Genchem Module
Genchem Module
GENERAL
CHEMISTRY 1
Learner’s Module
STEM
Chemistry is the study of matter—what it consists of, what its properties are, and how it
changes. Matter is anything that has mass and takes up space—that is, anything that is
physically real. Some things are easily identified as matter—the screen on which you are
reading this book, for example. Others are not so obvious. Because we move so easily
through air, we sometimes forget that it, too, is matter. Because of this, chemistry is a
science that has its fingers in just about everything. Being able to describe the ingredients
in a cake and how they change when the cake is baked, for example, is chemistry!
LESSON
1 STLCFI
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MATTER AND ITS
PROPERTIES
I. Content Standard The learners demonstrate understanding of the properties of
matter and its various forms
II. Performance The learners should be able to design using multimedia,
Standard demonstrations, or models, a representation or simulation of the
following:
A. Atomic structure
B. Gas behavior
C. Mass Relationships
D. Reactions
III. Learning Use properties of matter to identify substances and to
Competencies separate them
Recognize the formulas of common chemical substances
Compare consumer products on the basis of their
components for use, safety, quality and costs
Describe the various simple separation techniques such
as distillation and chromatography
IV. Learning The learners will be able to:
Outcome Use properties of matter to identify substances and
separate them
Recognize the formulas of common chemical substances
Compare consumer products on the basis of their
components for use, safety, quality and costs
Describe the various simple separation techniques such
as distillation and chromatography
PROPERTIES OF
MATTER
CLASSIFICATIONS OF
MATTER
SEPARATING
MIXTURES
PRE-
ASSESSMENT
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I. Define the following terms:
1. Matter
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2. Element
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3. Compound
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4. Mixtures
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5. Homogenous
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6. Heterogeneous
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7. Distillation
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8. Chromatography
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9. Suspension
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10. Colloids
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ESSENTIAL
QUESTIONS
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1. What is matter?
2. What are the properties of
matter?
3. How are we going to separate
mixtures? What are its techniques?
LESSON
DEVELOPMENT WITH
PROPERTIES OF MATTER
INTENSIVE
PROPERTY
PHYSICAL
PROPERTY
PROPERTIES EXTENSIVE
OF MATTER PROPERTY
CHEMICAL
PROPERTY
A. PHYSICAL PROPERTY
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The physical properties of matter are those that can be measured and observed
without changing the composition of the substances. It is further divided into two
classifications, namely the intensive physical property and the extensive physical
property.
The intensive physical property, also called as intrinsic property, does not depend
on the size or amount of the sample. For example, a 100 mL water and a 10 mL
water have the same boiling point (100˚C), freezing point (0˚C), and density (1
g/mL at 4˚C)
2. Extensive Physical
The extensive physical property or the extrinsic property is those that can be
affected by the size and amount of samples.
Examples of extensive properties are mass, volume, length, and shape of the
substance.
B. CHEMICAL PROPERTY
The chemical property of matter is the ability of a substance to react with other
substances such as air, water, acid, and base. Table 1 shows the various chemical
properties observed in matter.
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members of its chemical
family
Ionization Whether it will break into Sodium chloride (NaCl)
charged particles when in that enters in solution
solution with water or not ends up as Na+ and Cl-
ions
Toxicity Whether the substance can Allium genus contains
damage an organism or not thiosulphate, which in
high doses is toxic to dogs
and cats
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Group the characteristics of the given substance according to their physical
(extensive or intensive) or chemical properties.
Physical Properties
Characteristics of Some
Chemical Properties
Substances Intensive Extensive
Properties Properties
3. Uranium, a silver-
white radioactive metal,
melts at 1 132.3˚C and
boils at 3 818˚C. It has a
density of 19.09 g/cm3.
It burns in the air to form
U3O8. When finely
powdered, it
decomposes in cold
water. It produces a
green and volatile
compound, UF4. It also
reacts with acid to form
gas and salt
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CLASSIFIACTION OF MATTER
A. PURE SUBSTANCES
A pure substance is a matter that has definite composition and distinct properties. It can be either
an element or a compound.
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Figure 2. Representations of elements and compounds
1. ELEMENT
An element is the simplest form of matter since it is composed of only one kind of atom, the
smallest particle of an element. It is a pure substance that cannot be decomposed into a simpler
substance by ordinary chemical means.
Examples of elements are hydrogen, helium, carbon, iron, and nickel. Elements are
represented by symbols; the first letter of the symbol is always capitalized, but any following letters
are not. The symbols of some elements, such as C for carbon and He for helium, are derived from the
first letters of the name of the element. Other symbols are derived from the Latin names of the
element such as Cuprum (Cu) for copper, Aurum (Au) for gold, Natrium (Na) for sodium, and
Stannum (St) for tin.
2. COMPOUND
Elements react with each other to form a compound, a pure substance containing two or more
kinds of atom chemically combined in a definite proportion by mass. Unlike elements, compounds can
be separated into simpler substances, but only through chemical means.
An example of a compound is the sodium chloride (NaCl), which is formed when sodium (Na)
atom reacts with chlorine (Cl) atom. The properties of a compound are dramatically different from the
properties of the elements composing it. For instance, using the stated reaction, chlorine is a green,
poisonous gas that is very toxic. It was used as a weapon during the World War I. On the other hand,
sodium is a soft silvery metal that reacts vigorously with water and, if held in the hand, could burn it
severely. Together, however, these atoms produce the compound sodium chloride (table salt), a clear,
crystalline solid particles that is essential for human life.
Other examples of compounds are water (H 2O), carbon dioxide or dry ice (CO2), ammonia
(NH3), sucrose or table sugar (C12H22O11), caustic soda (NaOH), milk of magnesia (Mg(OH)2), slake
lime (Ca(OH)2), baking soda (NaHCO3), gypsum or plaster of Paris (CaSO 4), corundum (Al2O3),
laughing gas (N2O), aqua fortis (HNO3), and oil of Vitriol (H2SO4).
3. MIXTURES
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Mixtures can be either classified as homogenous and heterogenous
1. Homogenous mixture
A mixture whose composition varies from one position to another within the sample is
considered as heterogeneous. Heterogeneous mixtures can either a suspension or a colloid.
a. Suspensions consist of coarse particles which are visible to the naked eye. Its particles are
unstable since they settle down after a short period of time. Water with particles such as sand or flour
and muck are examples of suspension.
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ACTIVITY 2 TEST YOUR KNOWLEDGE
1. Toluene -
2. sodium chloride -
3. sucrose -
4. ethanol -
5. amalgam -
6. bronze -
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7. plaster of Paris -
8. milk of magnesia -
9. caustic soda -
For solutions, the general types exist in any of the three states of matter. It is based on the final state of
the solution or the solvent.
On the other hand, the classifications of colloids are based on the physical state of the dispersed phase
and the dispersing medium
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ACTIVITY 3 TEST YOUR UNDERSTANDING
1. Explain your understanding about the Table 1 on the comparison among the different kinds of
mixtures.
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___________________________________________________________________________________
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SEPARATING MIXTURES
1. DISTILLATION
2. CHROMATOGRAPHY
Chromatography is
another method of separating
complex mixtures. It has
various methods that can be
used in separating mixtures
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Figure 2. Paper chromatography setup and a paper chromatogram
such as paper chromatography, which makes use of an adsorbent (filter paper or chromatogram
paper). The separation depends upon the solubility of each component in the solvent. For example, in
the separation of each component of a water-based ink, the dye which is very soluble in the solvent
travels faster and moves up the paper while the dye that is less soluble travels slowly and is usually at
the lower part of the paper.
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2. Research the meaning of following separating mixtures, and draw and label their set up. You
can use a Long Bondpaper for your drawings.
1. Filtration
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3. Magnetic Separation
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4. Evaporation
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4 3 2 1
FEATURES
EXPERT ACCOMPLISHED CAPABLE BEGINNER
Quality of It is written It is written It had a It had no
Writing in an in an little style style or
extraordinary interesting or voice voice
voice and style and Give some Gives no
style voice information new
Very Somewhat but poorly information
informative informative organized and very
and well- and poorly
organized organized organized
Grammar Virtually no Few spelling A number So many
Usage and spelling, and of spelling, spelling,
Mechanics punctuation punctuations punctuation punctuation
or errors, or and
grammatical minor grammatical grammatical
errors grammatical errors errors that it
error interferes
with the
meaning
FEATURES
20 pts 18 pts 15 pts 10 pts
Elements and Planned carefully The artwork The student shows The student
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Principles of and showed an shows that the lack of planning showed little
Design advanced student applied and a little evidence of any
awareness of the the principles of evidence that an understanding of
elements and design while overall the elements an
principles of using one or more composition was principles of art.
design. Student elements planned No evidence of
went above and effectively. planning. Student
beyond Student met did the minimum
expectations expectations of work required
Craftsmanship All aspects of the With a little more The student Below average
and Neatness artwork were effort in finishing showed average craftsmanship, lack
considered and techniques, the craftsmanship; of pride in finished
patiently artwork could be adequate, or not as artwork. Showed
completed. The outstanding. good as the little evidence of
finished product is Overall, the student’s previous effort and/ or a
a result of careful project is clean abilities, a bit lack of
meticulous and without major careless. Minor understanding
planning. The defects like defects may be includes obvious
craftsmanship is folds/rips present deficits like folds,
outstanding. rips, stray marks,
Project is pristine and/ or breaks
and well kept.
Execution, The artwork was The artwork was The artwork was The artwork was
Originality, and successfully successfully partially but never fully
Uniqueness executed from executed from successfully completed.
concept to concept to executed
completion, with completion.
an original
approach
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CHAPTER
TEST
_________________ 2. Copper
_________________ 3. Sodium
_________________ 8. Amalgam
_________________ 9. Toluene
1. Water –
2. Wines –
3. Soil –
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5. Mud puddles –
6. Plastics –
7. Cement –
8. Blood plasma –
9. Smog –
SUMMARY
This lesson is about Matter and its Properties. You learned to:
REFERENCES
Rodil, M., et al. Conceptual Science and Beyond: General Chemistry 1. Brilliant
Cretions Publishing, Inc. Novaliches, Quezon City, 2017
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2
ATOMS, MOLECULES
LESSON AND IONS
LESSON MAP
ATOMS, MOLECULES
AND IONS
ISOTOPES
CHEMICAL
FORMULAS
STRUCTURAL
FORMULA AND
MOLECULAR
FORMULA
STLCFI
NAMING
20
COMPOUNDS
PRE-ASSESSMENT
1. Isotopes –
2. Chemical formula –
3. Structural formula –
4. Ionic compounds –
5. Anions –
6. Cations –
7. Binary compounds –
8. Tertiary compounds –
9. Molecular formula –
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ESSENTIAL
QUESTION
S
LESSON
DEVELOPMENT WITH
ACTIVITIES
ISOTOPES
Isotopes are atoms with the same atomic number but different mass numbers. Since the atomic
number is equal to the number of protons and the mass number is the sum of protons and neutrons,
it can also be said that isotopes are elements with the same number of protons but have a different
number of neutrons.
Two elements with known isotopes are hydrogen and oxygen. Hydrogen has three isotopes
namely, protium (1H1) with 1 proton and no neutrons, deuterium ( 1H2) with 1 proton and 1 neutron
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and tritium (1H3) with 1 proton and 2 neutrons. Oxygen has also three isotopes, namely, oxygen –
16 (8O16) (8 protons and 8 neutrons), oxygen – 17 ( 8O17) (8 protons and 9 neutrons), and oxygen –
18 (8O18) (8 protons and 10 neutrons).
Similar with other pure substances, isotopes also have important uses. Table 1 below shows some
samples of isotopes and their corresponding uses.
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ACTIVITY 1 TEST YOUR KNOWLEDGE
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CHEMICAL FORMULAS
a. The molecular formula indicates the actual number of each element in the
compound
b. The empirical formula is the simplest chemical formula. It only shows the
relative ratio between the number of atoms of the different elements present in the
compound.
To further differentiate chemical formula from empirical formula, consider the examples below.
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The structural formula shows how atoms are bonded to one another in a molecule. This is best
represented using molecular models like the ball-and-stick model and the space-filling-model. In the
ball-and-stick model kits, the atoms are represented by color-coded plastic ball with holes in them. The
stick represents the chemical bonds. In space-filling models, the atoms are represented by connected
balls, hence the bonds are not visible. The balls are proportional to the size of the atoms. Table 2
shows the molecular formula and structural formula, and molecular models of some common
molecules.
ACTIVITY 2
Ta ble 2. Molecu la r a n d Str u ctu r a l F ormu la s a n d Molecu la r Models of Some
Common Molecu les
1. On a short bond paper, draw the ball-and-stick model and the space filling model of the
following molecules. Be creative. You can use coloring materials.
a. methanol
b. ammonia
c. methane
d. carbon tetrachloride
e. hydrogen peroxide
NAMING COMPOUNDS
A. IONIC COMPOUNDS
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Ionic compounds are made of cations and anions. Hence in naming compounds, you should be familiar
with the name of cations and anions (summarized at the end of the lesson on page 23), and take note of
the following rules.
1. For binary compounds, metal cations take their names from the elements with the
anions take the first part of the name of the element, and add the suffix –ide at the end.
2. For ternary compounds which contain three elements, the cation goes first in its name
before the polyatomic ion which usually ends with –ite or –ate.
3. For compounds containing a metallic ion of variable charge, either the classical method
or the stock method of naming may be used. In the classical method, the name of the
metallic ion ends in –ous (for lower charge) an d-ic (for higher charge). In the stock
method, the metal is named first followed by the value of the charge written in Roman numeral
(enclosed in parenthesis).
B. MOLECULAR COMPOUNDS
1 . F o r o n e p a i r
1 , d i - 2 , t r i - 3
d e t e r m i n e t h e n
Examples
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CO – carbon monoxide CO2 – carbon dioxide
NO2 – nitrogen dioxide N2O4 – dinitrogen tetraoxide
2. For binary compounds, place the name of the first element; then, follow it with the
second element. The second element is named by adding –ide to the root of the element name.
Examples
HCl – hydrogen chloride Hl – hydrogen iodide
HBr – hydrogen bromide SiC – silicon carbide
3. For binary compounds considered as acids, use the prefix hydro- followed by the stem
name of the anion ending with –ic, then by the word “acid”
Examples
HCl – hydrochloric acid Hl – hydroiodic acid
HBr – hydrobromic acid HF – hydrofluoric acid
4. Oxy-acids, those that contain hydrogen, oxygen, and another element, is named in two
ways –
a. for anions ending with –ate, change –ate to –ic; then, follow it with the word
“acid”
b. for anions ending with –ite, change –ite to –ous; then, follow it with the word
“acid”
Examples
2. Give the name of the following compounds. Use the stock method in naming compounds
containing a metallic ion of the variable charge.
______________________a. CuSO4
________________________________b. AuCl3
________________________________c. Ag2CO3
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________________________________d. SrCO3
______________________e. (NH4)2Cr2O7
________________________________f. CaS
______________________g. NH4C2H3O2
________________________________h. SnO
______________________i. FeSO3
________________________________j. NaHCO3
FEATURES
20 pts 18 pts 15 pts 10 pts
Elements and Planned carefully The artwork The student shows The student
Principles of and showed an shows that the lack of planning showed little
Design advanced student applied and a little evidence of any
awareness of the the principles of evidence that an understanding of
elements and design while overall the elements and
principles of using one or composition was principles of art.
design. Student more elements planned No evidence of
went above and effectively. planning. Student
beyond Student met did the minimum
expectations expectations of work required
Craftsmanship All aspects of the With a little The student Below average
and Neatness artwork were more effort in showed average craftsmanship,
considered and finishing craftsmanship; lack of pride in
patiently techniques, the adequate, or not as finished artwork.
completed. The artwork could be good as the Showed little
finished product is outstanding. student’s previous evidence of effort
a result of careful Overall, the abilities, a bit and/ or a lack of
meticulous project is clean careless. Minor understanding
planning. The and without defects may be includes obvious
craftsmanship is major defects present deficits like folds,
outstanding. like folds/rips rips, stray marks,
Project is pristine and/ or breaks
and well kept.
Execution, The artwork was The artwork was The artwork was The artwork was
Originality, and successfully successfully partially but never fully
Uniqueness executed from executed from successfully completed.
STLCFI
30
concept to concept to executed
completion, with completion.
an original
approach
CHAPTER
TEST
1. Methane –
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31
2. Carbon tetrachloride-
3. Methanol –
4. Ammonia –
5. Water -
SUMMARY
SUMMARY/SYNTHESIS/GENERALIZATION
This lesson is about Atoms, Molecules and Ions. You learned to:
REFERENCE
S
Rodil, M., et al. Conceptual Science and Beyond: General Chemistry 1. Brilliant
Cretions Publishing, Inc. Novaliches, Quezon City, 2017
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2
CHEMICAL CALCULATIONS AND
REACTIONS
1. INTRODUCTION
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Chemical reactions are everywhere. They occur in almost all phenomena in the
universe everyday – from the formation of rain, photosynthesis, to product
manufacturing, to food digestion, and more. The list of activities that involve chemical
reactions is endless. This is why chemistry is necessary in every person’s life.
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1
PERCENT COMPOSITION
LESSON AND CHEMICAL
FORMULAS
LESSON
MAP
PERCENT
COMPOSITION AND
CHEMICAL FORMULAS
MASS PERCENTAGE
COMPOSITION
EMPIRICAL FORMULA
AND MOLECULAR
FORMULAS
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PRE-
ASSESSMENT
I. Find the molar mass of the ff. compounds. Show your solution.
1. C6H6 –
2. C2HCl3O2 –
3. SiO2 –
4. C2H3O2NH4 –
5. Zn(NO3)2 –
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ESSENTIAL
QUESTIONS
LESSON DEVELOPMENT
WITH ACTIVITIES
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Example:
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ACTIVITY 1 TEST YOUR KNOWLEDGE
1. The compound sodium thiosulfate, a photographic fixative, has a formula NA2S2O3. What is the
mass percentage of each element in the compound?
2. The atomic mass of C is 12 amu while H is 1 amu. What is the percentage composition of CH4?
3. Phosporic acid is a clear and odourless liquid found in carbonated beverages. What is the
percentage composition by mass of H?
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4. Caffeine (C8H10N4O) is a bitter substance found in coffee, tea, soft drinks, and chocolates. What
is the mass percentage of each element in the compound?
5. Acetaminophen, a pain reliever and a fever reducer, has the formula, C8H9O2N. What is the
mass percentage of H in the compound?
Example 1
MMT is a compound used as a gasoline supplement and octane rating booster. What is the empirical
formula of MMT it is 49.5% C, 3.2% H, 22.0% O, and 25.2 % Mn?
Example 2
An analysis of nicotine, one of more than 4 000 chemicals found in the smoke of tobacco products,
shows that it is 74.0 % C, 8.65 % H, and 17.35 % N. if the molar mass of nicotine is 162 g/mol, what
is the empirical formula and the molecular formula of nicotine?
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ACTIVITY 2 TEST YOUR KNOWLEDGE
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Name of Student:_______________________ Date: _____________
1. Find the empirical formula for a compound containing 40.6% C, 51% H and %$.2
% O.
CHAPTER
TEST
2. C20H14O4
3. NH4NO3
4. C4H4O4
5. CrK2O4
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B. Solve the following problem.
1. Corondum, the 9th hardest mineral, contains 52.94% Al and 47.06% O. based on their
composition, what is the empirical formula of the compound?
*Note: if after dividing by the smallest number, the subscript is still a decimal number
with decimal part of 5, multiply all subscript by 2.
SUMMARY
This lesson is about percent composition and chemical formulas. You learned to:
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REFERENCE
S
Rodil, M., et al. Conceptual Science and Beyond: General Chemistry 1. Brilliant
Cretions Publishing, Inc. Novaliches, Quezon City, 2017
2
CHEMICAL REACTIONS
LESSON AND CHEMICAL
EQUATIONS
LESSON
MAP
CHEMICAL REACTIONS
AND CHEMICAL
EQUATIONS
CHEMICAL REACTION
WRITING CHEMICAL
EQUATIONS
BALANCING CHEMICAL
PRE-
ASSESSMENT
1. Chemical reaction –
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2. Reactants –
3. Products –
4. Coefficient –
B. Write the number of atoms present in each of the element of the given compounds.
1. C6H12O6 –
2. NaHCO3 –
3. (NH4)2C2O4 –
4. Mg(NO3)2 –
5. KHC8H4O4 -
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LESSON
DEVELOPMENT WITH
CHEMICAL REACTION
A chemical reaction is a process in which at least one substance is produced as a result of chemical
change. The substances that enter into a chemical reaction are called reactants while the substances
formed from this reaction are called products. For example, in the reaction below is NaHCO3 is referred
to as reactant, whereas, Na2CO3, H2O, and CO2 are the products.
This symbolic representation of a chemical reaction is called a chemical equation. It uses symbols
and formulas to describe the changes that occur in the reaction. As can be seen, the reactants(s) is/are
written on the left-hand side and the product(s) on the right-hand side. Different symbols are used such
as follows:
5. (s), (l), (aq) signifies solid, liquid, gas, and aqueous reactants or products,
respectively; “aqueous” means that the substance is in a solution with
water.
7. 2NaHCO3 2 before the NaHCO3 is called the “coefficient” or the number of moles
in the substance; no coefficient indicates 1 mole
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1. Always follow the rules in writing formulas of the compound. For example, it is incorrect to write
NaCl2, CaO2, and NaSO4. It is because the charge of Na is +1, Cl is -1, Ca is +2, O is -2. Hence,
following the crisscross rule, it must be NaCl, CaO, and Na2SO4.
2. An element that is gaseous at room temperature is represented by its natural molecular formula.
a. It is incorrect to write H3, F, Cl, O, Br, I, N because hydrogen, fluorine, chlorine, oxygen,
and nitrogen are diatomic gases. Hence, they must be written as H2, F2, Cl2, O2, and N2.
b. It is incorrect to write He2, Ne2, Ar2, Kr2, Xe2 because helium, neon, argon, krypton, and
xenon are monoatomic gases. Therefore, they must be written as He, Ne, Ar, Kr, and Xe.
3. An element in solid or liquid state is represented in equations by the element’s chemical symbol.
e.g.
It is incorrect to write Na2 nor Hg2; they must be written only as Na or Hg.
A solid element can be denoted by the subscript (s) and a liquid element by the subscript (l)
When writing a chemical equation, you must first know how and where place the coefficient and the
subscript.
Always remember that a coefficient applies to the whole formula. Subscript, on the other hand,
affects only the element to which it is written.
Examples
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ACTIVITY 1 TEST YOUR UNDERSTANDING
Write the number of atoms present in each element of the given compound.
1. Mg(ClO3)2
2. (NH4)2C2O4
3. (NH4)2
4. KNaC8H4O
5. Ni(CH3CO2)2
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BALANCING CHEMICAL EQUATIONS
Antoine Lavoisier’s law of conservation of mass states that atoms can neither be created nor destroyed
in a chemical reaction; therefore, equations must be balanced.
A balanced equation has equal number of atoms on both sides; meaning, both the reactants and the
product share the same number of atoms.
The reactants in the second equation have 2 H atoms and 2 O atoms, whereas the product shows only 2
H atoms and 1 O atom.
Trial-and-error is applied in changing coefficients when balancing an equation. Remember that only
the coefficients can be changed, not the subscript. Also, fractions are not allowed in the final formula.
EXAMPLES
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ACTIVITY 2 TEST YOUR KNOWLEDGE
1. Fe + O2 Fe2O3
2. N2O N2O2
3. Zn + HCl ZnCl2 + H
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CHAPTER
TEST
1. ↑ -
3. + -
4. ↓ -
5. ∆ -
1. CH3COO –
2. H2CO3 –
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3. Ca(OH)2 –
4. (NH4)3PO4 –
5. 2Mg3(PO4)2 –
3. Fe + O2 Fe2O3
4. H2 + N2 NH3
SUMMARY
This lesson is about chemical reactions and chemical equations. You learned to:
REFERENCES
Rodil, M., et al. Conceptual Science and Beyond: General Chemistry 1. Brilliant
Creations Publishing, Inc. Novaliches, Quezon City, 2017
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LESSON 3 MASS RELATIONHIPS IN
CHEMICAL REACTIONS
MAP
WRITING CHEMICAL
LIMITING REAGENT
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AND PERCENT
56
CHEMICAL
PRE-
ASSESSMENT
Name of Student:_______________________ Date: _____________
_________________________________________________________________________________
_________________________________________________________________________________
_________________________________________________________________________________
_________________________________________________________________________________
3. limiting reagent
_________________________________________________________________________________
_________________________________________________________________________________
4. theoretical yield
_________________________________________________________________________________
_________________________________________________________________________________
5. excess reagent
_________________________________________________________________________________
______________________________________________________________________________
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ESSENTIAL
QUESTIONS
LESSON DEVELOPMENT
WITH ACTIVITIES
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Other concept of stoichiometry is known as mass-to-mole relationship or vice versa. Mass-to-mole
relationship is used to predict the mole of reactant/product from a given mass of reactant/product from
a given mole of another reactant/product.
The process can be facilitated by employing the molar mass in g/mol of the compound needed as
conversion ratio. Furthermore, the molar ratio between the given compound and the unknown
compound will be needed.
1. MASS-TO-MOLE RELATIONSHIP
EXAMPLE:
Platinum (Pt) reacts in hot agua regia, a mixture of nitric acid and sulfuric acid, to give aqueous
choloroplatinic acid (H2PtCl6), a reddish brown solid substance used in inedible inks and electroplanting
If 0.58 g Pt was reacted with hot agua regia, how many moles of H2PtCl6 were produced?
ACTIVITY 1
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Solve the following problems:
1. How many moles of HCl will be produced when 249 g of AlCl3 are reacted according to this
chemical equation?
2. Potassium thiosulfate (K2S2O3) is used to dechlorinate water. The reaction involved is as follows:
Assume that 38.85 g of K2S2O3 is used in the process of removing excess chlorine. How many moles of
HCl will be produced?
3. How many moles of Al2O3 will be produced when 23.9 of H2O are reacted according to this
chemical equation?
2. MOLE-TO-MASS RELATIONSHIP
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mass of moles of moles of
reactant/product product/reactant reactant/product
EXAMPLE
Potassium (K) metal, when reacted with H2O, yields potassium hydroxide (KOH) and H2.
2K + 2H2O 2KOH + H2
This is an exothermic reaction which the heat released is enough to cause the H2 to ignite and the aqueous
KOH to plaster. If accidentally, 8.65 mol K were put in water, how many grams of KOH will possibly plaster?
1. In extracting gold from ore, miners dissolve the gold using a metallurgical technique called
gold cyanidation. The chemical reaction for dissolution of Au is as follows.
What is the minimum amount of KCN (in grams) needed to extract 38.60 moles of Au?
2. Sulfuric acid (H2SO4), a highly corrosive strong mineral acid, reacts with Cu according to this
equation:
How many grams of sulfur dioxide (SO2) are created by this reaction if 4.78 mole of Cu react with
the H2SO4?
Before a chemist conducts a reaction, he/she usually calculates the needed amount of reactant to
ensure that nothing will be wasted. If this is not done, even if one of the reactants will be consumed
completely, a reactant remains as is at the end of the reaction.
The reactant consumed completely in the reaction is called the limiting reagent because the
maximum amount of products (theoretical yield) that will be formed depends on how much of this is
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present during the reaction. On the other hand, the reactant present in quantities greater than required
to react with the limiting reagent is called the excess reagent.
In reality, the quantity of product obtained in the reaction is less than the maximum amount
expected. This is called the theoretical yield. On the other hand, the quantity of product actually
obtained from the reaction is referred to as the actual yield. In determining the efficiency of the
reaction, percent yield is calculated as follows.
actual yield
% yield = x 100%
theoritical yield
EXAMPLE
One of the steps in producing nitric acid (HNO3) using the Ostwald process is:
a. limiting reagent
d. the amount of excess reagent left at the end of the reaction; and
To determine which of the given reactants are the limiting and the excess reagents, calculate the
moles of the product formed from the given quantities of the reactants. The reactant which forms the
lesser number of moles of product is the limiting reagent, while the reactant which forms the greater
number of moles of product is the excess reagent.
THEORETICAL YIELD
To determine the theoretical yield, calculate the mass of NO formed from the given quantity of limiting
reagent (4.398 g NH3). Remember that the maximum amount of products (theoretical yield) that will be
formed depends of how much limiting reagent is present during the reaction.
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AMOUNT OF EXCESS REAGENT LEFT
To determine the amount of excess reagent left at the end of the reaction, calculate the mass of the excess
reagent that reacts with the limiting reagent. Then, subtract the calculated mass to the given mass.
PERCENT YIELD
1. Phosphoric acid (H3PO4) is a key ingredient on soft drinks that gives it a sharper flavour. One
way to produce this acid is with the aid of mineral fluoroapatite (Ca5(PO4)3F) following this reaction
2. Thermite reaction is necessary to produce molten iron. This reaction involves Fe 3O4 and Al and is
described by:
If 198.5 g Al and 365.5 g Fe 3O4 are used, what mass of the excess reagent remains unused at the
end of the reaction?
CHAPTER
TEST
A. Solve the following problems.
1. Sulfuric acid (H2SO4), a highly corrosive strong mineral acid, reacts with Cu according to this
equation:
How many grams of sulfuric dioside (SO2) are created by this reaction if 6.80 mole of Cu react with
H2SO4?
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2. One of the steps in producing nitric acid (HNO3) using the Ostwald process is:
d.) the amount of excess reagent left at the end of the reaction; and
SUMMARY
This lesson is about mass relationships in chemical reaction. You learned to:
Calculate mole or mass ratios for a reaction in order to calculate the amount of reactant needed or
amount of product formed in terms of moles or mass
Calculate the percent yield and theoretical yield of the reaction
Explain the concept of limiting reagent in a chemical reaction and identify the excess reagents
REFERENCES
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Rodil, M., et al. Conceptual Science and Beyond: General Chemistry 1. Brilliant
Creations Publishing, Inc. Novaliches, Quezon City, 2017
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