Quiz – Ionic Equilibrium FIITJEE
1. Which of the following is most soluble?
(A) Bi2 S3 K sp 1 10
70
(B) MnS K sp 7 10
16
(C) CuS K sp 8 10
37
(D) Ag S K
2 sp 6 1051
2. If the equilibrium constant of BOH B OH at 25oC is 2.5 10 6 , then equilibrium constant for
BOH + H B H 2O at the same temeperature is
9 5 8 6
(A) 4.0 10 (B) 4.0 10 (C) 2.5 10 (D) 2.5 10
3. The pH of a solution of weak base at half neutralization with strong acid is 8. Kb for the base is
4 6 8
(A) 1.0 10 (B) 1.0 10 (C) 1.0 10 (D) None of these
6
4. The ionisation constant of an acid base indicator (a werak acid) is 1.0 10 . The ionised form of the indicaor
is red and unionised form is blue. The pH change required to alter the colour of indicaor from 80% red to 20%
red
(A) 0.80 (B) 1.20 (C) 1.40 (D) 2.00
5. K sp of Ca OH 2 is 4.0 10 6 . At what minimum pH, Mg 2 ions starts precipitating 0.01 Ca OH 2
(A) 2 log 2 (B) 2 log 2 (C) 12 log 2 (D) 12 log 2
5
6. A weak acid HX has the dissociation constant 1 10 M . It forms a salt NaX on reaction with alkali. The
percentage hydrolysis of 0.1 M solutions of NaX is
(A) 0.0001% (B) 0.01% (C) 0.1 % (D) 0.15%
5
7. An acid-base indicator has a K a 3.0 10 . The acid form of the indicator is red and the basic form is blue.
Then
(A) pH is 4.05 when indicator is 75 % red (B) pH is 5.00 when indicator is 75 % blue
(C) Both (A) and (B) are correct (D) None of these
8. When 0.002 mol of acid is added to 250 ml of a buffer solution, pH decrease by 0.02 units. The buffer capacity
of the system is
(A) 0.1 (B) 0.2 (C) 0.3 (D) 0.4
9. For a sparingly soluble salt Ap Bq , the relationship of its solublity product LS with its solublity (S) is
pq
p q p q pq p q
(A) LS S p pqq (B) LS S pqq p (C) LS S
pq
p pqq (D) LS S
10. Ag NH 3 Ag NH 3 , K1 3.5 10 3
Ag NH 3 NH 3 Ag NH 3 2 , K 2 1.7 103 . Then the formation constant of
Ag NH 3 2 is
6 6 9 9
(A) 6.08 10 (B) 6.08 10 (C) 6.08 10 (D) 6.08 10
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 - 3105005, 4754800, Fax : 0120 - 4271214
ANSWERS
Quiz – Ionic Equilibrium
1. B
2. C
3. B
4. B
5. C
6. B
7. C
8. D
9. A
10. A
FIITJEE Ltd., B – 4, Sec – 16, Noida (U.P), 201301, Ph : 0120 - 3105005, 4754800, Fax : 0120 - 4271214
