StructureofAtom Notes Part1 JEENEETIJSO MridulPandey

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IJSO (IOQJS 2022-23)

Structure of Atom

Pioneer Mridul Pandey Pioneer Mridul Pandey


Target IJSO (IOQJS 2022-23)

Structure of Atom

Malton : -

that exhibits inertia is called Matter


Anything .

Those
occupies some space
.

eq
-

Chair , Table ,
Pen eteo

Note : Light ,
Sound and Heats the form of energy .

Physical classification of Malter : -

Melting vapaurisation Ionisation


' '
Plasma
'

solid -
Liquid ← Gas ,

condensation
freezing Deionisation
Chemical classification of Malter : -

Matter
1

Pure substance Ampule'


substance
mixture
'

v v
t 1

Element Compound Homogenous Heterogenous


↳ solution 95nspension
'

Atom Inorganic Engine :


colloidal

* Elements : -

→ Itis the simplest form of the Maltese


smallest unit element is called Atom
'

of

an

94 Natural
Total Known Elements -_
118

Rest manmade .

* Compounds : -

Elements or molecules combine in a


fixed
proportion to form compound .

* Inorganic compounds : obtained from minerals .gs Nacl

* Organic compounds : obtained from organism .

egni Glucose .
\

Laws
of chemical combination

L Law chemical combination


.

of

According to the law of of


'
conservation mass matter
neither be created nor destroyed in any ctiemecal
'

reaction ,
It remains conserved -

Man
of reactants will be
equal to the mass of products .

Note → Reaction must be balanced .

cgi Hy 1- Cla → 2 HCl

tag +
71g 2×365
It I
=

73g 73g

2. Law
of constant
Proportions
'
A pure chemical contain the same elements
compound
combined together in fixed proportion Ty
'
a mass

egñ It we take water from river on


from an

ocean
,
both have oxygen and
hydrogen in
the same
proportions .

1: 8
Hao proportion
mass → 2:16 →
Daltons Atomic theory -

'

of averting particles called atoms


'

↳ All matter is made

2.) Atoms are indivisible particles which ,


cannot be created
or
destroyed in chemical reaction .

3) Atoms of given element are identical in mass


a

and chemical
properties ( law of conservation of mass)
A) Atoms ofdifferent element have different masses
a

and chemical
properties of law of constant proportions]
5.) Atoms combine in a
fixed ratio to form compounds

Atoms →

An atom is the smallest particles of matter of an elements


which takes part in chemical reaction .

Atoms very small and which cannot be seen


are even

through very powerful microscope .

Atomic radius = 159m


Nucleus radius =
-

lo 15m
Radiuslm ) Example
town Atomof Hydrogen
107m Molecule
ofwatoo
room molecule
of Haemoglobin
loom
to'm
hnainofsand
Ant
1ohm Watermelon

Modern day symbols of Elements →

Daltonwasthefinstscientisttousethesymbolsof elements
Benziliussuggutedthatthesymbolsofelementsshould
be made the
one or more letters
of name of
the elements .

Copper was taken from coypus place where itisfoundo


Discovery of Electron -

(study of cathode Ray)


> J.J. Thomson observed that , when atnigh voltage
is applied between the electrodes fitted
at
in discharge tube , a
verylow pressure
and
high voltage ,
some invisible radiations
are emitted from cathode .

>
At this stage wall of the discharge tube
near cathode starts
glowing .

Has at low pressure)


cathode

É☒¥*±• U -

Green Glow

Origin of cathode
Ray : -

Cathode
rays
are
first produced in
cathode due to bombardment of the
gas molecules
the high speed electrons first
try emitted
from the cathode .

Glowing is due to the bombardment of glass wall
Try
the cathode It be noted that when
rays may
.

the
gas pressure in the tube is latm , no

electric current flows through the tube • This


is because the are
poor conductor of
gases
electricity ?

Properties of cathode Rays : -

1) Cathode rays travel is straight line with high speedo

→ shadow of cross .


EEE

2.) Cathode rags made up of materials particles .

ionization of the gas through which they


3.) They cause

pass o

Hq → 24-1 + 2e-
A) Cathode rays carry negative citrange ,
because they
are
deflected in electric field as well as

magnetic field •

I>
z

'

They X rays when


they strikes
'

8) produce -

on the
hard metals
surface of eq W, Mo etc

→ L
nay

b) they affect the photographic plates .

7) they produce green fluorescence on the glass walls

of the discharge tube experiment .

2ns
eg
.
.

2) The nature of cathode rays does not depend the


upon
nature of gas taken in the tube discharge
and the nature of cathode material .

9) For each cathode


rays ,
the ratio of charge (e) to macs
is constant .
* charge -1.6×10-19
: coulomb I
determinedly Milliken
.

by oil drop experiment .

# Macs : 9.11 ✗ 1528g (nearly equal to 41837th of macs of proton

* specific charge : 10-19


Charge l 6 ✗ ,
176×10%1 gm
-
-

-
=
=

mass 9- I ✗ to 22g

Discovery of Proton : study of Canal Rays : -

Goldstein discovered the


presence of Positive Rays .

Heperformed discharge tube experiment in which he


took perforated cathode and passing through
the hole in the cathode gives
fluorescence on

the opposite
glass wall coated with 2ns
.

These
nays are called as Anode rays on Canal rays .

i¥¥*¥÷ _
H2 gas at 100 pressure .

"
Origin of Canal Rays
.

In the discharge tube the atoms

of gas lose negatively charged electrons .

These atoms , thus


acquire a positive charge .

The positively charged particle produced from hydrogen


was called the proto no
gas

Ha →
2h -1 + 2e-

Properties of Anode Rays : -

J They travel in straight lines However the speed


.
of
canal rays is less than cathode rays .

2.) they are made up of material particles .

3.)
They are
positively charged ,
hence
they are called
as canal rays .

A)
They nature of anode
rays depends on the nature of
gas taken in
the
discharge tube .

different gases taken in discharge charge


for tube the
to mass ratio of particles constituting the
the .

positive rays is different .


I

* Change : -
+1-6×10-19 coulombs .

1.672×10-2 kg
'

*
-

* Specificcharge =
depend on the nature
of gas
.

Neutron :( 's on

It was discovered Chadwick


' by by
bombarding Beaton with high speed d- particles
'
.

"
BE 244
'

g.
+ >
gc -1 on

2- particles
c) N→

N→ N→

N→

Alpha particle source N→ them

* charge : changeless or Neutral .

* Macs : 1.67s ✗ b- 24g


* Specific Charge : It is zero .

Among all the


elementary particles neutron is the hairiest
and least stable .
Properties of Electron, Proton and Neutron

Properties Electron Proton Neutron

Discovery J.J. Thomson Goldstein Chadwick

charge -16×10-11 +16×10-11 zero

mass 9-1×1-0 "kg 1.672×1-0"kg 1-675×10%2


ctvnge / Macs 1.76×18 clgm Natured has Zero

classical Moderns of Atom :


1) Thomson 's Atomic Model : -

According to thomson anatomies ,


a

sphere of positive charge having number


of embedded
a

electron in it and sufficient enough to


neutralize the positive charge .

Positively ctrarged
Watermelon Model
Plum
Pudding
Model
Electrons

→ This model is compared with a watermelon
in which seeds are embedded or
Pudding
in which resins are embedded .
Limitation : -

this model failed to explain the results of scattering


experiments of Rutherford and stability of Atom .

2.) Rutherford Atomic Model :


's

Rutherford performed 4- ray scattering


,

experiment in which he bombarded thin foils of metal like


gold (silver Ab Pt) with beam of fast
, ,
a
moving d- ray .

Observations conclusions :

1) Most of the 4- particles passedthrough


the gold fail without any deflection

2.) A few of the d- particles are

deflected fairly at large angles


and while some are small
angles •

very few
3) A deflected back their path
d- particles are
along
.
1) Atom is spherical and
mostly hollow with a lot of empty space .

at its centre
2.) It has small
positively charged part known as Nucleus .

3) The nucleus is surrounded By


Electrons The electrons revolve .

around the nucleus with speed in circular


very high
path called Orbit / shell] .

<
→ velocity change
'
* e- Fe
Fe Fc
¥
=

+
Fe =
Electrostatic force
Fc =

Centripetal force .

Failure
of Rutherford model of Atom : -

I
Maxwell Theory :( Electro-magnetic theory
•• When a
charged particle moves under the
influence
of attraction force it looses energy
continuously in the
form of electromagnetic
radiation
••
As result the electron should lose at every
a ,
energy
turn and it will fall into the nucleus which
makes atom unstable .
* Atomic Number :-( 2)
Atomic nlo.denotesthetatalno.fr
protons present in the nucleus of an atom .

ON

Tatalnoof electrons present in neutral atom .

z=p=e ( neutral atoms


-

* Mass Number :-( A)


Mass no is the total .
no .

@ protons
and neutrons present in the nucleus of an atom .

9- =p -1m

n= A -2


mass No
-

Atone:-c symbol of element


No .

* Isotopes : -

he atom
of element which have the
-

same

same atomic no
-

but different macs number are

called as isotopes .

eq ?
9:
,cP? ncis
.

'
IH 1h2, 1h3 , ,
Ptotium Deuterium Tritium
'
-
Note : Isotopes of an element differ in the number of
neutrons present in nucleus . But
they
always Trave same no of protons and .

electrons Iso they shoo same chemical property


.

but
different physical property .

* Isobars :
The atoms of different elements which have the
same mass numbers but different atomic numbers
are called isobars .

eg :
-

potato Kto , potato


They are
differ chemically .

* Iso tones : -

Tso tones are atoms of different elements


which have the same number of neutrons .

9 '

1h3 Het Both Trave 2 neutrons •


, 2

* Iso electronics : -

Atoms or ions which have same no .

of electrons is called as isoelectronicso


ego
,§i&+→ They
" "
Nat 1371 have toe
1, , 12mg ,
,
.
Bohr's Atomic Theory : -

To overcome the
objections of
Rutherford ,
Bohr proposed a
quantum
mechanical model o

1) Atom has a
centre called nucleus .

2.) Electrons revolve only in fixed circular path


( orbits with fixed energy ( fixed velocity) .

( n =
1,334,00
3.) guantisation Condition : -

Electron revolves only


in those circular orbit for which
angular
momentum ( L) is integral multiple of nI •

21T

n = no .

of shell
1- It 2¥ 3¥ 1¥

,

,

,

n =
b k shell
n =
2, L Shell
n =3
,
M shell

n =
9 , Nl shell

Tn =
planck constant
=
6.626 ✗ 10-3%-1see
Angular Momentum :-( E)
E=F×p→
t ↳
be e- me

Momentum V
radius
^

← r→
e- a-
= I ✗ m.ve

=
massive .
I e-
so

I =

mierlo __qo5

Angular momentum of electron is Muro

Mur =

n¥-, 0
Bohnguantisation Condition .

n= no -

of shell D= Planck constant


e-
velocity of electron =
6.626×10-38 / Sec
r =
radius
m= mats
of electron

4) While revolving the electrostaticforce between e-


and nucleus provides centripetal force .

+ > e- e-

Zxet Fe -
Electrostatic Foncelbetuteewzcihohge
Fe
Jpeg EiE2_ Go epsilon 8854187817
= = =

82
q,= et
Z
, qz = e-

5) If anybody revolve around the object having


any
and '

velocity
'
mass m
'
v1 .

✓ E Fe =
Fc
•<

éJI-
^
1-
Fe

.
=

41T C- 0

¥0 3¥ m¥-①
'
=

Mor -

2¥ -0 .

late; ?g÷= MII -

6) While in perteceelan orbit


revolving a
,
an e- neither

looses
gains energy nor
energy
.

( energy of an orbit /shell) is fixed ) .

n-I.sn pit
Calculation of radius velocity uh kinetic energy 1k
ID , ,
-
E)
potential energy of e- •

j Radius

2¥ = must @

Itai =m±
r

2
C) :-( 11 ) ( =

Atomic Number)

"
=¥mIz ,
rn=os > ✗ A

A) Find the radius of Ist 2nd sod ,


shell
of H -
atom .

For Istshell
,
8
,
= 0-53 ✗
f- Ao

2nd shell 02 0.53 ✗


& Ao
=

3ms hell , 83 = 0.53 ✗ 9 40


2.) Velocity
4- =
Ze÷
20h Can

be =

218×106×22 mlsec

3J
Energy of an Electron : -

Kinetic energy ( K -

E.) = 2=2 =
Izmail
28

Potential
-3¥ 9%-2
=

energy ( p.ES =

EKE + Ep -

E.
=

22¥ +
(-2%2)
En =
-
2=2
28

putting the value


of r -

?mz?e&
-13-6×32-2
-21T
En
E. / per
-_
=
eu
nzpf

tell __
1.6×10-1%-1 ahem .
For H -
atom

for Éts hell =

-13^6.2-22 ere = -

13 bell
-

2ndshell = -
13.6 . 12
ele =
-3.4 ele
z

34s hell

6.g #eie- -1-S7eie4Mshel1- -13.6.pz2-eie- -o-8seU


=
-13 -

Maximum Energy
-

n =p

at this
energy
e-
free
- -

from the nucleus •

136
Ionisation has oeecuredo
- so
-1.57
Energy Increases o

-
0.85
7) Electron can
accept energy ,
can lose
energy
8D If an
accept an energy it jumps
electron
to
higher energy level (excitation of e) .

of an loses
e-
energy
it return taek to
lower
energy level .

(de excitation of )
e-

9) An e- gains or loses only those energy which


in
are

level
equal
°
to
difference two
energy

E, + at =
Ez

GE =
Ez -

Ei
* This formula is applicable for une electronic species
( hydrogen or
hydrogen like species He's 42J Best

t { }
2
* K E -
. = Ze
- K Ed on
increasing r
, KE I
I

¥{ }
2
4- P E
. = -
Ze
,
P E d
.

on in erasing B P . E. a
g-

* TE
-22¥ T E
2¥ / increasing IT E t
}
=
on
.

P E
- = -2 .

K E .

, K E .
=
-

T E .
P E = 2T -
E

1) Ionisation Energy : -

minimum amount of energy


liberate
required to an electron
from the

ground state of isolated atom is called as

ionization
energy
.

n 1 = 1 n 2--00 .

2.) separating Energy : -

Minimum amount of required


energy
to remove an electron its excited state
from o

hi
=
33,4 -
Nz = A

3) Excitation Amount of
Energy : -

energy required to shift an


electron from ground state to any excited
state o n , = 1 na 3 3- & I =
-

,
A) Calculate the radius ratio of god and sth orbit
of Het
.

Solution

8--0.53-2-2
°

A- 2=2
,

53rd
=
osz .

13¥ = 9:25
Im
-

0.53 .
1532
2-

QD Calculate the electron placed in the


velocity of an

3M orbit of the
hydrogen atoms .

@ Also calculate the number of revolutions per


second that this electron makes around
the nucleus °

Solution

① On 2- 182×106
# 1sec
=
m

7-27×105 ml see
Us 2 182 ✗
106×31
= .
=

① Nerf revolutions pensee =

thrown
=
7-27×-105
2×3-14 ✗ 053×9×10-10

=
2.93 ✗ 10148ps
A) Calculate the energy of 4+2 ion for 2ndexcited state
solution
E =
13 6 ✗
Z÷z 2=3 n =z
- .

god
13.6 atom
/
= -

✗ = -

13-6 ele
-
Exercise- 1
1. Who lived from 460-370 BC and was among the first to suggest the idea of the atom?
a) Thomson
b) Dalton
c) Democritus
d) Aristotle

2. Which of the following is NOT a part of Dalton's atomic theory?


a) All elements are composed of atoms.
b) Atoms are always in motion.
c) Atoms of the same element are always identical.
d) Atoms that combine do so in simple, whole-number ratios.

3. Dalton's theory included which idea?


a) All atoms of all elements are the same size
b) Atoms of different elements always combine in one-to-one ratios.
c) Atoms of the same element are always identical.
d) Individual atoms can be seen with a microscope.

4. The number of atoms present in one molecule of the element is called as


a) atomicity
b) atomic number
c) atomic mass
d) mass number

5. All noble gas molecules are


a) Monoatomic
b) Diatomic
c) Triatomic
d) Both I and II

6. Ozone is a
a) monoatomic molecule
b) diatomic molecule
c) triatomic molecule
d) tetratomic molecule

7. Isotopes are atoms of the same element with:


a) different atomic numbers
b) different numbers of neutrons
c) different numbers of protons
d) different numbers of electrons
8. The positive particles of an atom are
a) electrons
b) positrons
c) neutrons
d) proton

9. Matter always has mass.


a) true
b) false

10. Used the word "atomos" to describe the indivisible atom.


a) Democritus
b) Thomson
c) Bohr
d) Dalton

11. Neutrons are present in all atoms except


(A) H.
(B) C.
(C) He.
(D) Ne

12. Structure of nuclei of three atoms A, B and C are given below –


A has 90 protons and 146 neutrons
B has 92 protons and 146 neutrons
C has 90 protons and 148 neutrons
Based on the above data, which of these atoms are isotopes and which are isobars?
(A) A and C are isotopes B and C are isobars
(B) A and B are isotopes A and C are isobars
(C) B and C are isobars A and B are isotopes
(D) A and C are isotopes A and B are isobars

13. Which of the following will have equal number of electrons?


(A) Cl and Br
(B) Na+ and Mg2+
(C) Ar and Ne
(D) Mg2+ and Ca2+

14. The ion that is isoelectronic with CO is


(A) O2+
(B) O2–
(C) CN–
(D) N2+
15. Among the following groups which represents the collection of isoelectronic species?
(A) NO+, C22-, O2–, CO
(B) N2, C22-, CO, NO
(C) CO, NO+, CN–, C22-
(D) NO, CN–, N2, O2–

16. 8AX atom is isotonic to 9B17 atom. The value of x is


(A) 8
(B) 16
(C) 9
(D) 17

17. 44. Isotone of an element has


(A) same number of electrons
(B) same number of protons
(C) same number of neutrons
(D) same number of neutrons & protons

18. Gases are bad conductors of electricity. Their conductivity may be increased by
(a) increasing the pressure as well as potential difference between the electrodes.
(b) decreasing the pressure as well as potential difference between the electrodes.
(c) decreasing the pressure and/or increasing the potential difference between the electrodes.
(d) increasing the pressure and/or decreasing the potential difference between the electrodes.

19. Which of the following is true for cathode ray?


(a) It is not deflected by magnetic field.
(b) It is an electromagnetic wave.
(c) It emits X-ray, when strikes a metal.
(d) It consists of all the negative particles present in the atoms.

20. The specific charge of cathode rays


(a) depends on the nature of the gas.
(b) depends on the material of the discharge tube.
(c) depends on the potential difference between cathode and anode.
(d) is a universal constant.

21. Which of the following is not a fundamental particle?


(a) Electron
(b) Proton
(c) Neutron
(d) X-rays

22. The cathode rays experiment demonstrated that


(a) α-particles are the nuclei of He atoms.
(b) the e/m ratio for the particles of the cathode rays varies gas to gas.
(c) cathode rays are streams of negatively charged particles.
(d) the mass of an atom is essentially all contained in its very small nucleus.

23. Which of the following particle is not deflected in the magnetic field?
(a) Electron
(b) Proton
(c) Neutron
(d) Deuteron

24. Which of the following particle have non-zero e/m ratio?


(a) Neutron
(b) Neutrino
(c) Positron
(d) Neutral meson

25. The e/m ratio is maximum for


(a) Na+
(b) Al3+
(c) H+
(d) Mg2+

26. Which of the following is not a correct statement according to Rutherford’s atomic model?
(a) 99% of mass of an atom is centred in the nucleus.
(b) Most of the part inside the atom is empty.
(c) The size of nucleus is very small in comparison to the atoms.
(d) Electrons revolve round the nucleus.

27. The e/m ratio of cathode rays is x unit, when hydrogen is filled in the discharge tube. What will
be its value, when deuterium (D2) is filled in it? [JEE Advanced]
(a) x unit
(b) x/2 unit
(c) 2x unit
(d) x/4 unit

28. How many protons are in an atom with an atomic number of 20, an atomic mass of 45, and a
charge of +2.
A. 20

B. 10

C. 2

D. 18
29. How many neutrons are in an atom with an atomic number of 20, an atomic mass of 45, and a
charge of +2.

A. 20

B. 25

C. 2

D. 18

30. How many electrons are in an atom with an atomic number of 20, an atomic mass of 45, and a
charge of +2?
A. 20

B. 45

C. 18

D. 2

31. What particle provided the positive charge for an atom?


A. proton

B. neutron

C. electron

D. nucleus

32. Which particle does not contribute mass to the atom?


A. Proton

B. Neutron

C. Electron

D. Nucleus

33. How many protons will an atom have it has an atomic number of 26, an atomic mass of 56 and a
charge of +3?
A. 29

B. 30

C. 26
D. 3

34. How many protons will an atom have if it has 36 electrons and a charge of -2?
A. 36

B. 38

C. 34

D. 2

35. How many protons will an atom have it it has 23 electrons and a charge of +3?
A. 23

B. 26

C. 20

D. 3

36. What characteristic of an element's atoms ALWAYS determines the element's identity?
A. the number of neutrons

B. the number of protons

C. the atomic mass

D. the number of valence electron

37. How many electron 11Na+ and 12Mg+2 have –


A. 11 , 12

B. 10, 11

C. 11. 10

D. 10, 10

38. Which of the following is not the isotope of hydrogen?


a) Protium
b) Deuterium
c) Iterium
d) Tritium

39. 8O16, 8O17, 8O18 are called:


a) Isotopes
b) Isotones
c) Isobars
d) Isoneutronic
40. Which isotope is used through the radioactive age estimation technique to obtain (determine) the
age of rocks?
A. Uranium isotope
B. Plutonium isotope
C. Thorium isotope
D. Carbon isotope

41. The radio isotope used to control the disease like blood cancer (Leukemia) is:
A. Phosphorus-32
B. Cobalt-60
C. Iodine-131
D. Sodium-24

42. Isotones are those which have:


A. Equal number of protons
B. Equal number of neutrons
C. Equal number of nucleons
D. None of these

43. In deuterium number of neutron is


A. 3
B. 2
C. 1
D. 0

44. The isotopes have similar


A. Chemical properties
B. Physical Properties
C. Number of Neutrons
D. Mass numbers

45. In C-14 number of neutron is


A. 6
B. 7
C. 8
D. 9

46. Which of the is isoelectronic with Neon


A. F-
B. Oxygen atom
C. Mg
D. N-
47. What is emitted during Alpha Radiation?
A. A helium nuclei.
B. positrons
C. Gamma Rays.
D. Helium atom
48. ALPHA makes the atomic number decrease by how many?

A. 1
B. 2
C. 3
D. 5
49. What is NOT a characteristic of an alpha particle?
A. A negatively charged electron
B. Stopped by paper
C. A positively charged particle
D. Low penetration
50. What do these isotopes of carbon all have in common?
126C, 136C, 146C

A. they all have the same number of neutrons & mass number
B. they all have the same atomic number and neutrons
C. they all have the same atomic number and electrons
D. they all have the same number of protons, atomic number, and mass number
Topic- Bohr Atomic Model
1. The ratio of radius of 2nd and 3rd Bohr orbit is
a) 3 : 2
b) 9 : 4

c) 2 : 3
d) 4 : 9
2. According to Bohr’s model, the angular momentum of an electron in 4th orbit is
a) h/3
b) h/2

c) 2h/π
d) 3h/2
3. The radius of Bohr’s first orbit in hydrogen atom is 0.053nm. The radius of second orbit of He + would be
a) 0.0265 nm

b) 0.053 nm
c) 0.116 nm
d) 0.212 nm
4. The minimum energy required to excite a hydrogen atom from its ground state

a) 13.6 eV
b) -13.eV
c) 3.4 eV
d) 10.2 eV

5. The ratio of kinetic energy and potential energy of an electron in a Bohr orbit of a hydrogen atom is
a) 1:2
b) -1:2
c) 1:1
d) -1:1
6. The ratio of potential energy and total energy of an electron in a Bohr orbit of a hydrogen atom is
a) 2:1
b)-1:2
c) 1:1

d) -1:2
7. The ratio of kinetic energy and total energy of an electron in a Bohr orbit of a hydrogen atom is
a) 1 : -1
b) -2:1
c) 1:1

d) -1:2

8. In a certain Bohr orbit the total energy is -4.9 eV for this orbit, the kinetic energy and potential energy are
respectively.

a) 9.8 eV, - 4.9 eV


b) 4.9 eV, - 98 eV
c) 4.9 eV, - 4.9 eV
d) 9.8 eV, - 9.8 eV

9. If speed of electron in first Bohr orbit of hydrogen be ‘x’, then speed of the electron in second orbit of He +
is:
a) x/2
b) 2x
c) x
d)4x
10. The ratio of the difference in energy between the first and second Bohr orbits to that between the
second and third Bohr orbit is
a) 1/2

b) 1/3
c) 4/9
d) 27/5
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