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WK4 Umbao L Cana GC2

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LESSON 4: PHYSICAL PROPERTIES OF SOLUTIONS

(SOLUTION STOICHIOMETRY AND COLLIGATIVE PROPERTIES OF SOLUTIONS)

PERFORMANCE TASK
DATE OF SUBMISSION: MARCH 1,2021

ACTIVITY 4

NAME: UMBAO, CHRISTOPHER D.L DATE SUBMITTED:

STRAND & SECTION: STEM L 12 CANA SCORE:. / 50

A. Write the letter of the correct answer on the space provide before each number. Show the
solution for the following problems. (5pts)

__D.___1. What is the concentration unit used in determining freezing point depression and boiling
point elevation?
a. Mass percent b. Mole fraction c. Molarity d. Molality

__C.___2. Sodium chloride is dissolved in water as given in the choices. Which solution is the most
concentrated?
a. 20 g of salt dissolved in 25 mL of H2O.
b. 15 g of salt dissolved in 18 mL of H2O
c. 6 g of salt dissolved in 5g of H2O
d. 10g of salt dissolved in 20 g of H2O

__D.___3. The solubility of a gas in a liquid depends on ____________.


a. temperature b. pressure c. nature of solute and solvent d. all of the above

___D.__4. In which of the following cases is pressure a factor in the solubility of the solute in the
solvent?
a. Sugar is dissolved in water.
b. Alcohol is dissolved in water.
c. Acetylene gas is mixed with oxygen in a blowtorch.
d. Carbon dioxide is dissolved in sparkling wine.

__D.___5. Which of the following would decrease the rate of dissolution in which a solid is dissolve in a
liquid?
a. Increasing the temperature of an exothermic reaction.
b. Grinding the solid into smaller pieces.
c. Applying pressure into the solution.
d. Supersaturating the solution.

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B. Solve the following problems (5 points each).

6-10. Using the following equation:


2NaOH + H2SO4 → 2H2O + Na2SO4

How many grams of sodium sulfate will be formed, if you start with 1.50 L of a 4.0 M
solution of sodium hydroxide?

GIVEN: VNaOH=1.50 L MMNa2S04= 142.04 g/mol


MNa0H= 4.0 M
REQUIRED: MASS OF Na2SO4

EQUATION: VNaOH ->MNaOH-> molNaOH ->M.R-> molNa2SO4 -> MMNa2SO4-> MASS Na2SO4

SOLUTION: 1.50 L x 4.0 molNaOH x 1 molNA2SO4 x 142.04 g Na2SO4


NaOH 1L 2 molNaOH 1 mol Na 2SO4

ANSWER: 426.12g Na2SO4

11- 15. How many grams of Ca(OH)2 are needed to neutralize 25.0 mL of 0.100 M HNO3? The
reaction proceeds as follows:
2HNO3 (aq) + Ca(OH)2 (s) → H2O (l) + Ca(NO3)2 (aq)

GIVEN: VHNO3=25 mL ≈ 0.025 L MMCa(OH)2= 74.01 g/mol


MHNO3= 0.100 M
REQUIRED: MASS OF Ca(OH)2

EQUATION: VHNO3 -MHNO3-> molHNO3 -M.R-> molCa(0H)2 –MMCa(OH)2-> MASS Ca(OH)2

SOLUTION: 0.025 L x 0.100 MHNO3 x 1 molCa(OH)2 x 74.01 g Ca(OH)2


HNO3 1L 2 molHNO 3 1 mol CaOH)2

ANSWER: 0.09 g Ca(OH)2

16- 20. At 40°C, the blood has an osmotic pressure of 8.02 atm. How many grams of glucose is
contained in a 5mL of intravenous injection to have the same osmotic pressure as the blood?
MM of glucose is 180 g/mol.

GIVEN: T = 40°C + 273 = 313 K MMGLUCOSE=180 g/mol


π = 8.02 atm
VSOLUTION = 5 mL ≈ 0.005 L

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REQUIRED: MASS OF GLUCOSE

EQUATION: M = π
RT
SOLUTION: M = 8.02 atm = 0.31 mol/L
(0.0821 L x atm/mol x K) (313 K)

0.31mol x 0.005 L = 0.00155 mol x 180 g


1L 1 mol

ANSWER: 0.279 g OF GLUCOSE ≈ 0.28

21- 25. What is the freezing point of a solution of 10 grams of glucose, C6H12O6, and 1500 g of
water?

GIVEN: MASSGLUCOSE= 10g FREEZING POINT= 0°C


MMGLUCOSE = 180 g/mol KF = 1.86° C/m
KgSOLVENT= 1500g≈ 1.5 Kg

REQUIRED: FREEZING POINT OF SOLUTION

SOLUTION: m = n solute = 10g/180g/mol


KgSOLVENT 1.5Kg

= 0.04m
: TF = KFm = (1.86°C/m)(0.04m)
= 0.07°C
: FpSOLUTION=FpSOLVENT - TF = 0°C – 0.07°C

ANSWER: = - 0.07°C

26- 30. Determine the boiling point of a solution of 10 grams of a substance of molecular weight
94 g/mol in 500 grams water.

GIVEN: MASS= 10g BOILING POINT= 100°C


MM = 94g/mol KF = 0.52° C/m
KgSOLVENT= 500g≈ 0.5 Kg

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REQUIRED: FREEZING POINT OF SOLUTION

SOLUTION: m = n solute = 10g/94g/mol


KgSOLVENT 0.5Kg

= 0.21m
: TB = KBm = (0.52°C/m)(0.21m)
= 0.11°C
: BpSOLUTION=BpSOLVENT + TB = 100°C + 0.11°C

ANSWER: = 100.11°C

31- 35. What weight of NaCl in 800g acetone is needed to bring boiling point to 60°C? (Boiling
point of pure acetone= 55.95°C ; Kb of acetone = 1.71 °C/m)

GIVEN: KB =1.71°C BP= 55.95°C MASSSOLVENT= 800 g ≈ 0.8 Kg

REQUIRED: WEIGHT OF NaCl

SOLUTION:

: TB = Kbm

60°C = 55.95°C + TB

60°C - 55.95°C = TB
4.05°C = TB

4.05 = 1.71 m
1.71 1.71
m= 2.37 m = n solute
0.8Kg
n solute = (0.8)(2.37) = 1.896 mol
m = 1.896 mol (58.44 g/mol) = 110.802 g

ANSWER: = 110.802 g

C. Explain each of the following phenomena (5 points each).

36 – 40. Fishes need oxygen to survive. Goldfish in a crowded aquarium has a better chance
of survival in cold water than in warm water.

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Warm water makes gases less soluble, which ensures oxygen leaves the water and the fish dies. Cold
water allows more oxygen to enter the body for a longer period of time. In cold water, solubility of
oxygen gas decreases.

41 – 45. Adding sugar to a glass of juice that already has crystals of sugar at the bottom
makes the juice sweeter.

Since the substance is already filled with sugar, adding more would have
no effect on the liquid. Adding more sugar will definitely make it sweeter.

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