DATE

04-02-2022

CODE

1 Time : 3 Hours
JEE MAIN - 08 (ISRO)
Maximum Marks : 300

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

INSTRUCTIONS TO CANDIDATES

 Question paper has three (03) parts: Physics, Chemistry and Mathematics.

 Each part has a total twenty five (25) questions divided into two (02) sections (Section-1 and Section-2).

 Total number of questions in Question paper are Seventy Five (75) and Maximum Marks are Three Hundred only (300).

Type of Questions and Marking Schemes

SECTION-1 (Maximum Marks : 80)

 This section contains TWENTY (20) questions

 Each question has FOUR options (1), (2), (3) and (4) ONLY ONE of these four option is correct

 Marking scheme :

 Full Marks : +4 If the corresponding to the answer is darkened

 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).

 Negative Marks : –1 In all other cases.

SECTION – 2 : (Maximum Marks : 20)

 This section contains FIVE (05) questions. The answer to each question is NUMERICAL VALUE with two digit integer

and decimal upto two digit.

 If the numerical value has more than two decimal places truncate/round-off the value to TWO decimal places.

e.g : if your answer is 7 please fill it 7.00

If your answer is 7.2 please fill it 7.20.

If your answer is 6.246 please fill it 6.25

If your answer is 6.341 please fill it 6.34

 Marking scheme :

 Full Marks : +4 If the corresponding to the answer is darkened

 Zero Marks : 0 In all other cases.

NAME OF THE CANDIDATE : ………………………………………………… ROLL NO. :………………..………………………..

I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.

------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator
 Physics

1. The bulk modulus of copper is 1.4 1011 Pa and the coefficient of linear expansion is
1.7 105 (C ) 1 . What hydrostatic pressure is necessary to prevent a copper block from expansing
when its temperature is increased from 20C to 30C ?
(A) 6.0 105 Pa (B) 7.1 107 Pa (C) 5.2 106 Pa (D) 40 atm

2. In the steady state of temperature the flow of heat across the body depends :
(A) only upon its thermal conductivity
(B) upon its thermal capacity
(C) upon its thermal conductivity and upon its thermal capacity
(D) neither upon its thermal conductivity nor upon its thermal capacity

3. Two rods are connected as shown. The rods are of same length and same cross sectional area. In
steady state, the temperature ( θ ) of the interface will be

(A) 60C (b) 73.3C (C) 46.7C (D) 37.3C

4. If the temperature of a black body is increased by 50% then the amount of radiation emitted by
it will
(A) Increase by 400% (B) Decrease by 400%
(C) Decrease by 50% (D) Increase by 50%

5. Radius of a sphere is R, density is d and specific heat is s, It is heated and then allowed to cool. Its
rate of decrease of temperature will be proportional to -
(A) Rds (B) 1/Rds (C) 1/R 2ds (D) R 2ds

6.. If a body at 27C emits 0.3 watt of heat then at 627C , it will emit heat equal to-
(A) 24.3 watt (B) 0.42 watt (C) 2.42 watt (D) 0.9 watt

Space for Rough Work

7. A body takes 4 minutes to cool from 100C to 70C . If the room temperature is 15C then how
many minutes will it need to cool from 70C to 40C -
(A) 4 (B) 5 (C) 6 (D) 7

8. Temperature of two hot bodies B1 and B2 are 100C and 80C respectively. The temperature of
surrounding is 40C . At t = 0, the ratio of rates of cooling of the two bodies (liquid) R1 : R 2 will
be -
(A) 3 : 2 (B) 5 : 4 (C) 2 : 1 (D) 4 : 5

9. Increasing the temperature of a black body

(A) Frequency and wavelength both increase for maximum radiation.
(B) Frequency and wavelength both decrease for miximum radiation.
(C) Wavelength increases while frequency decreases for maximum radiation.
(D) Frequency increases while wavelength decreases for maximum radiation.

10. Wein's displacement law is shown by the following relation m T  b then the curve drawn between
log T and log m will be -

(A) (B) (C) (D)

11. The value of g at a place decreases by 2%. The barometric height of mercury
(A) Increases by 2% (B) Decreases by 2%
(C) Remains unchanged (D) Sometimes increases and sometimes decreases

Space for Rough Work

12. A vertical U-tube of uniform inner cross section contains mercury in both sides of its arms. A
glycerin (density = 1.3 g / cm3 ) column of length 10 cm is introduced into one of its arms. Oil of
density 0.8 gm / cm3 is poured into the other arm until the upper surfaces of the oil and glycerin are
in the same horizontal level. Find the length of the oil column, Density of mercury = 13.6 g / cm3

(A) 10.4 cm (B) 8.2 cm (C) 7.2 cm (D) 9.6 cm

13. There is a 1mm thick layer of oil between a flat plate of area 102 m 2 and a big plate. How much
force is required to move the plate with a velocity of 1.5 cm / s 2 ? The coefficient of viscosity of oil
is 1 poise -
(A) 1.5  103 N (B) 1.3  105 N (C) 1.5  102 N (D) 1.5  102 N

14. An air bubble is formed at depth h below the surface of water. The pressure inside the bubble is-
( P0  atmospheric pressure, r  radius of bubble)
4T 2T
(A) (B)
r r
2T 4T
(C) P0  103 hg  (D) P0  103 hg 
r r

15. The surface energy of a liquid drop is u. It is sprayed into 1000 equal droplets. Then its surface
energy becomes-
(A) u (B) 10 u (C) 100 u (D) 1000 u

Space for Rough Work

16. Equal volumes of two immiscible liquids of densities  and 2 are filled in a vessel as shown in
figure. Two small holes are punched at depth h/2 and 3h/2 from the surface of lighter liquid. If v1
and v2 are the velocities of a flux at these two holes, then v1 / v2 is:

1 1 1 1
(A) (B) (C) (D)
2 2 2 4 2

17. A cylindrical vesssel filled with water upto height of H stands on a horizontal plane. The side wall of
the vessel has a plugged circular hole touching the bottom. The coefficient of friction between the
bottom of vessel and plane is μ and total mass of water plus vessel is M. What should be minimum
diameter of hole so that the vessel begins to move on the floor if plug is removed (here density of
water is  )
2 M M M
(A) (B) (C) (D) none
 H 2  H H

18. A solid metallic sphere of radius r is allowed to fall freely through air. If the frictional resistance due
to air is proportional to the cross - sectional area and to the square of the velocity, then the terminal
velocity of the sphere is proportional to which of the following?
(A) r 2 (B) r (C) r 3/2 (D) r1/2

19. Two drops of same radius are falling through air with steady velocity of v cm/s. If the two drops
coalesce, what would be the terminal velocity?
(A) 4v (B) (4)1/3 v (C) 2v (D) 64 v

20. A large tank is filled with water (density = 103 kg / m3 ) . A small hole is made at a depth 10m below
water surface. The range of water issuing out of the hole is R on ground. What extra pressure must
be applied on the water surface so that the range becomes 2R (take 1 atm = 105 Pa and g = 10 m/s2 ):

(A) 9 atm (B) 4 atm (C) 5 atm (D) 3 atm

Space for Rough Work

 (SECTION – 2)

 This section contains FIVE (05) questions. The answer to each question is NUMERICAL
VALUE with two digit integer and decimal upto two digit.

 If the numerical value has more than two decimal places truncate/round-off the value to TWO
decimal places.
e.g : if your answer is 7 please fill it 7.00
If your answer is 7.2 please fill it 7.20.
If your answer is 6.246 please fill it 6.25
If your answer is 6.341 please fill it 6.34

 Marking scheme :
 Full Marks : +4 If the corresponding to the anpswer is darkened
 Zero Marks : 0 In all other cases.
_______________________________________________________________________________________

21. A wall has two layer A and B each made of different material, both the layers have the same
thickness. The thermal conductivity of the material A is twice that of B. Under thermal equilibrium
the temperature difference across the wall B is 36C . The temperature difference across the wall A
is (in degree C)

22. A uniformly tapering vessel shown in fig. is filled with liquid of density 900 kg / m3 . The force that
acts on the base of the vessel due to liquid is (take g  10 m / s 2 ) (in N)

Space for Rough Work

23. A spherical ball of density  and radius 0.003m is dropped into a tube containing a viscous fluid
2
filled up to the 0cm mark as shown in the figure. Viscosity of the fluid = 1.260 N . m and its
density  L   / 2  1260 kg m . Assume the ball reaches a terminal speed by the 10cm mark. Find
3

the time taken by the ball to traverse the distance between the 10cm and 20cm mark. (in sec)
(g = acceleration due to gravity = 10 ms2 )

2 2
24. Water is pumped from a depth of 10m and delivered through a pipe of cross section 10 m upto a
height of 10m. If it is needed to deliver a volume 0.2 m3 per second, find the power required.
(in kW). Use g  10 m / s 2 

25. A soap bubble has radius R and thickness d (<<R) as shown. It collapses into a spherical drop. The
1
 R 3
ratio of excess pressure in the drop to the excess pressure inside the bubble is   . Fill the value
 nd 
of ' n '

Space for Rough Work

 Chemistry
26. The solubility of Mg (OH )2 is x mole/ltr. Then its solutbility products is –
(A) x3 (B) 5x3 (C) 4x3 (D) 2x2

27. The solubility in water of a sparingly soluble salt AB2 is 1.0 105 mol L1 . Its solubility product will
be
(A) 11015 (B) 11010 (C) 4 1015 (D) 4 1010

28.  
The molar solubility in mol L1 of a sparingly soluble salt Mx4 is ' s ' . The corresponding solubility
product is K sp . ' s ' is given in terms of K sp by the relation –
1 1 1 1
(A) S   K sp /128  4 (B) S  128K sp  4 (C) S   256 K sp  5 (D) S   K sp / 256  5

29. The solubility product of a salt having general formula Mx2 in water is 4 1012 . The concentration
of M 2 ions in the aqueous solution of the salt is –
(A) 1.0 104 M (B) 2.0 106 M (C) 4.0 1010 M (D) 1.6 104 M

30. The first and second dissociation constants of an acid H 2 A are 1.0 105 & 5.0 1010 respectively.
The overall dissociation constant of the acidwill be -
(A) 5.0 105 (B) 5.0 1015 (C) 5.0 1015 (D) 0.2 105

31. The pK a of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50%
of the acid is ionized is-
(A) 4.5 (B) 2.5 (C) 9.5 (D) 7.0

32. In a saturated solution of the sparingly soluble strong electrolyte AgIO3 (molecularmass = 283) the
equilibrium which sets in is - AgIO3( s ) Ag  ( aq )  IO3( aq )
If the solubility product K sp of AgIO3 at a given temperature is 1.0 108 , what is the mass of AgIO3
contained in 100ml of its saturated solution ?
(A) 28.3 102 g (B) 28.3 104 g (C) 1.0 107 g (D) 1.0 104 g

Space for Rough Work

33. The pK a of a weak acid, HA, is 4.80. The pK a of a weak base, BOH, is 4.78. The pH of an aqueous
solution of the corresponding salt,BA,will be –
(A) 4.79 (B) 7.01 (C) 9.22 (D) 9.58

34. Solid Ba  NO3 2 is gradually dissolved in a 1.0 104 M Na2CO3 solution.At what concentration of
Ba 2 will a precipitate begin to form? ( K sp for Ba CO3  5.1 10 9 )
(A) 5.1105 M (B) 8.1108 M (C) 8.1107 M (D) 4.1105 M

35. How many litres of water must be added to 1 litre of an aqueous solution of HCl with a pHof 1 to
create an aqueous solutionwith pH of 2?
(A) 0.9 L (B) 2.0 L (C) 9.0 L (D) 0.1 L

1 Kp
36. For the reaction CO  O2  CO2 the value of is –
2 Kc
1 1
(A) (B) RT (C) (D) RT
RT RT

37. Which of the following equilibria is not affected by change in volume of the flask –
(A) PCl5 ( g ) PCl3 ( g )  Cl2 ( g ) (B) N2 ( g )  3H2 ( g ) 2 NH3 ( g )
(C) N2 ( g )  O2 ( g ) 2 NO( g ) (D) SO2Cl2 ( g ) SO2 ( g )  Cl2 ( g )

38. For the reaction equilibrium N2O4 ( g ) 2 NO2 ( g ) the concentrations of N 2O4 and NO2 at
equilibrium are 4.8 102 and 1.2 10 mol L1 respectively. The value of K c for the reaction
2

is –
(A) 3 103 mol L1 (B) 3 103 mol L1 (C) 3.3 102 mol L1 (D) 3 101 mol L1

39. Consider the reaction equilibrium 2SO2 ( g )  O2 ( g ) 2SO3 ( g ) ; H 0  198 kJ On the basis
of Le Chatelier’s principle, the condition favourable for the forward reaction is -
(A) Lowering the temperature and increasing the pressure
(B) Any value of temperature and pressure
(C) Lowering of temperature as well as pressure
(D) Increasing temperature as well as pressure

Space for Rough Work

40. What is the equilibrium expression for the reaction P4( s )  5O2( g ) P4O10( s ) ?
(A) Kc   P4O10   P4 O2  (B) Kc   P4O10  5  P4 O2 
5

(C) Kc  O2  (D) Kc  1 O2 

5 5

Kp
41. For the reaction CO( g )  Cl2( g ) COCl2( g ) the is equal to –
Kc
1
(A) (B) RT (C) RT (D) 1.0
RT

42. The equilibrium constant for the reaction N2( g )  O2( g ) 2 NO( g ) at temperature T is 4 104 .
1 1
The value of K c for the reaction NO( g ) N 2( g )  O2( g ) at the same temeperature is –
2 2

(A) 2.5 102 (B) 50 (C) 4 104 (D) 0.02

43. For the reaction :

2 NO2( g ) 2 NO( g )  O2( g ) .  Kc  1.8 106 at 1840 C   R  0.0831 kJ /  mol. K  
When Kp and Kc are compared at 184ºC it is found that
(A) K p is less than K c
(B) K p is greater than K c
(C) Whether K p is greater than, less than or equal to K c depends upon the total gas pressure
(D) K p  K c

44. The exothermic formaton of ClF3 is represented by the equation :

Cl2( g )  3F2( g ) 2 ClF3( g ) ; r H  329 kJ
Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2 , F2 and
ClF3 ?
(A) Removing Cl2 (B) Increasing the temperature
(C) Adding F2 (D) Increasing the volume of the container

45. The equilibrium constants K p1 and K p 2 for the reactions X P  Q, respectively

2Y and Z
are in the ratio of 1 : 9. If the degree of dissociation of X and Z be equal then the ratio of total
pressures at these equilibria is –
(A) 1 : 1 (B) 1 : 3 (C) 1 : 9 (D) 1 : 36

Space for Rough Work

 (SECTION – 2)

 This section contains FIVE (05) questions. The answer to each question is NUMERICAL
VALUE with two digit integer and decimal upto two digit.

 If the numerical value has more than two decimal places truncate/round-off the value to TWO
decimal places.
e.g : if your answer is 7 please fill it 7.00
If your answer is 7.2 please fill it 7.20.
If your answer is 6.246 please fill it 6.25
If your answer is 6.341 please fill it 6.34

 Marking scheme :
 Full Marks : +4 If the corresponding to the answer is darkened
 Zero Marks : 0 In all other cases.

46. 0.252 M solution of pyridinium chloride C5 H 6 N Cl  was found to have a pH of 2.699. If K b for

pyridine, C5 H 5 N is x 1010 , then calculate x . Take log (0.252)  0.6 and 100.8  6.25 . 
47. Calculate the pH of a solution prepared by mixing 50.0 mL of 0.200 M CH 3COOH and 50.0 mL of
0.100 M NaOH.  K a (CH3COOH  1.8 105   log10 18  1.26

48.  
If moles of CuI K sp  5 1012 dissolve in 1.0 L of 0.10 M NaI solution is x 1011 , then
calculate x ?

49. An equilibrium mixture of N 2 , H 2 , and NH 3 at 700 K contains 0.036 M N 2 and 0.15 M H 2 . At this
temperature, K c for the reaction N2 ( g )  3H2 ( g ) 2 NH3 ( g ) is 0.29.If concentration of NH 3 at
equilibrium is x 103 , then calculate x .

50. At some temperature and under a pressure of 4 atm, PCl5 is 10% dissociated . Calculate the
pressure at which PCl5 will be 20% dissociated , temperature remaining same.

Space for Rough Work

 Mathematics
4n
C2 n 1.3.5...(4n  1)
51. If p then p is
2n
Cn {1.3.5....(2n  1)}2
1
(A) (B) 2 (C) 1 (D) 4
2

52. The coefficient of xn in polynomial

( x  2 n1 C0 ) ( x  2 n1C1 ) ( x  2 n1C2 ) ......( x  2 n 1
Cn ) is
(A) 2 n1
(B) 2 2 n1
1 (C) 22n (D) None of these

53. In a test there were n questions. In the test 2ni students gave wrong answer to at least i questions
where i = 1, 2, 3, ......n. If the total numbers of wrong answers given is 2047 then n is
(A) 12 (B) 11 (C) 10 (D) 13

54. Number of ways to distribute 10 distinct balls to 3 persons. One getting 2, 2nd getting 3 and 3rd
getting 5 balls is
10! 10! 10!
(A) (B) (C) (D) 10!
2! 3! .5!
2
2!3!5! 2!.5!

55. The total number of selections of at most n things from  2n  1 different things is 63. The value of n
is
(A) 3 (B) 2 (C) 4 (D) None

56. If ‘n’ is an integer between 0 and 21, then the minimum value of n! 21  n ! is
(A) 9!2! (B) 10!11! (C) 20! (D) 21!

57. If n Pr  n Pr 1 and n Cr n Cr 1 , then  n, r  

(A)  3, 2 (B)  4, 3 (C)  4, 2 (D) None
______________________________________________________________________________________
Space for Rough Work
 The largest term in the expansion of  2  3x  where x  2 is its
25
58.
(A) 13th term (B) 19th term (C) 20th term (D) 26th term

If x  1, then the coefficient of xn in 1  2 x  3 x 2  4 x 3  .... is

1/2
59.
(A) n (B) n  1 (C) 1 (D)  1

If 1  x   a0  a1 x  a2 x 2  ........  a10 x10 , then

10
60.
 a0  a2  a4  a6  a8  a10    a1  a3  a5  a7  a9 
2 2
is equal to
(A) 310 (B) 210 (C) 29 (D) None of these

The number of real negative terms in the binomial expansion of 1  ix 

4 n2
61. , n  N , x  0, is
(A) n (B) n  1 (C) n  1 (D) 2n

The coefficient of x50 in the expansion of 1  x   2 x 1  x   3x2 1  x   ...........  1001x1000

1000 999 998
62.
is
(A) 1000C50 (B) 1001C50 (C) 1002
C50 (D) 21001

If C0 , C1 , C2 ,.........Cn are the binomial coefficients in the expansion of 1  x  . n being even, then
n
63.
C0  C0  C1   C0  C1  C2   ..................  C0  C1  C2  ..................  Cn1  is equal to
(A) n2n (B) n.2n1 (C) n.2n3 (D) n.2n2

64. Two 4 - digits numbers are to be formed such that the sum of the number is also a 4 - digit number
and in no place the addition is with carrying. The number of ways of forming the numbers under
above conditions is
(A) 554 (B) 220 (C) 454 (D 36  553
______________________________________________________________________________________
Space for Rough Work
65. A is a set containing n elements. A subset P of A is chosen. The set A is reconstructed by repacing
the elements of P. A subset Q of A is again chosen. The number of ways of choosing P and Q so that
P  Q contains exactly two elements is
(A) 9 n C 2 (B) 3n  n C2 (C) n C2 3n  2 (D) 4n  3n

66. If n  3 and n  N , then  n


Cr  Cr .
C0 abc  C1  a  1 b  1 c  1  C2  a  2  b  2  c  2   ....   1 Cn  a  n b  n  c  n  
n

(A) 3 (B) 2 (C) 1 (D) 0

67. Exponent of 12 in 50 ! is :
(A) 20 (B) 21 (C) 22 (D) 23

68. The number of ways of selecting 10 balls from the unlimited number of red, green, white and yellow
balls, if selection must include 2 red and 3 yellow balls, is
(A) 56 (B) 112 (C) 48 (D) 96

69. The largest integer 'n' such that 33! is divisible by 2n is

(A) 31 (B) 32 (C) 33 (D) None of these

70. We are required to form different words with the help of the help of the letters of the word
INTEGER. Let m1 be the number of words in which I and N are never together and m2 be the number
m
of words which begin with I and end with R, then 1 is given by :
m2

(A) 42 (B) 30 (C) 6 (D) 12

______________________________________________________________________________________
Space for Rough Work
 (SECTION – 2)

 This section contains FIVE (05) questions. The answer to each question is NUMERICAL
VALUE with two digit integer and decimal upto two digit.

 If the numerical value has more than two decimal places truncate/round-off the value to TWO
decimal places.
e.g : if your answer is 7 please fill it 7.00
If your answer is 7.2 please fill it 7.20.
If your answer is 6.246 please fill it 6.25
If your answer is 6.341 please fill it 6.34

 Marking scheme :
 Full Marks : +4 If the corresponding to the answer is darkened
 Zero Marks : 0 In all other cases.

71. Triplet  x, y, z  is chosen from the set {1, 2, 3, 4....n}such that x  y  z. The number of such triplets
possible if n  10 is

72. The number of ordered triplets  a, b, c  such that L.C. M.  a, b   1000, L. C. M b, c   2000 and L.
C. M  c, a   2000 is____________.

73. The number of ordered pairs  m, n ; m, n{1, 2, 3, ......., 20} such that 3m  7n is a multiple of 10, is
equal to

74. A person has 6 friends and during a certain vacation he met them during several dinners. He found
that he dinned with all the 6 exactly on one day, with every 5 of them on 2 days, with every 4 of
them on 3 days with every 3 on 4 days; with every 2 on 5 days. Furthers every friend was present at
7 dinners and every friend was absent at 7 dinners. The number of dinner(s) he has alone is equal to

75. The number of garlands that can be formed using 3 flowers of 1 kind and 12 flowers of the 2nd kind
is

Space for Rough Work