MSDS - Strata Bond HA Comp B - 011116 - EN

STRATA BOND HA, COMPONENT B
Safety Data Sheet according to Regulation (EC) 2015/830 amending Regulation (EC) No 1907/2006 (REACH)
Prepared on: 18.07.2016
Revision date: 01.11.2016
Version no: 1.00-EN
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier:
Substance name: Strata Bond HA, component B
Index number: Not applicable (mixture)
Synonyms: Not applicable
CAS number: Not applicable (mixture)
EC number: Not applicable (mixture)
Registration number: excluded from registration (polymer).
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses:
Isocyanate component of the polyurethane system, fast reacting two-component injection resin. Strata-Bond HA can be used for the
rock consolidation, water stopping, gas sealing.
Uses advised against:
Any other uses than those listed should be consulted with the Supplier.
1.3. Details of the Supplier of the safety data sheet
Supplier:
DSI Schaum Chemie sp. z o.o. (limited liability company)
43-190 Mikołów, Poland
Podleska 72 Str.
Tel.: +48 32 355 90 81
Fax. +48 32 355 90 89
Email address of the person responsible for the MSDS: [email protected]
1.4. Emergency telephone number

(Poland) Manufacturer: +48 32 355 90 81, Monday – Friday: 7:30 – 15:30.
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Skin Irrit. 2; H315
Skin Sens 1; H317
Eye Irrit. 2; H319
Acute Tox. 4; H332
Resp. Sens 1; H334
STOT SE 3; H335
Carc. 2; H351
STOT RE 2; H373
Additional information:
For full text of Hazard- and EU Hazard-statements: see SECTION 16
2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008 [CLP]
DSI Schaum Chemie, sp. z o.o. Phone +48 32 355 90 81 Version 1.0-EN
ul. Podleska 72, Fax +48 32 355 90 89 Revision date 01.11.2016
43-190, Mikołów E-mail [email protected] Page 1
Poland
Hazard pictograms
Signal word:
Danger
Hazard statements:
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H332 – Harmful if inhaled.
H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H373 - May cause damage to organs repeated exposure.
Precautionary statements:
P260 – Do not breathe dust/fume/gas/mist/vapours/spray.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P284 - In case of inadequate ventilation wear respiratory protection.
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P353 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P308 + P313 - IF exposed or concerned: Get medical advice/attention. /international regulation.
Supplemental Hazard information:
EUH204 – Contains isocyanates. May produce an allergic reaction.
2.3. Other hazards

The substance does not meet the criteria for persistent, bioaccumulation and toxicity (PBT), or the criteria for Very Persistent and
Very Bioaccumulative (vPvB) in accordance with Annex XIII of 1907/2006/EC.
Additional information:
People with allergic anamneses (e.g., asthma, chronic bronchitis) should not work with this product.
Symptoms of adverse effects on the respiratory system may appear after a few hours. The main threat to the respiratory tract is dust,
vapours and aerosols.
SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Classification according to
Name %
CAS No EC No Regulation (EC) No
REACH Registration number [weight]
1278/2008 (CLP)
Skin Irrit. 2; H315
Skin Sens 1; H317
polymeric MDI
Eye Irrit. 2; H319
excluded from registration (polymer) 80-100 9016-87-9 Not applicable
Acute Tox. 4; H332
Resp. Sens 1; H334
STOT SE 3; H335
Poland
Carc. 2; H351
STOT RE 2; H373
Additional information: For full text of H-statements: see SECTION 16.
SECTION 4: First aid measures

4.1. Description of first aid measures

Move the exposed person to fresh air at once.

If any health problems occur, or in the event of any doubt or an accident, seek medical attention and provide the doctor with
information from the Safety Data Sheet. Always ensure the affected person peace of mind and ensure his/her warmth. If the affected
person is unconscious, lay him/her down and transport him/her to a doctor in a stabilised position. If the affected person is not
breathing, immediately commence artificial resuscitation. If the heart has stopped, indirect heart massage must be commenced
immediately.

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Rinse eyes for 15 minutes at least with plenty of water, holding eyelids wide open. Seek for medical attention. Avoid strong water
stream because of risk of the cornea injury.

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4.2. Most important symptoms and effects, both acute and delayed
Headache, nausea, shortness of breath, sore throat, redness of the skin. Repeated or prolonged contact may cause skin sensitization.
Repeated or prolonged contact may cause asthma.
4.3. Indication of any immediate medical attention and special treatment needed
Remove contaminated clothing and wash before reuse. If you feel unwell, seek medical advice immediately if possible, show the
label.
Advise to doctor:
Irritating to respiratory system and is a potential agent of causing allergic skin and respiratory tract. The first characteristics are
irritation of respiratory tract and bronchi. Depending on the size of the exposure and the persistence of symptoms may require longer
care. May cause skin and eye irritation as a result of reaction with water in the tissues.
Symptoms of exposure may appear late.
SECTION 5: Firefighting measures

5.1. Extinguishing media:
Suitable extinguishing media:
Carbon dioxide (CO2), dry powder or foam. Fight larger fires with water spray. Water jets. Use water jets only to cool the surfaces of
the containers exposed to fire to prevent them from bursting (explosion).
Unsuitable extinguishing media:
High volume water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products:
During a fire, produce a dense smoke containing hazardous products - carbon monoxide (CO), carbon dioxide (CO2), hydrogen
cyanide (HCN) in trace amounts, nitrogen oxides (NOx), isocyanate fumes. Do not inhale fumes and gases produce in the fire. See
also section 10.
Poland
5.3. Advice for firefighters
According to the size of fire, it may be necessary to use protective suits against the heat, individual breathing equipment, gloves,
protective goggles or facemasks and gloves.
Prevent fire extinguishing water and fire residues from contaminating surface water, the ground water system or into drains or sewers.
See also section 10.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For those not belonging to the staff assisting:
Forbid unauthorized access to the site contamination.
For those providing assistance:
Avoid contact with eyes and skin. Provide adequate ventilation. Wear appropriate protective equipment - see Section 8.
6.2. Environmental precautions:
Avoid discharge into surface water or sanitary sewer system. Do not allow material to contaminated ground water system. If the
product contaminates rivers, lakes or drains inform respective authorities.
6.3. Methods and material for containment and cleaning up

Absorb in sawdust, dry sand or with absorbent based on hydrated calcium silicate and collect mechanically into labelled containers
and deliver for disposal according to local regulations.
Damp waste left in an open container for a period of one hour to complete the reaction - the carbon dioxide is produced. Cured
residues in accordance with the recommendations set forth in Section 13
The released product may be neutralized with one of the two decontaminants, the composition of which is given below:
- Sodium carbonate: 5-10%; Washing agent: 0.2-2%, with addition of water to 100%.
- Ammonia solution: 3-8%; Washing agent: 0.2-2%, with addition of water to 100%.
6.4. Reference to other sections
Protective equipment and clothing - see section 8
Disposal of waste - see section 13 and 15.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Ensure adequate ventilation, general and local, exhaust. Observe regular review of ventilation equipment. Avoid contact with eyes.
Avoid contact with skin. Do not breathe vapours. Wear gloves and protective clothing. Do not eat, drink, smoke or store food in the
working areas. Immediately remove contaminated clothing and wash before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry place.
Protect from freezing. Store at temperatures from 10 to below 40 °C. The product can withstand short-term heating to 50 °C. See
also section 10. Suitable materials for the container: Polyethylene HDPE or steel. Do not store with food, drink and animal feed.
7.3. Specific end use(s):
No information on specific end-uses. See also subsection 1.2
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
8.1.1. Occupational Exposure limit values
Substance: 4,4`-methylenediphenyl diisocyanate
CAS Number: 101-68-8
Poland
Limit value (8 hours) Limit value short term)
Countries
ppm mg/m ppm mg/m3
Austria 0.005 0.05 0.01 0.1
Belgium 0.005 0.052
Denmark 0.005 0.05 0.01 0.1
European Union
France 0.01 0.1 0.02 0.2
Germany 0.05 0.05
Hungary 0.05 0.05
Poland 0.05 0.2
Spain 0.005 0.052
Sweden 0.002 0.03 0.005 0.05
Source: http://limitvalue.ifa.dguv.de/Webform_gw.aspx
8.1.2. DNEL/PNEC-values
Workers:
Acute/short-term exposure- systemic effects (dermal): DNEL = 50 mg/kg bw/day

Acute/short-term exposure- systemic effects (inhalation): DNEL = 0.1 mg/m3
Acute/short-term exposure- local effects (dermal): DNEL = 28.7 mg/cm2
Acute/short-term exposure- local effects (inhalation): DNEL = 0.1 mg/m3
Long-term exposure - systemic effects (inhalation): DNEL = 0.05 mg/m3
Long-term exposure - systemic effects (dermal): Not applicable.
Long-term exposure - local effects (inhalation): DNEL = 0.05 mg/m3
Long-term exposure - local effects (dermal): Not applicable.
General population:
Acute/short-term exposure- systemic effects (dermal): DNEL = 25 mg/kg bw/day
Acute/short-term exposure- systemic effects (inhalation): DNEL = 0.05 mg/m3
Acute/short-term exposure- systemic effects (oral): DNEL = 20 mg/kg bw/day
Acute/short-term exposure- local effects (dermal): DNEL = 17.2 mg/cm2
Acute/short-term exposure- local effects (inhalation): DNEL = 0.05 mg/m3
Long-term exposure - systemic effects (inhalation): DNEL 0.025 mg/m3
Long-term exposure - systemic effects (dermal): Not applicable.
Long-term exposure - systemic effects (oral): Not applicable.
Long-term exposure - local effects (inhalation): DNEL = 0.025 mg/m3
Long-term exposure - local effects (dermal): Not applicable.
Long-term exposure - local effects (oral): Not applicable.
PNEC aqua (freshwater): 1 mg/l

PNEC aqua (marine water): 0.1 mg/l
PNEC aqua (intermittent releases): 10 mg/l
PNEC STP: 1 mg/l
PNEC soil: 1 mg/kg soil dw (dry weight)
8.2. Exposure controls

Avoid contact with eyes, mucous membranes and inhalation of vapours.
It is forbidden to smoking, drinking, eating while working.
Poland
Observe the typical standards of hygiene at work.
Respiratory protection:
In conditions of insufficient ventilation, while spraying the product, it is recommended to wear a mask with the filter type A2-P2.
Eye protection:
Wear approved chemical safety goggles with side shields where eye exposure is reasonably probable, meet the requirements of EN
166.
Hand protection:
Use suitable protective gloves, such as: polychloroprene ≥0,5 mm thick and breakthrough time ≥480 minutes; nitril ≥0,35 mm thick
and breakthrough time ≥480 minutes; butyl rubber ≥0,5 mm thick and breakthrough time ≥480 minutes or fluoro-rubber ≥0,4 mm thick
and breakthrough time ≥480 minutes.
For prolonged or repeated skin contact use suitable protective gloves meet the requirements of EN 374
Skin protection:
According to the exposure when handling the product wear suitable protective clothing, aprons, protective boots.
General recommendations:
See also section 7.
Provide adequate ventilation. Remove contaminated clothing immediately. Wash hands before breaks and after work. Wash
contaminated gloves before removing. At work do not eat, drink or smoke. Avoid contact with skin. Do not get in eyes. Do not breathe
vapours.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Melting point/freezing point: <0 °C (DIN 51556)
Initial boiling point and boiling range: >300 °C (Read-across based on MDI mixed isomers - 26447-40-5.)
Flash point: >200 °C (open cup)
Flammability: Not flammable
Upper/lower flammability or explosive limits: Not flammable
Vapour pressure: <10-5 mbar (at 20 °C)
Vapour density (air=1): No data
Density: 1.20 +/- 0.03 g/cm3 (at 25 °C)
Water solubility: Reacts with water
Partition coefficient n-octanol/water: Not applicable
Poland
Auto-ignition temperature: > 600 °C (1013 hPa) (EU Method A.15)
Decomposition temperature: (Read-across based on oligomeric MDI- CAS 32055-14-4)
Viscosity: No data
Explosive properties: 200 ± 80 mPa*s (at 25 °C, dynamic) (ASTM D4899)
Oxidising properties: Not explosive
9.2. Other information

These data are not always consistent with the specifications of a particular batch of product. See product sheet for more detailed
information.
SECTION 10: Stability and Reactivity

10.1. Reactivity
Reacts with water, acids, alcohols, amines, bases and oxidants.
10.2. Chemical stability

The main removal mechanism of MDIs in the environment is hydrolysis. MDI reacts quickly with water to form predominantly solid,
insoluble polyurea. Under conditions typical of many types of environmental contact, i. e. with relatively poor dispersion of the denser
isocyanate, the interfacial reaction leads to the formation of a solid crust encasing partially or unreacted material. This crust restricts
ingress of water and egress of amine, and hence slows and modifies hydrolysis. Polymerise above 200° C, and produces carbon
dioxide.
10.3. Possibility of hazardous reactions

Reaction is slow with cold or warm water (<50°C), with hot water or steam the reaction is faster, producing carbon-dioxide causing
pressure increase. Acids, alcohols, amines, bases and oxidants cause fire and explosion hazard.
10.4. Conditions to avoid

High temperature, moisture, strong light.
10.5. Incompatible materials

Water, acids, alcohols, amines, bases and oxidants.
10.6. Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity
Acute toxicity - oral: Based on available data, the classification criteria are not met.
Rats LD50 > 2000 mg/kg bw
Method: 84/449/EEC
(Read-across based on methylenediphenyl diisocyanate - CAS 26447-40-5)
Acute toxicity - aerosol inhalation:
Rats LC50 > 2.24 mg/L air (1h)
Method: OECD Guideline 403
(Read-across based on 4,4'-methylenediphenyl diisocyanate - CAS 101-68-8.)
Acute toxicity - dermal: Based on available data, the classification criteria are not met.
Poland
Rabbit LD50 > 9400 mg/kg bw (24h)
Skin corrosion/irritation
Rabbits Irritating. (4 h/14 days)
(Read-across based on methylenediphenyl diisocyanate - CAS 26447-40-5.)
Serious eye damage/irritation
Rabbits Not irritating. (24 h/21 days)
(Read-across based on methylenediphenyl diisocyanate - CAS 26447-40-5.)
Summarized the available animal data would not support classification of MDI as an eye irritant. But together with human
occupational case reports in which symptoms of eye irritation were reported the legal classification as eye irritant should be applied.
Respiratory or skin sensitization:
Animal data as well as studies in humans provide evidence of possible skin sensitization, and of respiratory sensitization due to MDI.
Animal studies indicate that MDI is a strong allergen. Human case reports describe the occurrence of allergic contact dermatitis due
to MDI exposure.
Skin sensitization:
Mice Sensitizing.
Method: OECD Guideline 429 (LLNA)
Respiratory sensitization:
Guinea pig Sensitizing.
Method: Not available.
Germ cell mutagenicity:
Based on available data, the classification criteria are not met.
Gene mutation, in vitro:
Salmonella typhimurium Negative.
Method: EU Method B 13/14
Chromosome aberration, in vivo:
Rats (inhalation) Negative. (3 weeks; 1/week, 1 h/day)
Carcinogenicity
Rats (inhalation: aerosol) NOAEC = 0.2 mg/m3 air (toxicity) (2 years; 6 h/day, 5 days/week)
NOAEC = 1 mg/m3 air (carcinogenicity) (2 years; 6 h/day, 5 days/week)
LOAEC = 6 mg/m3 air (carcinogenicity) (2 years; 6 h/day, 5 days/week)
Reproductive toxicity:
Based on available data, the classification criteria are not met.
Effects on fertility: No fertility nor multigeneration studies are available for MDI.
Rats (inhalation) NOAEL = 4 mg/m3 air (developmental toxicity) ( 10 days; 1/day, 6 h)
NOAEL = 4 mg/m3 air (maternal toxicity) ( 10 days; 1/day, 6 h)
STOT-single exposure:
MDIs irritant the respiratory tract.
Poland
STOT-repeated exposure
Rats (inhalation: aerosol) LOAEC = 1.0 mg/m3 air (2 years; 6 h/day, 5 days/week)
Target organs: respiratory - lung.
Aspiration hazard:
Not classified due to lack of data
SECTION 12: Ecological information

12.1. Toxicity
Short-term toxicity to fish:
Freshwater fish (Brachydanio rerio) LC50 > 1000 mg/L (96 h)
Short-term toxicity to aquatic invertebrates:
Freshwater invertebrates (Daphnia magna) EC50 > 1000 mg/L (24 h)
Long-term toxicity to aquatic invertebrates:
Freshwater invertebrates (Daphnia magna) NOEC >= 10 mg/L (21 days)
Toxicity to aquatic algae and cyanobacteria:
Freshwater algae (Desemodesmus subspicatus) EC50 > 1640 mg/L (72 h)
Toxicity to microorganisms:
Microorganisms (activated sludge) EC50 > 100 mg/L (3 h)
12.2. Persistence and degradability
Photo-transformation in air:
Half-life (DT50): 1 day
Method: QSAR
Hydrolysis: MDI reacts with water to form predominantly inert polyurea.
Half-life (DT50): 20 h (at 25°C)
(Read-across based on oligomeric MDI - CAS 32055-14-4.)
Photo-transformation in water and soil:
There are no photo-transformation data in water and soil for the test substance. Biodegradation in water: Under test conditions no
biodegradation observed. (28 days)
Method: OECD Guideline 302 C
Biodegradation in water and sediment: Data waiving. In accordance with Annex XI, simulation biodegradation tests are technically
not feasible as the test substance reacts quickly with water. The corresponding PEC/PNEC ratios would be less than 1. Taking into
account the scientific and exposure arguments, it appears appropriate to waiver the long-term fish/plant/soil and sediment toxicity
studies.
12.3. Bioaccumulative potential
Bioaccumulation - aquatic/sediment: Due to the high reactivity of the substances of the MDI category with water, bioaccumulation
tests can in principle not be performed with these substances. However, one bioaccumulation test with 4,4'-MDI and a mesocosm
study with PMDI with an indication of bioaccumulation potential have been performed. As no analytical measurements were done, it
Poland
cannot be determined if the values are truly related to MDI. However, based on the available information and the reactivity of MDI
substances of the category approach, no new bioaccumulation study is deemed necessary.
BCF (Cyprinus carpio) 200 (28 days)
Method: OECD Guideline 305 E
12.4. Mobility in soil
There is no data available.
12.5. Results of PBT and vPvB assessment

Not applicable.
12.6. Other adverse effects

According to information provided by the manufacturer, the product has weak effects to the aquatic environment – class 1 by the
German classification (classification manufacturer).
Do not allow undiluted product or large quantities of it to reach surface water, ground water or sewage system.
The product is not mixed with water. In the reaction with water produces carbon dioxide, and inert non-biodegradable solid (polyurea).
Product is not classified as dangerous for the environment.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
Avoid or minimize waste material production. The material must be disposed in accordance with local or national rules (Waste Act).
Unrefined material is not suitable for disposal. Do not let waste material, even in small quantities, down to wastewater, sewage system
or watercourses. Emptied packaging must be passed to authorized waste receiver.
European Waste Catalogue code (EWC): 08 05 01*
SECTION 14: Transport Information

14.1. UN number
Not dangerous goods
14.2. UN proper shipping name
Not dangerous goods
14.3. Transport hazard class(es)
Not dangerous goods
14.4. Packing group
Not dangerous goods
14.5. Environmental hazards
No
14.6. Special precautions for user
Not dangerous goods
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
No regulation.
Poland
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
1. Regulation (EC) No. 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH) and establishing a European Chemicals Agency, amending
Directive 1999/45/EC and repealing Council Regulation (EEC). No 793/93 and Commission Regulation (EC) No 1488/94 as well as
Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC as amended,
(REACH) (Official Journal of the European Union L of 2006 No. 396, item 1).
2. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling
and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006 (OJ EU L of 2008 No. 35, item 1).
3. Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No. 1907/2006 of the European Parliament
and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (OJ EU L of 2015 No. 132).
4. Commission Directive No. 2000/39/EC; 2006/15/EC and 2009/161/EC establishing first, second and third lists of indicative
occupational exposure limit values (OJ EU L 2000, No. 142, item 47; OJ EU L 2006, No. 38, item 36; OJ EU L of 2009 No. 338, item
87).
15.2. Chemical Safety Assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The full version of the hazard classes and category codes:

Acute Tox. 4 – Acute toxicity (oral); category 4.
Carc. 2 - Carcinogenicity; category 2.
Eye Irrit. 2 – Serious eye damage/eye irritation; category 2.
Resp. Sens. 1 – Respiratory sensitisation, category 1.
Skin Irrit. 2 – Skin corrosion/irritation, category 2.
Skin Sens. 1B - Skin sensitisation, category 1B.
STOT RE 2 - Specific target organ toxicity — repeated exposure; category 2.
STOT SE 3 - Specific target organ toxicity — single exposure; category 3.
Full text of H-sentences (Hazard statements) referred to under sections 2 and 3:
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H332 – Harmful if inhaled.
H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H373 - May cause damage to organs repeated exposure.
According to information provided by the manufacturer, technical (polymers) MDI (pMDI) CAS 9016-87-9 (in the form of aerosol
respirable fraction) is classified as category 3 carcinogens.
The current edition of the safety data sheet replaces the previous edition.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal
and release and is not to be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in any process, unless specified
in the text.
END of the MSDS
Poland

MSDS - Strata Bond HA Comp B - 011116 - EN

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STRATA BOND HA, COMPONENT B

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.2. Label elements

2.3. Other hazards

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

SECTION 5: Firefighting measures

SECTION 6: Accidental release measures

6.3. Methods and material for containment and cleaning up

SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

Acute/short-term exposure- systemic effects (dermal): DNEL = 50 mg/kg bw/day

Acute/short-term exposure- systemic effects (dermal): DNEL = 25 mg/kg bw/day

Acute/short-term exposure- systemic effects (inhalation): DNEL = 0.05 mg/m3

Acute/short-term exposure- systemic effects (oral): DNEL = 20 mg/kg bw/day

Acute/short-term exposure- local effects (dermal): DNEL = 17.2 mg/cm2

Acute/short-term exposure- local effects (inhalation): DNEL = 0.05 mg/m3

Long-term exposure - systemic effects (inhalation): DNEL 0.025 mg/m3

Long-term exposure - systemic effects (dermal): Not applicable.

Long-term exposure - systemic effects (oral): Not applicable.

Long-term exposure - local effects (inhalation): DNEL = 0.025 mg/m3

Long-term exposure - local effects (dermal): Not applicable.

Long-term exposure - local effects (oral): Not applicable.

PNEC aqua (freshwater): 1 mg/l

8.2. Exposure controls

SECTION 9: Physical and chemical properties

Melting point/freezing point: <0 °C (DIN 51556)

Flash point: >200 °C (open cup)

Flammability: Not flammable

Upper/lower flammability or explosive limits: Not flammable

Vapour pressure: <10-5 mbar (at 20 °C)

Vapour density (air=1): No data

Density: 1.20 +/- 0.03 g/cm3 (at 25 °C)

Water solubility: Reacts with water

Partition coefficient n-octanol/water: Not applicable

Decomposition temperature: (Read-across based on oligomeric MDI- CAS 32055-14-4)

Explosive properties: 200 ± 80 mPa*s (at 25 °C, dynamic) (ASTM D4899)

Oxidising properties: Not explosive

9.2. Other information

SECTION 10: Stability and Reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

SECTION 12: Ecological information

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

SECTION 13: Disposal considerations

SECTION 14: Transport Information

SECTION 16: Other information

The full version of the hazard classes and category codes:

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