Bogue's Compounds: Unit 1
Bogue's Compounds: Unit 1
Bogue’s Compounds
Raw materials used for the manufacturing of cement contains lime, silica, alumina and Iron
oxides i.e. CaO, Al2O3, SiO2, Fe2O3, MgO all interact with one another in Kiln to form complex
compounds.
The Identification of the major compounds is largely based on R.H.Bogue’s work and
hence it is called Bogues compounds.
In addition to the four major compounds, there are many minor compounds formed in the
kiln namely K2O and Na2O3 referred to as alkalis. The influence of these compounds on the
properties of cement or hydrated compounds is not significant.
Tricalcium Silicate and Dicalcium Silicate are the most important compounds responsible for the
strength; together they constitute 70 to 80% of cement. The average C3S compound in modern
cement is about 45% and that of C2S about 25%.The presence of C3A in cement is undesirable it
contributes little or nothing to the strength of cement except at the early ages and when the
hardened cement paste is attacked by sulphates, expansions due to the formation of calcium
sulfoaluminate from C3A may result in disruption of the hardened paste. However C3A acts as a
flux and thus reduces the temperature of burning clinker and facilitates the combination of lime
and silica.
The Equation suggested by Bogue for calculating the percentage of major compounds is
given below:
C2 S = 2.87(SiO2) -0.754(3CaO.SiO2)
C4AF = 3.04(Fe2O3)
Solids:
C-S-H
CH
Ettringite
Monosulphate hydrate
Residual unhydrated cement.
Voids:
Entrapped air (>1mm)
Entrapped air (75-500µm)
Capillary pores
Interlayer space.
Water:
Capillary water
Absorbed water
Interlayer water
Chemically combined water.
Calcium silicate hydrate phase, abbreviated as C-S-H, makes up to 50 to 60% of the volume of
solids in a completely hydrated Portland cement paste and is, therefore, the most important phase
determining the properties of the paste.
Calcium hydroxide crystals also called (portlandite) constitutes 20 to25% of the volume of solids
in the hydrated paste compared with C-S-H, the strength contribution potential of calcium
hydroxide is limited as a result of considerably lower surface area.
The gross space available for the product of hydration consists of the absolute volume of dry
cement together with the volume of water added to the mix.
The water bound chemically by C3S and C2S was shown to be very approximately 24 and
21% of the mass of the silicates respectively. The corresponding figure for C 3A and C4AF are
40 and 37% respectively.
The final reaction of hydration of C4AF is
C4AF + 22Ca (OH) 2 + 10H ------->C3AH6 + C3FH6
It is inadequate to state amount of water combined chemically. It is preferable therefore to
consider non-evaporable water. This water determines under specified conditions, is taken as
23% of the mass of anhydrous cement.
The specific gravity of the products of the hydration of cement is such that they occupy
greater volume than absolute volume of unhydrated cement but smaller than the sum of
volume of dry cement and the non-evaporable water by approximately 0.254 of the volume of
latter.
An average value of specific gravity of the products of hydration in a saturated state is 2.16.
Example:
The non-evaporable water is about 23% of the mass of cement i.e. 23ml
The solid particles of hydration occupy a volume equal to the sum of volumes of unhydrous
cement and water less 0.254 of the volume of non-evaporable water i.e.
Where Wg =19ml
= 67.9ml
Summarizing, we have
The decrease in volume of 5.9ml represents the empty capillary space distributed
throughout the hydrated cement paste
5.9ml
Empty
capillary
42.0ml pours
water
19ml
Gel water
31.8ml 48.9ml
cement Solid product
The higher the water/cement ratio, the greater the initial spacing between the cement grains and
the greater the volume of residual voids not filled by hydration products.
There is one thing missing on the graph. For a given cement content, the workability of the
concrete is reduced if the water/cement ratio is reduced. A lower water cement ratio means less
water, or more cement and lower workability.
However if the workability becomes too low the concrete becomes difficult to compact and the
strength reduces. For a given set of materials and environment conditions, the strength at any age
depends only on the water-cement ratio, providing full compaction can be achieved.
3. Coarse / fine aggregate ratio:
Following points should be noted for coarse/fine aggregate ratio:
If the proportion of fines is increased in relation to the coarse aggregate, the overall aggregate
surface area will increase.
If the surface area of the aggregate has increased, the water demand will also increase.
Assuming the water demand has increased, the water cement ratio will increase.
Since the water cement ratio has increased, the compressive strength will decrease.
1. For a given workability an increase in the proportion of cement in a mix has little effect on the
water demand and results in a reduction in the water/cement ratio.
2. The reduction in water/cement ratio leads to an increase in strength of concrete.
3. Therefore, for a given workability an increase in the cement content results in an increase in
strength of concrete.
5. Age of concrete:
The degree of hydration is synonymous with the age of concrete provided the concrete has not
been allowed to dry out or the temperature is too low.
In theory, provided the concrete is not allowed to dry out, then it will always be increasing albeit
at an ever reducing rate. For convenience and for most practical applications, it is generally
accepted that the majority of the strength has been achieved by 28 days.
6. Compaction of concrete:
Any entrapped air resulting from inadequate compaction of the plastic concrete will lead to a
reduction in strength. If there was 10% trapped air in the concrete, the strength will fall down in
the range of 30 to 40%.
8. Relative humidity
If the concrete is allowed to dry out, the hydration reaction will stop. The hydration reaction
cannot proceed without moisture. The three curves shows the strength development of similar
concretes exposed to different conditions.
9. Curing
It should be clear from what has been said above that the detrimental effects of storage of concrete
in a dry environment can be reduced if the concrete is adequately cured to prevent excessive
moisture loss.
Where is the yield value indicating the cohesion of the material, is a constant having the
dimensions of viscosity and termed plastic viscosity. This mathematical relationship is called
Bingham model.
T= g + hN
Where T is the torque measured, at N rps, and g and h are constants proportional to the cohesion
and plastic viscosity, respectively, of the mixture.
It has been found that the two mixtures having identical values for consistency, compaction
factor, and Vee-Bee time. On the other hand, when these value differ, two mixtures may show
similarity in any one of the three standard tests, but will behave differently in the other two.
The behavior of concrete departs significantly from the Bingham model in at least one of the
following respects.
In case the flow curve is concave upward, i.e. one of which the slope increases with shear rate, it
indicates that the shearing forces are destroying some structure that existed in the material when it
was unstressed, the progress of destruction being greater for higher shear rates. The curve ABC of
below figure is obtained as the rate of shear is gradually increased up to C,
(1) At stress below 30% of ultimate strength, the transition zone cracks remain stable. The stress-
strain plot remains linear.
(2) At stress between 30% and 50% of ultimate strength, the transition zone microcracks begin to
increase in length, width and numbers. The stress-strain plot becomes non-linear.
(3) At 50 to 60% of the ultimate stress, cracks begin to form in the matrix. With further increase
to about 75% of the ultimate stress, the cracks in the transition become unstable, and crack
propagation in the matrix will increase. The stress-strain curve bends towards the horizontal.
(4) At 75 to 80% of the ultimate stress, the stress reaches a critical stress level for spontaneous
crack growth under a sustained stress. Cracks propagate rapidly in both the matrix and the
transition zone. Failure occurs when the cracks join together and become continuous.
• Concrete is not a truly elastic material, as evident from the nonlinear stress-strain curve for
concrete, shown in the following Fig.7
Calculation of the above four types of moduli of elasticity for concrete has been explained
below using a typical stress-strain curve, as shown in the following Fig.8
Note: For lightweight concrete the above values of Ec28 should be multiplied by the factors
(ρ/2400)2 and (ρ/150)2 respectively.
ACI Building Code 318-89 recommends the following expression for (Ec) in terms of cylinder
compressive strength (fcyl), for normal weight concrete (i.e. concrete with density, ρ ≈ 2400
kg/m3):
ELong = EShort/(1+θ),
Where θ is creep coefficient and Creep coefficient is the ratio of creep strain to
elastic strain
ELong < Eshort
Modulus of elasticity determined through the longitudinal vibration test by velocity of sound or
frequency of sound is termed as dynamic modulus of elasticity (Ed) Dynamic modulus of
elasticity of concrete (Ed) is approximately taken as equal to the initial tangent modulus of
elasticity of concrete. Ed is more as creep effect is not considered.
Dynamic modulus of elasticity for normal and light weight concrete in GN/m2 (GPa) is given by
Conduct NDT on concrete prism Subject beam to longitudinal vibration at its natural frequency
and measure the resonant frequency (n, Hz) or the UPV (km/s) through it.
Ed = Kn2L2ρ ; If L in mm,
ρ in kg/m3, then
Ed = 4x10-15n2L2ρ, in GPa
Appx. Ranges of Resonant Frequencies of Concrete beam 100 x 100 x 500 mm Transverse
900–1600 Hz, Longitudinal 2500–4500 Hz.
If n= 4000 Hz, Ed = 38.4 GPa
Conduct NDT on concrete prism and measure the UPV (km/s) through it. UPV = Path
length/Transit time
Measure load and the corresponding deformation as the load is increased. Draw the stress strain
curve.
Strain =Dial gauge reading/gauge length = dl/L Stress = Load/Cross sectional area= P/A
Poisson’s ratio
In analysis and design of some type of structure the knowledge of poisson’s ratio is required.
When a material is compressed in one direction, it usually tends to expand in the other two
directions perpendicular to the direction of compression. This phenomenon is called the Poisson
effect. Poisson's ratio µ is a measure of the Poisson effect. The Poisson ratio is the ratio of the
fraction (or percent) of expansion divided by the fraction (or percent) of compression, for small
values of these changes. µ = 0.15 - 0.20 – Actual value to be found from strain measurements on
concrete cylinder using extensometer.
An alternate method for finding Poisson’s ratio is from UPV test and by finding the fundamental
natural frequency of longitudinal vibration of concrete beam. The Poisson’s ratio can be found
from the following equation. The Poisson’s ratio is slightly higher and it ranges from 0.2 to 0.24.
Since concrete is a composite material, consisting of cement paste and aggregate, its modulus of
elasticity depends on the moduli of elasticity and the volume fractions of cement paste and
aggregate, as follows:
• Ep depends on the porosity of cement paste and the porosity of cement paste depends on the
gel/space ratio (Ep is approximately proportional to the cube of the gel/space ratio) and gel/space
ratio finally depends on the w/c ratio (gel/space ratio is inversely proportional to w/c ratio)
Note: The reason behind relating Ep with compressive strength of concrete lies in the fact that the
compressive strength is also affected in the same way as, Ep
• Ea for lightweight aggregates is found to be much lower than that for the normal weight
aggregate. This is why the elastic modulus of lightweight concrete is less than that of the normal-
weight aggregate (Ec, light weight concrete = 0.4 to 0.8 Ec, normal weight concrete)
Note: The effect of moisture condition of specimen is reverse in case of the compressive
strength.
3. Condition of curing
Another factor affecting the modulus of elasticity of concrete is the manner in which the test
cylinders were cured. In general, concrete specimens that were cured in moist conditions resulted
in a modulus value higher than those cured in dry conditions. This is due to the fact that in dry
conditions concrete is more likely to have drying shrinkage. Drying shrinkage causes small
cracks. These small cracks thus will cause the concrete to have a reduced modulus of elasticity.
5. Mix proportion (C + A + W): All ingredients will have its own effect. For a given mix, the
effect of one variable should be considered keeping all other variables constant.