Safety Data Sheet: Section 1. Identification
Safety Data Sheet: Section 1. Identification
Safety Data Sheet: Section 1. Identification
Section 1. Identification
GHS product identifier : Primer P 400
Product code : 135504
Relevant identified uses of the substance or mixture and uses advised against
Surface treatment products
ethylbenzene ≤3 100-41-4
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
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Primer P 400
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Primer P 400
Specific hazards arising : Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
containment and cleaning up explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Date of issue/Date of revision : 05.06.2020 Date of previous issue : No previous validation Version :1 6/16
Primer P 400
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
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Primer P 400
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
toluene - 3 -
xylene - 3 -
ethylbenzene - 2B -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
toluene Category 3 - Narcotic effects
xylene Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
toluene Category 2 - -
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Primer P 400
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Juvenile (Fledgling, Hatchling,
Weanling)
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Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days
xylene Acute EC50 90 mg/l Fresh water Crustaceans - Cypris subglobosa 48 hours
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 6.53 mg/l Marine water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2.93 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
toluene 2.73 90 low
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
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Primer P 400
Packing group II II II II II
Environmental No. No. No. No. No.
hazards
Additional information
DOT Classification : Reportable quantity 1149.4 lbs / 521.84 kg [158.45 gal / 599.82 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
Limited quantity Yes.
Packaging instruction Exceptions: 150. Non-bulk: 202. Bulk: 242.
Quantity limitation Passenger aircraft/rail: 5 L. Cargo aircraft: 60 L.
Special provisions IB2, T4, TP1
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Explosive Limit and Limited Quantity Index 1
Passenger Carrying Road or Rail Index 5
IMDG : Emergency schedules F-E, S-D
IATA : Quantity limitation Passenger and Cargo Aircraft: 5 L. Packaging instructions: 353.
Cargo Aircraft Only: 60 L. Packaging instructions: 364. Limited Quantities - Passenger
Aircraft: 1 L. Packaging instructions: Y341.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
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Primer P 400
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ethylbenzene 100-41-4 ≤3
Supplier notification toluene 108-88-3 ≥75 - ≤90
ethylbenzene 100-41-4 ≤3
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: TOLUENE; METHYLBENZENE; XYLENE;
DIMETHYLBENZENE; ETHYL BENZENE; ETHYLBENZENE
New York : The following components are listed: Toluene; Xylene mixed; Ethylbenzene
New Jersey : The following components are listed: TOLUENE; BENZENE, METHYL-; XYLENES;
BENZENE, DIMETHYL-; ETHYL BENZENE; BENZENE, ETHYL-
Pennsylvania : The following components are listed: BENZENE, METHYL-; BENZENE, DIMETHYL-;
BENZENE, ETHYL-
California Prop. 65
WARNING: This product can expose you to chemicals including Ethylbenzene, which is known to the State of
California to cause cancer, and Toluene, which is known to the State of California to cause birth defects or other
reproductive harm. For more information go to www.P65Warnings.ca.gov.
Ethylbenzene Yes. -
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
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Primer P 400
Flammability 3
Physical hazards 0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
3 Flammability
Health 2 0 Instability
Special hazards
Date of issue/Date of revision : 05.06.2020 Date of previous issue : No previous validation Version :1 15/16
Primer P 400
Date of issue/Date of revision : 05.06.2020 Date of previous issue : No previous validation Version :1 16/16