EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name

AdSint® PA12 natur

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Laser sintering
Coatings
Composites
Uses advised against
No data available.

1.3 Details of the supplier of the safety data sheet

Address
Advanc3d Materials GmbH
Brandstwiete 1
20457 Hamburg
Telephone no. +49 (0) 40 30 3933 11
Fax no. +49 (0) 40 303933 13
Advice on Safety Data Sheet
[email protected]

1.4 Emergency telephone number

For medical advice (in German and English):
+49 (0)551 192 40 (Giftinformationszentrum Nord)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification information
This product does not meet the classification and labelling criteria given in the Regulation (EC) No 1272/2008 (CLP).

2.2 Label elements

Not relevant

2.3 Other hazards

No data available.

SECTION 3: Composition/information on ingredients

3.1 Substances
Not applicable. The product is not a substance.

3.2 Mixtures
Chemical characterization
Polyamide 12, contains additives
Hazardous ingredients
This product does not contain substances to be mentioned according to EU Regulation No 1907/2006 (REACH),
annex II.

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EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

SECTION 4: First aid measures

4.1 Description of first aid measures
General information
In case of persisting adverse effects, consult a physician. Remove contaminated clothing and shoes and launder
thoroughly before reusing.
After inhalation
Remove affected person from the immediate area. Ensure supply of fresh air.
After skin contact
Wash off immediately with soap and water.
After eye contact
Remove contact lenses. Rinse eye thoroughly under running water keeping eyelids wide open and protecting the
unaffected eye (at least 10 to 15 minutes). Seek medical assistance.
After ingestion
Do not induce vomiting. Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person.
Call a doctor.

4.2 Most important symptoms and effects, both acute and delayed
No data available.

4.3 Indication of any immediate medical attention and special treatment needed
No data available.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media
Water spray jet
Unsuitable extinguishing media
High power water jet

5.2 Special hazards arising from the substance or mixture

In the event of fire, the following can be released: Carbon monoxide (CO); Carbon dioxide (CO2); Ammonia (NH3);
Hydrogen cyanide (HCN); Toxic gases/vapours

5.3 Advice for firefighters

Fire-fighting operations, rescue and clearing work under effect of combustion and smoulder gases just may be done
with breathing apparatus. Wear protective clothing.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Avoid contact with skin, eyes and clothing. Ensure adequate
ventilation. Keep away sources of ignition.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.

6.2 Environmental precautions

Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil.

6.3 Methods and material for containment and cleaning up

Take up mechanically. Send in suitable containers for recovery or disposal.

6.4 Reference to other sections

No data available.

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EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
Provide good ventilation of working area (local exhaust ventilation, if necessary). Avoid contact with skin and eyes.
Handle with care - avoid bumps, friction and impact.
General protective and hygiene measures
Do not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Avoid contact with eyes and
skin. Remove soiled or soaked clothing immediately. Do not inhale dust. Wash hands before breaks and after work.
Provide eye wash fountain in work area.
Advice on protection against fire and explosion
Keep away from sources of heat and ignition. Avoid formation of dust. Take precautionary measures against static
charges.
Dust explosion class
St2

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions
Keep container tightly closed and dry in a cool, well-ventilated place.
Recommended storage temperature
Value < 60 °C
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers
of same material as the original one.

7.3 Specific end use(s)

No data available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limit values
No Substance name CAS no. EC no.
1 DUST
List of approved workplace exposure limits (WELs) / EH40
total inhalable dust
TWA 10 mg/m³
List of approved workplace exposure limits (WELs) / EH40
respirable dust
true
TWA 4 mg/m³

8.2 Exposure controls

Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In
case of dust formation, take appropriate measures for breathing protection in the event workplace threshold values
are not specified. Particle filter P2
Eye / face protection
Safety glasses (EN 166)

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EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

Hand protection
In case of intensive contact, wear protective gloves (EN 374). Sufficient protection is given wearing suitable protective
gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the
protective gloves should be tested in any case for its specific work-station suitability (i.e. mechanical resistance,
product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to
the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when
physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Appropriate Material nitrile rubber
Other
Normal chemical work clothing. Antistatic shoes
Environmental exposure controls
No data available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Form/Colour
Powder
20
white
20

Odour
No data available
Odour threshold
No data available
pH value
Value > 4
Remarks
3
Suspension in water 4

Boiling point / boiling range

Remarks Decomposes below boiling point.
Melting point / melting range
Value 160
160 - 200 °C 200

Decomposition point / decomposition range

Value 370 °C 370

Flash point
No data available
Auto-ignition temperature
Value
3
> 400 °C 400

Oxidising properties
No data available
Explosive properties
No data available
Flammability (solid, gas)
No data available
Lower flammability or explosive limits
Value 30-60 g/m³
Reference substance
30- 60
Dust-air mixture 33

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EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

Upper flammability or explosive limits

No data available
Vapour pressure
No data available
Vapour density
No data available
Evaporation rate
No data available
Relative density
No data available
Density
Value 1.020 - 1.150 kg/m³
Reference temperature
1.020
20 °C 1.150

Bulk density
Value 200 - 500 kg/m³
Reference temperature
200
20 °C 500

Solubility in water
Remarks insoluble
Solubility(ies)
No data available
Partition coefficient: n-octanol/water
No data available
Viscosity
No data available

9.2 Other information

Other information
No data available.

SECTION 10: Stability and reactivity

10.1 Reactivity
No data available.

10.2 Chemical stability

Stable under recommended storage and handling conditions (See section 7).

10.3 Possibility of hazardous reactions

danger of dust explosion

10.4 Conditions to avoid

Temperatures > 60°C; Protect from humid air and water. Heat, naked flames and other ignition sources.

10.5 Incompatible materials

No data available.

10.6 Hazardous decomposition products

Ammonia (NH3); Toxic gases/vapours; Hydrogen cyanide (HCN)

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EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute oral toxicity
No data available
Acute dermal toxicity
No data available
Acute inhalational toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Reproduction toxicity
No data available
Carcinogenicity
No data available
STOT-single exposure
No data available
STOT-repeated exposure
No data available
Aspiration hazard
No data available
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact may cause mechanical irritation through dust particles. Eye contact may cause mechanical irritation
Skin contact
may c ause
through dust particles.
mechanical
irritation
through dust
particl es.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
913
Repeated and prolonged exposure to high dust concentrations may lead to irritation of the respiratory tract.

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EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

SECTION 12: Ecological information

12.1 Toxicity
Toxicity to fish (acute)
No data available
Toxicity to fish (chronic)
No data available
Toxicity to Daphnia (acute)
No data available
Toxicity to Daphnia (chronic)
No data available
Toxicity to algae (acute)
No data available
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No data available

12.2 Persistence and degradability

Biodegradability
No Product Name
1 AdSint® PA12 natur
Evaluation not degradable

12.3 Bioaccumulative potential

No data available.

12.4 Mobility in soil

No data available.

12.5 Results of PBT and vPvB assessment

No data available.

12.6 Other adverse effects

No data available.

12.7 Other information

Other information
710
Do not discharge product unmonitored into the environment.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement
with the regional waste disposal company.
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the
regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified
by the regional disposer.

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EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

SECTION 14: Transport information

14.1 Transport ADR/RID/ADN
The product is not subject to ADR/RID/ADN regulations.

14.2 Transport IMDG

The product is not subject to IMDG regulations.

14.3 Transport ICAO-TI / IATA

The product is not subject to ICAO-TI / IATA regulations.

14.4 Other information

No data available.

14.5 Environmental hazards

Information on environmental hazards, if relevant, please see 14.1 - 14.3.

14.6 Special precautions for user

No data available.

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not relevant

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations

Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any
substances considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC)
1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain
substances that are considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject
to Authorisation) as laid down in Article 57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON
THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, PREPARATIONS AND ARTICLES
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any
substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances
This product is not subject to Part 1 or 2 of Annex I.

15.2 Chemical safety assessment

For this mixture a chemical safety assessment has not been carried out.

SECTION 16: Other information

Sources of key data used to compile the data sheet:
Regulation (EC) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case.
EC Directives 2000/39/EC, 2006/15/EC, 2009/161/EU
National Threshold Limit Values of the corresponding countries as amended in each case.
Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.
The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the corresponding
chapter.
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 , D-21107 Hamburg
Tel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: [email protected]

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EC safety data sheet

Trade name: AdSint® PA12 natur

Current version : 1.0.0, issued: 09.09.2015 Replaced version: -, issued: - Region: GB

This information is based on our present state of knowledge and experience.

The security data sheet describes products with a view to the security requirements.
However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid
relationship.

Document protected by copyright. Alterations or reproductions require the express written permission of UMCO
.
Umwelt Consult GmbH.

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