Crystal Simple Green® Industrial Cleaner & Degreaser

SAFETY DATA SHEET in accordance with REGULATION (EC) No 1907/2006 & (EU) No 2015/282

1 IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY

Product Identifier: Crystal Simple Green® Industrial Cleaner & Degreaser

Manufacturer Numbers: Please see Section 16
Relevant identified uses of mixture: Cleaning/Degreasing agent for all rinsable surfaces.
Relevant identified uses advised against: Surfaces not tolerate to degreasing agents, non-rinsable surfaces.
Company: Sunshine Makers Inc. SIMPLE GREEEN France
15922 Pacific Coast Highway 58, avenue de Wagram
Huntington Beach, California 92649 75017 PARIS
USA Tel : 01 46 94 69 90
Telephone: +1 562 795 6000 (M-F, PST, 8am – 5pm) +33 1 48 90 6699 (M-F, PST, 8am – 5pm)
Fax: +1 562 592 3034 +33 09 81 40 83 67
Email: [email protected] [email protected]
Emergency Telephone: Chem Tel (24 hr, International) - +1-813-248-0585

2 HAZARDS IDENTIFICATION

Classification according to Regulation (EC) No 1272/2008 [CLP] : Eye Irritant 2

Label Elements Hazard Pictograms:
Signal Word: Warning.
Hazard Statements: H319: Causes serious eye irritation
Precautionary Statements: P280: Wear eye protection.
P264: Wash hands thoroughly after handling.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
Supplemental Hazard Information: Not applicable
Other Hazards: None known.

3 COMPOSITION/INFORMATION ON INGREDIENTS
CLP Annex VI Classification According to
CAS No. EC No. Index No. REACH No. % weight Name (EC) No 1272/2008 (CLP)
68439-46-3 614-482-0 - exempt 1 - 5% C9-11 Ethoxylated Alcohol Eye Dam. 1 - H318
68-04-2 200-75-3 - 01-2119457027-40 1 - 5% Sodium Citrate Not classified
51981-21-6 257-573-7 - 01-2119493601-38 1 - 5% Tetrasodium N,N- Not classified
bis(carboxymethyl)-L-glutamate
497-19-8 207-838-8 - 01-2119485498-19 1 - 5% Sodium Carbonate Eye Irrit. 2 - H319
77-92-9 201-069-1 - 01-2119457026-42 0,1 – 1% Citric Acid Not Classified
For full text of H statements and symbols see section 16

4 FIRST AID MEASURES

General Notes: Dilution of concentrate to 20% reduces possibility of eye irritation.

Following Inhalation: Move to fresh air in case of inhalation overexposure. If coughing or irritation persists consult a
physician.
Following Skin Contact: Wash with water. If redness, swelling or persistent irritation occurs consult a physician.
Following Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention.

SDS ID# 72900-17B Page 1 of 5

 Crystal Simple Green® Industrial Cleaner & Degreaser
SAFETY DATA SHEET in accordance with REGULATION (EC) No 1907/2006 & (EU) No 2015/282

4 FIRST AID MEASURES - continued

Following Ingestion: Clean mouth with water. Drink plenty of water. Do not induce vomiting. If you feel unwell seek medical
advice immediately.
Self-protection of the first aider: Treat Symptomatically.

Acute effects: None known or expected.

Delayed effects: None known or expected.
Immediate medical attention / special treatment: None needed.

5 FIRE FIGHTING MEASURES

Suitable Extinguishing Media: Use dry chemical, CO2, water spray or “alcohol” foam.
Unsuitable Extinguishing Media: High volume water Jet.
Hazardous combustion products: No hazards or reactions expected.
Advice for firefighters: No special equipment needed for this product. Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

6 ACCIDENTAL RELEASE MEASURES

Non-Emergency Personal
Protective Equipment: Use protective goggles.
Emergency Procedures: For small and large spills, wipe with absorbent material or soak with absorbent material and dispose
of properly – see section 13
Emergency Responders: See instructions above.
Environmental Precautions: Do not allow into open waterways and ground water systems. Local authorities should be advised if
significant spillages cannot be contained.
Methods for containment: Dike or divert spill from access to open waterways, or capping of drains.
Methods for cleaning up: Soak up with inert absorbent material (i.e. sand).
Other information: Refer to section 13 for appropriate disposal.

7 HANDLING AND STORAGE

Precautions for safe handling

Protective Measures: Avoid spray back and splashing. Keep container tightly closed when not in use.
Measures to prevent fire: Not applicable. Non flammable liquid.
Measure to prevent aerosol and dust generation: Not applicable.
Measures to protect environment: Avoid spills and keep away from drains.
Advice on general occupational hygiene: Do not eat, drink and smoke in work area. Wash hands after using. Remove
contaminated clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities
Technical Measures and storage conditions: Store in cool dry area. Keep container tightly closed.
Packing Materials: Suitable for storage in HDPE and PET plastics.
Requirements for storage rooms and vessels: Do not allow to freeze or overheat.
Storage Class - Further information on storage conditions: Germany - LGK 12 (TRGS 510).
Specific End Uses - Recommendations: Cleaner / Degreaser used manually or with pressure washers and parts washers.
Specific End Uses - Industrial sector specific solutions: See above

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 Crystal Simple Green® Industrial Cleaner & Degreaser
SAFETY DATA SHEET in accordance with REGULATION (EC) No 1907/2006 & (EU) No 2015/282

8 EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Limit Values: Sodium Carbonate (497-19-8) – Czech Republic - 10 mg/m3 Ceiling; 5mg/m3 TWA
Sodium Carbonate (497-19-8) – Romania - 3 mg/m3 STEL; 1 mg/m3 TWA

Exposure Controls
Appropriate Engineering Controls Avoid spray back and splashing. Keep container tightly closed when not in use.
Personal Protection Equipment
Eye and Face Protection: If splashing is likely use protective glasses or goggles.
Skin Protection - Hands: Not needed. Extended usage with dermally sensitive individuals may require nitrile gloves.
Skin Protection – Other skin protection: Not needed.
Respiratory Protection: Not needed. In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal Hazards: Not needed.

Environmental exposure controls: Do not allow into open waterways and ground water systems.

9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Clear Colorless Liquid Vapour Density: Not tested

Odor: Detergent; No Added Odor Relative Density ASTM D-4017: 1,025 g/ml
Odor Threshold: Not determined Solubility: 100% in water
pH ASTM D-1293: 10,0 – 11,0 Partition Coefficient: Not tested
Freezing Point ASTM D-1177: 0 – 3,33oC (32 - 38oF) Auto-Ignition Temperature: None, see flash point
Boiling Point ASTM D-1120: 101oC (213,8oF) Decomposition Temperature: Not tested
Flash Point ASTM D-93: None Viscosity: Not tested
Evaporation Rate: Not tested Explosive Properties: None, see flash point
Flammability: None, see flash point Oxidizing Properties: None, contains no oxidizers
Vapour Pressure: Not determined VOCs CARB Method 310: 0,4%
Upper/Lower Flammability or explosive limits: Not applicable

10 STABILITY AND REACTIVITY

Reactivity: Not reactive.

Chemical Stability: Storage or exposure to temperatures above 38°C (100°F) for more than twenty-four hours may cause
surfactants to break down and a resulting loss of efficacy.
Possibility of Hazardous Reactions: No known hazardous reactions
Conditions to avoid: Excessive heat, light or freezing temperatures
Incompatible Materials: Materials susceptible to degreasing agents.
Hazardous decomposition products: No known hazardous decomposition products.

11 TOXICOLOGICAL INFORMATION

Acute Toxicity (for mixture)- Oral (LD50, rat, mg/kg): > 50001 Dermal (LD50, rat, mg/kg): > 50001
Inhalation (LC50, rat, mg/l/4h): Contains no ingredients classifiable in this category
Skin Corrosion /Irritation: Non-irritant per Dermal Irritection® assay modeling. No animal testing performed.
Serious Eye damage/Irritation: Slight irritant per Ocular Irritection® assay modeling. No animal testing performed.
Respiratory or skin sensitization: No. 2 Carcinogenicity: No. 2
Germ cell mutagenicity: No. 2 Reproductive toxicity: No. 2
Summary of evaluation of CMR properties: Mixture and ingredients are not classifiable according to CLP in this category.
STOT-single exposure: No. 2 STOT-repeated exposure: No. 2
Aspiration hazard: No. 2
SDS ID# 72900-17B Page 3 of 5
 Crystal Simple Green® Industrial Cleaner & Degreaser
SAFETY DATA SHEET in accordance with REGULATION (EC) No 1907/2006 & (EU) No 2015/282

11 TOXICOLOGICAL INFORMATION - continued

1 calculated via (EC) No 1272/2008 on Classification, Labelling and Packaging of substances and mixtures. No animal testing performed.
2 Mixture, based on ingredients, is not classifiable according to CLP in this category.

12 ECOLOGICAL INFORMATION

Toxicity
Acute Chronic
Fish: Aquatic Toxicity – Low , based on Fish: Not tested
Crustacea: OECD 201, 202, 203 + Microtox: EC50 Crustacea: Not tested
Algae/aquatic plants: & IC50 ≥100 mg/L. Algae/aquatic plants: Not tested
Other organisms: Not tested Other organisms: Not tested

Persistence and degradability:

Abiotic Degradation: Surfactant degrades abiotically Physical- and photo-chemical elimination: Not assessed
Biodegradation: Readily Biodegradable per OECD 301D, closed bottle test.
Bioaccumulative potential
Partition coefficient n-octanol/ water (log Kow): Not assessed Bioconcentration factor (BCF): Not assessed
Mobility in soil
Known or predicted distribution to environmental compartments: Unknown
Surface Tension: Not tested Adsorption/Desorption: Not tested
Results of PBT and vPvB assessment: Contains no ingredients known as PBT or vPvB.
Other adverse effects: Unknown
Additional Information: None

13 DISPOSAL CONSIDERATIONS

Unused and Used liquid disposal: May be considered hazardous in your area depending on usage and tonnage of disposal – check
product IDS and with local, national and European waste management legislation for appropriate methods of disposal. Waste
should not be disposed of by release to sewers.
Empty Container disposal Triple rinse plastic bottles and offer all up for recycling.
Never dispose of preparation into lakes, streams, and open bodies of water or storm drains.
Be sure to follow any National or Regional provisions that may be in force.

14 TRANSPORTATION INFORMATION

DOT / TDG: Not classified as hazardous. ICAO-TI/ IATA-DGR: Not classified as hazardous.
IMO / IDMG: Not classified as hazardous. ADR / RID / ADN: Not classified as hazardous.
AND tank vessels: Not classified as hazardous.

UN Number: Not applicable UN Proper Shipping Name: Cleaning Compound, Liquid NOI
Transport Hazard Class(es): Non-Hazardous
Packing Group: Not applicable
Environmental Hazards: Not applicable
Special Precautions for User: Check section 3, section 7 and IDS for ingredient classification
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SDS ID# 72900-17B Page 4 of 5

 Crystal Simple Green® Industrial Cleaner & Degreaser
SAFETY DATA SHEET in accordance with REGULATION (EC) No 1907/2006 & (EU) No 2015/282

15 REGULATORY INFORMATION

This mixture contains only ingredients which have been subject to a pre-registration according to Regulation (EC) No. 1907/2006
(REACH).
Detergent Regulation 648/2004/EC : Please see separate IDS for full ingredient disclosure

Germany – Water Classification Sodium Carbonate (497-19-8) – ID Number 222, Hazard Class 1
Ethoxylated Alcohol (68439-46-3) – ID Number 670, Hazard Class 2
Citric Acid (77-92-9) – ID Number 57, Hazard Class 1
Russia: Citric Acid (77-92-9) 0,1 mg/m3 MAC

Additional Markings: None.

VOC Content: 0,4% (4 g/L) in concentrate

Chemical Safety Assessment: No chemical safety assessment has been carried out for this mixture by the supplier.

16 OTHER INFORMATION

Abbreviations
H318 – Causes serious eye damage
H319 – Causes serious eye irritation
Classification according to Regulation (EC) Nr. 1272/2008
Classification Procedure
Eye Corrosive/Irritant, Category 2 – H319 InVitro Irritection Test Data and Calculation

Manufacturer Numbers: Size Manufacturer Number UPC

500 mL 0600500172905; 0610501272905 0-43318-72905-8
946 mL 0607500100032; 0617501200032 0-43318-00193-2
946 mL 0607500172932; 0617501272932 0-43318-00194-9
946 mL 0607500172932; 0617501272932 0-43318-00196-3
1L 0607500172901; 0617501272901 0-43318-00161-1
1L 0600500172901; 0600501272901; 0610501272901; 72901 0-43318-72901-0
10 L 0600500172910; 0610500272910; 72910 0-43318-72910-2
20 L 0600500172912 0-43318-00252-6
208 L 0600500172920; 72920 0-43318-72920-1

The statements in this Safety Data Sheet were made to the best of our knowledge and are as accurate as possible. They are given
for information only. They do not constitute a contractual guarantee of a product’s properties. They must neither be altered nor
transferred to other products.
Date of Issue: 23.10.2017 Replaces Data Sheet of: 09.02.2017
Indication of changes: Update to pH range and stability statement.
Responsible Party for SDS: Simple Green Research & Development Department, [email protected]

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