Safety Data Sheet Mikro Chlor
Safety Data Sheet Mikro Chlor
Safety Data Sheet Mikro Chlor
1907/2006
Mikro Chlor
1.2 Relevant identified uses of the substance or mixture and uses advised against
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Hazard pictograms :
Hazard Statements : H314 Causes severe skin burns and eye damage.
H411 Toxic to aquatic life with long lasting effects.
3.2 Mixtures
Hazardous components
sodium metasilicate 6834-92-0 Skin corrosion Category 1B; H314 >= 5 - < 10
229-912-9 Specific target organ toxicity - single
01-2119449811-37 exposure Category 3; H335
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Alcohols, C13-15, 157627-86-6 Acute toxicity Category 4; H302 >= 1 - < 2.5
branched and linear, Skin irritation Category 2; H315
ethoxylated Serious eye damage Category 1; H318
Acute aquatic toxicity Category 1; H400
For the full text of the H-Statements mentioned in this Section, see Section 16.
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for
at least 15 minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Get medical attention immediately.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes.
Use a mild soap if available. Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention
immediately.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give
anything by mouth to an unconscious person. Get medical
attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
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Sulphur oxides
Oxides of phosphorus
Advice for non-emergency : Ensure adequate ventilation. Keep people away from and upwind
personnel of spill/leak. Avoid inhalation, ingestion and contact with skin and
eyes. When workers are facing concentrations above the
exposure limit they must use appropriate certified respirators.
Ensure clean-up is conducted by trained personnel only. Refer to
protective measures listed in sections 7 and 8.
Advice for emergency : If specialised clothing is required to deal with the spillage, take
responders note of any information in Section 8 on suitable and unsuitable
materials.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods for cleaning up : Sweep up and shovel into suitable containers for disposal.
Advice on safe handling : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not
breathe dust/fume/gas/mist/vapours/spray. Use only with
adequate ventilation. Wash hands thoroughly after handling.
Mixing this product with acid or ammonia releases chlorine gas.
Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Remove and wash contaminated clothing before re-use.
Wash face, hands and any exposed skin thoroughly after
handling. Provide suitable facilities for quick drenching or flushing
of the eyes and body in case of contact or splash hazard.
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Requirements for storage : Keep out of reach of children. Keep container tightly closed. Store
areas and containers in suitable labeled containers.
Storage temperature : 0 °C to 40 °C
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nose and mouth during breathing and is therefore available for deposition in
the respiratory tract. Respirable dust approximates to the fraction that
penetrates to the gas exchange region of the lung. Fuller definitions and
explanatory material are given in MDHS14/3.
47 Where dusts contain components that have their own assigned WEL, all the
relevant limits should be complied with.
2 Where no specific short-term exposure limit is listed, a figure three times the
long-term exposure should be used
DNEL
Sodium Carbonate : End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term local effects
Value: 10 mg/m3
PNEC
sodium metasilicate : Fresh water
Value: 7.5 mg/l
Marine water
Value: 1 mg/l
Intermittent use/release
Value: 7.5 mg/l
Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Remove and wash contaminated clothing before re-use.
Wash face, hands and any exposed skin thoroughly after
handling. Provide suitable facilities for quick drenching or flushing
of the eyes and body in case of contact or splash hazard.
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Skin and body protection : Personal protective equipment comprising: suitable protective
(EN 14605) gloves, safety goggles and protective clothing
Respiratory protection (EN : When respiratory risks cannot be avoided or sufficiently limited by
143, 14387) technical means of collective protection or by measures, methods
or procedures of work organization, consider the use of certified
respiratory protection equipment meeting EU requirements
(89/656/EEC, 89/686/EEC), or equivalent, with filter type:P
Appearance : powder
Colour : white
Odour : Chlorine
pH : 10.1 - 10.5, 1 %
Flash point : Not applicable.
Odour Threshold : Not applicable and/or not determined for the mixture
Melting point/freezing point : Not applicable and/or not determined for the mixture
Initial boiling point and : Not applicable and/or not determined for the mixture
boiling range
Evaporation rate : Not applicable and/or not determined for the mixture
Flammability (solid, gas) : Not applicable and/or not determined for the mixture
Upper explosion limit : Not applicable and/or not determined for the mixture
Lower explosion limit : Not applicable and/or not determined for the mixture
Vapour pressure : Not applicable and/or not determined for the mixture
Relative vapour density : Not applicable and/or not determined for the mixture
Relative density : 0.95 - 1.15
Water solubility : soluble
Solubility in other solvents : Not applicable and/or not determined for the mixture
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Partition coefficient: n- : Not applicable and/or not determined for the mixture
octanol/water
Auto-ignition temperature : Not applicable and/or not determined for the mixture
Thermal decomposition : Not applicable and/or not determined for the mixture
Viscosity, kinematic : Not applicable and/or not determined for the mixture
Explosive properties : Not applicable and/or not determined for the mixture
Oxidizing properties : Yes
10.1 Reactivity
None known.
None known.
Product
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Components
sodium metasilicate
LD50 rat: 500 mg/kg
precipitated silica
LD50 rat: > 20,000 mg/kg
Components
precipitated silica
LD50 rabbit: > 5,000 mg/kg
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Chronic Exposure : Health injuries are not known or expected under normal use.
12.1 Ecotoxicity
Product
Toxicity to fish : no data available
Toxicity to daphnia and other : no data available
aquatic invertebrates
Toxicity to algae : no data available
Components
Toxicity to fish : Sodium Carbonate
96 h LC50 Lepomis macrochirus (Bluegill sunfish): 300 mg/l
sodium metasilicate
96 h LC50 Fish: 210 mg/l
Components
Toxicity to daphnia and other : Sodium Carbonate
aquatic invertebrates 48 h EC50 Ceriodaphnia (water flea): 213.5 mg/l
Product
no data available
Components
Biodegradability : Sodium Carbonate
Result: Not applicable - inorganic
sodium metasilicate
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precipitated silica
Result: Not applicable - inorganic
no data available
no data available
Product
Assessment : This substance/mixture contains no components considered to be
either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.
no data available
Dispose of in accordance with the European Directives on waste and hazardous waste.Waste
codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Product : The product should not be allowed to enter drains, water courses
or the soil. Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in
compliance with local regulations. Dispose of wastes in an
approved waste disposal facility.
Guidance for Waste Code : Inorganic wastes containing dangerous substances. If this product
selection is used in any further processes, the final user must redefine and
assign the most appropriate European Waste Catalogue Code. It
is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in
compliance with applicable European (EU Directive 2008/98/EC)
and local regulations.
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The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
National Regulations
Other regulations : The Chemicals (Hazard Information and Packaging for Supply)
Regulations.
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Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1
thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth
REVISED INFORMATION: Significant changes to regulatory or health information for this revision
is indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Product category : PC35 Washing and cleaning products (including solvent based
products)
Environmental release : ERC8a Wide dispersive indoor use of processing aids in open
category systems
Skin Protection : No
Respiratory Protection : No
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Respiratory Protection : No
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