StructureofAtom Notes Part1 JEENEETIJSO MridulPandey
StructureofAtom Notes Part1 JEENEETIJSO MridulPandey
StructureofAtom Notes Part1 JEENEETIJSO MridulPandey
Structure of Atom
Structure of Atom
Malton : -
Those
occupies some space
.
eq
-
Chair , Table ,
Pen eteo
Note : Light ,
Sound and Heats the form of energy .
solid -
Liquid ← Gas ,
condensation
freezing Deionisation
Chemical classification of Malter : -
Matter
1
v v
t 1
* Elements : -
of
→
an
94 Natural
Total Known Elements -_
118
Rest manmade .
* Compounds : -
egni Glucose .
\
Laws
of chemical combination
of
reaction ,
It remains conserved -
Man
of reactants will be
equal to the mass of products .
tag +
71g 2×365
It I
=
73g 73g
2. Law
of constant
Proportions
'
A pure chemical contain the same elements
compound
combined together in fixed proportion Ty
'
a mass
ocean
,
both have oxygen and
hydrogen in
the same
proportions .
1: 8
Hao proportion
mass → 2:16 →
Daltons Atomic theory -
'
and chemical
properties ( law of conservation of mass)
A) Atoms ofdifferent element have different masses
a
and chemical
properties of law of constant proportions]
5.) Atoms combine in a
fixed ratio to form compounds
Atoms →
lo 15m
Radiuslm ) Example
town Atomof Hydrogen
107m Molecule
ofwatoo
room molecule
of Haemoglobin
loom
to'm
hnainofsand
Ant
1ohm Watermelon
Daltonwasthefinstscientisttousethesymbolsof elements
Benziliussuggutedthatthesymbolsofelementsshould
be made the
one or more letters
of name of
the elements .
>
At this stage wall of the discharge tube
near cathode starts
glowing .
É☒¥*±• U -
Green Glow
Origin of cathode
Ray : -
Cathode
rays
are
first produced in
cathode due to bombardment of the
gas molecules
the high speed electrons first
try emitted
from the cathode .
→
Glowing is due to the bombardment of glass wall
Try
the cathode It be noted that when
rays may
.
the
gas pressure in the tube is latm , no
→ shadow of cross .
→
EEE
pass o
Hq → 24-1 + 2e-
A) Cathode rays carry negative citrange ,
because they
are
deflected in electric field as well as
magnetic field •
I>
z
'
8) produce -
on the
hard metals
surface of eq W, Mo etc
→ L
nay
2ns
eg
.
.
-
=
=
mass 9- I ✗ to 22g
the opposite
glass wall coated with 2ns
.
These
nays are called as Anode rays on Canal rays .
i¥¥*¥÷ _
H2 gas at 100 pressure .
"
Origin of Canal Rays
.
Ha →
2h -1 + 2e-
3.)
They are
positively charged ,
hence
they are called
as canal rays .
A)
They nature of anode
rays depends on the nature of
gas taken in
the
discharge tube .
* Change : -
+1-6×10-19 coulombs .
1.672×10-2 kg
'
*
-
* Specificcharge =
depend on the nature
of gas
.
Neutron :( 's on
"
BE 244
'
g.
+ >
gc -1 on
2- particles
c) N→
N→ N→
N→
Positively ctrarged
Watermelon Model
Plum
Pudding
Model
Electrons
→
→ This model is compared with a watermelon
in which seeds are embedded or
Pudding
in which resins are embedded .
Limitation : -
Observations conclusions :
very few
3) A deflected back their path
d- particles are
along
.
1) Atom is spherical and
mostly hollow with a lot of empty space .
at its centre
2.) It has small
positively charged part known as Nucleus .
<
→ velocity change
'
* e- Fe
Fe Fc
¥
=
+
Fe =
Electrostatic force
Fc =
Centripetal force .
Failure
of Rutherford model of Atom : -
I
Maxwell Theory :( Electro-magnetic theory
•• When a
charged particle moves under the
influence
of attraction force it looses energy
continuously in the
form of electromagnetic
radiation
••
As result the electron should lose at every
a ,
energy
turn and it will fall into the nucleus which
makes atom unstable .
* Atomic Number :-( 2)
Atomic nlo.denotesthetatalno.fr
protons present in the nucleus of an atom .
ON
@ protons
and neutrons present in the nucleus of an atom .
9- =p -1m
n= A -2
→
mass No
-
No .
* Isotopes : -
he atom
of element which have the
-
same
same atomic no
-
called as isotopes .
eq ?
9:
,cP? ncis
.
'
IH 1h2, 1h3 , ,
Ptotium Deuterium Tritium
'
-
Note : Isotopes of an element differ in the number of
neutrons present in nucleus . But
they
always Trave same no of protons and .
but
different physical property .
* Isobars :
The atoms of different elements which have the
same mass numbers but different atomic numbers
are called isobars .
eg :
-
They are
differ chemically .
* Iso tones : -
9 '
* Iso electronics : -
To overcome the
objections of
Rutherford ,
Bohr proposed a
quantum
mechanical model o
1) Atom has a
centre called nucleus .
( n =
1,334,00
3.) guantisation Condition : -
21T
n = no .
of shell
1- It 2¥ 3¥ 1¥
•
,
•
,
•
,
•
n =
b k shell
n =
2, L Shell
n =3
,
M shell
n =
9 , Nl shell
Tn =
planck constant
=
6.626 ✗ 10-3%-1see
Angular Momentum :-( E)
E=F×p→
t ↳
be e- me
Momentum V
radius
^
← r→
e- a-
= I ✗ m.ve
=
massive .
I e-
so
I =
mierlo __qo5
Mur =
n¥-, 0
Bohnguantisation Condition .
n= no -
+ > e- e-
Zxet Fe -
Electrostatic Foncelbetuteewzcihohge
Fe
Jpeg EiE2_ Go epsilon 8854187817
= = =
82
q,= et
Z
, qz = e-
velocity
'
mass m
'
v1 .
✓ E Fe =
Fc
•<
éJI-
^
1-
Fe
m¥
.
=
41T C- 0
¥0 3¥ m¥-①
'
=
Mor -
2¥ -0 .
looses
gains energy nor
energy
.
n-I.sn pit
Calculation of radius velocity uh kinetic energy 1k
ID , ,
-
E)
potential energy of e- •
j Radius
2¥ = must @
Itai =m±
r
①
2
C) :-( 11 ) ( =
Atomic Number)
"
=¥mIz ,
rn=os > ✗ A
For Istshell
,
8
,
= 0-53 ✗
f- Ao
be =
218×106×22 mlsec
3J
Energy of an Electron : -
Kinetic energy ( K -
E.) = 2=2 =
Izmail
28
Potential
-3¥ 9%-2
=
energy ( p.ES =
EKE + Ep -
E.
=
22¥ +
(-2%2)
En =
-
2=2
28
?mz?e&
-13-6×32-2
-21T
En
E. / per
-_
=
eu
nzpf
tell __
1.6×10-1%-1 ahem .
For H -
atom
-13^6.2-22 ere = -
13 bell
-
2ndshell = -
13.6 . 12
ele =
-3.4 ele
z
34s hell
Maximum Energy
-
n =p
at this
energy
e-
free
- -
136
Ionisation has oeecuredo
- so
-1.57
Energy Increases o
-
0.85
7) Electron can
accept energy ,
can lose
energy
8D If an
accept an energy it jumps
electron
to
higher energy level (excitation of e) .
of an loses
e-
energy
it return taek to
lower
energy level .
(de excitation of )
e-
level
equal
°
to
difference two
energy
E, + at =
Ez
GE =
Ez -
Ei
* This formula is applicable for une electronic species
( hydrogen or
hydrogen like species He's 42J Best
t { }
2
* K E -
. = Ze
- K Ed on
increasing r
, KE I
I
¥{ }
2
4- P E
. = -
Ze
,
P E d
.
on in erasing B P . E. a
g-
* TE
-22¥ T E
2¥ / increasing IT E t
}
=
on
.
P E
- = -2 .
K E .
, K E .
=
-
T E .
P E = 2T -
E
1) Ionisation Energy : -
ionization
energy
.
n 1 = 1 n 2--00 .
hi
=
33,4 -
Nz = A
3) Excitation Amount of
Energy : -
,
A) Calculate the radius ratio of god and sth orbit
of Het
.
Solution
8--0.53-2-2
°
A- 2=2
,
53rd
=
osz .
13¥ = 9:25
Im
-
0.53 .
1532
2-
3M orbit of the
hydrogen atoms .
Solution
① On 2- 182×106
# 1sec
=
m
7-27×105 ml see
Us 2 182 ✗
106×31
= .
=
thrown
=
7-27×-105
2×3-14 ✗ 053×9×10-10
=
2.93 ✗ 10148ps
A) Calculate the energy of 4+2 ion for 2ndexcited state
solution
E =
13 6 ✗
Z÷z 2=3 n =z
- .
god
13.6 atom
/
= -
✗ = -
13-6 ele
-
Exercise- 1
1. Who lived from 460-370 BC and was among the first to suggest the idea of the atom?
a) Thomson
b) Dalton
c) Democritus
d) Aristotle
6. Ozone is a
a) monoatomic molecule
b) diatomic molecule
c) triatomic molecule
d) tetratomic molecule
18. Gases are bad conductors of electricity. Their conductivity may be increased by
(a) increasing the pressure as well as potential difference between the electrodes.
(b) decreasing the pressure as well as potential difference between the electrodes.
(c) decreasing the pressure and/or increasing the potential difference between the electrodes.
(d) increasing the pressure and/or decreasing the potential difference between the electrodes.
23. Which of the following particle is not deflected in the magnetic field?
(a) Electron
(b) Proton
(c) Neutron
(d) Deuteron
26. Which of the following is not a correct statement according to Rutherford’s atomic model?
(a) 99% of mass of an atom is centred in the nucleus.
(b) Most of the part inside the atom is empty.
(c) The size of nucleus is very small in comparison to the atoms.
(d) Electrons revolve round the nucleus.
27. The e/m ratio of cathode rays is x unit, when hydrogen is filled in the discharge tube. What will
be its value, when deuterium (D2) is filled in it? [JEE Advanced]
(a) x unit
(b) x/2 unit
(c) 2x unit
(d) x/4 unit
28. How many protons are in an atom with an atomic number of 20, an atomic mass of 45, and a
charge of +2.
A. 20
B. 10
C. 2
D. 18
29. How many neutrons are in an atom with an atomic number of 20, an atomic mass of 45, and a
charge of +2.
A. 20
B. 25
C. 2
D. 18
30. How many electrons are in an atom with an atomic number of 20, an atomic mass of 45, and a
charge of +2?
A. 20
B. 45
C. 18
D. 2
B. neutron
C. electron
D. nucleus
B. Neutron
C. Electron
D. Nucleus
33. How many protons will an atom have it has an atomic number of 26, an atomic mass of 56 and a
charge of +3?
A. 29
B. 30
C. 26
D. 3
34. How many protons will an atom have if it has 36 electrons and a charge of -2?
A. 36
B. 38
C. 34
D. 2
35. How many protons will an atom have it it has 23 electrons and a charge of +3?
A. 23
B. 26
C. 20
D. 3
36. What characteristic of an element's atoms ALWAYS determines the element's identity?
A. the number of neutrons
B. 10, 11
C. 11. 10
D. 10, 10
41. The radio isotope used to control the disease like blood cancer (Leukemia) is:
A. Phosphorus-32
B. Cobalt-60
C. Iodine-131
D. Sodium-24
A. 1
B. 2
C. 3
D. 5
49. What is NOT a characteristic of an alpha particle?
A. A negatively charged electron
B. Stopped by paper
C. A positively charged particle
D. Low penetration
50. What do these isotopes of carbon all have in common?
126C, 136C, 146C
A. they all have the same number of neutrons & mass number
B. they all have the same atomic number and neutrons
C. they all have the same atomic number and electrons
D. they all have the same number of protons, atomic number, and mass number
Topic- Bohr Atomic Model
1. The ratio of radius of 2nd and 3rd Bohr orbit is
a) 3 : 2
b) 9 : 4
c) 2 : 3
d) 4 : 9
2. According to Bohr’s model, the angular momentum of an electron in 4th orbit is
a) h/3
b) h/2
c) 2h/π
d) 3h/2
3. The radius of Bohr’s first orbit in hydrogen atom is 0.053nm. The radius of second orbit of He + would be
a) 0.0265 nm
b) 0.053 nm
c) 0.116 nm
d) 0.212 nm
4. The minimum energy required to excite a hydrogen atom from its ground state
a) 13.6 eV
b) -13.eV
c) 3.4 eV
d) 10.2 eV
5. The ratio of kinetic energy and potential energy of an electron in a Bohr orbit of a hydrogen atom is
a) 1:2
b) -1:2
c) 1:1
d) -1:1
6. The ratio of potential energy and total energy of an electron in a Bohr orbit of a hydrogen atom is
a) 2:1
b)-1:2
c) 1:1
d) -1:2
7. The ratio of kinetic energy and total energy of an electron in a Bohr orbit of a hydrogen atom is
a) 1 : -1
b) -2:1
c) 1:1
d) -1:2
8. In a certain Bohr orbit the total energy is -4.9 eV for this orbit, the kinetic energy and potential energy are
respectively.
9. If speed of electron in first Bohr orbit of hydrogen be ‘x’, then speed of the electron in second orbit of He +
is:
a) x/2
b) 2x
c) x
d)4x
10. The ratio of the difference in energy between the first and second Bohr orbits to that between the
second and third Bohr orbit is
a) 1/2
b) 1/3
c) 4/9
d) 27/5
1
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