15.0 Nuclear & Atomic Physics My NC Notes PDF
15.0 Nuclear & Atomic Physics My NC Notes PDF
15.0 Nuclear & Atomic Physics My NC Notes PDF
In the early 1900’s the most popular model of the atom was ‘the plum pudding’
model; which assumed that the atom is composed of electrons surrounded by a
soup of positive charge to balance the electron's negative charge, like negatively-
charged ‘plums’ surrounded by positively-charged ‘pudding. This was disapproved
by Ernest Rutherford.
He
found
that:
Most alpha particles were undeflected and passed straight through the gold foil.
Some were deflected through small angles.
A very small number were turned back through angles greater than 900!
ATOMIC STRUCTURE
SUB-ATOMIC PARTICLES
An atom is the smallest part of a chemical element that has the chemical
properties of that element (reacts in the same way).
It isn't the smallest thing that exists despite what you may have heard.
All atoms are made up of three sub-atomic particles - particles smaller than an
atom.
Protons and neutrons are nucleons because they are found in the nucleus.
All nucleons have a relative mass of 1.
Protons have a relative electric charge of +1.
Neutrons have a relative electric charge of 0.
Electrons are not nucleons because they are not found in the nucleus.
Electrons are found around the outside of the atom in shells.
They have a relative charge of -1 but almost no mass (1/1840 of the mass of a
proton).
The atomic (proton) number tells us the number of protons in an atom's nucleus.
eg. 8O has 8 protons while 20Ca has 20 protons.
Atomic number also tells us the number of electrons in an electrically neutral atom
That is, Z= proton number = number of electrons.
The mass (nucleon) number tells us the total number of nucleons (this is the
number of protons + the number of neutrons).
So, a 146C atom contains 6 protons because its atomic number is 6, the remaining 8
nucleons must be neutrons.
Isotopes
Neutrons make no difference to the chemistry of an element. They just make
atoms heavier.
So, different versions of the same element can exist - they must have the same
number of protons in their nuclei, but the number of neutrons can vary.
These are isotopes.
Definition: Isotopes are atoms of the same element having the same proton
(atomic) number but different numbers of neutrons.
Isotopes have the same chemical properties because they have the same number
of electrons, but different physical properties (e.g. mass, density) because they
have different masses.
6
Li, 73Li, and 83Li exist and all of these isotopes have the same chemical properties
3
(react in the same way because each of them have 3 protons in their nucleus and 3
electrons in their shells).
37
17 Cl
EXPECTED ANSWERS
1. a). (i). 17
(ii). 35-17 =18
(iii). 17
(iv). 35 [4]
(ii)
ATOM ELECTRONS PROTONS NEUTRONS MASS NUMBER
(Atomic No.) (A-Z) (A)
Z
35
17 Cl 17 17 18 35
37
17 Cl 17 17 20 37
[8]
15.2 RADIOACTIVITY
STABLE ATOM
Has stable nucleus with the same number of protons and neutrons.
UNSTABLE ATOMS
RADIOACTIVE DECAY
Is the breakdown of a large unstable nucleus with the emission (release) of nuclear
particles to form stable nuclei of other elements.
What is RADIOACTIVITY?
Is the spontaneous random emission of particles from within the nucleus of an atom.
Spontaneous means the process is unpredictable.
Random means particles are emitted any time with no set pattern and in any direction.
Spontaneous random means unpredictable emission of particles, at any time, with no set
pattern and in any direction.
When a massive atom breaks down the emitted nuclear particles and energy are called
nuclear radiation.
NUCLEAR RADIATION
Consist of two nuclear particles namely alpha (α) particles and beta (β) particles plus
gamma (γ) radiation.
Table: The Nature of nuclear radiation
NUCLEAR PARTICLE/ ALPHA (α) α) ) BETA (α) β) PARTICLE) PARTICLE GAMMA (α) γ) RAYS) RAYS
RADIATION PARTICLES
1. NATURE Helium nuclei 42He 2+ Fast-moving electron Electromagnetic (e.m)
0 waves
−1 e
PENETRATING POWER
Explanation
1. A GM tube is placed close to the radioactive source. A large count rate is measured.
2. Paper, aluminium and lead (or thick concrete) are placed in line with source.
3. A GM tube is placed behind the paper. There is a large decrease in the count rate
showing that alpha (α) particles are absorbed/stopped by paper.
4. A GM tube is placed behind the aluminium sheet. There is a very small decrease in the
count rate showing that beta (β) particles have been absorbed/stopped by the aluminium
sheet.
5. A GM tube is placed behind the lead (or thick concrete). No count rate is detected. This
shows that gamma (γ) radiation is absorbed/stopped by lead (or thick concrete).
6. This experiment shows that the penetrating power of alpha (α) particles is much smaller
and the penetrating power of gamma (γ) radiation is much bigger than that of either
alpha (α) particles or beta (β) particles.
7. When nuclear radiation is fired at an object, some of it is absorbed, some passes through
and some is reflected.
Conclusion
Alpha particles have very poor penetrating power. These cannot even pass through a thin
sheet of paper.
Beta particles have penetrating power more than alpha rays. These can easily pass
through a thin sheet of paper but are stopped by thin sheet of aluminium metal.
Gamma rays can easily pass through aluminium sheets but are stopped by a thick block of
lead metal
Alpha (α) particles are larger and therefore have greater chances of colliding with other
particles of matter and so have less likelihood of travelling or penetrating far.
Alpha (α) particles are strongly positive so they easily pull off electrons from atoms of
matter.
An alpha (α) particle ionises more atoms than a beta (β) particle and therefore lose its
kinetic energy faster. That is why an alpha (α) particle has a small penetrating power.
Alpha (α) particles are strongly ionising. If you breathe in alpha (α) particle they can
damage your lung.
A beta (β) particle has a smaller charge than an alpha (α) particle as well as a smaller
mass and a higher speed. Therefore it penetrates further than the alpha (α) particle.
A beta (β) particle penetrates better than alpha (α) particle and is therefore less
dangerous in the body.
Alpha (α) particles experience a smaller deflection because they are heavier.
Beta (β) particles experience a larger deflection because they are lighter.
Alpha (α) particles and beta (β) particles are deflected because they are charged.
Gamma (γ) rays are not deflected because they are not charged.
Unlike charges attract. Therefore negatively charged beta particles are attracted to the
positive plate and positively charged alpha particles are attracted to the negative plate.
Beta particles are attracted to the North Pole of the magnet since they are negatively
charged.
Alpha particles are attracted to the South Pole of the magnet since they are positively
charged.
NUCLEAR EQUATIONS
QUESTION
A polonium–212 nucleus decays spontaneously while at rest, with the emission of an alpha-
particle. What daughter nucleus is produced during this alpha-decay?
Solution
212 4 ?
84 Po → 2 He+ ? X The total number on top on the left must equal the total number on top
on the right.
The same applies for the bottom.
Once you realise that the atomic number of the daughter product is 82 you then go to the
periodic table of elements to identify this atom – it this case the element ‘lead’ has an
atomic number of 82
212
84 Po → 42 He+ 208
82 Pb
EXAMPLE
1. Carbon-14 undergoes β –decay to Nitrogen.decay to Nitrogen.
QUESTION
Cobalt−60 is a radioactive isotope and emits beta particles.
Write an equation to represent the decay of cobalt−60.
Solution
60
Co → −10e + ?? X
27
The total number on top on the left must equal the total number on top on the
right.
The same applies for the bottom.
Once you realise that the atomic number of the daughter product is 28 you then go
to the periodic table of elements to identify this atom – it this case the element
‘Nickel’ has an atomic number of 28.
60 0 60
27 Co → −1e + 28 ¿
Where the * sign indicates that the daughter nuclide is the same element as the
parent nuclide.
Obviously, the more atoms that are present, the greater will be the activity (the number
of disintegrations per second).
Half- life (T1/2) of an element is the average time it takes for the number of
undecayed atoms to halve.
Half- life is the time taken for the amount of a radioactive isotope to fall to half its
original value.
Half- life is the time for the radioactivity of an isotope to be reduced to half its
initial value.
The longer the half -life of an isotope the longer it stays radioactive.
DECAY CURVES
Half-life = T1/2 - 0
A graph showing how the count rate decreases as time goes by will have a curve like
the one shown in the picture below.
For any particular radioisotope the count rate and time will be different but the shape
of the curve will be the same.
2. Go down to half the original count rate (820 counts) and draw a horizontal line to
the curve.
Then draw a vertical line down from the curve.
You can read off the half-life where the line crosses the time axis.
1. If you are given two count rates and you know how long it takes to get from one to
the other, then you can calculate the half-life of the material.
The method for this is shown below.
2. If you know the half-life of a material, you can calculate what the count rate will be
at some time in the future.
The method for this is shown below.
Question
The half-life of a material is 3 hours. If the initial count rate is 544 Bq, what will the
count rate be after 15 hours?
1. If you know the half-life of a material, you can calculate what the count rate will be
at some time in the future.
The method for this is shown on the section.
2. If you are given two count rates and you know how long it takes to get from one to
the other, then you can calculate the half-life of the material.
The method for this is shown below.
Question
The count rate of a material is 2016 Bq.
After 35 days it has fallen to 63. What is the half-life?
Answer.
Put the count rate in boxes and use arrows to represent the half-life.
After each half-life the count rate is halved.
An = Ao ( 12 ) n
WORKED EXAMPLES
Q1. A radioactive source registers 1000 counts per minute when first used. 6 minutes later
the count rate falls to 125 counts per minute. Calculate the half-life this radioisotope.
Ans 1. Original count rate AO = 1000
LET number of half-lives = n
Final count rate An= 125
Ao
= 2n
An
1000
= 2n
125
8 =2n
23 = 2n
n= 3
Thus the activity has halved 3 times during the 6 minute interval.
time interval
THEREFORE, Half-life =
n
6
=3
= 2 minutes
= 2 minutes
Q2. The original count rate of a radioactive source is 2000. What will be the
count rate after 20 hours if its half-life is 5 hours?
time interval
Ans2. n =
half −life
20
=
5
=4
1
An = Ao
2 () n
= 2000 ( 12 ) 4
2000
=
16
= 125
Q3. In 168 s the activity Thorium falls to 1/8 of its original value. What is its
half-life?
Ao
An = 2n
1
1/ 8 =2n
8 = 2n
23 =2n
n=3
timeinterval
Half-life =
n
168 s
=
3
= 56 seconds
time interval
Half-life =
n
168 s
=
3
= 56 seconds
Q4. Given that the half-life of radium-226 is 1620 years, calculate the time it
takes for 100g of Radium to have its activity fall to 1/8 its original value. [3]
1
An = Ao 2 n ()
1
8 x 100g = 100g ( 12 ) n
1
8 = ( 12 ) n
2n = 23
n=3
Time taken = Half-life x n
= 1620 years x 3
= 4860 years
Nuclear Fission
Nuclear Fission is the process in which the nucleus of a heavy atom, such as
Uranium-235 or Plotonium-236, is split into two smaller or daughter nuclei and
three neutrons along with the release of energy when bombarded by a slow
moving neutron.
The amount of energy released from this mass can be calculated using Einstein's
equation below:
or E = mc2
The energy resulting from the mass loss is in the form of kinetic energy of the
daughter nuclei and neutron and electromagnetic radiation in the form of gamma
rays.
2. The unstable energetic nucleus distorts and the repulsion between the protons
begins to separate the nucleus.
3. The repulsion between the protons becomes strong enough to separate the
nucleus into two separate nuclei along with the release of a large amount of
energy.
4. Two daughter nuclei are formed from the fission and possess a large amount of
the energy from the nuclear reaction in the form of kinetic energy. These are
accompanied with three neutrons.
5. The neutrons that are released can go on to collide with other uranium atoms
causing more fission and more neutrons to be released. This is called a chain
reaction.
The new atoms that are formed are radioactive and are called daughter nuclei.
Nuclear fission is releases large amounts of heat energy that can be used to
generate electricity.
The amount of energy released during nuclear fission is much larger than the
energy released when substances react chemically. For instance, 1 kg of
uranium undergoing fission can release the same energy as burning 10 000kg of
coal!
Uranium is not the only element that can be used in nuclear power. Plutonium is
an alternative fuel.
QUESTION
Nuclear disintegrations occur in radioactivity and in fission. Distinguish between
radioactivity and fission.
SOLUTION
Radioactivity is the breaking down of unstable nuclei with the emission of one or
more types of radiation.
Nuclear Fission is the breaking down of a large nucleus into two smaller nuclei with
the release of energy (and neutrons).
Nuclear fusion
Nuclear fusion is the joining of two light nuclei to form a heavier nucleus. It is
the process by which energy is released in stars e.g. the sun.
An example of a fusion reaction is that of two deuterium nuclei fusing together
to give a helium nucleus. Deuterium is an isotope of hydrogen. The reaction is as
follows:
Both nuclei contain 1 proton and 1 neutron. They carry a positive charge
and repel each other. An increase in temperature increases the kinetic
energy of the nuclei and they move around at increasing speeds.
Question
Determine the decrease in the mass of the sun when it releases 1.8 x 106 J of
energy.
Solution
E
E = mc2 therefore m =
c2
1.8 x 106
m= 2
(3 x 10 8)
= 2 x 10-11 kg
USES OF RADIOACTIVITY
Cosmic radiations from outer space displaced neutrons from nuclei in the
Earth's outer atmosphere. These neutrons then collide with nitrogen nuclei to
produce carbon-14. Living organisms like plants and animals absorb and give
out carbon-14 when they are alive. The half-life of carbon-14 is about 5730
years. So there is negligible disintegration over the lifetime of most organisms.
However when they die, no more absorption of carbon-14 occurs. The C-14
BACKGROUND RADIATION
Is the radiation we are exposed to in our atmosphere.
It comes from both natural and artificial sources.
Natural sources of radiation are cosmic rays, the sun, rocks in the earth’s
crust, air and naturally occurring radioisotopes.
Artificial sources include atomic/nuclear bombs, nuclear power stations,
medical isotopes, industrial radioisotopes, food and nuclear wastes.
DANGERS OF RADIOACTIVITY
We cannot avoid exposure of radiation in small doses due to background
radiation; however large doses are dangerous to our health.
The effects of human exposure to large doses of radioactive radiation
include:
a) Damage to cells and tissues of the body due to the ionising effect of
radiation.
b) Mutation of genes.
c) Leukaemia/cancer of the blood
d) Damage to blood leading to lower resistance to normal diseases.
e) Sterility
f) Serious abnormalities
g) Burns, redness and sores on the skin.
Danger from alpha-particles is small unless they enter the body.
Beta-particles and gamma rays cause burns and delayed effects such as eye
cataracts and cancer.
Large exposure to beta-particles and gamma rays can lead to radiation
sickness and death.
SAFETY PRECAUTIONS