SECTION 1 - PRODUCT IDENTIFICATION

PRODUCT NAME: PART #69 - MEKP Hardener

PRODUCT SYNONYM(S): Luperox DDM-9

CHEMICAL FAMILY: Ketone Peroxide

PRODUCT USE: Polymerization Initiator

FIBRE GLAST DEVELOPMENTS CORP. TELEPHONE: (937) 833-5200

385 CARR FAX: (937) 833-6555
BROOKVILLE, OH 45309 FOR CHEMICAL EMERGENCY
CALL (801) 629-0667 24 HRS.

SECTION 2 - HAZARDS IDENTIFICATION

Emergency Overview

Color : Colourless
Physical state : liquid
Form : oily
Odor : sweet

*Classification of the substance or mixture:

Organic peroxides, Type D, H242
Skin corrosion, Category 1B, H314
Serious eye damage, Category 1, H318
Chronic aquatic toxicity, Category 3, H412

*For the full test of the H-Statements mentioned in this Section, see Section 16.

GHS – Labeling

Hazard pictograms :

Signal word : DANGER

Hazard statements:
H242: Heating may case a fire.
H314: Causes severe skin burns and eye damage.
H412: Harmful to aquatic life with long lasting effects.

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Supplemental Hazard Statements:
Organic peroxide. Hazardous decomposition may occur.
Precautionary statements:

Prevention:
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P220: Keep/Store away from clothing/combustible materials.
P234: Keep only in original container.
P264: Wash skin thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection face protection.

Response:
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 +P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contaminated contact
lenses, if present and easy to do so. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P363: Wash contaminated clothing before reuse.

Storage:
P405: Store locked up.
P410: Protect from sunlight.
P411: Maximum storage temperature is specified on label and in section 7 of SDS.
P420: Store away from other materials.

Disposal:
P501: Dispose of contents/container to an approved waste disposal plant.

Supplemental information:

Potential Health Effects:

If swallowed, may cause severe irritation and injury to the mouth, throat and digestive tract.

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Cas-No. Wt/Wt GHS Classification**

Propanoic acid, 2-methyl-, 2,2-dimethyl-1-

6846-50-0 > = 57 - < 59 % H412
(1-methylethyl)-1,3-propanediyl ester
2-butanone, peroxide 1338-23-4 > = 32 - < 34 % H302, H314, H318, H242
2,4-Pentanediol, 2-methyl- 107-41-5 > = 5.5 - < 6.5 % H319, H336
2-Butanone 78-93-3 >=1-<2% H225, H319, H336

**For the full text of H-Statements mentioned in this Section, see Section 16.

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 SECTION 4 - FIRST AID MEASURES

Inhalation:
If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.

Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes
before reuse.

Eyes:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention
immediately.

Ingestion:
If swallowed, DO NOT induce vomiting. Get medical attention immediately. If victim is fully conscious, give a cupful
of water. Never give anything by mouth to an unconscious person. Rinse mouth.

SECTION 5 - FIRE FIGHTING MEASURES

Extinguishing media (suitable):

Water spray, Carbon dioxide (CO2), Foam, Dry chemical

Protective equipment:
Firefighters and others who may be exposed to products of combustion should wear full firefighting turn out gear
(full Bunker Gear) and self-contained breathing apparatus (pressure demand/NIOSH approved or equivalent).

Further firefighting advice:

Fight fire with large amounts of water from a safe distance.
Cool closed containers exposed to fire with water spray.
Closed containers of this material may explode when subjected to heat from surrounding fire.
After a fire, wait until the material has cooled to room temperature before initiating clean-up activities.
Do not allow run-off from firefighting to enter drains or water courses.
Firefighting equipment should be thoroughly decontaminated after use.

Fire and explosion hazards:

Contact with incompatible materials or exposure to temperatures exceeding the SADT may result in a self-
accelerating decomposition reaction with release of flammable vapors which may auto ignite.
When burned, the following hazardous products of combustion can occur:
Carbon oxides
Hazardous organic compounds

SECTION 6 - ACCIDENTAL RELEASE MEASURES

In case of spill or leak:

Prevent further leakage or spillage if you can do so without risk. Evacuate area of all unnecessary personnel.
Ventilate the area. Eliminate all ignition sources. Avoid generation of vapors. Contain and collect spillage with non-
combustible absorbent material such as clean sand, earth, diatomaceous earth or non-acidic clay and place into
suitable properly labeled containers for prompt disposal. DO NOT USE peat moss. DO NOT USE vermiculite. Sweep
or scoop up using non-sparking tools and place into suitable properly labeled containers for prompt disposal. The
sweepings should be wetted down further with water. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers, Consult a regulatory specialist to determine appropriate state or local

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reporting requirements, for assistance in waste characterization and/or hazardous waste disposal and other
requirements listed in pertinent environmental permits. Add inhibitor to prevent polymerization.

SECTION 7 - HANDLING & STORAGE

Handling

General information on handling:

Contact with materials to avoid or exposure to temperatures exceeding the SADT may result in a self-accelerating
decomposition reaction with release of flammable vapors which may auto ignite.
Do not taste or swallow.
Do not get in eyes, on skin, or on clothing.
Avoid breathing vapor or mist.
Keep away from heat, sparks and flames.
No smoking.
Use only with adequate ventilation.
Wash thoroughly after handling.
Prevent product contamination.
Keep container tightly closed and away from combustible materials.
Keep only in the original container.
Do not reuse container as it may retain hazardous product residue.
Emptied container retains vapor and product residue.
Container hazardous when empty.
Improper disposal or reuse of this container may be dangerous and/or illegal.

Storage

General information on storage conditions:

Store in well ventilated area away from heat and sources of ignition such as flame, sparks and static electricity.
Store in closed containers, in a secure area to prevent container damage and subsequent spillage. Outside or
detached storage is preferred. Store out of direct sunlight in a cool well-ventilated place. Store in original
container. Store away from combustibles and materials to avoid. Refer also to National Fire Protection Association
(NFPA) Code 400, Hazardous Materials Code.

Storage stability – Remarks:

Follow the recommended storage temperatures provided in this Section in order to maintain stability and oxygen
content.

Storage incompatibility – General:

Store away from excessive heat, sources of ignition, and reactive materials.
Store separate from:
Strong acids
Strong bases
Strong oxidizing agents
Reducing agents
Accelerators
Friedel - Crafts reaction catalyst
transition metal salts
metal ions
Brass
Copper
Iron
For all Organic Peroxides, compatible materials of contact are stainless steel 304 or 316 (preferred), high-density
polyethylene (HDPE), polytetrafluoroethylene or glass linings.

Temperature tolerance – Do not store below: -

50 °F (10 °C)

Temperature tolerance – Do not store above:

100 °F (38 °C)

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 SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

Airborne Exposure Guidelines:

2-Butanone, peroxide (1338-23-4)

US. ACGIH Threshold Limit Values

Ceiling Limit Value 0.2 ppm

2, 4-Petanediol, 2-methyl-(107-41-5)

US. ACGIH Threshold Limit Values

Ceiling Limit Value 25 ppm

2-Butanone (78-93-3)

US. ACGIH Threshold Limit Values

Time weighted average 200 ppm
Short Term Exposure Limit (STEL) 300 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

PEL: 200 ppm (590 mg/m3)

Only those components with exposure limits are printed in this section. Limits with skin contact designation above
have skin contact effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent
significant cutaneous absorption may be required. Limits with a sensitizer designation above mean that exposure to
this material may cause allergic reactions.

Engineering controls:
Investigate engineering techniques to reduce exposures below airborne exposure limits or to otherwise reduce
exposures. Provide ventilation if necessary to minimize exposures or to control exposure levels to below airborne
exposure limits (if applicable see above). If practical use local mechanical exhaust ventilation at sources of air
contamination such as open process equipment.

Consult ACGIH ventilation manual or NFPA Standard 91 for design of exhaust systems.

Respiratory protection:
Avoid breathing vapor or mist. Where airborne exposure is likely or airborne exposure limits are exceeded (if
applicable, see above), Use NIOSH approved respiratory protection equipment appropriate to the material and/or
its components. Full face piece equipment is recommended and, if used, replaces need for face shield and/or
chemical goggles. Consult respirator manufacturer to determine appropriate type equipment for a given
application. Observe respiratory use limitations specified by NIOSH or the manufacturer. For emergency and other
conditions where they may be a potential for significant exposure or where exposing may be significantly exceeded,
use an approved full face positive-pressure, self-contained breathing apparatus or positive-pressure airline with
auxiliary self-contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134.

Skin protection:
Wear appropriate chemical resistant protective clothing and chemical resistant gloves to prevent skin contact.
Consult glove manufacturer to determine appropriate type glove material for given application. Wear chemical
goggles, a face shield, and chemical resistant clothing such as a rubber apron when splashing may occur. Rinse
immediately if skin is contaminated. Remove contaminated clothing immediately and wash before reuse. Clean
protective equipment before reuse. Provide a safety shower at any location where skin contact can occur. Wash
thoroughly after handling.

Eye protection:
Where there is potential for eye contact, wear a face shield, chemical goggles, and have eye flushing equipment
immediately available.

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 SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES

Color : Colourless

Physical State : Liquid

Form : Oily

Odor : Sweet

Odor Threshold : No data available.

Flash Point : The flashpoint of this product is greater than the Self Acceleration
Decomposition Temperature (SADT)

Auto-ignition Temperature : No data available.

Lower flammable limit (LFL) : No data available.

Upper flammable limit (UFL) : No data available.

pH : No data available.

Density : 1.0077 g/cm3 (68 °F (20 °C))

Specific Gravity (Relative density) : 1.0088 (68 °F (20 °C)) Water=1 (liquid)

Vapor pressure : 5.20 mmHg (66 °F (19 °C))

Vapor Density : No data available.

Boiling point/boiling range : Decomposes before boiling. Rate of decomposition increases with
rising temperature.

Freezing point : No data available.

Evaporation rate : No data available.

Solubility in water : slightly soluble.

Refractive index : 1.456

Viscosity, dynamic : 17.30 mPa.s 68 °F (20 °C)

Oil/water partition coefficient : No data available.

Self-Accelerating Decomposition : 167 °F (75 °C) 45 pound container

Temperature (SADT)

Thermal decomposition : Decomposes on heating.

Active oxygen content : 8.7 – 9.0 %

Flammability : See GHS Classification in Section 2.

SECTION 10 - STABILITY & REACTIVITY

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Stability:
This material is chemically unstable and should only be handled under specified conditions.

Hazardous reactions:
Hazardous polymerization does not occur.

Materials to avoid:
Strong acids
Strong bases
Strong oxidizing agents
Reducing agents
Accelerators
Friedel – Crafts reaction catalyst
Transition metal salts
Metal ions
Brass
Copper
Iron
For all Organic Peroxides, compatible materials of contact are stainless steel 304 or 316 (preferred), high-density
polyethylene (HDPE), polytetrafluoroethylene or glass linings.

Conditions/hazards to avoid:
SADT – Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size will
undergo a self-accelerating decomposition reaction. This reaction will generate flammable vapors which may auto
ignite. The length of time to generate a decomposition reaction, after the SADT has been reached or exceeded, is
dependent upon how much the SADT has been exceeded and the length of time needed for the reaction exotherm
(heat spike from increasing decomposition rate) to initiate a rapid decomposition reaction. Typically, SADT is
inversely proportional to package size. Larger packages will have a lower SADT due to smaller ratio to heat transfer
area to volume of product. See HANDLING AND STORAGE section of this SDS for specified conditions. See
Hazardous Decomposition Products below.

Hazardous decomposition products:

Temperatures at or above SADT can result in the release of hazardous decomposition products which are
flammable and may auto ignite
Thermal decomposition giving flammable and toxic products:
Carbon oxides
Hazardous organic compounds

SECTION 11 - TOXICOLOGICAL INFORMATION

Data for LUPEROX® DDM-9

Acute Toxicity

Oral:
Acute toxicity estimate 2,859 mg/kg.

Dermal:
Acute toxicity estimate > 5,000 mg/kg.

Inhalation:
4 h Acute toxicity estimate > 40 mg/l. (vapor)

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Data for Propanoic acid, 2-methyl-, 2,2-dimethyl-1-(1-methylethyl)-1,3 –propanediyl ester (6846-50-0)

Acute toxicity

Oral:
No deaths occurred. (rat) LD0 > 2,000 mg/kg.
Dermal:
No deaths occurred. (rabbit) LD0 > 2,000 mg/kg.

Inhalation:
No deaths occurred. (rat) 6 h LC0 > 5.3 mg/l.

Skin Irritation:
Not irritating. (Rabbit) Irritation Index: 0/8. (4 h)

Eye Irritation:
Causes mild eye irritation. (Rabbit)

Skin Sensitization:
Not a sensitizer. Repeated skin exposure. (guinea pig) No skin allergy or irritation was observed.

Repeated dose toxicity

Repeated oral administration to rat / affected organ(s): kidney, liver / signs: clinical chemistry changes, changes in
organ weights, hyaline droplet nephropathy / (not considered relevant in humans)

Sub chronic dietary administration to a dog/No adverse systemic effects reported.

Genotoxicity

Assessment in Vitro:
No genetic changes were observed in laboratory tests using: bacteria, animal cells

Developmental toxicity
Reproductive/Developmental Effects Screening Assay. Dietary (rat) / No birth defects were observed.

Reproductive effects
Reproductive/Developmental Effects Screening Assay. Dietary (rat) / No toxicity to reproduction. At high dose:
levels produced toxic effects in the mothers and offspring.

Human Experience

Skin contact
No skin allergy was observed. (studied using human volunteers)

Data for 2-Butanone, peroxide (1338-23-4)

Acute toxicity

Oral:
Harmful if swallowed. (rat) LD50 = 1,017 mg/kg. (35 - 39 %) (In solution in Dimethyl phthalate)

Dermal:
Harmful in contact with skin. (rabbit) LD50 = 4,000 mg/kg. (35 - 39 %) (In solution in Dimethyl phthalate)

Inhalation:
Practically nontoxic. (rat) 4 h LC50 = 17 mg/l. (35 - 39 %) (aerosol, In solution in Dimethyl phthalate)

Skin irritation:
Causes severe skin burns. (Rabbit) (4 h) (33%) (occluded exposure, in solution in Dimethyl phthalate)

Eye irritation:
Causes serious eye damage. (rabbit) OECD Test Guideline 405 (33 - 39 %) (In solution in Dimethyl phthalate)

Skin Sensitization:

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Not a sensitizer. Guinea pig maximization test. No skin allergy was observed (40%) (In solution in Dimethyl
phthalate)

Repeated dose toxicity

Repeated oral administration to Rat / affected organ(s): stomach, liver / signs: Irritation of the gastric mucosa,
increased organ weight

Subchronic dermal administration to rat and mouse / affected organ(s): skin/ signs: severe damage / No adverse
systemic effects reported.

Genotoxicity

Assessment in Vitro:
Both positive and negative responses for genetic changes were observed in laboratory tests using:
Bacteria, animal cells

Genotoxicity

Assessment in Vivo:
No genetic changes were observed in laboratory testing using: mice

Developmental toxicity

Reproductive/Developmental Effects Screening Assay. Oral (Rat) / No birth defects were observed.

Reproductive effects
Reproductive/Developmental Effects Screening Assay. Oral (Rat) / No toxicity to reproduction.

Human experience
Skin contact:
No skin allergy was observed. (studied using human volunteers)

Skin allergy was observed. Isolated case reports after exposure to a mixture containing this substance.

Human experience
Eye contact:
Eyes: Pain, tearing, sensitivity to light, irritation. Mist and/or vapor are reported to cause irritation when proper
industrial hygiene controls/procedures are not used. (based on reports of occupational exposure to workers)
(severity of effects depends on extent of exposure)

Eyes: Pain, causes severe burns. (accidental exposure to concentrated solutions) (based on reports of occupational
exposure to workers) (severity of effects depends on extent of exposure)

Human experience
Ingestion:
Esophagus: Severe irritation, burns. (accidental exposure to concentrated solutions)

Data for 2,4-Pentanediol, 2-methyl-(107-41-5)

Acute toxicity

Oral:
No deaths occurred. (rat) LD0 > 2,000 mg/kg. signs: GI tract irritation, central nervous system depression

Dermal:
No deaths occurred. (rat) LD0 > 2,000 mg/kg.

Inhalation:
No deaths occurred. (rat) 8 h LC0 >= 0.34 mg/l (70 ppm). (saturated vapor)

Specific target organ toxicity – single exposure:

May cause drowsiness or dizziness.

Skin irritation:
Practically non-irritating. (Rabbit) (4 h)

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Eye irritation:
Causes serious eye irritation (Rabbit)

Skin Sensitization:
Not a sensitizer. Repeated skin exposure. (Guinea pig) No skin allergy or irritation was observed.

Repeated dose toxicity

Subchronic oral administration to rat / affected organ(s): kidney, liver, Stomach / signs: Irritation of the gastric
mucosa / No significant impairment of function.

Repeated inhalation administration to rat / affected organ(s): upper respiratory tract / Local irritation (Aerosol)

Genotoxicity

Assessment in Vitro:
No genetic changes were observed in laboratory tests using: bacteria, animal cells

Developmental toxicity
Exposure during pregnanancy. Oral (rat) / No birth defects were observed. (delays in development, at doses that
produce effects in mothers)

Reproductive effects
Reproductive/Developmental Effects Screening Assay. Oral (rat) / No toxicity to reproduction. At high dose: Effects
on offspring / (increased mortality in the offspring, decreased growth rate)

Human experience
Inhalation:
Discomfort. (severity of effects depends on extent of exposure) (studied using human volunteers)

Human experience
Skin contact:
No skin allergy was observed. (studied using human volunteers)

Local irritation, redness, swelling. (subjects with dermatitis or eczema)

Central nervous system depression. (severity of effects depends on extent of exposure)

Human experience
Eye contact:
Discomfort, slightly irritating. (liquid or aerosol) (studied using human volunteers) (severity of effects depends on
extent of exposure)

Data for 2-Butanone (78-93-3)

Acute toxicity

Oral:
May be harmful if swallowed. (rat) LD50 = 2,600 - 5,400 mg/kg.

Dermal:
Practically nontoxic. (rabbit) LD50 > 6,400 - 8,000 mg/kg.

Inhalation:
Practically nontoxic. (rat) 4 h LC50 = 34.5 mg/l (11700 ppm).

Specific target organ toxicity – single exposure:

May cause drowsiness or dizziness.

Skin Irritation:
Causes skin irritation. (Rabbit) (24 h)

Eye Irritation:
Causes serious eye irritation. (Rabbit) Draize Test 21/110).

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Skin Sensitization:
Not a sensitizer. Buehler method. (Guinea pig) No skin allergy was observed

Repeated dose toxicity

Sub chronic inhalation administration to Rat / affected organ(s): liver / signs: blood chemistry changes, changes in
organ weights.

Repeated inhalation administration to rat, mouse, cat, chicken / no nervous system injuries

Carcinogenicity
Chronic dermal application administration to Mouse / signs: No increase in tumor incidence was reported.

Genotoxicity

Assessment in Vitro:
No genetic changes were observed in laboratory tests using: bacteria, animal cells, human cells

Both positive and equivocal responses have been reported in tests using: yeast

Genotoxicity

Assessment in Vivo:
No genetic changes were observed in laboratory tests using: mice, hamster

Developmental toxicity

Exposure during pregnancy. Inhalation (Mouse) / No birth defects were observed. (skeletal variations, delays in
development)
Exposure during pregnancy. Inhalation (Rat) / No birth defects were observed. (delays in development, at doses
that produce effects in mothers)

Reproductive effects
Reproduction test. Drinking water (Rat) / No toxicity to reproduction / (similar material)

Human experience
Inhalation:
Upper respiratory tract: irritation. (vapor)

Central nervous system: drowsiness, dizziness. Exposure to other materials makes the association questionable.
(based on reports of occupational exposure to workers)

Nervous system: altered reflexes, changes in motor activity. Exposure to other materials makes the association
questionable. (based on reports of occupational exposure to workers)

Human experience
Skin contact:
Skin: No skin allergy was observed. (studied using human volunteers)

Skin: dermatitis, cracking. Has a degreasing effect on the skin. (repeated or prolonged exposure)

Human exposure
Eye contact:
Eyes: irritating. (vapor)

SECTION 12 - ECOLOGICAL INFORMATION

Chemical Fate and Pathway

Data on this material and/or its components are summarized below.

Data for Propanoic acid, 2-methyl-, 2,2-dimethyl-1-(1-methylethyl)-1,3-propanediyl ester (6846-50-0)

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Biodegradation
Inherently biodegradable. (aerobic, 28 d) biodegradation 71 % / The 10 day time window criterion is not fulfilled.

Theoretical Biological Oxygen Demand:

Theoretical oxygen demand (ThOD)=2,400 mg/g

Bio-accumulation:

BCF=670 (without metabolism)

BCF = 14,611 (with metabolism)

BCF = 5.2 – 31 (Carp)

Octanol Water Partition Coefficient:

Log Pow = 4.04 – 4.91 (calculated)

Data for 2-Butanone, peroxide (1338-23-4)

Biodegradation:
Readily biodegradable. (28 d) biodegradation 87 % / OECD guideline 301D (Closed bottle test)

Octanol Water Partition Coefficient:

Log Pow < 0.3, at 77 °F (25 °C) (Method: OECD Test Guideline 117)

Data for 2,4-Pentanediol, 2-methyl-(107-41-5)

Biodegradation:
Readily biodegradable. (28 d) biodegradation 81% / OECD Test Guideline 301 F

Octanol Water Partition Coefficient:

Log Pow=-0.14 (Method: calculated)

Data for 2-Butanone (78-93-3)

Biodegradation:
Readily biodegradable. (28 d) biodegradation 98% / OECD Test Guideline 301 D

Octanol Water Partition Coefficient:

Log Pow=0.3

Photodegradation:
Hal-life direct photolysis = 6.9 days
(is rapidly degraded in air by OH radicals)

Ecotoxicology
Data on this material and/or its components are summarized below.

Data for Propanoic acid, 2-methyl-,2,2-dimethyl-1-(1_methylethyl)-1,3-propanediyl ester (6846-50-0)

Aquatic toxicity data:

No effect up to the limit of solubility. Lepomis macrochirus (Bluegill sunfish) 96 h NOEC > 6 mg/l

Aquatic invertebrates:
No effect up to the limit of solubility. Daphnia magna (Water flea) 48 h EC50 > 1.46mg/l

Algae:
No effect up to the limit of solubility. Selenastrum capricornutum 72 h EC50 (growth rate) > 7.49 mg/l

Chronic toxicity to aquatic invertebrates:

Harmful. Daphnia magna (Water flea) 21 d NOEC (reproduction) = 0.7 mg/l

Data for 2-Butanone, peroxide (1338-23-4)

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Aquatic toxicity data:
Harmful. Poecilia reticulate (guppy) 96 h LC50 = 44.2 mg/l (In solution in Dimethyl phthalate)

Aquatic invertebrates:
Harmful. Daphnia (water flea) 48 h EC50 = 39 mg/l (In solution in Dimethyl phthalate)

Algae:
Toxic. Pseudokirchneriella subcapitata (green algae) 72 h ErC50 = 5.6 mg/l (In solution in Dimethyl phthalate)

Microorganisms:
Respiration inhibition/ Activated sludge 30 min EC50=48 mg/l (In solution Dimethyl phthalate)

Data for 2,4-Pentanediol, 2-methyl-(107-41-5)

Aquatic toxicity data:

Practically nontoxic. Gambusia affinis (Mosquito fish) 96 h LC50 = 8,510 mg/l

Aquatic invertebrates:
Practically nontoxic. Daphnia magna (water flea) 48 h EC50 = 3,200 – 5,410 mg/l

Algae:
Practically nontoxic. Selenastrum capricornutum 72 h EC50 > 429 mg/l

Microorganisms:
Bacteria 10 d NOEC > 1,000 mg/l

Chronic toxicity to aquatic plants:

Practically nontoxic. Pseudokirchneriella subcapitata (green algae) 72 d NOEC = 429 mg/l

Data for 2-Butanone (78-93-3)

Aquatic toxicity data:

Practically nontoxic. Pimephales promelas (fathead minnow) 96 h LC50 = 3,200 mg/l

Aquatic invertebrates:
Practically nontoxic. Daphnia magna (Water flea) 48 h EC50 = 308 mg/l

Algae:
Practically nontoxic. Pseudokirchneriella subcapitata (green algae) 72 h EC50=1972 mg/l

Microorganisms:
Pseudomonas putida 16 h Toxicity threshold=1150 mg/l

SECTION 13 - DISPOSAL CONSIDERATIONS

Waste Disposal:
Dilution followed by incineration is the preferred method. Dilution ration of 10:1 in a clean, compatible, combustible
solvent (i.e., Fuel Oil #2, mineral oil) will reduce reactivity hazard during incineration and transportation. Dispose
of in accordance with federal, state and local regulations. Consult a regulatory specialist to determine appropriate
state or local reporting requirements, for assistance in waste characterization and/or hazardous waste disposal and
other requirements listed in pertinent environmental permits. Note: Chemical additions to, processing of, or
otherwise altering this material may make this waste management information incomplete, inaccurate, or
otherwise inappropriate. Furthermore, state and local waste disposal requirements may be more restrictive or
otherwise different from federal laws and regulations.

Take appropriate measures to prevent release to the environment.

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 SECTION 14 - TRANSPORT INFORMATION

US Department of Transportation (DOT):

UN Number 3105
Proper shipping name : Organic peroxide type D, liquid
Technical name : Methyl ethyl ketone peroxide(s), ≤45%
Class : 5.2
Marine pollutant : No
Reportable quantity : 10 lbs (Methyl ethyl ketone peroxide(s))

International Maritime Dangerous Goods Code (IMDG):

UN Number 3105
Proper shipping name : Organic peroxide type D, liquid
Technical name : Methyl ethyl ketone peroxide(s), ≤45%
Class : 5.2
Marine Pollutant : No

SECTION 15 - REGULATORY INFORMATION

Chemical Inventory Status

EU EINECS EINECS Conforms to

United States TSCA Inventory TSCA The components of this product are all on the TSCA
Inventory

Canadian Domestic Substances List (DSL) DSL All components of this product are on the Canadian
DSL

China. Inventory of Existing Chemical IECSC (CN) Conforms to

Substances in China (IECSC)

Japan. ENCS – Existing and New Chemical ENCS (JP) Conforms to

Substances Inventory

Japan. ISHL – Inventory of Chemicals ISHL (JP) Conforms to

Inventory (KECI)

Korea. Korean Existing Chemicals KECI (KR) Conforms to

Inventory (KECI)

Philippines Inventory of Chemicals PICCS (PH) Conforms to

And Chemical Substances (PICCS)

Australia Inventory of Chemical AICS Conforms to

Substances (AICS)
United States – Federal Regulations

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SARA Title III – Section 302 Extremely Hazardous Chemicals:

Chemical Name CAS-No. SARA SARA

Reportable Threshold
Quantities Planning
Quantity
HYDROGEN PEROXIDE 7722-84-1 1000 lbs. 1000 lbs.

SARA Title III – Section 311/312 Hazard Categories:

Acute Health Hazard, Reactivity Hazard

SARA Title III – Section 313 Toxic Chemicals:

This material does not contain any chemical components with known CAS numbers that exceed the threshold (De
Minimis) reporting levels established by SARA Title III, Section 313.

Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) – Reportable

Quantity (RQ):

Chemical Name CAS-No. Reportable quantity

2-Butanone, peroxide 1338-23-4 10 lbs.
2-Butanone 78-93-3 5000 lbs.

United States – State Regulations

New Jersey Right to Know

Chemical Name CAS-No.
2-Butanone, peroxide 1338-23-4
2,4-Pentanediol, 2-methyl 107-44-5
2-Butanone 78-93-3

New Jersey Right to Know – Special Health Hazard Substance(s)

Chemical Name CAS-No.
2-Butanone, peroxide 1338-23-4
2-Butanone 78-93-3

Pennsylvania Right to Know

Chemical Name CAS-No.

Propanoic acid, 2-methyl-, 2,2-dimethyl-1-(1-methylethyl)- 6846-50-0
1,3-propanediyl ester

2-Butanone, peroxide 1338-23-4

2,4-Pentanediol, 2-methyl- 107-41-5

2-Butanone 78-93-3
HYDROGEN PEROXIDE 7722-84-1

Pennsylvania Right to Know – Environmentally Hazardous Substance(s)

Chemical Name CAS-No.

2-Butanone, peroxide 1338-23-4
2-Butanone 78-93-3
HYDROGEN PEROXIDE 7722-84-1

PDCT-SDS-00019 [Version 1.00]

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California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any
other reproductive defects.

SECTION 16 – OTHER INFORMATION

Revision Date

August 28, 2019

Full text of H-Statements referred to under sections 2 and 3.

H225 Highly flammable liquid and vapour

H242 Heating may cause fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.

The information accumulated herein is believed to be accurate but is not warranted to be, whether originating with
Fibre Glast Developments Corporation or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances.

PDCT-SDS-00019 [Version 1.00]

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