2015 U.S.

NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Chemistry Olympiad Examinations Task Force

OLYMPIAD EXAMINATIONS TASK FORCE

Seth N. Brown, Chair, University of Notre Dame, Notre Dame, IN
James Ayers, Mesa State College, Grand Junction, CO
Mark DeCamp, University of Michigan, Dearborn, MI (retired)
Xu Duan, Holton-Arms School, Bethesda, MD
Valerie Ferguson, Moore HS, Moore, OK
Julie Furstenau, Thomas B. Doherty HS, Colorado Springs, CO
Kimberly Gardner, United States Air Force Academy, CO
Paul Groves, South Pasadena HS, South Pasadena, CA
David W. Hostage, Taft School, Watertown, CT
Dennis Kliza, Kincaid School, Houston, TX
John Kotz, State University of New York, Oneonta, NY (retired)
Adele Mouakad, St. John's School, San Juan, PR
Jane Nagurney, Scranton Preparatory School, Scranton, PA
Ronald Ragsdale, University of Utah, Salt Lake City, UT (retired)

DIRECTIONS TO THE EXAMINER

This test is designed to be taken with an answer sheet on which the student records his or her responses. All answers are to be marked
on that sheet, not written in the booklet. Each student should be provided with an answer sheet and scratch paper, both of which must
be turned in with the test booklet at the end of the examination. Local Sections may use an answer sheet of their own choice.

The full examination consists of 60 multiple-choice questions representing a fairly wide range of difficulty. A periodic table and other
useful information are provided on page two of this exam booklet for student reference.

Only non-programmable calculators are to be used on the ACS local section exam. The use of a programmable calculator, cell phone,
or any other device that can access the internet or make copies or photographs during the exam is grounds for disqualification.

Suggested Time: 60 questions—110 minutes

DIRECTIONS TO THE EXAMINEE

DO NOT TURN THE PAGE UNTIL DIRECTED TO DO SO.

This is a multiple-choice examination with four choices for each question. There is only one correct or best answer to each question.
When you select your choice, blacken the corresponding space on the answer sheet with your pencil. Make a heavy full mark, but no
stray marks. If you decide to change your answer, be certain to erase your original answer completely.

Property of ACS USNCO – Not for use as USNCO Local Section Exam after March 31, 2015
Distributed by the American Chemical Society, 1155 16 th Street, N.W., Washington, DC 20036
All rights reserved. Printed in U.S.A.
 ABBREVIATIONS AND SYMBOLS CONSTANTS
amount of substance n Faraday constant F molar mass M
R = 8.314 J•mol– •K–
1 1
ampere A free energy G mole mol
R = 0.0821 L•atm•mol– •K–
1 1
atmosphere atm frequency  Planck’s constant h
F = 96,500 C•mol–
atomic mass unit u 1
gas constant R pressure P
Avogadro constant NA gram g rate constant k
F = 96,500 J•V •mol–
–1 1
Celsius temperature °C hour h reaction quotient Q
NA = 6.022  1023 mol–
1
centi– prefix c joule J second s
coulomb C kelvin K speed of light c h = 6.626  10–34 J•s
density d kilo– prefix k temperature, K T
c = 2.998  108 m•s–
1
electromotive force E liter L time t
energy of activation Ea measure of pressure mm Hg vapor pressure VP 0 °C = 273.15 K
enthalpy H milli– prefix m volt V 1 atm = 760 mm Hg
entropy S molal m volume V Specific heat capacity of H2O =
equilibrium constant K molar M 4.184 J•g–1•K–1

EQUATIONS

RT  H  1 
o
k  E  1 1 
E  Eo  ln Q ln K      constant ln  2   a   
nF  R  T   k1  R  T1 T2 

1 PERIODIC TABLE OF THE ELEMENTS 18

1A 8A
1 2
H 2 13 14 15 16 17 He
1.008 2A 3A 4A 5A 6A 7A 4.003

3 4 5 6 7 8 9 10
Li Be B C N O F Ne
6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S Cl Ar
22.99 24.31 3B 4B 5B 6B 7B 8B 8B 8B 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.61 74.92 78.96 79.90 83.80
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.3 138.9 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 (209) (210) (222)
87 88 89 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn (Uut) Fl (Uup) Lv (Uus) (Uuo)
(223) (226) (227) (261) (262) (263) (262) (265) (266) (281) (272) (285) (284) (289) (288) (293) (294) (294)

58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.1 140.9 144.2 (145) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.0 231.0 238.0 (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (262)

Page 2 Property of ACS USNCO – Not for use as USNCO Local Section Exam after March 31, 2015
 DIRECTIONS
 When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
 There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
 Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.

1. Benzene, C6H6, reacts with oxygen, O2, to form CO2 and 7. Which calcium compound is not appreciably more
H2O. How much O2 is required for the complete soluble in 0.1 M hydrochloric acid than it is in pure
combustion of 1.0 mol C6H6? water?
(A) 6.0 mol (B) 7.5 mol (A) Limestone, CaCO3
(C) 9.0 mol (D) 12 mol (B) Slaked lime, Ca(OH)2
(C) Gypsum, CaSO4 • 2 H2O
2. A 10.00 g sample of a soluble barium salt is treated with
an excess of sodium sulfate to precipitate 11.21 g BaSO4 (D) Hydroxyapatite, Ca5(OH)(PO4)3
(M = 233.4). Which barium salt is it?
8. Which metal reacts most vigorously with water at 25 °C?
(A) BaCl2 (M = 208.2)
(A) Na (B) Mg (C) K (D) Ca
(B) Ba(O2CH)2 (M = 227.3)
(C) Ba(NO3)2 (M = 261.3) 9. Each of the following forms a colored aqueous solution
EXCEPT
(D) BaBr2 (M = 297.1)
(A) Cr(NO3)3 (B) Co(NO3)2
3. What is the concentration of nitrate ion in a 425 mL
(C) Cu(NO3)2 (D) Zn(NO3)2
solution containing 32.0 g of Mg(NO3)2 (M = 148.3)?
(A) 0.216 M (B) 0.432 M 10. A student wishes to measure 37 mL of a liquid. Which
apparatus would be most suitable?
(C) 0.508 M (D) 1.02 M
(A) 50 mL graduated cylinder
4. The formula for terbium phosphate is TbPO4. The
(B) 50 mL volumetric pipet
formula for terbium sulfate is
(C) 50 mL beaker
(A) Tb2SO4 (B) TbSO4
(D) 50 mL Erlenmeyer flask
(C) Tb2(SO4)3 (D) Tb(SO4)2
11. A 2.0 mL sample of a colorless solution, when treated
5. A 25.0 mL sample of 0.15 M silver nitrate, AgNO3, is
with a few drops of 2 M hydrochloric acid, forms a white
reacted with a 3.58 g sample of calcium chloride, CaCl2
precipitate which dissolves when the solution is heated to
(M = 111.0). Which of the following statements is true?
boiling. The original solution could have contained
(A) Silver nitrate is the limiting reactant and calcium which of the following cations?
nitrate precipitates. I. 0.1 M Ag+ II. 0.1 M Pb2+
(B) Silver nitrate is the limiting reactant and silver (A) I only (B) II only
chloride precipitates.
(C) Either I or II (D) Neither I nor II
(C) Calcium chloride is the limiting reactant and calcium
nitrate precipitates. 12. Which compound has the lowest normal boiling point?
(D) Calcium chloride is the limiting reactant and silver (A) HF (B) HCl (C) HBr (D) HI
chloride precipitates.
13. Which of the following would lead to an increase in the
6. Which aqueous solution exhibits the largest freezing vapor pressure of a liquid?
point depression? I. Increasing the temperature II. Adding a nonvolatile
(A) 1.0 m KBr (B) 0.75 m C6H12O6 solute
(A) I only (B) II only
(C) 0.5 m MgCl2 (D) 0.25 m Ga2(SO4)3
(C) Both I and II (D) Neither I nor II

Property of ACS USNCO – Not for use as USNCO Local Section Exam after March 31, 2015 Page 3
 14. A student is separating CHCl3 (bp = 61 °C) from 19. The cubic unit cell of a perovskite structure containing
CHCl2CHCl2 (bp = 146 °C) by distillation. She has just atoms of types A, B, and C is illustrated below. What is
begun to collect the first distillate in the receiving flask. the empirical formula of this substance?
At what position in the apparatus will the temperature be
61 °C?

= A

= B

= C

(A) ABC (B) ABC3 (C) AB4C6 (D) AB8C12

20. The enthalpy change under standard conditions for which

(A) A (B) B (C) C (D) D of the reactions below would be equal to the ∆H°f of
NaOH(s)?
15. How is the enthalpy of vaporization of a substance related (A) Na(s) + H2O(l)  NaOH(s) + 1/2 H2(g)
to its enthalpy of fusion?
(B) Na(s) + 1/2 O2(g) + 1/2 H2(g)  NaOH(s)
(A) The enthalpy of vaporization is greater than the
enthalpy of fusion. (C) Na(s) + 1/2 H2O2(l)  NaOH(s)
(B) The enthalpy of vaporization is equal to the enthalpy (D) Na+(aq) + OH–(aq)  NaOH(s)
of fusion.
(C) The enthalpy of vaporization is less than the 21. A 37.5 g piece of gold at 83.0 °C is added to 100. g H2O
enthalpy of fusion. at 22.0 °C in a well-insulated cup. What is the
temperature after the system comes to equilibrium? (The
(D) There is no general relationship between a specific heat capacity of Au is 0.129 J•g–1•K–1)
substance's enthalpy of vaporization and enthalpy of
fusion. (A) 22.7 °C (B) 23.0 °C
(C) 25.0 °C (D) 52.5 °C
16. A 3.0 L sample of helium gas is stored in a rigid, sealed
container at 25 °C and 1.0 atm pressure. The temperature 22. Which of these reactions has ∆S° > 0?
is increased to 125 °C. What is the new pressure of the
gas? (A) S8(l)  S8(s, monoclinic)

(A) 0.20 atm (B) 0.75 atm (B) H2(g) + O2(g)  H2O2(aq)
(C) 1.3 atm (D) 5.0 atm (C) H2(g) + 2 Ag+(aq)  2 H+(aq) + 2 Ag(s)
(D) PCl5(g)  PCl3(g) + Cl2(g)
17. Diamond is an example of what kind of solid?
(A) Ionic (B) Metallic 23. Given the enthalpy changes:
(C) Molecular (D) Network covalent A+BC ∆H = –35 kJ•mol–1
A+DE+F ∆H = +20 kJ•mol–1
18. Which of the following is a mathematical statement of the FC+E ∆H = +15 kJ•mol–1
first law of thermodynamics?
What is ∆H for the reaction 2A + B + D → 2 F?
(A) ∆V = (nR/P)∆T (B) ∆E = q + w
(A) 0 kJ•mol–1 (B) –30 kJ•mol–1
(C) ∆H = ∆E + P∆V (D) ∆G = ∆H – T∆S
(C) –40 kJ•mol–1 (D) –70 kJ•mol–1

Page 4 Property of ACS USNCO – Not for use as USNCO Local Section Exam after March 31, 2015
 24. The Ka of phosphoric acid, H3PO4, is 7.6  10–3 at 25 °C. 31. When 0.10 M solutions of ammonium acetate, barium
For the reaction acetate, and sodium acetate are ranked from least basic to
most basic, what is the correct ordering?
H3PO4(aq) H2PO4–(aq) + H+(aq)
(A) NH4C2H3O2 < NaC2H3O2 < Ba(C2H3O2)2
∆H° = –14.2 kJ/mol. What is the Ka of H3PO4 at 60 °C?
(B) Ba(C2H3O2)2 < NH4C2H3O2 < NaC2H3O2
(A) 4.2  10–3 (B) 6.8  10–3
(C) NaC2H3O2 < Ba(C2H3O2)2 < NH4C2H3O2
(C) 8.5  10–3 (D) 1.8  10–2
(D) NaC2H3O2 < NH4C2H3O2 < Ba(C2H3O2)2
25. For the reaction
32. What is the solubility of MgF2 (Ksp = 6.8  10–9) in pure
5 O2(g) + 4 NH3(g)  4 NO(g) + 6 H2O(g) water?
if NH3 is being consumed at a rate of 0.50 M•s–1, at what (A) 6.8  10–9 mol•L–1 (B) 5.8  10–5 mol•L–1
rate is H2O being formed?
(C) 8.2  10–5 mol•L–1 (D) 1.2  10–3 mol•L–1
(A) 0.33 M•s–1 (B) 0.50 M•s–1
(C) 0.75 M•s–1 (D) 3.0 M•s–1 33. What is the ratio Kc/Kp for the following reaction at 723 °C?
O2(g) + 3 UO2Cl2(g) U3O8(s) + 3 Cl2(g)
26. The rate of decomposition of hydrogen peroxide is first
order in H2O2. At [H2O2] = 0.150 M, the decomposition (A) 0.0122 (B) 1.00 (C) 59.4 (D) 81.8
rate was measured to be 4.83 × 10–6 M•s–1. What is the
rate constant for the reaction? 34. What is [H3O+] in a solution formed by dissolving 1.00 g
NH4Cl (M = 53.5) in 30.0 mL of 3.00 M NH3
(A) 2.15 × 10–4 s–1 (B) 3.22 × 10–5 s–1
(Kb = 1.8  10–5)?
(C) 4.83 × 10–6 s–1 (D) 7.25 × 10–7 s–1
(A) 2.7  10–9 M (B) 5.5  10–10 M
27. In the reaction A  B, a plot of 1/[A] vs. t is found to be (C) 1.2  10–10 M (D) 1.4  10–12 M
linear. What is the reaction order in A?
35. Copper(II) hydroxide, Cu(OH)2, has Ksp = 2.2  10–20.
(A) Zeroth order (B) First order
For the reaction below, Keq = 4.0  10–7. What is Kf for
(C) Second order (D) Third order Cu(NH3)42+?
Cu(OH)2(s) + 4 NH3(aq) Cu(NH3)42+(aq) + 2 OH–(aq)
28. The half-life of iodine-131 is 8.02 days. How long will it
take for 80.% of the sample to decay? (A) 8.8  10–27 (B) 5.5  10–14
(A) 2.6 days (B) 13 days (C) 1.8  1013 (D) 1.1  1026
(C) 19 days (D) 32 days
36. A 0.100 M aqueous solution of H2SeO3 is titrated with 1.000
29. For the reaction M NaOH solution. At the point marked with a circle on the
titration curve, which species represent at least 10% of the
Cl2(aq) + 2 Br–(aq)  Br2(aq) + 2 Cl–(aq) total selenium in solution?
which of the following could be used to monitor the rate?
I. pH meter II. Spectrophotometer
(A) I only (B) II only
(C) Either I or II (D) Neither I nor II

30. For a reversible exothermic reaction, what is the effect of

increasing temperature on the equilibrium constant (Keq)
and on the forward rate constant (kf)?
(A) Keq and kf both increase
(B) Keq and kf both decrease
(C) Keq increases and kf decreases
(A) H2SeO3 only (B) Both H2SeO3 and HSeO3–
(D) Keq decreases and kf increases
(C) HSeO3– only (D) Both HSeO3– and SeO32–

Property of ACS USNCO – Not for use as USNCO Local Section Exam after March 31, 2015 Page 5
 37. What is the oxidation number of C in formaldehyde, CH2O? 43. What is the value of the quantum number l for a 5p
orbital?
(A) –2 (B) 0 (C) +2 (D) +4
(A) 1 (B) 2 (C) 3 (D) 4
38. In a galvanic cell in which the following spontaneous
reaction takes place, what process occurs at the cathode? 44. Which element has chemical properties most similar to
4+ 3+ 3+ those of P?
3 Ce (aq) + Cr(s)  3 Ce (aq) + Cr (aq)
(A) N (B) Al (C) S (D) As
(A) Reduction of Cr3+(aq)
(B) Reduction of Ce4+(aq) 45. Which metal has the lowest melting point?
(C) Oxidation of Cr(s) (A) Li (B) Na (C) K (D) Rb
(D) Oxidation of Ce3+(aq) 46. Which gas-phase atom has no unpaired electrons in its
ground state?
39. Which two half reactions, when coupled, will make a
galvanic cell that will produce the largest voltage under (A) Li (B) Be (C) B (D) C
standard conditions?
47. Which halogen atom has the greatest electron affinity?
I. Cu2+(aq) + 2 e–  Cu(s) E = +0.34 V
(A) F (B) Cl (C) Br (D) I
II. Pb2+(aq) + 2 e–  Pb(s) E = –0.13 V
III. Ag+(aq) + e–  Ag(s) E = +0.80 V 48. Which electronic transition in atomic hydrogen
3+
IV. Al (aq) + 3 e –
 Al(s) E = –1.66 V corresponds to the emission of visible light?

(A) I and II (B) I and IV (A) n = 5  n = 2 (B) n = 1  n = 2

(C) II and IV (D) III and IV (C) n = 3  n = 4 (D) n = 3  n = 1

40. An electrolysis cell is operated for 3000 s using a current 49. Which species are linear?
of 1.50 A. From which 1.0 M solution will the greatest I. NO2+ II. I3–
mass of metal be deposited?
(A) I only (B) II only
(A) TlNO3 (B) Pb(NO3)2
(C) Both I and II (D) Neither I nor II
(C) ZnCl2 (D) In(NO3)3
50. The peroxymonosulfate anion, HSO5–, has
41. The reduction of O2 to H2O in acidic solution has a
standard reduction potential of +1.23 V. What is the (A) five sulfur-oxygen bonds and no oxygen-oxygen
effect on the half-cell potential at 25 °C when the pH of bonds.
the solution is increased by one unit? (B) four sulfur-oxygen bonds and one oxygen-oxygen
+ –
O2(g) + 4 H (aq) + 4 e  2 H2O(l) bond.
(A) The half-cell potential decreases by 59 mV. (C) three sulfur-oxygen bonds and two oxygen-oxygen
bonds.
(B) The half-cell potential increases by 59 mV.
(D) one sulfur-oxygen bond and four oxygen-oxygen
(C) The half-cell potential decreases by 236 mV. bonds.
(D) The half-cell potential increases by 236 mV.
51. Which statement about bonding is correct?
42. Given the two standard reduction potentials below, what (A) A  bond has cylindrical symmetry about the
is the Ksp of Ag2CrO4 at 25 °C? bonding axis.
Ag2CrO4(s) + 2 e–  2 Ag(s) + CrO42–(aq) (B) A π bond is twice as strong as a  bond.
Eº = +0.446 V
(C) A double bond consists of two π bonds.
Ag+(aq) + e–  Ag(s) Eº = +0.799 V
(D) A π bond results from the sideways overlap of
(A) 8.64  1011 (B) 1.08  10–6 hybridized orbitals.
(C) 1.16  10–12 (D) 1.11  10–39

Page 6 Property of ACS USNCO – Not for use as USNCO Local Section Exam after March 31, 2015
 52. What is the geometry of the chlorate ion, ClO3–?
(A) trigonal planar (B) trigonal pyramidal
(C) T-shaped (D) zigzag

53. What is the bond order in NO?

(A) 1.0 (B) 1.5 (C) 2.0 (D) 2.5

54. In the Lewis structure of ozone, O3, what is the formal

charge on the central oxygen?
(A) 2– (B) 1– (C) 0 (D) 1+

55. Hydrogenation of an alkene converts it to an

(A) alkane. (B) alkyne.
(C) alcohol. (D) aldehyde.

56. What is the relationship between the two compounds

below?
CH3CH2CH(CH3)CH2CH3 CH3CH2CH2CH(CH3)CH3

(A) Identical (B) Stereoisomers

(C) Geometric isomers (D) Structural isomers

57. Which class of organic compounds does NOT contain

oxygen?
(A) Alcohol (B) Amide
(C) Amine (D) Ketone

58. Compared to ionic compounds of similar molar mass,

hydrocarbons typically have
I. Higher water solubility II. Higher melting points

(A) I only (B) II only

(C) Both I and II (D) Neither I nor II

59. Which of the following compounds could contain exactly

one triple bond?
(A) C5H10 (B) C5H12 (C) C6H10 (D) C6H12

60. Which of the following is NOT classified as a

biopolymer?
(A) Collagen (B) Glucose
(C) Cellulose (D) Chitin

END OF TEST

Property of ACS USNCO – Not for use as USNCO Local Section Exam after March 31, 2015 Page 7
 Olympiad 2015
USNCO Local Section Exam
KEY

Number Answer Number Answer

1. B 31. A
2. A 32. D
3. D 33. D
4. C 34. C
5. B 35. C
6. A 36. C
7. C 37. B
8. C 38. B
9. D 39. D
10. A 40. A
11. B 41. A
12. B 42. C
13. A 43. A
14. B 44. D
15. A 45. D
16. C 46. B
17. D 47. B
18. B 48. A
19. B 49. C
20. B 50. B
21. A 51. A
22. D 52. B
23. B 53. D
24. A 54. D
25. C 55. A
26. B 56. D
27. C 57. C
28. C 58. D
29. B 59. C
30. D 60. B