Calcium Hypochlorite Hydrated Mixture Msds
Calcium Hypochlorite Hydrated Mixture Msds
Calcium Hypochlorite Hydrated Mixture Msds
2. HAZARD IDENTIFICATION
Pictograms
Dangerous Goods Classification Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods
by Road & Rail (ADG Code)
Environmental Protection Authority (New Zealand)
Hazardous Substances and New Organisms Amendment Act 2015
HSNO Classifications Physical 5.1.1B Oxidising substances that are liquids or solids: medium hazard
Hazards
Health 6.1D Substances that are acutely toxic - Harmful
Hazards
8.1A Substances that are corrosive to metals
8.2C Substances that are corrosive to dermal tissue UN PGIII
8.3A Substances that are corrosive to ocular tissue
Environmental 9.1A Substances that are very ecotoxic in the aquatic environment
Hazards
9.2A Substances that are very ecotoxic in the soil environment
9.3C Substances that are harmful to terrestrial vertebrates
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Chemical Entity Formula CAS Number Proportion
Available Chlorine (as Calcium hypochlorite) Ca(ClO)2 7778-54-3 >=65 %
Sodium chloride NaCl 7647-14-5 <=20 %
Calcium hydroxide Ca(OH)2 1305-62-0 <=6 %
Water H2O 7732-18-5 5.5 - 10 %
Calcium chloride CaCl2 10043-52-4 <=4 %
Calcium carbonate CaCO3 471-34-1 <=1 %
General Measures If safe to do so, move undamaged containers from fire area. Do not move cargo if cargo has been exposed to heat.
Cool containers with flooding quantities of water until well after fire is out - If impossible, withdraw from area and let
fire burn. Avoid getting water inside containers: a violent reaction may occur. Dam fire control water for later disposal.
ALWAYS stay away from tank ends.
Flammability Conditions OXIDISING SUBSTANCE: Non-combustible; however, will accelerate burning when involved in a fire.
Extinguishing Media Use flooding quantities of water for extinction - Do not use dry chemicals, Carbon dioxide (CO2) or foam. Large fire:
Flood fire area with water from a protected position.
Fire and Explosion Hazard Risk of violent reaction or explosion: May explode from heating, shock, friction or contamination. May ignite
combustibles. Containers may explode when heated. Runoff may create fire or explosion hazard.
- Chlorite salts may react dangerously with hydrocarbons (fuels), organic matter, other contaminants or when hot,
molten and confined; and in this condition, should be treated as an explosive.
Hazardous Products of Fire may produce irritating, toxic, and/or corrosive gases, including Carbon oxides, halogenated compounds, metal
Combustion oxides.
Special Fire Fighting Contain runoff from fire control or dilution water - Runoff may pollute waterways; Runoff may create fire or explosion
Instructions hazard.
Personal Protective Equipment Liquid-tight chemical protective clothing (splash suit) in combination with self-contained breathing apparatus (SCBA)
should be used. Structural firefighter’s uniform will provide limited protection.
Flash Point No Data Available
Lower Explosion Limit No Data Available
Upper Explosion Limit No Data Available
Auto Ignition Temperature No Data Available
Hazchem Code 1W
General Response Procedure Ensure adequate ventilation. ELIMINATE all ignition sources. Prevent exposure to heat. Do not contaminate - Keep
combustibles away from spilled material. Clean up all spills immediately. Avoid dust formation. Do not breathe dust
and prevent contact with eyes, skin and clothing.
Clean Up Procedures Use clean, non-sparking tools to transfer material to a clean, dry container for disposal and cover loosely (see
SECTION 13). Do not seal disposal containers tightly. Move container from spill area.
Containment Stop leak if safe to do so - Prevent entry into waterways, drains or confined areas. Prevent dust cloud.
Decontamination All water utilised to assist in fume suppression, decontamination or fire suppression may be contaminated and must
be contained before disposal and/or treatment. Monitor all exit water for available chlorine and pH.
Environmental Precautionary Spillages and decontamination runoff should be prevented from entering drains and watercourses. Advise local
Measures authorities of any contaminated water release.
Evacuation Criteria Spill or leak area should be isolated immediately. Keep unauthorised personnel away. Keep upwind and to higher
ground. Large spill: Immediately contact Police or Fire Brigade; Consider downwind evacuation.
Personal Precautionary Do not touch damaged containers or spilled material unless wearing appropriate protective clothing (see SECTION 8).
Measures Large spill: Wear self-contained breathing apparatus (SCBA) and chemical splash suit. Structural firefighter’s uniform
will provide limited protection.
Handling Safety showers and eyewash facilities should be provided within the immediate work area for emergency use. Ensure
adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Keep exposure to this
product to a minimum, and minimise the quantities kept in work areas. Avoid dust formation. Do not breathe dust
and prevent contact with eyes, skin and clothing. Do not ingest. Wear protective gloves/protective clothing/eye
protection/face protection (see SECTION 8). OXIDISING MATERIAL: Keep away from heat and all sources of ignition -
No smoking. Do not contaminate - Take any precaution to avoid mixing with combustibles. Do not mix with or allow
product to come into contact with any other chemicals, including different types of chlorinating chemicals. Do not
add water to product - Always add product to large quantities of water to fully dissolve (but in case of fire, drench
with water). Use clean, spark-proof tools and explosion-proof equipment. Avoid release to the environment - Collect
spillage (see SECTION 6).
Storage Store in a cool, dry and well-ventilated place, out of direct sunlight. Keep container tightly closed. Protect containers
from physical damage. Check containers regularly for corrosion or leaks. Protect from moisture/humidity - Do not
allow to get damp. If product becomes contaminated or decomposes, do NOT reseal container. Keep away from
heat and all sources of ignition - No smoking. Keep/store away from combustible and other incompatible materials
(see SECTION 10). Store locked up.
- Prolonged storage at elevated temperatures will significantly shorten the shelf life, and may result in rapid
decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products.
Container Keep in the original container. Empty containers retain product residue and can be hazardous. Do not reuse
container.
General Information Highly reactive oxidising chlorine compound; May cause fire or explosion. Gradually decomposes to produce chlorine
gas. Contact with acids liberates toxic (chlorine) gas.
Chemical Stability Stable at room temperature in closed container under normal storage and handling conditions.
Conditions to Avoid Avoid dust formation. Keep away from heat and all sources of ignition. Do not contaminate. Protect from
moisture/humidity.
Materials to Avoid Incompatible/reactive with other pool treatment products, acids, organics, nitrogen-containing compounds, dry
powder fire extinguishers (containing mono-ammonium phosphate), oxidisers, corrosive, flammable or combustible
materials.
Hazardous Decomposition Fire/decomposition may produce irritating, toxic, and/or corrosive gases, including Carbon oxides, halogenated
Products compounds, metal oxides, Chlorine gas.
Hazardous Polymerisation This product will not undergo polymerisation reactions.
General Information If recycling or reclamation is not possible, dispose of (contents/container) via a commercial waste disposal service
and in accordance with local/regional/national regulations.
Special Precautions for Land Fill No information available.
Proper Shipping Name CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16%
water
Class 5.1 Oxidising Substances
Subsidiary Risk(s) No Data Available
EPG 31 Oxidizing Substances
UN Number 2880
Hazchem 1W
Pack Group II
Special Provision No Data Available
Proper Shipping Name CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16%
water
Class 5.1 Oxidising Substances
Subsidiary Risk(s) No Data Available
EPG 31 Oxidizing Substances
UN Number 2880
Hazchem 1W
Pack Group II
Special Provision No Data Available
Proper Shipping Name CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16%
water
Class 5.1 Oxidising Substances
Subsidiary Risk(s) No Data Available
EPG 31 Oxidizing Substances
UN Number 2880
Hazchem 1W
Pack Group II
Special Provision No Data Available
Proper Shipping Name CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16%
water
Class 5.1 Oxidising Substances
Subsidiary Risk(s) No Data Available
ERG 140 Oxidizers
UN Number 2880
Hazchem 1W
Pack Group II
Special Provision No Data Available
Sea Transport
IMDG Code
Proper Shipping Name CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16%
water
Class 5.1 Oxidising Substances
Subsidiary Risk(s) No Data Available
UN Number 2880
Hazchem 1W
Pack Group II
Special Provision No Data Available
EMS F-H, S-Q
Marine Pollutant Yes
Air Transport
IATA DGR
Proper Shipping Name Calcium hypochlorite, hydrated with >= 5.5% and <= 16% water
Class 5.1 Oxidising Substances
Subsidiary Risk(s) No Data Available
UN Number 2880
Hazchem 1W
Pack Group II
Special Provision No Data Available
Dangerous Goods Classification Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods
by Road & Rail (ADG Code)
General Information CHLORINATING COMPOUNDS (incl. Calcium hypochlorite) are listed in Schedule 6 of the SUSMP.
Poisons Schedule (Aust) Schedule 6
National/Regional Inventories
Related Product Codes CAHYPO0500, CAHYPO0600, CAHYPO0700, CAHYPO0800, CAHYPO0900, CAHYPO1000, CAHYPO1001,
CAHYPO1002, CAHYPO1003, CAHYPO1004, CAHYPO1005, CAHYPO1006, CAHYPO1007, CAHYPO1008,
CAHYPO1009, CAHYPO1010, CAHYPO1011, CAHYPO1012, CAHYPO1013, CAHYPO1014, CAHYPO1015,
CAHYPO1016, CAHYPO1017, CAHYPO1018, CAHYPO1019, CAHYPO1020, CAHYPO1021, CAHYPO1022,
CAHYPO1023, CAHYPO1100, CAHYPO1200, CAHYPO1210, CAHYPO1500, CAHYPO1600, CAHYPO1800,
CAHYPO1801, CAHYPO1802, CAHYPO1803, CAHYPO1804, CAHYPO1805, CAHYPO1806, CAHYPO2000,
CAHYPO2001, CAHYPO2002, CAHYPO2003, CAHYPO2004, CAHYPO2005, CAHYPO2006, CAHYPO2100,
CAHYPO2500, CAHYPO3000, CAHYPO3001, CAHYPO4000, CAHYPO4001, CAHYPO4500, CAHYPO5000,
CAHYPO5500, CAHYPO6000, CAHYPO6500, CAHYPO6501, CAHYPO6502, CAHYPO6503, CAHYPO6504,
CAHYPO6505, CAHYPO6506, CAHYPO6507, CAHYPO6508, CAHYPO6509, CAHYPO6510, CAHYPO6511,
CAHYPO6512, CAHYPO6513, CAHYPO6514, CAHYPO6515, CAHYPO6540, CAHYPO6800, CAHYPO6801,
CAHYPO6802, CAHYPO6803, CAHYPO6804, CAHYPO6900, CAHYPO7000, CAHYPO7015, CAHYPO7040,
CAHYPO7500, CAHYPO8000, CAHYPO8001, CAHYPO8500, CAHYPO8501, CAHYPO8700, CAHYPO8800,
CAHYPO8900, CAHYPO9000, CAHYPO9001, CAHYPO9025, CAHYPO9100, CAHYPO9200, CAHYPO9201,
CAHYPO9202, CAHYPO9203, CAHYPO9300, CAHYPO9301, CAHYPO9302, CAHYPO9400, CAHYPO9401,
CAHYPO9405, CAHYPO9410, CAHYPO9500, CAHYPO9501, CAHYPO9502, CAHYPO9600, CAHYPO9601,
CAHYPO9602, CAHYPO9700, CAHYPO9701, CAHYPO9800, CAHYPO9900
Revision 4
Revision Date 20 Sep 2016
Key/Legend < Less Than
> Greater Than
AICS Australian Inventory of Chemical Substances
atm Atmosphere
CAS Chemical Abstracts Service (Registry Number)
cm² Square Centimetres
CO2 Carbon Dioxide
COD Chemical Oxygen Demand
deg C (°C) Degrees Celcius
EPA (New Zealand) Environmental Protection Authority of New Zealand
deg F (°F) Degrees Farenheit
g Grams
g/cm³ Grams per Cubic Centimetre
g/l Grams per Litre
HSNO Hazardous Substance and New Organism
IDLH Immediately Dangerous to Life and Health
immiscible Liquids are insoluable in each other.
inHg Inch of Mercury
inH2O Inch of Water
K Kelvin
kg Kilogram
kg/m³ Kilograms per Cubic Metre
lb Pound
LC50 LC stands for lethal concentration. LC50 is the concentration of a material in air which causes the death of
50% (one half) of a group of test animals. The material is inhaled over a set period of time, usually 1 or 4 hours.
LD50 LD stands for Lethal Dose. LD50 is the amount of a material, given all at once, which causes the death of 50%
(one half) of a group of test animals.
ltr or L Litre
m³ Cubic Metre
mbar Millibar
mg Milligram
mg/24H Milligrams per 24 Hours
mg/kg Milligrams per Kilogram
mg/m³ Milligrams per Cubic Metre
Misc or Miscible Liquids form one homogeneous liquid phase regardless of the amount of either component
present.
mm Millimetre
mmH2O Millimetres of Water
mPa.s Millipascals per Second
N/A Not Applicable
NIOSH National Institute for Occupational Safety and Health
NOHSC National Occupational Heath and Safety Commission
OECD Organisation for Economic Co-operation and Development
Oz Ounce
PEL Permissible Exposure Limit
Pa Pascal
ppb Parts per Billion
ppm Parts per Million
ppm/2h Parts per Million per 2 Hours
ppm/6h Parts per Million per 6 Hours
psi Pounds per Square Inch
R Rankine
RCP Reciprocal Calculation Procedure
STEL Short Term Exposure Limit
TLV Threshold Limit Value
tne Tonne
TWA Time Weighted Average
ug/24H Micrograms per 24 Hours
UN United Nations
wt Weight