Assignment 01
Assignment 01
ENCH 607
Assignment 01-Introduction and equations of state & Physical and Thermodynamic
Properties of NG
1. Calculate the volume of 100 kg CO2 (MW = 44 g/mol, w = 0.225) at 4 MPa and
50 oC using the followings:
a. Ideal gas law?
b. Generalized compressibility chart?
c. Pitzer-Curl Tables?
d. van der Waals equation of state?
e. Peng-Robinson equation of state?
2. A storage tank contains a gas mixture with compositions listed in the table below. The
tank held at a pressure of 10.19 MPa and a temperature of 271 K. Calculate:
a. The molar volume (m3/kmol) and the density (kg/m3) of the mixture using the
Kay’s rule and the Katz correlation?
b. The molar volume (m3/kmol) and the density (kg/m3) of the mixture using the
approach of Wichert and Aziz to adjust for CO2 and H2S?
c. If the gas flows to a processing facility at a rate of 2800 x 103Sm3/d, what is the
mass flow of the gas in kg/s?
d. Using the result from part b, and the flow rate from part c, what is the actual
volumetric flow rate of the gas at the plant in m3/s?
e. Determine the standard gas flow rate in MMSCFD if the standard conditions are
60 oF and 14.69 psia?
Component Mole fraction
(y)
N2 0.0050
CO2 0.2250
H2S 0.1000
C1 0.6610
C2 0.0070
C3 0.0015
i-C4 0.0003
n-C4 0.0002
1.0000
Component xi
CO2 0.080
C1 0.040
C2 0.100
C3 0.080
iC4 0.100
nC4 0.070
iC5 0.120
nC5 0.150
C6 0.150
C7 0.110
1.000
ENCH 607/Assignment #01 Page 2 of 3 September 16, 2022
Due date: September 22, 2022
Component yi
C1 0.900
C2 0.040
C3 0.030
i-C4 0.010
n-C4 0.020
1.000
5. A gas of the following composition flow at a rate of 70 million standard cubic feet
per day (MMSCFD). It is at a pressure of 600 psig, and a temperature of 78°F.
Component yi
CO2 0.0106
C1 0.9010
C2 0.0499
C3 0.0187
i-C4 0.0065
n-C4 0.0045
i-C5 0.0017
n-C5 0.0019
C6 0.0029
C7+* 0.0023
1.0000
*Assume properties of C7+ are the
average of C7 and C8
6. A liquid mixture at 49°C and 1820 kPa has the following composition:
ENCH 607/Assignment #01 Page 3 of 3 September 16, 2022
Due date: September 22, 2022
Component yi
N2 0.0000
CO2 0.0000
C1 0.0350
C2 0.0712
C3 0.3210
i-C4 0.0670
n-C4 0.1360
i-C5 0.1073
n-C5 0.0926
n-C6 0.1076
C7+* 0.0623
Total 1.0000
* C7+ is assumed to be C8
Determine the density of this mixture using the Standing and Katz method and
compare it to the result from ASPEN-HYSYS, explain differences if any.