MSDS NAOH FLAKE (Kop LTL)

太洋贸易（上海）有限公司
LAUTAN LUAS （SHANGHAI） CO., LTD

Add: No. 281 Hunan Road, Shanghai China Postcode:200031
Tel: 86-21-54651941，54655092 Fax: 86-21-54655093
MATERIAL SAFETY DATA SHEET
1.Product and Company Identification
SODIUM HYDROXIDE FLAKE

Trade / Commercial Name
( CAUSTIC SODA WHITE FLAKES 99% MIN.)
Chemical Name Sodium hydroxide - FLAKE
Formula NaOH
Chemical Family
Synonyms Caustic soda; Sodium hydrate; White Caustic
Un No 1823 Hazchem Code 2r
ERG No 154 EAC 59
2. Composition
Hazardous Components Sodium hydroxide > 98 % MIN.
3. Hazards Identification
Corrosive
Poisonous if inhaled or swallowed.
Skin contact poisonous.
Contact could cause burns to skin and eyes.
Fire could produce irritating or poisonous gases.
Runoff from fire-control or dilution water could cause pollution.
Severe burns of eyes and skin; respiratory tract irritant.
Can react explosively with certain chemicals.
4. First Aid Measures
First Aid Skin Wash off with water.

Remove clothing.
Shower thoroughly.
First Aid Eyes Flush eyes with water for 15 minutes.
Hold eyelids open while washing.
First Aid Ingested Do not induce vomiting.
Give oxygen.
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Tel: 86-21-54651941，54655092 Fax: 86-21-54655093
Remove from contaminated area.

First Aid Inhalation Give oxygen.
5. Fire Fighting Measures
Some of these materials may react violently with water.

SMALL FIRES: Dry chemical, CO2, Halon, water spray or alcohol foam.
LARGE FIRES: Water spray, fog or standard foam is recommended.
Move container from fire area if you can do it without risk.
Cool containers that are exposed to flames with water from the
side until well after the fire is out. Stay away from ends of tanks.
Keep unnecessary people away; isolate hazard area and deny entry.
Stay upwind; keep out of low areas.
Positive-pressure self-contained breathing apparatus (SCBA) and
chemical protective clothing that is specifically recommended by the shipper
or manufacturer may be worn. It will provide little or no thermal protection.
Structural firefighter's protective clothing is NOT effective
with these materials.
6. Accidental Release Measures
Full protective clothing including breathing apparatus

Dilute (substance may be washed to drain with a lot of water)
PRECAUTIONS:
Restrict access to area.
Provide adequate protective equipment and ventilation.
Remove sources of heat and flame.
Notify occupational and environmental authorities.
SPILL OR LEAK:
Do not touch spilled material.
Stop leak if you can do it without risk.
Use water spray to reduce vapours.
SMALL SPILLS:
Takeup with sand or other noncombustible absorbent material
and place into containers for later disposal.
LARGE SPILLS:
Dike liquid spill for later disposal
2
Tel: 86-21-54651941，54655092 Fax: 86-21-54655093
7. Handling And Storage
Separation of at least 3M from the following classes is recommended.

Flammable Liquids Flammable Solids
Spontaneously Combustibles Poison
Fire separation of at least 5M or 4Hr fire resistant wall
from the following classes is recommended.
Flammable Gases Dangerous When Wet
Oxidizing Agents Organic Peroxides
Storage in the same room or space is prohibited with the following classes:
The rooms or spaces should be at least 10M apart.
Explosives Radioactive
8. Exposure Controls/Personal Protection
Occupational Exposure Limits T W A OEL-RL SHORT TERM OEL-RL
PPMa) MG/M3b) PPMa) MG/M3b)
-C2-2
C = Ceiling Limit
Controls The control measures appropriate for a particular worksite depend
on how this material is used and on the extent of exposure.
The best protection is to enclose operations and/or provide
local exhaust ventilation at the site of chemical release.
Use a non-sparking, grounded ventilation system separate from other
exhaust ventilation systems. Exhaust directly to the outside.
Supply sufficient replacement air to make up for air removed.
Have a safety shower/eye wash fountain readily available in the immediate
work area
Personal Protection If engineering controls and work practices are not effective in
controlling this material, then wear suitable personal protection
equipment, including chemical safety goggles & face shield, boots,
imperious gloves, coveralls, & respiratory protection.
Have appropriate equipment available for use in emergencies.
9. Physical & Chemical Properties
White to slightly coloured pellets, lumps, sticks or flakes.

Boiling Point: solid: 1390 oC.
50% solution: 142 oC to 148 oC.
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Tel: 86-21-54651941，54655092 Fax: 86-21-54655093
Melting Point: solid: 310 to 320 oC.

50% solution: 12 to 15 oC.
Solidification Point: 50% solution: 5 oC.
Completely soluble in water. Solid reacts with water with release
of appreciable heat. Solids and concentrated solutions are
highly hygroscopic.
Solid exposed to air dissolves in absorbed moisture and reacts
with carbon dioxide forming harmless sodium carbonate.
10. Stability And Reactivity
Conditions to Avoid Warm ammoniacal silver nitrate, nitrobenzene, sodium tetrahydroborate,

1,1,1- trichloroethanol, cyanogen azide,
Incompatible Materials It reacts with acids with release of heat. Solutions react with aluminium, zinc,
tin and their alloys with release of highly flammable hydrogen.
Other
11. Toxicological Information
see section 3.
12. Ecological Information
No ecological problems are expected when the product is handled and used with due care.
13. Disposal Considerations
Disposal Method Product There are no uniform EC regulations for the disposal of chemicals or residues.
Chemical residues generally count as special waste.
The disposal of the latter is regulated in the EC member countries through
corresponding laws and regulations.
We recommend that you contact the authorities in charge or approved
waste disposal companies which will advise you on how to dispose of special
waste.
Disposal Method Packaging Disposal in accordance with local legal provisions.
4
Tel: 86-21-54651941，54655092 Fax: 86-21-54655093
14. Transport Information
UN No 1823 Hazchem Code 2r

ERG No 154 EAC 59
ARD/RID Class NA
IMDG Code 8215 IMDG-Packaging Group II

Marine Pollutant True
Class Class: 8 Corrosive Group: II
Subsidiary Risks None
Tremcard Number 121/80G13
15. Regulatory Information
EEC Hazard Classification 8

Risk Phases R35 Causes severe burns
Safety Phases S2, S26, S27, S37/38
Keep out of reach of children
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advise
Wear suitable gloves and eye/face protection
National Legislation
16. Other Information
Reason for Alteration: General update.
The information contained herein is based on the present state of our knowledge.
It characterizes the product with regard to the appropriate safety precautions.
It does not represent a guarantee of the properness of the product.

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太洋贸易（ 上海） 有限公司

LAUTAN LUAS （SHANGHAI） CO., LTD

MATERIAL SAFETY DATA SHEET

1.Product and Company Identification

SODIUM HYDROXIDE FLAKE

Hazardous Components Sodium hydroxide > 98 % MIN.

4. First Aid Measures

First Aid Skin Wash off with water.

Remove from contaminated area.

5. Fire Fighting Measures

Some of these materials may react violently with water.

6. Accidental Release Measures

Full protective clothing including breathing apparatus

7. Handling And Storage

Separation of at least 3M from the following classes is recommended.

8. Exposure Controls/Personal Protection

Occupational Exposure Limits T W A OEL-RL SHORT TERM OEL-RL

PPMa) MG/M3b) PPMa) MG/M3b)

9. Physical & Chemical Properties

White to slightly coloured pellets, lumps, sticks or flakes.

Melting Point: solid: 310 to 320 oC.

10. Stability And Reactivity

Conditions to Avoid Warm ammoniacal silver nitrate, nitrobenzene, sodium tetrahydroborate,

11. Toxicological Information

12. Ecological Information

13. Disposal Considerations

14. Transport Information

UN No 1823 Hazchem Code 2r

IMDG Code 8215 IMDG-Packaging Group II

Tremcard Number 121/80G13

15. Regulatory Information

EEC Hazard Classification 8

16. Other Information

Reason for Alteration: General update.

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太洋贸易（上海）有限公司