Akzo Nobel India Limited

Safety Data Sheet

PHA046 INTERTHANE 990 PART B
Version Number 8 Revision Date 12/24/20

1. Product and company identification

1.1. Product identifier INTERTHANE 990 PART B

Product Code PHA046
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use Refer Technical Data Sheet.
For professional use only.
Application Method Refer Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet
Importer or
Manufacturer Akzo Nobel India Limited
Plot No. 62P, 62A, 62B, 43E,
Hoskote Industrial Area, Pilgumpa Hoskote Taluk,
Bangalore 562114. India

Telephone No. +91 80 22895000 / + 91 80 71717000

Fax No. +91 80 22895500 / + 91 80 71717500
1.4. Emergency telephone number (24 hour) +91 80 22895000 / + 91 80 71717000
For Poisons Advice telephone +91 80 22895000 / + 91 80 71717000 For Advice to
Doctors & Hospitals only

2. Hazard identification of the product

2.1. Classification of the substance or mixture

Flam. Liq. 3;H226 Flammable liquid and vapour.
Acute Tox. 4;H332 Harmful if inhaled.
Skin Irrit. 2;H315 Causes skin irritation.
Eye Irrit. 2;H319 Causes serious eye irritation.
Skin Sens. 1;H317 May cause an allergic skin reaction.
Resp. Sens. 1;H334 May cause allergy or asthma symptoms of breathing difficulties if inhaled.
STOT SE 3;H335 May cause respiratory irritation. Specific Target Organs: ( respiratory system)
Aquatic Acute 3;H402 Harmful to aquatic life.
Aquatic Chronic 2;H411 Toxic to aquatic life with long lasting effects.
2.2. Label elements
Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.

Danger
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms of breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H402 Harmful to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

[Prevention]:
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking.
P235 Keep cool.
P240 Ground / bond container and receiving equipment.
P241 Use explosion-proof electrical / ventilating / light / equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe mist / vapours / spray.
P261 Avoid breathing dust / fume / gas / mist / vapours / spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
[Response]:
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin
with water / shower.
P304+312 IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell.
P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if
present and easy to do - continue rinsing.
P321 Specific treatment (see information on this label).
P331 Do NOT induce vomiting.
P333+313 If skin irritation or a rash occurs: Get medical advice / attention.
P337 If eye irritation persists:
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304+341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor / physician.
P362 Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P370+378 In case of fire: Use alcohol resistant foam, CO2, powder, water spray for extinction. Do not use
water jet.
P391 Collect spillage.
[Storage]:
P403+233 Store in a well ventilated place. Keep container tightly closed.
P405 Store locked up.
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.
2.3. Other hazards
This product contains no PBT/vPvB chemicals.

3. Composition/information on ingredients

This product contains the following substances that present a hazard.

Ingredient/Chemical Designations Weight % GHS Classification Notes
HDI Homopolymer >50 Acute Tox.4;H332 [1]
CAS Number: 0028182-81-2 Skin Sens. 1;H317
STOT SE 3; H335
Solvent naphtha (petroleum), light aromatic 10- <25 Flam. Liq. 3;H226 [1]
CAS Number: 0064742-95-6 Asp. Tox. 1;H304
Skin Irrit. 2;H315
Eye Irrit. 2;H319
Acute Tox 4; H332
STOT SE 3; H335
STOT SE 3;H336
Aquatic Chronic 2;H411
1,2,4-trimethylbenzene 2.5- <10 Flam. Liq. 3;H226 [1][2]
CAS Number: 0000095-63-6 Acute Tox. 4;H332
Eye Irrit. 2;H319
STOT SE 3;H335
Skin Irrit. 2;H315
Aquatic Chronic 2;H411
hexamethylene-1,6-di iscocyanate <1 Acute Tox. 4;H302 [1][2]
CAS Number: 0000822-06-0 Eye Irrit. 2;H319
STOT SE 3;H335
Skin Irrit. 2;H315
Resp. Sens. 1;H334
Skin Sens. 1;H317
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.

*The full texts of the Hazard (H) phrases are shown in Section 16.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence do not
require reporting in this section.

4. First aid measures

4.1. Description of first aid measures

General
In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person.

Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial
respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give
nothing by mouth.

Skin Contact
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin
cleanser. Do NOT use solvents or thinners.

Eye Contact
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.

Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.

4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed and notes for
physician
No data available

5. Fire-fighting measures

5.1. Extinguishing media

Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray.

Do not use - water jet.

Note; Fire will produce dense black smoke. Decomposition products may be hazardous to health. Avoid
exposure and use breathing apparatus as appropriate.

Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and
contaminants from fire fighting to enter drains or water courses.
5.2. Special hazards arising from the substance or mixture
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
5.3. Advice for fire-fighters
Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and
contaminants from fire fighting to enter drains or water courses.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a
major spill or spillage in a confined space evacuate the area and check that solvent vapour levels are
below the Lower Explosive Limit before re-entering.
6.2. Environmental precautions
Do not allow spills to enter drains or watercourses.
6.3. Methods and material for containment and cleaning up
Ventilate the area and avoid breathing vapours. Take the personal protective measures listed in section 8.
Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in a
suitable container. The contaminated area should be cleaned up immediately with a suitable
decontaminant. One possible (flammable) decontaminant comprises (by volume): water (45 parts), ethanol
or isopropyl alcohol (50 parts), concentrated (d:0,880) ammonia solution (5 parts). A non-flammable
alternative is sodium carbonate (5 parts), water (95 parts). Add the same decontaminant to any residues
and allow to stand for several days in a non-sealed container until no further reaction occurs. Once this
stage is reached, close container and dispose of in accordance with the waste regulations (see section
13). Do not allow spills to enter drains or watercourses.If drains or sewers are contaminated, inform the
local water company immediately. In the case of contamination of rivers, streams or lakes the
Environmental Protection Agency should also be informed.

7. Handling and storage

7.1. Precautions for safe handling

Handling
Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should only be
employed in processes in which this product is used under appropriate medical supervision.

In Storage
Handle containers carefully to prevent damage and spillage.

Precautions should be taken to minimise exposure to atmospheric humidity or water as carbon dioxide
may be formed which, in closed containers can result in pressurisation. Care should be taken when re-
opening partly used containers.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks
and electrical equipment are protected to the appropriate standard.
This coating contains solvents. Solvent vapours are heavier than air and may spread along floors. Vapours
may form explosive mixtures with air. Areas of storage, preparation and application should be ventilated to
prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour
concentrations higher than the occupational exposure limits.

7.2. Conditions for safe storage, including any incompatibilities

Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
Avoid skin and eye contact. Avoid inhalation of vapours and spray mists. Observe label precautions. Use
personal protection as shown in section 8.

Smoking, eating and drinking should be prohibited in all preparation and application areas.

Never use pressure to empty a container; containers are not pressure vessels.
There are no exposure scenarios, see details in section 1.

7.3. Specific end use(s)

Store in a well ventilated, dry place away from sources of heat and direct sunlight.

Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack
more than 3 pallets high.

Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Keep in the original container or one of the same material.

Prevent unauthorised access.

All sources of ignition (hot surfaces, sparks, open flames etc) should be excluded from areas of
preparation and application. All electrical equipment (including torches) should be protected (Ex) to the
appropriate standard.

The product may charge electrostatically. Always use earthing leads when pouring solvents and
transferring product. Operators should wear clothing which does not generate static (at least 60% natural
fibre) and antistatic footwear; floors should be of conducting type.

8. Exposure controls and personal protection

8.1. Control parameters

From the listed Exposure Standards for Atmospheric Contaminants (ACGIH) as amended.

Material PEL (Short Term) PEL (Long Term) Comments

ppm mg/m³ ppm mg/M3
HDI Homopolymer 0.07 0.02 ---
hexamethylene-1,6-di iscocyanate - 0.07 0.005 0.034 ---
(P) Peak exposure limit
(R) Suppliers Recommended Limit
(Sk) There is a risk of absorption through unbroken skin
(Sen) Sensitiser
(Cat1) Category 1 - established human carcinogen
(Cat2) Category 2 - probable human carcinogen
(Cat3) Category 3 - substances suspected of having carcinogenic potential

DNEL/PNEC values
No Data Available

8.2. Exposure controls

Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local
exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of
particulates and any vapour below occupational exposure limits suitable respiratory protection must be
worn.
Provide adequate ventilation. This should be achieved by the use of local exhaust ventilation and good
general extraction. Air-fed protective respiratory equipment must be worn by spray operators even when
good ventilation is provided . In other operations, if local exhaust ventilation and good general extraction
are not sufficient to maintain concentrations of particulates and solvent vapour below the WEL, suitable
respiratory protection must be worn. (See Personal Protection)

Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be
employed in any process in which this preparation is used.

Examination of lung function should be carried out on a regular basis on persons spraying this preparation.

Eye Protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Eyewear should comply with the appropriate standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes.

An eyewash station is suggested as a good work place practice.

Skin Protection
Gloves of an appropriate material should be worn during mixing and application.

Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams
may help to protect areas which are difficult to cover such as the face and neck. They should however not
be applied once exposure has occurred. Petroleum jelly based types such as Vaseline should not be used.
All parts of the body should be washed after contact.

Respiratory Protection
When concentrations exceed the exposure limits shown above workers must wear appropriate respirators
approved in accordance with Directive 89/656/EEC and the Personal Protection Equipment Regulations.
Provision of other controls such as exhaust ventilation should be considered if practical.

An air fed respirator must be worn when applying this product in a confined space. Even in open spaces,
an air fed respirator should be worn when spraying.
If applying by brush or roller in an open, well ventilated area, air fed respirators could be replaced by a
charcoal filter mask.

Thermal hazards
No Data Available
9. Physical and chemical properties

Colour Colourless Liquid

Odour Smell of Solvent
Odour threshold Not Measured
pH N/A
Melting point / freezing point (°C) Not Measured
Initial boiling point and boiling range (°C) 137
Flash Point ( ) 49
Evaporation rate (Ether = 1) Not Measured
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: 1.1
Upper Explosive Limit: 7
Vapour pressure (Pa) Not Measured
Vapour Density Heavier than air.
Specific Gravity 1.07
Solubility in Water Immiscible
Partition coefficient n-octanol/water (Log Kow) Not Measured
Autoignition temperature Not Measured
Decomposition temperature Not Measured
Viscosity (cSt) N/A

9.2. Other information

No further information

10. Stability and reactivity

10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7). In a fire, hazardous
decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen, hydrogen
cyanide may be produced.

Keep away from oxidising agents, strongly alkaline and strongly acid materials, amines, alcohols and
water. Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with
water resulting in evolution of carbon dioxide. In closed containers, pressure build up could result in
distortion,blowing and in extreme cases bursting of the container.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon
monoxide, carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.

11. Toxicological information

Acute toxicity

Exposure to solvent vapour concentrations from the component solvents in excess of the stated
occupational exposure limits may result in adverse health effects such as mucous membrane and
respiratory system irritation and adverse effects on the kidneys, liver and central nervous system.
Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme
cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible
damage.
Based on the properties of the isocyanate content of this product, respiratory exposure may cause acute
irritation and/or sensitisation of the respiratory system resulting in asthmatic symptoms, wheezing and a
tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to
airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure
may lead to permanent respiratory disability. Persons with a chronic or recurrent respiratory disease
should not be employed in any process in which these products are used.

The preparation has been assessed using the Acute Toxicity Data listed below, and classified for
toxicological hazards accordingly. See section 2 for details.

Inhalation Inhalation
Oral LD50, Skin LD50,
Ingredient Vapour LD50, Dust/Mist LD50,
mg/kg mg/kg
mg/L/4hr mg/L/4hr
1,2,4-trimethylbenzene - (95-63-6)
3,400.00, Rat 3,160.00, Rabbit 18.00, Rat Not Applicable

HDI Homopolymer - (28182-81-2)

5,000.00, Rat Not Applicable Not Applicable Not Applicable

hexamethylene-1,6-di iscocyanate -
(822-06-0) Not Applicable Not Applicable Not Applicable Not Applicable

Solvent naphtha (petroleum), light

aromatic - (64742-95-6) 6,800.00, Rat 3,400.00, Rabbit Not Applicable Not Applicable

Item Category Hazard

Acute Toxicity (mouth) Not Classified Not Applicable
Acute Toxicity (skin) Not Classified Not Applicable
Acute Toxicity (inhalation) 4 Harmful if inhaled.
Skin corrosion/irritation 2 Causes skin irritation.
Eye damage/irritation 2 Causes serious eye irritation.
Sensitization (respiratory) 1 May cause allergy or asthma symptoms of
breathing difficulties if inhaled.
Sensitization (skin) 1 May cause an allergic skin reaction.
Germ toxicity Not Classified Not Applicable
Carcinogenicity Not Classified Not Applicable
Reproductive Toxicity Not Classified Not Applicable
Specific target organ systemic toxicity 3 May cause respiratory irritation.
(single exposure)
Specific target organ systemic Toxicity Not Classified Not Applicable
(repeated exposure)
Aspiration hazard Not Classified Not Applicable

12. Ecological information

12.1. Toxicity
The preparation has been assessed according to the GHS criteria and is classified as dangerous for the
environment, using the toxicity data listed below.

There are no data available on the product itself.

The product should not be allowed to enter drains or water courses.

Aquatic Ecotoxicity

96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae,

Ingredient
mg/l mg/l mg/l
HDI Homopolymer - (28182-81-2)
100.00, Danio 100.00, Daphnia
rerio magna 100.00 (72 hr), Scenedesmus
subspicatus

Solvent naphtha (petroleum), light

aromatic - (64742-95-6) 6.14, Daphnia 19.00 (72 hr), Selenastrum
9.22, Oncorhynchus magna capricornutum
mykiss

1,2,4-trimethylbenzene - (95-63-6)
7.72, Pimephales 3.60, Daphnia Not Applicable
promelas magna

hexamethylene-1,6-di iscocyanate -
(822-06-0) 82.80, Danio rerio 89.10, Daphnia
magna 77.40 (72 hr), Desmodesmus
subspicatus

12.2. Persistence and degradability

There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available

13. Disposal considerations

13.1. Waste treatment methods

Do not allow into drains or water courses. Wastes and empty containers should be disposed of in
accordance with local regulations.

Using information provided in this data sheet advice should be obtained from the local Waste Regulation
Authority as to whether special waste regulations apply.

14. Transport information

14.1. UN number 1263

14.2. UN Proper Shipping Name (PSN) Paint
14.3. Transport hazard class(es)

Road and Rail Transport UN1263, PAINT, PG III

IMDG Class/Div 3 Sub Class

reference :

Ems F-E,S-E

ICAO/IATA Class 3 Sub Class

14.4. Packing group III

14.5. Environmental hazards

Road and Rail Environmentally Hazardous: Yes

Transport

IMDG Marine Pollutant: Yes ( Solvent naphtha (petroleum), light aromatic )

reference :

14.6. Special precautions for user

No further information
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not Applicable

15. Regulatory information

This product and all its components complies with the chemical and transport regulations from the country
listed in section 1.3.
Other regulatory information specific to the hazardous chemical(s):

None noted.

16. Other information

The information on this SDS is based upon the present state of our knowledge and on current laws.
The product should not be used for purposes other than shown in the product data sheet without first
obtaining written advice.
It is always the responsibility of the user to take all necessary steps to meet the demands of applicable
legislation.

The full text of the phrases appearing in section 3 is:

H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 Vapours may cause drowsiness and dizziness
H411 Toxic to aquatic life with long lasting effects.

This SDS is valid for 5 years from the revised date on page 1.
The revision date is in American format (e.g. MM/DD/YY).

End of document

All information concerning this product and/or suggestions for handling and use contained herein are
offered in good faith and are believed to be reliable. Akzo Nobel however makes no warranty as to
the accuracy of and/or sufficiency of such information.