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Question Paper Code : 20373
B.B/1Tech, DEGREE EXAMINATIONS, APRILMAY 2022,
Fourth/fth semester
Chemical tingineering
(CH 8191 — INSTRUMENTAL, METHODS OF ANALYSIS
a] Engineering)
(Common to Chemical and Blectroche!
(Regulations 2017)
Maximum : 100 marks
Time : Three hours
Answer ALL, questions.
PART A — (10 « 2 = 20 marks)
gant
2 Differentiate analytical and instrumental
Distinguish between single and double beam spectrophotometer
Differentiate calibration and standardization
‘The transmittance of 3x10™ M solution in a 1 cm cell is 19.2%. Calculate
absorption and absorption co-efficient.
What is turbidity? How it is expressed?
Why water cannot be used as a medium to record IR spectra of samples?
Whatis the significance of fingerprint region in IR spectroscopy?
What is carrier gas?
What is the use of gradient elution in column chromatography?
PART B— (6 x L 65 marks)
11. (a) Explain the different types of radiation sources used in analytical
3)
instruments. “
Or
Concentration of sample is directly proportional to sworn Milica
and derive an expression for the same. * a
&
te _
(b)sctrophotometer.
12, (a) Describe the working model of double beam visible 9
a3)
or
max rules and Wodward-Fieser rules for
xima. aa)
(b) Explain the Epsilon
determining absorption
18. (a) Summarize any four quantitative applications of UV-Visible
spectroscop
(13)
Or
(b) What is calibration? Explain in detail the most calibration of
instrumental methods. a3)
14. (a) Explain the principle, instrumentation, advantages and disadvantages of
cay
Infrared spectrophotometer.
Or
(b) Write briefly about the IR radiation sources. Describe the qualitative
analysis of alkanes, alken?® and carbonyl compounds using IR
spectroscopy. a3)
15. (a) Explain the working principl: (Gas chromatography and add a note on
the applications of various columns and detectors used sy
Or
given in mMoles/litzes. Caleulate Risen
My suValso determineMhich anelytolwilllhave'a loner
time? 8)
e - a,
of analyte Cs Gm ne K rn M4
A Cee Cs [Co= elt AnalyteA 10 7
Analyte 7 10
L
=> nt ii) ‘The molar absorptive of a particular solute is 2x10". Calculate the
SG [Cn transmittance through 2 curveted with a 5.00 em light path for a
B= OS 210° ff) solution. @
=> F/Io Ce
(b) Explain the application of chromatography in complete demineralization
Oy a of water. 7 (a5)
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mp
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University of Salahaddin College of Science Department of Chemistry Course Book Instrumental Analysis For Fourth Stage M.Sc. in Chemistry Ph.D. in Chemistry Academic Year: 2010-2011