HC Docx1
HC Docx1
HC Docx1
HC
1.
Which of the following alkene, has the slowest rate of the hydrogenation?
C C C
C (III)
C (I)
(II)
(B) II (D) IV
2.
The organic compounds A and B are obtained by subjecting 1 butene to HBO and OMDM, respectively. (HBOHydroboration oxidation and OMDM oxymercuration demercuration). A and B can be distinguished by (A) Iodoform test (B) Fehling solution test of the dehydrogenated products of A and B (C) Tollen s reagent test of the dehydrogenated products of A and B (D) All the three tests : A, B and C
3.
OH H CH3
E
2
P
S
Br
N2
(Optically active)
The correct statement about the products of the two parallel reactions is: (A) The product P is optically inactive due to internal compensation while Q is optically inactive due external compensation. (B) The product P is racemic mixture while Q is a meso compound (C) Both P and Q are achiral molecule and hence optically inactive (D) Both P and Q are optically active. 4. A mixture of methane, ethylene and acetylene gases are passed through a woulf bottle containing ammonical Cu2Cl2 . The gas coming out is (A) Methane (C) Methane and ethylene 5. (B) Acetylene (D) The original mixture
A 10 gm mixture of butane and 2butene reacts with 8.0 gm of bromine dissolved in CCl4 . Calculate the percentage of butane in the mixture (A) 72% (C) 50% (B) 28% (D) 68%
(IV)
QB-HC-2
6.
1butene subjected to HBO and OMDM separately will yield products that can be distinguished by
(A) Tollends reagent test after subjecting the products to dehydrogenation (B) Iodoform test (C) Fehling solution test after subjecting them to dehydrogenation (D) All the three 7. In the reaction
M | t p Br p
Na liq. NH
the product P is: (A) A pure compound which is optically inactive due to internal compensation (B) A binary mixture which is optically inactive due to external compensation (C) A binary mixture which is optically active (D) A pure compound which is optically inactive due to absence of chiral reaction 8. Arrange the CH bonds labelled 1, 2, 3 and 4 in the molecule (given below) in increasing order of their ease for homolytic fission.
H H H 3 3 2 H 2 H 1 H CH3
(A)
3 1
(C) 4 1 2 3 9. The compound with the highest boiling point is: (A) n- Hexane (C) 2,2- Dimethyl propane
10.
The maximum number of isomers for an alkene with the molecular formula C4H8 is: (A) 2 (C) 4 (B) 3 (D) 5
11.
The compound 1,2- butadiene has: (A) Only sp - hybridised carbon atoms (C) Both sp - sp2 hybridized carbon atoms (B) Only sp2- hybridized carbon atoms (D) sp, sp2 and sp3 - hybridized carbon atoms
r or mixt r )
(B) 1 3 (D) 2
4 1 3
QB-HC-3
12.
When propyne is treated with aqueous H2SO4 in presence of HgSO4 the major product is (A) Propanal (C) Propyl hydrogen sulphate (B) Acetone (D) Propanol
13.
A and B are,
H3C
(A)
H3C
B , 3
(B)
H3C
CH2
CH2
B , 3
(C)
H3C
CH2
CH2
H3C
O B , H3C CH3
(D)
H3C
14.
(A)
Cl2HC H
(C)
H3C CHCl2
15.
Which of the following dienes is expected to have least value of enthalpy of hydrogenation? (A)
H2C CH2
H2C
(C)
CH3
CH2
BH
CH C
H3C
Cl
(B)
H3C
Cl H3C OH Cl HO
(D)
Cl
(B)
CH2 H2C
(D)
H2C
CH2
QB-HC-4
16.
O || C (CH2)4
O || C
H on ozonolysis is
17
O
h ! NBS 3CH3 p x 1 qal p Y. Y is CH i nt
Br
(A)
Br
(C)
Br
18.
H3C OH
HBr p X, X is
H3C
Br OH
(A)
H3C
(C)
OH Br
19.
(A)
(C)
H CH3
20.
H 2C
CH3
CH3
Which is not true about the above alkene? (A) It is not capable to show geometrical isomerism. (B) It is optically active and on hydrogenation it produces optically inactive product.
Br
(B)
CH3
(D)
Br
CH3
H3C
(B)
Br
H3C
Br OH
(D)
(B)
H H3 C
(D)
H3 C
QB-HC-5
(C) On treatment with hot acidic KMnO 4 it produces resolvable acid. (D) On treatment with HOBr it produces 1 bromo 3 methyl 2 pentanol. 21.
H3 C CH3
(major )
CH3 CH3
Cl
(A)
H 3C HO OH
(C)
H 3C Cl
22.
H3 C H
H
4
CH3
Which is true about the above reaction? (A) Bromine addition take place in syn manner (B) Product is optically inactive due to external compensation (C) Addition take place via free radical formation (D) Product is optically inactive due to internal compensation 23. Which of the following alkene has the lowest heat of hydrogenation?
H H
CH2
(A)
H H
H3C
(C)
H3C H
24.
What will the correct product (A) and (B) respectively of the following reaction?
R
H2 ( 1 le) p Ni (200-300)
2 p CCl
Br
Cl
(B)
OH
(D)
H 3C O Cl
(B)
H
CH3 H
CH3 H
(D)
H3C
QB-HC-6
R H H H R Br , Br
R Br R Br H R H H R Br Br , , H
R R H Br , Br
(A)
(B)
(C)
(D)
25.
Which of the following will be the correct product (P) of the reaction
H 3C CH2
NBS P ? p
(A)
Br H3 C
Br
(B)
H 3C Br
CH2
(C)
H 3C CH2
(D)
Br CH2
26.
E R C | C R Rate ! r1 p
The relation between r1 and r2 if R is an alkyl group is: (A) r1 = r2 (C) r1 " r2 (B) r1 ! (D) r1
1 r2 2
r2
27.
O3 / Zn p ( ) H O
2
O H3C
. ( ) is
H
(A)
CH3 CH3
(B)
CH3 CH3
(C)
CH3
(D)
QB-HC-7
28.
O .Zn
(A)
H3C CH3
(B)
H3C
29.
H2 C Cl
Cl
H3 C p
Cl
HCl H2 O2
(B)
H2C Cl
(C)
H2 C Cl
(D)
H3C Cl
H3C Br CH
H3C
(A)
H H C 6 H5 CH3
(C)
H5 C6 C6 H5
31.
HBO, OMDM and acid catalysed hydration will give same product in (A) (B)
H3C
(C)
H H
alcoholic KOH A. A is p E
2
30.
CH
C 6 H5 H3C C6 H5
(B)
H5 C6 H
(D)
None is correct
CH2
CH2
CH3
(D)
QB-HC-8
32.
The ozonolysis of 1,2dimethyl benzene i.e. o xylene gives (B) Methyl glyoxal (D) All the three above
33.
(A)
H3C
E1CB
(A)
CH3 CH3
(B)
ethanolic p KOH
Saytzeff product
E1
(B)
CH3
(C)
E1CB
(C)
(D)
H3C CH3
Cl
ethanolic KOH p
E1
(D)
(A) AC, BA, CB, DD (C) AC, BA, CD, DB 34. Match LIST X with LIST Y LIST X (A)
CH2
BH / THF
2 2
3 p H O / OH
(B)
CH2
2 4 p
dil. H SO
(B) Alcohol which can undergo reaction with NaOI to give yellow ppt.
(C)
CH2
(C) Alkane
CH2
(D) Alcohol which will undergo reaction with pcc. (B) AD BA CB DC (D) AD BA CD DC
QB-HC-9
35.
R 2C ! CHR
(2)
R 2C ! CH2
(3)
RCH ! CHR
( 4)
RCH ! CH2
(5)
(A) 1 " 2 " 3 " 4 " 5 (C) 1 " 2 " 4 " 3 " 5 36.
(A)
OH CH3
(B)
O 2N
CH3
(C)
HO
(D)
CH3
37
p
NaBH 4
RO / Hg 2 / H
CH3
CH3
(A)
(B)
H 3C CH3 OR
CH3
CH3
CH3
(C)
H3C CH3 OH
(D)
H3C CH3 OR
38.
When acetylene is passed through conc. solution of Cu2Cl2 and ammonium chloride containing some dil HCl and the substance formed reacts with dil HCl at 160rC, if forms another substance which then polymerizes. The polymer formed is (A) Benzene (C) Neoprene (B) Polyisoprene (D) PMMA
39.
Arrange (I) CH2 = CH - CH3, (II) CH2 = CH - C6H5, (III) CH 2 = CH - Cl in increasing order of ease of cationic polymerization. (A) III < II < I (C) III < I < II (B) I < II < III (D) II < I < III
40.
QB-HC-10
Br
Product will be (A) cis alkene (C) mixture of cis and trans alkene 41. In the reaction sequence
CH3 I ( i ) BH 3 CH3 CH ! CH2 p[ x ] will be
( ii ) CH 3 COOH
42.
H
KNH 2 p . (
Br
Ph
H
Ph
(A)
Ph Ph O H
(C)
Ph OH
43.
Which among the following compound will give 1,4-addition reaction (A)
CH2 H2C
CH3
(C)
H2C O
44.
! "
H3 C
C H
will be
(B)
Ph
Ph
Ph
(D)
H Br
(B)
H2C
CN
(D)
All of these
# $
" !
H C
CH3
% %
QB-HC-11
X will be (A) 2-methylbutane derivative (C) Cyclopropane derivative 45. In the reaction sequence (B) Pentane derivative (D) All of these
H3C H3C
O O O
CH3 H
4 p ro
NaBH
ct will be
H3C
(C)
H3C
OH an
H3C OH
(D)
an
46.
(A)
CH3
(B)
(C) 47
H2C CH2
(D)
All of these
X will be
OH OH
(A)
CH3 OH
(B)
H 3C
CH2
OH
(C)
HO
CH2
(D)
H3C CH3
48
HCl p P
CH2
&
H3C
&
(A)
(B)
H2C
CH2
&
'
P Cl
(A)
H Me (d-for )
(B)
Cl Me (l-for )
(C)
CH2Cl
49.
(A)
CH3 H3C
(B)
H3C
CH3
(C)
CH3
CH3
(D)
CH2 H3C
50.
(A)
(B)
Br
Br
(C)
(D)
51.
Which of the following carbides on hydrolysis gives propyne? (A) Be2C (C) CaC2 (B) Al4C3 (D) Mg2C3
52.
O 2N C CH3
O O
Hg / H p P, P is :
2
(A)
O2 N H3C
(B)
O 2N CH3 O
(
H
QB-HC-12
CH3
QB-HC-13
(C)
O 2N O H3C
(D)
None of these
53.
H /( ( ) p
CH3 H3C
3 p( Y ). ( ) and ( Y ) are
H O
55.
H3C CH3
(A)
H3C I
CH3
(B)
H3C I
CH3
(C)
H3C CH3
(D)
I H3C