polymerization. Linear, branched and network polymers, classification of polymers. Chain
UNIT-I growth (free radical) and step growth polymerization and copolymerization. 15 hrs.
Polydispersion-average molecular weight concept, Number, weight and viscosity average
molecular weights, The practical significance of molecular weight, Molecular weight
determination using viscosity method, Osmometry, Cryoscopy, Ebullioscopy (qualitative
description) Polymer degradation and environmental concerns.
Electrochemistry II
Chemical and concentration cells with and without transference. Effect of temperature on
cell voltage. Electrode polarization and overvoltage. Polarography and its applications.
UNIT-II Amperometry and coulometry. Cyclic voltametry. 15 hrs.
Corrosion: Definition, types, theories and mechanism for dry and wet corrosion, special
types of corrosion. Chemical passivators and passivations. corrosion inhibitors.
Fuel cells: Principle, types and their functioning.
Photochemistry
Photophysical and photochemical processes, Grothus-Draper law, Stark-Einstein’s law of
photochemical equivalence and quantum yie ld. Electronic excitation of molecules, Frank-
Condon principle. Examples of low and high quantum yields. Photostationary equilibrium.
Photosensetization, Photochemical formation of HCl, HBr and HI and rate of
UNIT-III 15 hrs.
photochemical reactions. Actinometry. Luminescence phenomenon: Timescales of
photophysical processes, phosphorescence, fluorescence, chemluminescence. Quenching
of fluorescence, Stern-Volmer equation. Photochemistry of stratospheric ozone,
harvesting of light during plant photosynthesis, photochemistry of vision. Solar energy
conversion.
REFERENCES

1.
Atkins P. and Paula J. D. (2006), Physical Chemistry, 8th Edition (International Student
Edition) Oxford Univ. Press, New Delhi.
2.
Glasstone, S. (1990), Text Book of Physical Chemistry, 2nd Edition Reprint, Macmillan and Co. Ltd., New
York
3.
Puri, B. R., Sharma, L.R. and Pathania, M. S. (2009), 44st Edition, Principles of Physical
Chemistry, Vishal Publ. Co., Jalandhar
4.
Bahl, B.S., Bahl A. and Tuli, G.D. (2007), Essentials of Physical Chemistry, 25th Edition,
S. Chand, New Delhi.
5. Engel T. and Reid P. (2007), Physical Chemistry, Pearson Prentice Hall, Noida.
6. Mahan B. H. (2009), University Chemistry,3rd Edition, Narosa Publishing House, New Delhi.

16
 The Maharaja Sayajirao University of Baroda
Faculty of Science, ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III CORE CREDIT 3
Semester II HOURS 45
Chemistry-X

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Isomerism in complexes
Stability of complexes formed by transition metal ions and the factors influencing it. ML
andLM interaction in metal complexes.
Introduction to organometallic compounds, Metal carbon -bonds, σ-bonding in metal
UNIT-I carbonyls and nitrosyls. 15 hrs.
Mechanism of inorganic reactions: Hard and soft acids and bases, classification of
acceptors and donors, the concept of acceptor A and B. Metal and ligand substitution
reactions.
Complementary and non-complementary redox processes, atom transfer and electron
transfer mechanisms. Metal complexes in biology and medicine.
Mass Spectrometry
Principle, Instrumentation, types of ionization, types of fragmentation, nitrogen rule,
isotope peaks, McLafferty rearrangement, fragmentation of simple organic molecules such
as hydrocarbons, halides, ethers, alcohols, phenols, aldehydes, ketones acids and acid
derivatives.
UNIT-II 15 hrs.
Nuclear Magnetic Resonance (NMR) Spectroscopy: Nuclear magnetic resonance,
instrumentation, proton NMR, nuclear shielding and deshielding, chemical shift, spin-spin
splitting, NMR characteristics of simple organic molecules.
Interpretation of UV, IR and NMR spectra, problems based on combined use of spectral
data.
Phase equilibria II
Liquid-gas and liquid-liquid systems, Ideal/non-ideal liquids, Raoult’s Law, Henry’s Law,
Fractional distillation of binary miscible liquids. Column efficiency, Azeotropes, Breaking of
azeotropism, Lever rule, partial miscibility of liquids, lower and upper critical solution
temperature, Immiscible liquid pairs, steam distillation. Three component systems,
UNIT-III 15 hrs.
triangular plots: Partially miscible three liquid systems. (Formation of one, two and three
immiscible pairs).
Nernst Distribution law: Defination, Thermodynamic derivation, Association and
dissociation of solute in one solvent, Applications, study of complex ions, solvent
extraction.
REFERENCES
1. Lee J.D., (1991) Concise Inorganic Chemistry, 4th Edition, Chapman and Hall,
2. Emeleus H.J. and Sharpe A.G., (1994) Modern Aspects of Inorganic Chemistry, 4th Edition UBS
3. Banerjea D., (1993) Coordination Chemistry, Tata McGraw Hill

17
4. Cotton F.A. and Wilkinson G., (1988) Basic Inorganic Chemistry, Wiley Eastern.
5. Huheey J.E. (1983) Inorganic Chemistry: Principles of Inorganic Chemistry, 4th Edition, Harper-Collins
Dyer J.R; Applications of Spectroscopy of Organic Compounds, Prentice Hall of India Ltd. New Delhi,
6
(2005).
Silverstein R M, Webster F X, Kiemle D; Spectrometric Identification of Organic Compounds, John Wiley &
7
Sons, New York, (2005).
8 Kalsi P.S; Spectroscopy of Organic Compounds, New Age International Ltd. New Delhi (2004).
Jag Mohan Organic Spectroscopy: Principles and Applications, Narosa Publishing House, New Delhi.
9
(2004)
Sharma Y R; Elementary Organic Spectroscopy-Principles and Chemical Applications, S. Chand and Co,
10
New Delhi, (2007)
11 Morrison R.T. and Boyd R.N; Organic Chemistry, Prentice Hall, New Delhi.
12 Loudon G M; Organic Chemistry, Oxford, New York (2002)
13 Graham Solomons T.W., Fryhle C., Organic Chemistry, John Wiley, (2002).
Puri, B. R., Sharma, L.R. and Pathania, M. S. (2005), 41st Edition, Principles of Physical Chemistry,
14
Vishal Publ. Co., Jalandhar
Glasstone, S. (1990), Text Book of Physical Chemistry, 2nd Edition Reprint, Macmillan and Co. Ltd., New
15
York
16 V.R.Gowarikar, N.V. Viswanathan & J. Sreedhar, Polymer Science , New Age (1986)

18
 The Maharaja Sayajirao University of Baroda
Faculty of Science, ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Discipline Specific Elective-1 CREDIT 2
Semester II Advanced Materials HOURS 30

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Materials for Electronics
Preparation of high purity Silicon, silicon based semiconductors and devices.
Silicones: Synthesis and structure of silicone fluids, greases, resins and rubbers, Thermal
stability, water and chemical resistance, applications in various fields.( medicines,
UNIT-I 15 hrs.
electronic, construction)
Ceramics: General properties, classification, raw materials and formation of clay, types
and typical properties of clays, manufacturing process of potteries, use of ceramics in
resistors and capacitors. Refractories: Properties, classification, manufacture of fire clay
bricks, silica bricks, super refractories and insulating refractories.
Composite materials
Introduction, Limitations of conventional engineering materials, role of matrix in
composites, classification, matrix materials, reinforcements, metal matrix composites,
polymer matrix composites, fiber reinforced composites, environmental effects on
UNIT-II composites, applications of composites. 15 hrs.
Nano-materials: Overview of nano-structures and nano-materials; classification.
Preparation of gold and silver metallic nano particles, self-assembled nano structures,
control of nano architecture. Carbon nano tube and nano wires, Bio inorganic nano-
materials.
REFERENCES
1. Sharma, B. K., Industrial Chemistry including chemical engineering, Goel Publ. House, Meerut.
2. Thompson D. (Ed.), Insights into speciality Inorganic chemicals, RSC, Cambridge, U.K.
3. Poole, C. P. and Owens, F.J. Introduction to nanotechnology, John Wiley & Sons.
4. Rodger, G.E., Inorganic and solid state chemistry, Cengage Learning India Edition.

19
 The Maharaja Sayajirao University of Baroda
Faculty of Science, ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Discipline Specific Elective- 2 CREDIT 2
Semester II Enzymes and Energy in Bio-systems HOURS 30

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Enzymes
Introduction, Classification, Characteristics and salient features of enzymes, Factors
affecting enzyme actions, Mechanism of Chymotripsin, Coenzymes and Cofactors-their
role in biological reactions, Specificity and Stereospecificity of enzymes, Enzyme inhibitors
UNIT-I 15 hrs.
and their importance.
Nucleic acids: Nucleosides and nucleotide, Structure and synthesis and reactions of
Adenine, Guanine, Cytosine, Uracil and Thymine, Structure of DNA, Types of RNA and their
importance.
Energy in Bio-systems
Energy obtained by oxidation of foodstuff in cells, Introduction to catabolism and
anabolism, ATP: Universal currency of cellular energy, ATP hydrolysis and free energy
UNIT-II change, Agents for transfer of electrons in biological redox system: NAD+ and FAD, 15 hrs.
Outline of catabolic pathways of carbohydrates: Glycolysis, Kreb’s cycle and
Fermentation, Interrelationship in the metabolic pathways of Protein, fat and
Carbohydrate, Caloric Value of food, Standard caloric content of food types.
REFERENCES
1. Morrison R.T., Boyd R.N.; Organic Chemistry, Prentice Hall of India, NewDelhi (VI Ed).
2. Pine S.H; (1993) Organic Chemistry, McGraw Hill, New Delhi.
3. Loudon G M; (2002) Organic Chemistry, Oxford, New York.
4.
Roberts J.D. and Caserio M.C., (1992) Basic Principles of Organic Chemistry, 2nd
Edition, W.A. Benjamin Inc., California, USA.
5. Graham Solomons T.W. and Fryhle C., (2002) Organic Chemistry, John Wiley
6.
Nelson, D. L. & Cox, M. M.(2008) Lehninger’s Principles of Biochemistry 7th Ed., W. H.
Freeman NY .
7. Finar I.L; (2013 print) Organic Chemistry, Vol 2, Pearson Edu. Ltd
8. Berg, J.M., Tymoczko, J.L. & Stryer, L. (2002) Biochemistry, W.H. Freeman NY.

20
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-‘22

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Elective-1 CREDIT 8
Semester II Inorganic Analysis Practical-II HOURS 180

OBJECTIVES:
Practical Training

COURSE CONTENT / SYLLABUS

Qualitative Inorganic Analysis and Inorganic Preparations
1. Introduction to and practice of semi- micro qualitative analysis and spot
reactions with
simple mixtures of ions.

Qualitative analysis of mixtures containing maximum six radicals including an ion

of a rare element: 60
(a) Cations of: Ag, Pb, Hg, Cu, Cd, Sn, Bi, As, Sb, Fe, Al, Cr, Co, Ni, Mn,
Zn, Ca, Sr, Ba, Mg, Na and K. NH4+ .
(b) Cations of rare elements: W, Mo, Ce, Ti, Th, Zr, U, V and Li.
(c) Anions : Cl-, Br-, I-, NO2- , NO3-, S2-, SO32-, SO42-, CrO42-, Cr2O72-,CO32-, PO43-

2. Synthesis and estimation of purity of fine chemicals (Any five).

REFERENCES

1.
Mendham J., Denney R C, Barnes J B, MJK Thomas, (2003) Vogel’s Textbook of Quantitative Chemical
Analysis, 6th Edition, Pearson Education, New Delhi.
2. Suehla G, (!989)Vogel’s Qualitative Inorganic Analysis, 6th Edition, Orient Longman,
3. Shah R C, (1996)Inorganic Analysis Part-I, 5th Edition Baroda Book Depot, Vadodara
4. Shah R C, (1996)Inorganic Analysis Part-II R C Shah, 5th Edition, Baroda Book Depot, Vadodara
5
John Bassett (Editor) Vogel's Textbook of Quantitative Inorganic Analysis, Including Elementary
Instrumental Analysis, 4th edition, Longman Science and Tech
6 Shah R C, (2001) Organic Analysis Part I Qualitative Analysis Baroda Book Depot,
7 Shoemaker, D. P., Garland, C.W. and Nibler, J.W. (1996), Experiments in Physical Chemistry, McGraw Hill
8 Findlay, A. (1972), Practical Physical Chemistry, 9th Edition, B.P. Levitt, Longman, London.
9
Athawale,V. D. and Mathur, P. (2001), Experimental Physical Chemistry, 1st Edition, New Age
International Publication, New Delhi.
10 Yadav, J.B. (2003), Advanced Practical Physical Chemistry, Goel Pub., Meerut.

21
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-‘22

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Elective-2 CREDIT 8
Semester II Organic Practical-II HOURS 180

OBJECTIVES:
Practical Training

COURSE CONTENT / SYLLABUS

Organic Estimation and Organic Preparation
1. i) Estimation of Aniline/ Phenol
ii) Estimation of Amides
iii) Estimation of Glucose
iv) Estimation of Esters

2. i) 7-Hydroxy-4-methyl coumarin from resorcinol

60
ii) p-Bromo acetanilide from acetanilide
iii) Acetyl salicylic acid (aspirin) from salicylic acid
iv) Cinnamic acid from benzaldehyde
v) 1,4-Diacetoxy benzene from hydroquinone
vi) m-Nitroaniline from m-dinitrobenzene
vii) 1-Phenylazonaphthol from -naphthol

REFERENCES

1.
Mendham J., Denney R C, Barnes J B, MJK Thomas, (2003) Vogel’s Textbook of Quantitative Chemical
Analysis, 6th Edition, Pearson Education, New Delhi.
2. Suehla G, (!989)Vogel’s Qualitative Inorganic Analysis, 6th Edition, Orient Longman,
3. Shah R C, (1996)Inorganic Analysis Part-I, 5th Edition Baroda Book Depot, Vadodara
4. Shah R C, (1996)Inorganic Analysis Part-II R C Shah, 5th Edition, Baroda Book Depot, Vadodara
5
John Bassett (Editor) Vogel's Textbook of Quantitative Inorganic Analysis, Including Elementary
Instrumental Analysis, 4th edition, Longman Science and Tech
6 Shah R C, (2001) Organic Analysis Part I Qualitative Analysis Baroda Book Depot,
7 Shoemaker, D. P., Garland, C.W. and Nibler, J.W. (1996), Experiments in Physical Chemistry, McGraw Hill
8 Findlay, A. (1972), Practical Physical Chemistry, 9th Edition, B.P. Levitt, Longman, London.
9
Athawale,V. D. and Mathur, P. (2001), Experimental Physical Chemistry, 1st Edition, New Age
International Publication, New Delhi.
10 Yadav, J.B. (2003), Advanced Practical Physical Chemistry, Goel Pub., Meerut.

22
 The Maharaja Sayajirao University of Baroda
Faculty of Science ACADEMIC YEAR
Department of Chemistry 2021-‘22

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Elective-3 CREDIT 8
Semester II Physical Chemistry Practical-II HOURS 180

OBJECTIVES:
Practical Training

COURSE CONTENT / SYLLABUS

Physical Chemistry Experiments:
1. Dissociation constant of weak acid/base by Conductometry.
2. Phase diagram of a two component solid-liquid system.
3. Kinetics of inversion of cane sugar by Polarimetry.
4. Kinetics of catalytic decomposition of H2O2.
5. Verification of Onsager equation for strong electrolyte by conductometry. 60
6. Kinetics of reaction between K2S2O8 and KI
7. Kinetics of reaction between KBrO3 and KI.
8. Kinetics of hydrolysis of methyl acetate by NaOH.
9. Kinetics of reaction between KMnO4 and Oxalic acid.
10. Paper / Thin Layer Chromatography
REFERENCES

1.
Mendham J., Denney R C, Barnes J B, MJK Thomas, (2003) Vogel’s Textbook of Quantitative Chemical
Analysis, 6th Edition, Pearson Education, New Delhi.
2. Suehla G, (!989)Vogel’s Qualitative Inorganic Analysis, 6th Edition, Orient Longman,
3. Shah R C, (1996)Inorganic Analysis Part-I, 5th Edition Baroda Book Depot, Vadodara
4. Shah R C, (1996)Inorganic Analysis Part-II R C Shah, 5th Edition, Baroda Book Depot, Vadodara
5
John Bassett (Editor) Vogel's Textbook of Quantitative Inorganic Analysis, Including Elementary
Instrumental Analysis, 4th edition, Longman Science and Tech
6 Shah R C, (2001) Organic Analysis Part I Qualitative Analysis Baroda Book Depot,
7 Shoemaker, D. P., Garland, C.W. and Nibler, J.W. (1996), Experiments in Physical Chemistry, McGraw Hill
8 Findlay, A. (1972), Practical Physical Chemistry, 9th Edition, B.P. Levitt, Longman, London.
9
Athawale,V. D. and Mathur, P. (2001), Experimental Physical Chemistry, 1st Edition, New Age
International Publication, New Delhi.
10 Yadav, J.B. (2003), Advanced Practical Physical Chemistry, Goel Pub., Meerut.

23
 The Maharaja Sayajirao University of Baroda
Faculty of Science, ACADEMIC YEAR
Department of Chemistry 2021-2022

The M S University of Baroda, Vadodara

Bachelor of Science
YEAR III Foundation Course CREDIT 2
Semester II HOURS 30
Environmental Chemistry

OBJECTIVES:

COURSE CONTENT / SYLLABUS

Analytical Chemistry
Solvent extraction: Batch, continuous and counter current methods of solvent extraction,
solvent extraction systems for inorganic species, effect of pH on such systems, important
analytical and industrial applications. Thermal methods of analysis: Theory of 15 hrs.
UNIT-I
thermogravimetry (TG), basic principle of instrumentation Techniques for quantitative
estimation of mixtures. Electroanalytical methods: Classification of electroanalytical
methods, basic principle of pH metric, potentiometric and conductometric titrations.
Techniques used for the determination of equivalence points.
Environmental Chemistry
Segments of the atmosphere, Air pollutants and their effects – green house effect, ozone
depletion, photochemical smog, acid rain and other effects, air sampling and analysis of
UNIT-II sulphur dioxide, oxides of nitrogen, suspended particulate matter, respirable particulate 15 hrs.
matter, ozone, carbon monoxide, hydrocarbons and volatile organic compounds (BTX)
Water pollutants and their general effects, general methods of treatment of waste
water, techniques for measuring water pollution, analysis of water pollutants.
REFERENCES
1. D. Harvey, Modern Analytical Chemistry, , McGraw Hill Higher Education, New York, 2000.
2. G.D. Christian Analytical Chemistry, , 6th Edn., John Wiley & Sons, Inc., U.S.A., 2004.
3. D.A. Skoog, F.J. Holler, S.R. Crouch, Instrumental Analysis, , Cengage Learning, India, 2010.
4. A. J. Bard, L. R. Faulkner, "Electrochemical Methods," 1980, Wiley, NYC.
G. H. Jeffery, J. Bassett, J. Mendham and R. C. Denny, Vogel’s Text Book of Quantitative
5.
Chemical Analysis, 5th Edn. , ELBS, 1991.
6. S.M. Khopkar, Environmental Pollution analysis, ,Wiley Eastern Ltd.
Stanley Manahan, Environmental Chemistry, , Lewis Publishers CRC Press, USA. , 10th Edition
7.
(2017)
L.H. Keith, Identification and Analysis of Organic Pollutants in water., Arber Science
8.
Publications. 1977

****

24