Flame Retardant Expanded

Standards 2009

Latest list of PBDEs

185 & growing

Latest list of
PBDE Metabolites
(Hydroxy & Methoxy
derivatives)
44 & growing

Methods
EPA 1614
EPA 527
ISO/DIS 22032

Fluorinated PBDE
Congeners
New

Bromobiphenyl
Congeners
New

Industrial
Flame Retardants

Bromophenols and
Flame Retardants Bromoanisoles
AccuStandard New
Brominated Flame Retardants in the Environment
Brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecane (HBCD) have
become ubiquitous global environmental contaminants because of their widespread use in numerous household and commercial
products. They have been detected in sediments, biota, house dust, sewage sludge, air, water samples, and human and wildlife tissues.
In the past years an impressive amount of information has become accessible on the persistence, bioaccumulative and toxic properties
of PBDEs and HBCD.

There are 209 congeners of PBDEs. They are produced industrially as mixtures (designated penta-BDE, octa-BDE, and deca-BDE).
Some PBDEs break down further in the environment and in the body to other PBDEs and to other compounds. AccuStandard has
synthesized over 185 of the 209 congeners, plus dozens of their hydroxy and methoxy metabolites.

AccuStandard has separated the three major constituents of technical mixtures of HBCD (alpha, beta, gamma). These three
stereoisomers, as well as a technical mixture, are available as chemical reference standards at AccuStandard.

In addition, AccuStandard offers a wide variety of PBDE mixtures and calibration sets using the pure individual congeners of PBDEs,
which were synthesized and analyzed in house. Standards of branded technical products such as BromkalTM and FiremasterTM, and
many other industrial flame retardants can also be requested. Fluorinated PBDEs, Bromobiphenyls, Bromophenols and -anisols add to
the big number of brominated compounds available through AccuStandard.

Upon special request, compounds can be offered in various concentrations and mixes, or as neat materials. Custom standards are an
economical and time saving way to have a standard prepared for your individual needs. To make an online Custom Quotes Request, go
to AccuStandard.com.

Table of Contents

List of PBDE Congeners 1-3

Tech Grade PBDEs 4
PBDE Mixtures (including EPA Method 527) 4
ISO/DIS 22032 Calibration Curve 4
EPA Method 1614 5
PBDE Metabolites 6
Fluorinated PBDE Congeners NEW 7
HBCD Isomers 8
Bromobiphenyl Congeners 8
Bromophenols 8
Bromoanisoles 8
Industrial Flame Retardants 9
Other Flame Retardants 9

©AccuStandard 2009
 Individual Polybromodiphenyl Ethers (PBDEs)
AccuStandard has synthesized and cataloged 185 pure PBDE congeners for use as standards for toxicology research and in the identification of unknown
substances in environmental samples.

Compound CAS No. Conc. Solvent Cat. No. (1 mL)

2-Bromodiphenyl ether 7025-06-1 50 µg/mL Isooctane BDE-001S
3-Bromodiphenyl ether 6876-00-2 50 µg/mL Isooctane BDE-002S
4-Bromodiphenyl ether 101-55-3 50 µg/mL Isooctane BDE-003S
2,2'-Dibromodiphenyl ether 51452-87-0 50 µg/mL Isooctane BDE-004S
2,3-Dibromodiphenyl ether 446254-14-4 50 µg/mL Isooctane BDE-005S
2,3'-Dibromodiphenyl ether 147217-72-9 50 µg/mL Isooctane BDE-006S
2,4-Dibromodiphenyl ether 171977-44-9 50 µg/mL Isooctane BDE-007S
2,4'-Dibromodiphenyl ether 147217-71-8 50 µg/mL Isooctane BDE-008S
2,5-Dibromodiphenyl ether 33513-66-3 50 µg/mL Isooctane BDE-009S
2,6-Dibromodiphenyl ether 51930-04-2 50 µg/mL Isooctane BDE-010S
3,3'-Dibromodiphenyl ether 6903-63-5 50 µg/mL Isooctane BDE-011S
3,4-Dibromodiphenyl ether 189084-59-1 50 µg/mL Isooctane BDE-012S
3,4'-Dibromodiphenyl ether 83694-71-7 50 µg/mL Isooctane BDE-013S
3,5-Dibromodiphenyl ether 46438-88-4 50 µg/mL Isooctane BDE-014S
4,4'-Dibromodiphenyl ether 2050-47-7 50 µg/mL Isooctane BDE-015S
2,2',3-Tribromodiphenyl ether 147217-74-1 50 µg/mL Isooctane BDE-016S
2,2',4-Tribromodiphenyl ether 147217-75-2 50 µg/mL Isooctane BDE-017S
2,2',5-Tribromodiphenyl ether 407606-55-7 50 µg/mL Isooctane BDE-018S
2,2',6-Tribromodiphenyl ether 147217-73-0 50 µg/mL Isooctane BDE-019S
2,3,3'-Tribromodiphenyl ether 147217-76-3 50 µg/mL Isooctane BDE-020S
2,3,4-Tribromodiphenyl ether 337513-67-4 50 µg/mL Isooctane BDE-021S
2,3,4'-Tribromodiphenyl ether 446254-15-5 50 µg/mL Isooctane BDE-022S
2,3,5-Tribromodiphenyl ether 446254-16-6 50 µg/mL Isooctane BDE-023S
2,3',4-Tribromodiphenyl ether 147217-77-4 50 µg/mL Isooctane BDE-025S
2,3',5-Tribromodiphenyl ether 337513-75-4 50 µg/mL Isooctane BDE-026S
2,3',6-Tribromodiphenyl ether 337513-53-8 50 µg/mL Isooctane BDE-027S
2,4,4'-Tribromodiphenyl ether 41318-75-6 50 µg/mL Isooctane BDE-028S
2,4,5-Tribromodiphenyl ether 337513-56-1 50 µg/mL Isooctane BDE-029S
2,4,6-Tribromodiphenyl ether 155999-95-4 50 µg/mL Isooctane BDE-030S
2,4',5-Tribromodiphenyl ether 65075-08-3 50 µg/mL Isooctane BDE-031S
2,4',6-Tribromodiphenyl ether 189084-60-4 50 µg/mL Isooctane BDE-032S
2',3,4-Tribromodiphenyl ether 147217-78-5 50 µg/mL Isooctane BDE-033S
2',3,5-Tribromodiphenyl ether 446254-17-7 50 µg/mL Isooctane BDE-034S
3,3',4-Tribromodiphenyl ether 147217-80-9 50 µg/mL Isooctane BDE-035S
3,3',5-Tribromodiphenyl ether 147217-79-6 50 µg/mL Isooctane BDE-036S
3,4,4'-Tribromodiphenyl ether 147217-81-0 50 µg/mL Isooctane BDE-037S
3,4,5-Tribromodiphenyl ether 337513-54-9 50 µg/mL Isooctane BDE-038S
3,4',5-Tribromodiphenyl ether 50 µg/mL Isooctane BDE-039S
2,2',3,3'-Tetrabromodiphenyl ether 50 µg/mL Isooctane BDE-040S
2,2',3,4-Tetrabromodiphenyl ether 337513-68-5 50 µg/mL Isooctane BDE-041S
2,2',3,4'-Tetrabromodiphenyl ether 446254-18-8 50 µg/mL Isooctane BDE-042S
2,2',3,5-Tetrabromodiphenyl ether 446254-19-9 50 µg/mL Isooctane BDE-043S
2,2',3,5'-Tetrabromodiphenyl ether 446254-20-2 50 µg/mL Isooctane BDE-044S
2,2',3,6'-Tetrabromodiphenyl ether 446254-22-4 50 µg/mL Isooctane BDE-046S
2,2',4,4'-Tetrabromodiphenyl ether 5436-43-1 50 µg/mL Isooctane BDE-047S
2,2',4,5-Tetrabromodiphenyl ether 337513-55-0 50 µg/mL Isooctane BDE-048S
2,2',4,5'-Tetrabromodiphenyl ether 243982-82-3 50 µg/mL Isooctane BDE-049S
2,2',4,6-Tetrabromodiphenyl ether 446254-23-5 50 µg/mL Isooctane BDE-050S
2,2',4,6'-Tetrabromodiphenyl ether 189084-57-9 50 µg/mL Isooctane BDE-051S
2,2',5,5'-Tetrabromodiphenyl ether 446254-24-6 50 µg/mL Isooctane BDE-052S
2,2',5,6'-Tetrabromodiphenyl ether 446254-25-7 50 µg/mL Isooctane BDE-053S
2,2',6,6'-Tetrabromodiphenyl ether 50 µg/mL Isooctane BDE-054S
2,3,3',4-Tetrabromodiphenyl ether 50 µg/mL Isooctane BDE-055S
2,3,3',4'-Tetrabromodiphenyl ether 50 µg/mL Isooctane BDE-056S
2,3,3',5-Tetrabromodiphenyl ether 50 µg/mL Isooctane BDE-057S
2,3,3',5'-Tetrabromodiphenyl ether 50 µg/mL Isooctane BDE-058S
2,3,4,4'-Tetrabromodiphenyl ether 446254-31-5 50 µg/mL Isooctane BDE-060S
2,3,4,5-Tetrabromodiphenyl ether 446254-32-6 50 µg/mL Isooctane BDE-061S
2,3,4,6-Tetrabromodiphenyl ether 446254-33-7 50 µg/mL Isooctane BDE-062S

2,3,5,6-Tetrabromodiphenyl ether 50 µg/mL Isooctane BDE-065S

2,3,4',5-Tetrabromodiphenyl ether 446254-34-8 50 µg/mL Isooctane BDE-063S

2,3',4,4'-Tetrabromodiphenyl ether 189084-61-5 50 µg/mL Isooctane BDE-066S

2,3',4,5-Tetrabromodiphenyl ether 446254-37-1 50 µg/mL Isooctane BDE-067S
2,3',4,5'-Tetrabromodiphenyl ether 446254-38-2 50 µg/mL Isooctane BDE-068S
2,3',4,6-Tetrabromodiphenyl ether 327185-09-1 50 µg/mL Isooctane BDE-069S
2,3',4',5-Tetrabromodiphenyl ether 446254-39-3 50 µg/mL Isooctane BDE-070S
2,3',4',6-Tetrabromodiphenyl ether 189084-62-6 50 µg/mL Isooctane BDE-071S
2,3',5,5'-Tetrabromodiphenyl ether 446254-40-6 50 µg/mL Isooctane BDE-072S
2,3',5',6-Tetrabromodiphenyl ether 446254-41-7 50 µg/mL Isooctane BDE-073S
2,4,4',5-Tetrabromodiphenyl ether 446254-42-8 50 µg/mL Isooctane BDE-074S
2,4,4',6-Tetrabromodiphenyl ether 189084-63-7 50 µg/mL Isooctane BDE-075S
2',3,4,5-Tetrabromodiphenyl ether 446254-43-9 50 µg/mL Isooctane BDE-076S
3,3',4,4'-Tetrabromodiphenyl ether 93703-48-1 50 µg/mL Isooctane BDE-077S
3,3',4,5-Tetrabromodiphenyl ether 446254-45-1 50 µg/mL Isooctane BDE-078S
3,3',4,5'-Tetrabromodiphenyl ether 446254-48-4 50 µg/mL Isooctane BDE-079S
3,3',5,5'-Tetrabromodiphenyl ether 103173-66-6 50 µg/mL Isooctane BDE-080S
3,4,4',5-Tetrabromodiphenyl ether 446254-50-8 50 µg/mL Isooctane BDE-081S

Continued on next page

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 Individual Polybromodiphenyl Ethers (PBDEs)
Compound CAS No. Conc. Solvent Cat. No. (1 mL)
2,2',3,3',4-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-082S
2,2',3,3',5-Pentabromodiphenyl ether 446254-51-9 50 µg/mL Isooctane BDE-083S
2,2',3,4,4'-Pentabromodiphenyl ether 182346-21-0 50 µg/mL Isooctane BDE-085S
2,2',3,4,5-Pentabromodiphenyl ether 446254-53-1 50 µg/mL Isooctane BDE-086S
2,2',3,4,5'-Pentabromodiphenyl ether 446254-54-2 50 µg/mL Isooctane BDE-087S
2,2',3,4,6-Pentabromodiphenyl ether 446254-55-3 50 µg/mL Isooctane BDE-088S
2,2',3,4,6'-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-089S
2,2',3,4',5-Pentabromodiphenyl ether 446254-57-5 50 µg/mL Isooctane BDE-090S

2,2',3,5,6-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-093S

2,2',3,5,5'-Pentabromodiphenyl ether 446254-59-7 50 µg/mL Isooctane BDE-092S

2,2',3,5,6'-Pentabromodiphenyl ether 446254-61-1 50 µg/mL Isooctane BDE-094S

2,2',3',4,5-Pentabromodiphenyl ether 446254-64-4 50 µg/mL Isooctane BDE-097S
2,2',3',4,6-Pentabromodiphenyl ether 38463-82-0 50 µg/mL Isooctane BDE-098S
2,2',4,4',5-Pentabromodiphenyl ether 60348-60-9 50 µg/mL Isooctane BDE-099S
2,2',4,4',6-Pentabromodiphenyl ether 189084-64-8 50 µg/mL Isooctane BDE-100S
2,2',4,5,5'-Pentabromodiphenyl ether 446254-65-5 50 µg/mL Isooctane BDE-101S
2,2',4,5,6'-Pentabromodiphenyl ether 446254-66-6 50 µg/mL Isooctane BDE-102S
2,2',4,5',6-Pentabromodiphenyl ether 446254-67-7 50 µg/mL Isooctane BDE-103S
2,2',4,6,6'-Pentabromodiphenyl ether 446254-68-8 50 µg/mL Isooctane BDE-104S
2,3,3',4,4'-Pentabromodiphenyl ether 373594-78-6 50 µg/mL Isooctane BDE-105S
2,3,3',4,5-Pentabromodiphenyl ether 446254-69-9 50 µg/mL Isooctane BDE-106S
2,3,3',4',5-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-107S
2,3,3',4,5'-Pentabromodiphenyl ether 446254-71-3 50 µg/mL Isooctane BDE-108S
2,3,3',4,6-Pentabromodiphenyl ether 446254-72-4 50 µg/mL Isooctane BDE-109S

2,3,3',5,6-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-112S

2,3,3',5,5'-Pentabromodiphenyl ether 446254-74-6 50 µg/mL Isooctane BDE-111S

2,3,4,4',5-Pentabromodiphenyl ether 446254-77-9 50 µg/mL Isooctane BDE-114S

2,3,4,4',6-Pentabromodiphenyl ether 446254-78-0 50 µg/mL Isooctane BDE-115S

2,3,4',5,6-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-117S

2,3,4,5,6-Pentabromodiphenyl ether 189084-65-9 50 µg/mL Isooctane BDE-116S

2,3',4,4',5-Pentabromodiphenyl ether 446254-80-4 50 µg/mL Isooctane BDE-118S

2,3',4,4',6-Pentabromodiphenyl ether 189084-66-0 50 µg/mL Isooctane BDE-119S
2,3',4,5,5'-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-120S
2,3',4,5',6-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-121S
2',3,3',4,5-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-122S
2',3,4,4',5-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-123S
2',3,4,5,5'-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-124S
2',3,4,5,6'-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-125S
3,3',4,4',5-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-126S
3,3',4,5,5'-Pentabromodiphenyl ether 50 µg/mL Isooctane BDE-127S
2,2',3,3',4,4'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-128S
2,2',3,3',4,5-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-129S
2,2',3,3',4,5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-130S
2,2',3,3',4,6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-131S
2,2',3,3',5,5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-133S
2,2',3,3',6,6'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-136S
2,2',3,4,4',5-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-137S
2,2',3,4,4',5'-Hexabromodiphenyl ether 182677-30-1 50 µg/mL Isooctane BDE-138S
2,2',3,4,4',6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-139S
2,2',3,4,4',6'-Hexabromodiphenyl ether 243982-83-4 50 µg/mL Isooctane BDE-140S
2,2',3,4,5,5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-141S
2,2',3,4,5,6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-142S
2,2',3,4,5,6'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-143S
2,2',3,4,5',6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-144S
2,2',3,4,6,6'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-145S

2,2',3,4',5,6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-147S

2,2',3,4',5,5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-146S

2,2',3,4',5,6'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-148S

2,2',3,4',6,6'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-150S
2,2',4,4',5,5'-Hexabromodiphenyl ether 68631-49-2 50 µg/mL Isooctane BDE-153S
2,2',4,4',5,6'-Hexabromodiphenyl ether 207122-15-4 50 µg/mL Isooctane BDE-154S
2,2',4,4',6,6'-Hexabromodiphenyl ether 35854-94-5 50 µg/mL Isooctane BDE-155S
2,3,3',4,4',5-Hexabromodiphenyl ether 35854-94-5 50 µg/mL Isooctane BDE-156S
2,3,3',4,4',5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-157S
2,3,3',4,4',6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-158S
2,3,3',4,5,5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-159S
2,3,3',4,5,6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-160S
2,3,3',4,5',6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-161S
2,3,3',4',5,5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-162S
2,3,4,4',5,6-Hexabromodiphenyl ether 189084-58-0 50 µg/mL Isooctane BDE-166S
2,3',4,4',5,5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-167S
2,3',4,4',5',6-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-168S
0 3,3',4,4',5,5'-Hexabromodiphenyl ether 50 µg/mL Isooctane BDE-169S

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 Individual Polybromodiphenyl Ethers (PBDEs)
Compound CAS No. Conc. Solvent Cat. No. (1 mL)
2,2',3,3',4,4',5-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-170S
2,2',3,3',4,4',6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-171S
2,2',3,3',4,5,5'-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-172S
2,2',3,3',4,5,6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-173S
2,2',3,3',4,5',6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-175S
2,2',3,3',4',6,6'-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-176S
2,2',3,3',4',5,6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-177S
2,2',3,3',5,5',6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-178S
2,2',3,4,4',5,5'-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-180S
2,2',3,4,4',5,6-Heptabromodiphenyl ether 189084-67-1 50 µg/mL Isooctane BDE-181S
2,2',3,4,4',5,6'-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-182S
2,2',3,4,4',5',6-Heptabromodiphenyl ether 207122-16-5 50 µg/mL Isooctane BDE-183S
2,2',3,4,4',6,6'-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-184S
2,2',3,4,5,5',6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-185S
2,2',3,4,5,6,6'-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-186S
2,2',3',4',5,6,6'-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-188S
2,3,3',4,4',5,5'-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-189S
2,3,3',4,4',5,6-Heptabromodiphenyl ether 189084-68-2 50 µg/mL Isooctane BDE-190S
2,3,3',4,4',5',6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-191S
2,3,3',4,5,5',6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-192S
2,3,3',4',5,5',6-Heptabromodiphenyl ether 50 µg/mL Isooctane BDE-193S
2,2',3,3',4,4',5,5'-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-194S
2,2',3,3',4,4',5,6-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-195S
2,2',3,3',4,4',5,6'-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-196S
2,2',3,3',4,4',6,6'-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-197S
2,2',3,3',4,5,5',6-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-198S
2,2',3,3',4,5',6,6'-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-201S
2,2',3,3',5,5',6,6'-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-202S
2,2',3,4,4',5,5',6-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-203S
2,2',3,4,4',5,6,6'-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-204S
2,3,3',4,4',5,5',6-Octabromodiphenyl ether 50 µg/mL Isooctane BDE-205S
2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether 50 µg/mL Isooctane BDE-206S
2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether 50 µg/mL Isooctane BDE-207S-R1
2,2',3,3',4,5,5',6,6'-Nonabromodiphenyl ether 50 µg/mL Isooctane BDE-208S
Decabromodiphenyl ether 1163-19-5 50 µg/mL Isooctane:Toluene 9:1 BDE-209S

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 Tech Grade PBDEs, Specific Mixtures and Calibration Curve Set
Technical Grade PBDEs
PBDE Technical Grade PBDE Congeners common to DE-71 (Pentas) Great Lakes Study
Price / Technical Mixtures (Bromkal™) BDE-710-GL $ 250 / 1 x 1 mL
50 µg/mL in Isooctane Cat. No. 1 mL 50 µg/mL each in Isooctane
BDE-BROMKAL $ 275 / 1 x 1 mL
Bromkal DE-70-5 (Pentas) BDE-705 $ 90
10 µg/mL each in Isooctane 6 comps.
Bromkal DE-71 (Pentas) BDE-710 90 Bromkal DE-71
Bromkal DE-73-6 (Hexas) BDE-736 90
2,4,4'-Tribromodiphenyl ether (#28)
Bromkal DE-79-8 (Octas) BDE-798 90
FR-300BA (Deca) FRS-009N 15 / 10 mg
2,2',4,4'-Tetrabromodiphenyl ether (#47) DE-79 (Octas) Great Lakes Study
2,2',4,4',5-Pentabromodiphenyl ether (#99) BDE-798-GL $ 250 / 1 x 1 mL
100 µg/mL in Toluene FRS-009S 15
2,2',4,4',6-Pentabromodiphenyl ether (#100) 50 µg/mL each in Isooctane
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153)
™ Bromkal is a registered Trade Mark of Chemische Fabrik Kalk
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) Bromkal DE-79

Specific Mixtures

PBDEs Most Common in the PBDEs Common to California California Method 750-M Standard
Environment Environment BDE-CALEWS $ 600 / 1 x 1 mL
BDE-USE $ 250 / 1 x 1 mL 10 µg/mL each in Isooctane 13 comps.
BDE-CAE-1 $ 300 / 1 x 1 mL
10 µg/mL each in Isooctane 5 comps. 10 µg/mL each in Isooctane 7 comps.
2,2',4-Tribromodiphenyl ether (#17)
2,2',4,4'-Tetrabromodiphenyl ether (#47) 2,4,4'-Tribromodiphenyl ether (#28)
2,4,4'-Tribromodiphenyl ether (#28)
2,2',4,4',5-Pentabromodiphenyl ether (#99) 2,2',4,4'-Tetrabromodiphenyl ether (#47)
2',3,4-Tribromodiphenyl ether (#33)
2,2',4,4',6-Pentabromodiphenyl ether (#100) 2,3',4,4'-Tetrabromodiphenyl ether (#66)
2,2',4,4'-Tetrabromodiphenyl ether (#47)
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 2,3',4',6-Tetrabromodiphenyl ether (#71)
2,2',4,4',5-Pentabromodiphenyl ether (#99)
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 2,2',4,4',5-Pentabromodiphenyl ether (#99)
2,2',4,4',6-Pentabromodiphenyl ether (#100)
2,2',4,4',6-Pentabromodiphenyl ether (#100)
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153)
2,2',3,4,4',5'-Hexabromodiphenyl ether (#138)
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154)
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153)
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154)
PBDEs - Columbia River Study PBDEs - Lake Michigan Study 2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183)
BDE-CR $ 550 / 1 x 1 mL BDE-LMS $ 400 / 1 x 1 mL 2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl ether (#209)
10 µg/mL each in Isooctane 12 comps. 10 µg/mL each in isooctane 9 comps. 2,2',6,6'-Tetrabromobisphenol A

4,4'-Dibromodiphenyl ether (#15) 2,4,4'-Tribromodiphenyl ether (#28)

2,4,4'-Tribromodiphenyl ether (#28) 2,2',4,4'-Tetrabromodiphenyl ether (#47) Method 527 - PBDE Standard
2',3,4-Tribromodiphenyl ether (#33) 2,3',4,4'-Tetrabromodiphenyl ether (#66) M-527-BDE $ 250 / 1 x 1 mL
2,2',4,4'-Tetrabromodiphenyl ether (#47) 2,2',3,4,4'-Pentabromodiphenyl ether (#85) 50 µg/mL each in 5 comps.
2,2',4,5'-Tetrabromodiphenyl ether (#49) 2,2',4,4',5-Pentabromodiphenyl ether (#99) Isooctane:Ethyl Acetate (8:2)
2,3',4,4'-Tetrabromodiphenyl ether (#66) 2,2',4,4',6-Pentabromodiphenyl ether (#100)
2,4,4',6-Tetrabromodiphenyl ether (#75) 2,2',3,4,4',5'-Hexabromodiphenyl ether (#138) 2,2',4,4'-Tetrabromodiphenyl ether
2,2',4,4',5-Pentabromodiphenyl ether (#99) 2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 2,2',4,4',6-Pentabromodiphenyl ether
2,2',4,4',6-Pentabromodiphenyl ether (#100) 2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 2,2',4,4',5-Pentabromodiphenyl ether
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 2,2',4,4',5,5'-Hexabromodiphenyl ether
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 2,2',4,4',5,5'-Hexabromobiphenyl
2,2',4,4',6,6'-Hexabromodiphenyl ether (#155)

Calibration Curve Set

ISO/DIS 22032 ISO/DIS 22032
Calibration Curve Set Internal Standard
ISO/DIS-22032-SET $ 475 / 7 x 1 mL BDE-47, 99 & 100
At stated conc. (ng/mL) in Isooctane 8 comps. each ISO22032-IS-1-5ML $ 50 / 1 x 5 mL
ISO22032-IS-1-10ML $ 75 / 1 x 10 mL
ISO/DIS-22032 01 02 03 04 05 06 07 100 ng/mL each in Isooctane
2,2’,4,4’-Tetrabromodiphenyl ether (#47) 5 12.5 25 50 100 150 250
2,2’,4,4’,5-Pentabromodiphenyl ether (#99) 5 12.5 25 50 100 150 250 2,2',4,4'-Tetrabromodiphenyl ether
2,2’,4,4’,6-Pentabromodiphenyl ether (#100) 5 12.5 25 50 100 150 250
2,2’,4,4’,5,5’-Hexabromodiphenyl ether (#153) 5 12.5 25 50 100 150 250
2,2’,4,4’,5,6’-Hexabromodiphenyl ether (#154) 5 12.5 25 50 100 150 250
2,2’,3,4,4’,5’,6-Heptabromodiphenyl ether (#183) 5 12.5 25 50 100 150 250 Internal Standard
2,3,3’,4,4',5,5’,6-Octabromodiphenyl ether (#205) 5 12.5 25 50 100 150 250 BDE-153, 154 & 183
2,2’,3,3’,4,4’,5,5’,6,6’-Decabromodiphenyl ether (#209) 25 50 100 200 500 700 1000 ISO22032-IS-2-5ML $ 50 / 1 x 5 mL
ISO22032-IS-2-10ML $ 75 / 1 x 10 mL
100 ng/mL each in Isooctane

2,2',3,4,4',5,6-Heptabromodiphenyl ether

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 EPA Method 1614
Mixtures of PBDEs Standard Solution for Accuracy & Precision Technical Note
BDE-AAP-A $ 195 / 1 x 1 mL BDE-AAP-A-15X $ 750 / 1 x 1 mL Responding to the need for the analysis
At stated conc. in Isooctane 39 comps. At stated conc. in Isooctane 39 comps. of polybrominated diphenyl ether
ng/mL µg/mL (PBDE) congeners, the EPA has
2-Bromodiphenyl ether (#1) 100 2-Bromodiphenyl ether (#1) 1.5 developed Method 1614. Method 1614
3-Bromodiphenyl ether (#2) 100 3-Bromodiphenyl ether (#2) 1.5 is recommended for analysis of
4-Bromodiphenyl ether (#3) 100 4-Bromodiphenyl ether (#3) 1.5 aqueous, solid, tissue, and multi-phase
2,4-Dibromodiphenyl ether (#7) 100 2,4-Dibromodiphenyl ether (#7) 1.5 environmental samples. Each
2,4'-Dibromodiphenyl ether (#8) 100 2,4'-Dibromodiphenyl ether (#8) 1.5 formulation is prepared using PBDEs
2,6-Dibromodiphenyl ether (#10) 100 2,6-Dibromodiphenyl ether (#10) 1.5 which are synthesized and analyzed by
3,3'-Dibromodiphenyl ether (#11) 100 3,3'-Dibromodiphenyl ether (#11) 1.5 AccuStandard.
3,4-Dibromodiphenyl ether (#12) 100 3,4-Dibromodiphenyl ether (#12) 1.5
3,4'-Dibromodiphenyl ether (#13) 100 3,4'-Dibromodiphenyl ether (#13) 1.5
4,4'-Dibromodiphenyl ether (#15) 100 4,4'-Dibromodiphenyl ether (#15) 1.5
2,2',4,-Tribromodiphenyl ether (#17) 100 2,2',4-Tribromodiphenyl ether (#17) 1.5
2,3',4-Tribromodiphenyl ether (#25) 100 2,3',4-Tribromodiphenyl ether (#25) 1.5
2,4,4'-Tribromodiphenyl ether (#28) 100 2,4,4'-Tribromodiphenyl ether (#28) 1.5
2,4,6-Tribromodiphenyl ether (#30) 100 2,4,6-Tribromodiphenyl ether (#30) 1.5
2,4',6-Tribromodiphenyl ether (#32) 100 2,4',6-Tribromodiphenyl ether (#32) 1.5
2',3,4-Tribromodiphenyl ether (#33) 100 2',3,4-Tribromodiphenyl ether (#33) 1.5
3,3',4-Tribromodiphenyl ether (#35) 100 3,3',4-Tribromodiphenyl ether (#35) 1.5
3,4,4'-Tribromodiphenyl ether (#37) 100 3,4,4'-Tribromodiphenyl ether (#37) 1.5
2,2',4,4'-Tetrabromodiphenyl ether (#47) 100 2,2',4,4'-Tetrabromodiphenyl ether (#47) 1.5
2,2',4,5'-Tetrabromodiphenyl ether (#49) 100 2,2',4,5'-Tetrabromodiphenyl ether (#49) 1.5
2,3',4,4'-Tetrabromodiphenyl ether (#66) 100 2,3',4,4'-Tetrabromodiphenyl ether (#66) 1.5
2,3',4',6-Tetrabromodiphenyl ether (#71) 100 2,3',4',6-Tetrabromodiphenyl ether (#71) 1.5
2,4,4',6-Tetrabromodiphenyl ether (#75) 100 2,4,4',6-Tetrabromodiphenyl ether (#75) 1.5
3,3',4,4'-Tetrabromodiphenyl ether (#77) 100 3,3',4,4'-Tetrabromodiphenyl ether (#77) 1.5
2,2',3,4,4'-Pentabromodiphenyl ether (#85) 150 2,2',3,4,4'-Pentabromodiphenyl ether (#85) 2.25
2,2',4,4',5-Pentabromodiphenyl ether (#99) 150 2,2',4,4',5-Pentabromodiphenyl ether (#99) 2.25
2,2',4,4',6-Pentabromodiphenyl ether (#100) 150 2,2',4,4',6-Pentabromodiphenyl ether (#100) 2.25
2,3,4,5,6-Pentabromodiphenyl ether (#116) 150 2,3,4,5,6-Pentabromodiphenyl ether (#116) 2.25
2,3',4,4',5-Pentabromodiphenyl ether (#118) 150 2,3',4,4',5-Pentabromodiphenyl ether (#118) 2.25
2,3',4,4',6-Pentabromodiphenyl ether (#119) 150 2,3',4,4',6-Pentabromodiphenyl ether (#119) 2.25
3,3',4,4',5-Pentabromodiphenyl ether (#126) 150 3,3',4,4',5-Pentabromodiphenyl ether (#126) 2.25
2,2',3,4,4',5'-Hexabromodiphenyl ether (#138) 200 2,2',3,4,4',5'-Hexabromodiphenyl ether (#138) 3.0
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 200 2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 3.0
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 200 2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 3.0
2,2',4,4',6,6'-Hexabromodiphenyl ether (#155) 200 2,2',4,4',6,6'-Hexabromodiphenyl ether (#155) 3.0
2,3,4,4',5,6-Hexabromodiphenyl ether (#166) 200 2,3,4,4',5,6-Hexabromodiphenyl ether (#166) 3.0
2,2',3,4,4',5,6-Heptabromodiphenyl ether (#181) 250 2,2',3,4,4',5,6-Heptabromodiphenyl ether (#181) 3.75
2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 250 2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 3.75
2,3,3',4,4',5,6-Heptabromodiphenyl ether (#190) 250 2,3,3',4,4',5,6-Heptabromodiphenyl ether (#190) 3.75

Mixture of Commonly Occurring PBDE PBDE Congeners of Primary Interest

Congeners for Precision and Recovery BDE-CSM $ 225 / 1 x 1 mL
At stated conc. in Isooctane 8 comps.
BDE-COC $ 600 / 1 x 1 mL
µg/mL
At stated conc. in Isooctane 14 comps.
2,4,4'-Tribromodiphenyl ether (#28) 20
µg/mL
2,2',4,4'-Tetrabromodiphenyl ether (#47) 20
2,2',4,-Tribromodiphenyl ether (#17) 5
2,2',4,4',5-Pentabromodiphenyl ether (#99) 20
2,4,4'-Tribromodiphenyl ether (#28) 5
2,2',4,4',6-Pentabromodiphenyl ether (#100) 20
2,2',4,4’-Tetrabromodiphenyl ether (#47) 5
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 20
2,3',4,4'-Tetrabromodiphenyl ether (#66) 5
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 20
2,3',4',6-Tetrabromodiphenyl ether (#71) 5
2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 20
2,2',3,4,4'-Pentabromodiphenyl ether (#85) 5
Decabromodiphenyl ether (#209) 200
2,2',4,4',5-Pentabromodiphenyl ether (#99) 5
2,2',4,4',6-Pentabromodiphenyl ether (#100) 5
2,2',3,4,4',5'-Hexabromodiphenyl ether (#138) 5
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 5
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 5
2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 5
2,3,3',4,4',5,6-Heptabromodiphenyl ether (#190) 5
Decabromodiphenyl ether (#209) 25

PBDE Congeners of Primary Interest

Calibration Mix Matrix Spiking Solution PBDEs in Method 1614
BDE-CM $ 65 / 1 x 1 mL BDE-MS $ 40 / 1 x 1 mL BDE-EPA-SET $ 500 / 8 x 1 mL
At stated conc. in Isooctane 8 comps. At stated conc. in Isooctane 8 comps. 50 µg/mL each in Isooctane 8 comps.
µg/mL ng/mL
2,4,4'-Tribromodiphenyl ether (#28) 2.5 2,4,4'-Tribromodiphenyl ether (#28) 1 2,4,4'-Tribromodiphenyl ether (#28)
2,2',4,4'-Tetrabromodiphenyl ether (#47) 2.5 2,2',4,4'-Tetrabromodiphenyl ether (#47) 1 2,2',4,4'-Tetrabromodiphenyl ether (#47)
2,2',4,4',5-Pentabromodiphenyl ether (#99) 2.5 2,2',4,4',5-Pentabromodiphenyl ether (#99) 1 2,2',4,4',5-Pentabromodiphenyl ether (#99)
2,2',4,4',6-Pentabromodiphenyl ether (#100) 2.5 2,2',4,4',6-Pentabromodiphenyl ether (#100) 1 2,2',4,4',6-Pentabromodiphenyl ether (#100)
2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 2.5 2,2',4,4',5,5'-Hexabromodiphenyl ether (#153) 1 2,2',4,4',5,5'-Hexabromodiphenyl ether (#153)
2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 2.5 2,2',4,4',5,6'-Hexabromodiphenyl ether (#154) 1 2,2',4,4',5,6'-Hexabromodiphenyl ether (#154)
2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 2.5 2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183) 1 2,2',3,4,4',5',6-Heptabromodiphenyl ether (#183)
Decabromodiphenyl ether (#209) 25 Decabromodiphenyl ether (#209) 10 Decabromodiphenyl ether (#209)

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 PBDE Metabolites:
Hydroxy & Methoxy Polybromodiphenyl Ether Congeners
Hydroxylated and methoxylated PBDEs may be formed as metabolites of the widely used PBDE flame retardants. AccuStandard’s aim is to
synthesize authentic OH-and MeO-PBDE reference standards for analytical and toxicological studies. Since this is an ongoing project, please check
the website for the latest update of this list or request specific congeners to be synthesized.

Short Form Compound Conc. Solvent Cat. No. (1 mL)

Hydroxy
2'-OH-BDE-003 2'-Hydroxy-4-monobromodiphenyl ether 50 µg/mL AcCN HBDE-1001S-CN
3'-OH-BDE-007 3'-Hydroxy-2,4-dibromodiphenyl ether 50 µg/mL AcCN HBDE-2001S-CN
2'-OH-BDE-007 2'-Hydroxy-2,4-dibromodiphenyl ether 10 µg/mL AcCN HBDE-2002S-CN-0.2X
4'-OH-BDE-017 4'-Hydroxy-2,2',4-tribromodiphenyl ether 50 µg/mL AcCN HBDE-3001S-CN
3'-OH-BDE-028 3'-Hydroxy-2,4,4'-tribromodiphenyl ether 50 µg/mL AcCN HBDE-3002S-CN
2'-OH-BDE-028 2'-Hydroxy-2,4,4'-tribromodiphenyl ether 50 µg/mL AcCN HBDE-3003S-CN
4-OH-BDE-042 4-Hydroxy-2,2',3,4'-tetrabromodiphenyl ether 10 µg/mL AcCN HBDE-4001S-CN-0.2X
4'-OH-BDE-049 4'-Hydroxy-2,2',4,5'-tetrabromodiphenyl ether 10 µg/mL AcCN HBDE-4002S-CN-0.2X
3-OH-BDE-047 3-Hydroxy-2,2',4,4'-tetrabromodiphenyl ether 50 µg/mL AcCN HBDE-4003S-CN
5-OH-BDE-047 5-Hydroxy-2,2',4,4'-tetrabromodiphenyl ether 50 µg/mL AcCN HBDE-4004S-CN
6-OH-BDE-047 6-Hydroxy-2,2',4,4'-tetrabromodiphenyl ether 10 µg/mL AcCN HBDE-4005S-CN-0.2X
10 µg/mL Toluene HBDE-4005S-T-0.2X
2'-OH-BDE-068 2'-Hydroxy-2,3',4,5'-tetrabromodiphenyl ether 10 µg/mL AcCN HBDE-4006S-CN-0.2X
10 µg/mL Toluene HBDE-4006S-T-0.2X
50 µg/mL AcCN HBDE-4006S-CN
50 µg/mL Toluene HBDE-4006S-T
2'-OH-BDE-075 2'-Hydroxy-2,4,4',6-tetrabromodiphenyl ether 10 µg/mL AcCN HBDE-4007S-CN-0.2X
4-OH-BDE-090 4-Hydroxy-2,2',3,4',5-pentabromodiphenyl ether 10 µg/mL AcCN HBDE-5001S-CN-0.2X
6-OH-BDE-085 6-Hydroxy-2,2',3,4,4'-pentabromodiphenyl ether 10 µg/mL AcCN HBDE-5002S-CN-0.2X
6-OH-BDE-087 6-Hydroxy-2,2',3,4,5'-pentabromodiphenyl ether 10 µg/mL AcCN HBDE-5003S-CN-0.2X
6-OH-BDE-082 6-Hydroxy-2,2',3,3',4-pentabromodiphenyl ether 10 µg/mL AcCN HBDE-5005S-CN-0.2X
6'-OH-BDE-099 6'-Hydroxy-2,2',4,4',5-pentabromodiphenyl ether 10 µg/mL AcCN HBDE-5006S-CN-0.2X
5'-OH-BDE-099 5'-Hydroxy-2,2',4,4’,5-pentabromodiphenyl ether 10 µg/mL AcCN HBDE-5007S-CN-0.2X
6-OH-BDE-157 6-Hydroxy-2,3,3',4,4',5'-hexabromodiphenyl ether 10 µg/mL AcCN HBDE-6001S-CN-0.2X
6-OH-BDE-140 6-Hydroxy-2,2',3,4,4',6'-hexabromodiphenyl ether 10 µg/mL AcCN HBDE-6002S-CN-0.2X

4-OH-BDE-187 4-Hydroxy-2,2',3,4',5,5',6-heptabromodiphenyl ether 50 HBDE-7001S

3-OH-BDE-154 3-Hydroxy-2,2',4,4',5',6-hexabromodiphenyl ether 10 µg/mL AcCN HBDE-6003S-CN-0.2X

6-OH-BDE-180 6-Hydroxy-2,2',3,4,4',5,5'-heptabromodiphenyl ether 50 HBDE-7002S

µg/mL AcCN
µg/mL AcCN

Methoxy
2'-MeO-BDE-003 2'-Methoxy-4-monobromodiphenyl ether 50 µg/mL MeOH MOBDE-1001S
3'-MeO-BDE-007 3'-Methoxy-2,4-dibromodiphenyl ether 50 µg/mL MeOH MOBDE-2001S
2'-MeO-BDE-007 2'-Methoxy-2,4-dibromodiphenyl ether 10 µg/mL MeOH MOBDE-2002S-0.2X
4'-MeO-BDE-017 4'-Methoxy-2,2',4-tribromodiphenyl ether 50 µg/mL MeOH MOBDE-3001S
3'-MeO-BDE-028 3'-Methoxy-2,4,4'-tribromodiphenyl ether 50 µg/mL MeOH MOBDE-3002S
2'-MeO-BDE-028 2'-Methoxy-2,4,4'-tribromodiphenyl ether 50 µg/mL MeOH MOBDE-3003S
4-MeO-BDE-042 4-Methoxy-2,2',3,4'-tetrabromodiphenyl ether 10 µg/mL MeOH MOBDE-4001S-0.2X
4'-MeO-BDE-049 4'-Methoxy-2,2',4,5'-tetrabromodiphenyl ether 10 µg/mL MeOH MOBDE-4002S-0.2X
3-MeO-BDE-047 3-Methoxy-2,2',4,4'-tetrabromodiphenyl ether 50 µg/mL MeOH MOBDE-4003S
5-MeO-BDE-047 5-Methoxy-2,2',4,4'-tetrabromodiphenyl ether 50 µg/mL MeOH MOBDE-4004S
6-MeO-BDE-047 6-Methoxy-2,2',4,4'-tetrabromodiphenyl ether 10 µg/mL MeOH MOBDE-4005S-0.2X
2'-MeO-BDE-068 2'-Methoxy-2,3',4,5'-tetrabromodiphenyl ether 10 µg/mL MeOH MOBDE-4006S-0.2X
2'-MeO-BDE-075 2'-Methoxy-2,4,4',6-tetrabromodiphenyl ether 50 µg/mL MeOH MOBDE-4007S
4-MeO-BDE-090 4-Methoxy-2,2',3,4',5-pentabromodiphenyl ether 10 µg/mL MeOH MOBDE-5001S-0.2X
6-MeO-BDE-085 6-Methoxy-2,2',3,4,4'-pentabromodiphenyl ether 10 µg/mL MeOH MOBDE-5002S-0.2X
6-MeO-BDE-087 6-Methoxy-2,2',3,4,5'-pentabromodiphenyl ether 10 µg/mL MeOH MOBDE-5003S-0.2X
6-MeO-BDE-082 6-Methoxy-2,2',3,3',4-pentabromodiphenyl ether 10 µg/mL MeOH MOBDE-5005S-0.2X
6'-MeO-BDE-099 6'-Methoxy-2,2',4,4',5-pentabromodiphenyl ether 10 µg/mL MeOH MOBDE-5006S-0.2X
5'-MeO-BDE-099 5'-Methoxy-2,2',4,4',5-pentabromodiphenyl ether 10 µg/mL MeOH MOBDE-5007S-0.2X
3-MeO-BDE-100 3-Methoxy-2,2',4,4',6-pentabromodiphenyl ether 50 µg/mL MeOH MOBDE-5008S
6-MeO-BDE-157 6-Methoxy-2,3,3',4,4',5'-hexabromodiphenyl ether 10 µg/mL MeOH MOBDE-6001S-0.2X
6-MeO-BDE-140 6-Methoxy-2,2',3,4,4',6'-hexabromodiphenyl ether 10 µg/mL MeOH MOBDE-6002S-0.2X

4-MeO-BDE-187 4-Methoxy-2,2',3,4',5,5',6-heptabromodiphenyl ether 50 MOBDE-7001S

3-MeO-BDE-154 3-Methoxy-2,2',4,4',5',6-hexabromodiphenyl ether 10 µg/mL MeOH MOBDE-6003S-0.2X

6-MeO-BDE-180 6-Methoxy-2,2',3,4,4',5,5'-heptabromodiphenyl ether 50 MOBDE-7002S

µg/mL MeOH

4-MeO-BDE-188 4-Methoxy-2,2',3,4',5,6,6'-heptabromodiphenyl ether 50 MOBDE-7003S

µg/mL MeOH

4'-Methoxy-2,2',3,3',4,5',6,6'-heptabromodiphenyl ether 50 MOBDE-8001S

µg/mL MeOH
4'-MeO-BDE-201 µg/mL MeOH

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 Fluorinated PBDE

Some research suggests that a fluorine substitution of the PBDE parent compound could be used as an internal standard for PBDE analysis,
replacing the more costly 13C labeled PBDEs currently used. In addition, FBDEs can be used for ECD (Electron Capture Detection) analysis
where the more expensive 13C labeled PBDEs cannot. Experimental testing also suggests that the use of FBDEs as internal standards show
improved precision in PBDE analysis. AccuStandard has synthesized the following FBDEs for use as internal standards and has committed to
adding to this list based on requests from analytical chemists:

Short Form Compound Conc. Solvent Cat. No. (1 mL)

F-BDE-007 3'-Fluoro-2,4-dibromodiphenyl ether 25 µg/mL Isooctane FBDE-2001S-0.5X
50 µg/mL Isooctane FBDE-2001S
F-BDE-012 3'-Fluoro-3,4-dibromodiphenyl ether 25 µg/mL Isooctane FBDE-2002S-0.5X
50 µg/mL Isooctane FBDE-2002S
F-BDE-025 4'-Fluoro-2,3',4-tribromodiphenyl ether 25 µg/mL Isooctane FBDE-3001S-0.5X
50 µg/mL Isooctane FBDE-3001S
F-BDE-027 4'-Fluoro-2,3',6-tribromodiphenyl ether 25 µg/mL Isooctane FBDE-3002S-0.5X
50 µg/mL Isooctane FBDE-3002S
F-BDE-028 2'-Fluoro-2,4,4'-tribromodiphenyl ether 25 µg/mL Isooctane FBDE-3003S-0.5X
50 µg/mL Isooctane FBDE-3003S
F-BDE-028 3'-Fluoro-2,4,4'-tribromodiphenyl ether 25 µg/mL Isooctane FBDE-3004S-0.5X
50 µg/mL Isooctane FBDE-3004S
F-BDE-069 4'-Fluoro-2,3',4,6-tetrabromodiphenyl ether 25 µg/mL Isooctane FBDE-4001S-0.5X
50 µg/mL Isooctane FBDE-4001S
F-BDE-067 4'-Fluoro-2,3',4,5-tetrabromodiphenyl ether 25 µg/mL Isooctane FBDE-4002S-0.5X
50 µg/mL Isooctane FBDE-4002S
F-BDE-047 6-Fluoro-2,2',4,4'-tetrabromodiphenyl ether 25 µg/mL Isooctane FBDE-4003S-0.5X
50 µg/mL Isooctane FBDE-4003S
F-BDE-066 6-Fluoro-2,3',4,4'-tetrabromodiphenyl ether 25 µg/mL Isooctane FBDE-4004S-0.5X
50 µg/mL Isooctane FBDE-4004S
2F-BDE-047 5,5'-Difluoro-2,2',4,4'-tetrabromodiphenyl ether 25 µg/mL Isooctane FBDE-4005S-0.5X
50 µg/mL Isooctane FBDE-4005S
F-BDE-100 3-Fluoro-2,2',4,4',6-pentabromodiphenyl ether 25 µg/mL Isooctane FBDE-5002S-0.5X
50 µg/mL Isooctane FBDE-5002S
2F-BDE-099 3,6-Difluoro-2,2',4,4',5-pentabromodiphenyl ether 25 µg/mL Isooctane FBDE-5003S-0.5X
50 µg/mL Isooctane FBDE-5003S
2F-BDE-085 5,6-Difluoro-2,2',3,4,4'-pentabromodiphenyl ether 25 µg/mL Isooctane FBDE-5004S-0.5X
50 µg/mL Isooctane FBDE-5004S
2F-BDE-119 3,5-Difluoro-2,3',4,4',6-pentabromodiphenyl ether 25 µg/mL Isooctane FBDE-5005S-0.5X
50 µg/mL Isooctane FBDE-5005S
F-BDE-160 4'-Fluoro-2,3,3',4,5,6-hexabromodiphenyl ether 25 µg/mL Isooctane FBDE-6001S-0.5X
50 µg/mL Isooctane FBDE-6001S
F-BDE-139 3-Fluoro-2,2',4,4',5,6-hexabromodiphenyl ether 25 µg/mL Isooctane FBDE-6002S-0.5X
50 µg/mL Isooctane FBDE-6002S
2F-BDE-201 4',6-Difluoro-2,2',3,3',4,5,5',6'-octabromodiphenyl ether 25 µg/mL Isooctane FBDE-8001S-0.5X
50 µg/mL Isooctane FBDE-8001S
F-BDE-208 4'-Fluoro-2,2',3,3',4,5,5',6,6'-nonabromodiphenyl ether 25 µg/mL Isooctane FBDE-9001S-0.5X
50 µg/mL Isooctane FBDE-9001S

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 HBCD Isomers, Bromobiphenyls, Bromophenols and -anisoles
Hexabromocyclododecane (HBCD) Isomers
Price /
Compound CAS No. Conc. Matrix Cat. No. (1 mL)
α-Hexabromocyclododecane 100 µg/mL Toluene HXBCD-01
β-Hexabromocyclododecane 100 µg/mL Toluene HXBCD-02
γ-Hexabromocyclododecane 100 µg/mL Toluene HXBCD-03

Bromobiphenyl Congeners
Compound CAS No. Conc. Matrix Cat. No. (1 mL)
2-Bromobiphenyl 2052-07-5 50 mg NEAT B-001N
35 µg/mL Isooctane B-001S
1 mg/mL Acetone M-8081-SS-X
3-Bromobiphenyl 2113-57-7 50 mg NEAT B-002N
35 µg/mL Isooctane B-002S
4-Bromobiphenyl 92-66-0 50 mg NEAT B-003N
35 µg/mL Isooctane B-003S
2,2'-Dibromobiphenyl 13029-09-9 10 mg NEAT B-004N
35 µg/mL Isooctane B-004S
2,4-Dibromobiphenyl 53592-10-2 25 mg NEAT B-007N-10MG
35 µg/mL Isooctane B-007S
2,5-Dibromobiphenyl 57422-77-2 25 mg NEAT B-009N
35 µg/mL Isooctane B-009S
2,6-Dibromobiphenyl 59080-32-9 5 mg NEAT B-010N-5MG
35 µg/mL Isooctane B-010S
4,4'-Dibromobiphenyl 92-86-4 10 mg NEAT B-015N
35 µg/mL Isooctane B-015S
2,2',5-Tribromobiphenyl 59080-34-1 10 mg NEAT B-018N
35 µg/mL Isooctane B-018S
2,3',5-Tribromobiphenyl 59080-35-2 10 mg NEAT B-026N
35 µg/mL Isooctane B-026S
2,4,5-Tribromobiphenyl 115245-07-3 35 µg/mL Isooctane B-029S
2,4,6-Tribromobiphenyl 59080-33-0 25 mg NEAT B-030N
35 µg/mL Isooctane B-030S
2,4',5-Tribromobiphenyl 59080-35-3 10 mg NEAT B-031N
35 µg/mL Isooctane B-031S
2,2',4,5'-Tetrabromobiphenyl 60044-24-8 5 mg NEAT B-049N-5MG
35 µg/mL Isooctane B-049S
2,2',5,5'-Tetrabromobiphenyl 59080-37-4 10 mg NEAT B-052N
35 µg/mL Isooctane B-052S
2,2',5,6'-Tetrabromobiphenyl 60044-25-9 5 mg NEAT B-053N-5MG
35 µg/mL Isooctane B-053S
3,3',4,4'-Tetrabromobiphenyl 77102-82-0 35 µg/mL Isooctane B-077S
3,3',5,5'-Tetrabromobiphenyl 16400-50-3 35 µg/mL Isooctane B-080S
2,2',4,5,5'-Pentabromobiphenyl 67888-96-4 5 mg NEAT B-101N
35 µg/mL Isooctane B-101S
2,2',4,5',6-Pentabromobiphenyl 59080-39-6 5 mg NEAT B-103N
35 µg/mL Isooctane B-103S
2,2',4,4',5,5'-Hexabromobiphenyl 59080-40-9 35 µg/mL Isooctane B-153S
2,2',4,4',6,6'-Hexabromobiphenyl 59261-08-4 5 mg NEAT B-155N
35 µg/mL Isooctane B-155S
3,3',4,4',5,5'-Hexabromobiphenyl 77607-09-1 35 µg/mL Isooctane B-169S
2,2',3,3',4,5',6,6'-Octabromobiphenyl 69887-11-2 35 µg/mL Isooctane B-200S
Decabromobiphenyl 13654-09-6 25 mg NEAT B-209N
35 µg/mL Isooctane B-209S

Bromophenols Bromoanisoles (Bromophenyl methyl ether)

Each at 100 µg/mL in Toluene Each at 50 µg/mL in Methanol

Compound CAS No. Cat. No. (1 mL) Compound CAS No. Cat. No. (1 mL)
3-Bromophenol BP-003S 2-Bromoanisole 578-57-4 BAN-01
4-Bromophenol BP-004S 3-Bromoanisole 2398-37-0 BAN-02
2,3-Dibromophenol 57383-80-9 BP-023S 4-Bromoanisole 104-92-7 BAN-03
2,4-Dibromophenol BP-024S 2,3-Dibromoanisole BAN-04
2,5-Dibromophenol 28165-52-8 BP-025S 2,4-Dibromoanisole 21702-84-1 BAN-05
2,6-Dibromophenol BP-026S 2,5-Dibromoanisole BAN-06
3,5-Dibromophenol 626-41-5 BP-035S 2,6-Dibromoanisole BAN-07
2,3,4-Tribromophenol BP-234S 3,5-Dibromoanisole 74137-36-3 BAN-08
2,4,5-Tribromophenol BP-245S 2,4,5-Tribromoanisole BAN-09
2,4,6-Tribromophenol BP-246S 2,4,6-Tribromoanisole 607-99-8 BAN-10
3,4,5-Tribromophenol BP-345S
2,3,4,5-Tetrabromophenol BP-2345S
2,3,4,6-Tetrabromophenol BP-2346S
2,3,5,6-Tetrabromophenol BP-2356S
Pentabromophenol 608-71-9 BP-23456S

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 Industrial Flame Retardants
Bromine Containing Industrial Flame Retardants
Compound CAS No. Active Ingredient Conc. Matrix Cat. No. (1 mL)
Bromkal™ DE-70-5 (Tech grade) Penta BDEs 50 µg/mL Isooctane BDE-705
Bromkal DE-71 (Tech grade) Penta BDEs 50 µg/mL Isooctane BDE-710
Bromkal DE-73-6 (Tech grade) Hexa BDEs 50 µg/mL Isooctane BDE-736
Bromkal DE-79-8 (Tech grade) Octa BDEs 50 µg/mL Isooctane BDE-798
Dow FR-250 27858-07-7 Octabromobiphenyl 100 µg/mL Isooctane B-250S
35 µg/mL Isooctane B-250S-0.35X
Firemaster BP4A
™
79-94-7 Tetrabromobisphenol A 10 mg NEAT FRS-006N
100 µg/mL Toluene FRS-006S
Firemaster BP-6 59536-65-1 Hexabromobiphenyl 10 mg NEAT B-600N
35 µg/mL Isooctane B-600S-0.35X
100 µg/mL Isooctane B-600S
Firemaster PHT4 632-79-1 Tetrabromophthalic anhydride 10 mg NEAT FRS-007N
100 µg/mL Toluene FRS-007S
Firemaster T23P Tris(2,3-dibromopropyl)phosphate 10 mg NEAT FRS-008N
100 µg/mL Toluene FRS-008S
Firemaster 680 (Tech grade) 37853-59-1 1,2-Bis(2,4,6-tribromophenoxyl)ethane 50 mg NEAT FRS-037N
100 µg/mL Toluene FRS-037S
Firemaster 2100 (Tech grade) Decabromodiphenylethane 50 mg NEAT FRS-036N
FR-300BA (Deca) 1163-19-5 Decabromodiphenyl ether 85.5% 10 mg NEAT FRS-009N
100 µg/mL Toluene FRS-009S
FR-651A 87-84-3 Pentabromochlorocyclohexane 10 mg NEAT FRS-010N
100 µg/mL Toluene FRS-010S
FR-1138 3296-90-0 Dibromoneopentyl glycol 85.0% 10 mg NEAT FRS-011N
100 µg/mL Toluene FRS-011S
HBCD SP-75C (Great Lakes) 3194-55-6-GL 1,2,5,6,9,10-Hexabromocyclododecane 10 mg NEAT FRS-028N
100 µg/mL Toluene FRS-028S
HCDBCO 51939-55-1 Hexachlorocyclopantadienyl-dibromocyclooctane 10 mg NEAT FRS-039N
100 µg/mL Toluene FRS-039S
Hexabromobenzene (Michigan Chemical) 87-82-1 Hexabromobenzene 10 mg NEAT FRS-012N
100 µg/mL Toluene FRS-012S
Hexabromobenzene (White Chemical) 87-82-1 Hexabromobenzene 10 mg NEAT FRS-013N
100 µg/mL Toluene FRS-013S
Pentabromobenzylacrylate (Tech) 59447-55-1 Pentabromobenzylacrylate 10 mg NEAT FRS-035N
100 µg/mL Toluene FRS-035S
Pentabromobenzylbromide (Tech) 1163-19-5 Pentabromobenzylbromide 10 mg NEAT FRS-030N
100 µg/mL Toluene FRS-030S
Pentabromotoluene 87-83-2 Pentabromotoluene 10 mg NEAT FRS-018N
100 µg/mL Toluene FRS-018S
TBECH 3322-93-8 1,2-Dibromo-4-(1,2-dibromoethyl)cyclohexane 10 mg NEAT FRS-038N
100 mg/mL MeOH FRS-038S
Tetrabromobisphenol A bis(hydroxyethyl ether) (Tech) Tetrabromobisphenol A bis(hydroxyethyl ether) 50 mg NEAT FRS-032N
4162-45-2 100 µg/mL Toluene FRS-032S
Tetrabromo-o-chlorotoluene Tetrabromo-o-chlorotoluene 10 mg NEAT FRS-021N
100 µg/mL Toluene FRS-021S
TP-69 Tris(2,3-dibromopropyl)phosphate 10 mg NEAT FRS-023N
100 µg/mL Toluene FRS-023S15

Other Industrial Flame Retardants

Compound CAS No. Active Ingredient Conc. Matrix Cat. No. (1 mL)
Chlorafin™ 40 63449-39-8 Chlorinated Paraffin 10 mg NEAT FRS-002N
100 µg/mL Toluene FRS-002S
Chlorendic anhydride 115-27-5 Chlorendic anhydride 10 mg NEAT FRS-001N
100 µg/mL Toluene FRS-001S
Bis(2-Chloroethyl)ether 111-44-4 Bis(2-Chloroethyl)ether 100 µg/mL MeOH APP-9-027
5 mg/mL MeOH AS-E0016
4-Chlorophenyl phenyl ether 7005-72-3 4-Chlorophenyl phenyl ether 100 µg/mL MeOH APP-9-047
5 mg/mL MeOH AS-E0038
Chlorowax 500C™
63449-39-8 Chlorinated Hydrocarbons 59.0% 10 mg NEAT FRS-004N
100 µg/mL Toluene FRS-004S
Diable 700X Chlorinated Hydrocarbons 70.0% 10 mg NEAT FRS-005N
100 µg/mL Toluene FRS-005S
Hexachlorobutadiene 87-68-3 Hexachlorobutadiene 10 mg NEAT FRS-017N
100 µg/mL Toluene FRS-017S
Paroil 179-HV
™
63449-39-8 Chlorinated Paraffin 10 mg NEAT FRS-015N
100 µg/mL Toluene FRS-015S
Paroil 170-8 63449-39-8 Chlorinated Paraffin 10 mg NEAT FRS-016N
100 µg/mL Toluene FRS-016S
Phosgard C 22-R
™
4351-70-6 Halogenated organic phosphate ester 10 mg NEAT FRS-019N
100 µg/mL Toluene FRS-019S
Phosgard 2XC-20 Halogenated organic phosphate ester 10 mg NEAT FRS-020N
100 µg/mL Toluene FRS-020S
Tetrachlorobisphenol A 79-95-8 Tetrachlorobisphenol A 10 mg NEAT FRS-022N
100 µg/mL Toluene FRS-022S
Unichlor 40-90
™
63449-39-8 Chlorinated Hydrocarbons 38.5% 10 mg NEAT FRS-024N
100 µg/mL Toluene FRS-024S
Unichlor 502-50 63449-39-8 Chlorinated Hydrocarbons 52.0% 10 mg NEAT FRS-025N
100 µg/mL Toluene FRS-025S
Unichlor 70AX 63449-39-8 Chlorinated Hydrocarbons 70.0% 10 mg NEAT FRS-026N
100 µg/mL Toluene FRS-026S

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