Scribd Logo
Upload

Welcome to Scribd!

  • 141 views

    Appendices D: Problems: Etoh

    Uploaded by

    Jensen Myles Collas
    1) The ethanol-ethyl acetate mixture forms a parabolic temperature-composition curve. For a 0.8 mole fraction ethanol liquid, the first vapor will have 0.7562 mole fraction ethanol and the last liquid drop will be pure ethanol. 2) The benzene-toluene mixture forms a biconvex temperature-composition curve. For a 0.5-0.5 mole fraction benzene-toluene liquid, the first vapor bubble will appear at 92.091°C with a composition of 0.713 mole fraction benzene.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Appendices D: Problems: Etoh

    Uploaded by

    Jensen Myles Collas
    141 views4 pages
    1) The ethanol-ethyl acetate mixture forms a parabolic temperature-composition curve. For a 0.8 mole fraction ethanol liquid, the first vapor will have 0.7562 mole fraction ethanol and the last liquid drop will be pure ethanol. 2) The benzene-toluene mixture forms a biconvex temperature-composition curve. For a 0.5-0.5 mole fraction benzene-toluene liquid, the first vapor bubble will appear at 92.091°C with a composition of 0.713 mole fraction benzene.

    Original Title

    Appendices-Dexpt-3

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    1) The ethanol-ethyl acetate mixture forms a parabolic temperature-composition curve. For a 0.8 mole fraction ethanol liquid, the first vapor will have 0.7562 mole fraction ethanol and the last liquid drop will be pure ethanol. 2) The benzene-toluene mixture forms a biconvex temperature-composition curve. For a 0.5-0.5 mole fraction benzene-toluene liquid, the first vapor bubble will appear at 92.091°C with a composition of 0.713 mole fraction benzene.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    141 views4 pages

    Appendices D: Problems: Etoh

    Uploaded by

    Jensen Myles Collas
    1) The ethanol-ethyl acetate mixture forms a parabolic temperature-composition curve. For a 0.8 mole fraction ethanol liquid, the first vapor will have 0.7562 mole fraction ethanol and the last liquid drop will be pure ethanol. 2) The benzene-toluene mixture forms a biconvex temperature-composition curve. For a 0.5-0.5 mole fraction benzene-toluene liquid, the first vapor bubble will appear at 92.091°C with a composition of 0.713 mole fraction benzene.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 4

    Appendices D: Problems

    1). From the data given in the following table, construct a complete temperature-composition

    diagram for the system ethanol-ethyl acetate for 1.013 bar. A solution containing 0.80 mole

    fraction ethanol is distilled completely at 1.013 bar. (a) What type of a curve is the mixture? (b)

    What is the composition of the first vapour to come off? (c) What is the composition of the last

    drop of liquid to evaporate?

    Given:

    BP,°C 77.15 76.7 75.0 72.6 71.8 71.6 72.0 72.8 74.2 76.4 77.7 78.3

    XEtOH, 0 0.025 0.1 0.24 0.36 0.462 0.563 0.71 0.833 0.942 0.982 1.0

    (L)

    YEtOH, 0 0.07 0.164 0.295 0.398 0.462 0.507 0.6 0.735 0.88 0.965 1.0

    (V)

    Required: a) Type of Curve of the mixture

    b) Composition of the first vapor to come off

    c) Composition of the last drop of liquid to evaporate

    Solution

    80

    78

    76
    BOILING POINT (°C)

    74
    Liquid
    Vapor
    72

    70

    68
    0 0.2 0.4 0.6 0.8 1 1.2
    Mole Fraction Ethanol
    a) The Temperature-composition diagram of the mixture is parabolic in shape.

    b) The liquid phase of with 0.8 mole fraction will start boiling at the temperature 73.966°C

    and equilibrium vapor to that temperature has a mole fraction of 0.7562.

    c) Since all of the ethyl acetate will be separated eventually from the mixture as the

    temperature increases, the composition of the last drop will be pure ethanol.

    2) The vapor pressures of toluene and benzene have the following values in the temperature

    range between their boiling points at 1 bar. (a) Calculate the compositions of the vapor and liquid

    phases at each temperature and plot the boiling point diagram. (b) What type of a curve is the

    mixture? (c) If a solution containing 0.5 mole fraction benzene and 0.5 mole fraction of toluene is

    heated, at hat temperature will the first bubble of vapor appear and what will be its composition?

    Given:

    BP, °C 79.4 88 94 100 110

    P°benzene, bar 1.00 1.285 1.526 1.801

    P°toluene, bar 0.508 0.616 0.742 1.00

    Required: a) Compositions of the vapor and liquid phases at each temperature and plot the

    boiling point diagram.

    b) Type of curve of the mixture


    c) The temperature and composition in which the first bubble of vapour appears after

    a solution containing 0.5 mole fraction benzene and 0.5 mole fraction toluene is heated.

    Solution:

    a)

    Let X B=mole fraction of Benzene X T =mole fraction of Benzene

    X B + X T =1 X T =1−X B

    At 79.4°C At 88°C

    X B ( P° B ) + X T ( P ° T )=PT X B ( P° B ) + X T ( P ° T )=Patm

    X B ( P° B ) +(1−X B) ( P ° T ) =P T X B ( P° B ) +(1−X B) ( P ° T ) =P atm

    XB¿ XB¿

    X B=1 1.285 ( X¯B ) +0.508 −0.508


    ¯ ( X¯B ) =1 ¯¿

    X B (P ° B) 1.285 ( X¯B )−0.508 ( X¯B )=1 −0.508


    ¯ ¯¿
    Y B= =1 ¿ ¿ Y B =1
    PT
    ¯¿
    0.777 ¯¿ ¿
    0.777 ¯¿ (X B )=0.492 ¿¿
    0.777 ¯¿ ¿

    X B=0.6332

    X B (P ° B)
    Y B= =0.6332 ¿ ¿ Y B =0.8127
    PT

    At 94°C At 100°C

    X B ( P° B ) + X T ( P ° T )=Patm X B ( P° B ) + X T ( P ° T )=Patm

    X B ( P° B ) +(1−X B) ( P ° T ) =P atm X B ( P° B ) +(1−X B) ( P ° T ) =P atm

    XB¿ XB¿

    1.526 ( X¯B ) +0. 616 −0.


    ¯ 616 ( X¯B )=1 ¯¿ 1. 801 ( X¯B ) + 0.742 −0.
    ¯ 742 ( X¯B ) =1 ¯¿

    1. 526 (X¯B )−0. 616 (X¯B )=1 −0


    ¯ .616 ¯
    ¿ 1. 801 (X¯B)−0.742 ( X¯B )=1 −0.
    ¯ 742 ¯¿

    ¯¿
    1.059 ¯¿ ¿
    1.059 ¯¿ ( X B )=0.258 ¿¿
    1.059 ¯¿ ¿
    ¯¿ X B=0.2436
    0 .91 ¯¿ ¿
    ¯
    0. 91 ¿ ( X B)=0. 384 ¿¿
    0. .91 ¯¿ ¿ X B (P ° B)
    Y B= =0. 2436 ¿ ¿ Y B =0. 4387
    PT
    X B=0.4220

    X B (P ° B)
    Y B= =0. 4420 ¿ ¿ Y B =0. 6745
    PT

    At 79.4°C
    TEMPERATURE-COMPOSITION DIAGRAM
    X B ( P° B ) + X T ( P ° T )=PT 120
    Temperate,°C

    100
    X B ( P° B ) +(1−X B) ( P ° T ) =P T 80
    60 Liquid
    40 Vapor
    X B ( 0 ) + ( 1− X B ) ¿
    20
    0
    X B=0 0 0.2 0.4 0.6 0.8 1 1.2

    Mole Fraction Benzene


    0( P ° B )
    Y B= =1¿ ¿ Y B =0
    PT

    b) The temperature-composition diagram is biconvex in shape

    c)

    The temperature will be 92.091°C and the


    composition will be YB=0.713

    You might also like