for argon

in this process CY
Calculate the enthalpy change (2000, 4M)
at
1,2-pentadiene (C). The equilibrium was maintained is 12,49 JK mol
1759C. Calculate AG° for the following equilibria. and methane on
of 3.67 L of ethylene
mixture
B A, AG ? 75. A gas 6.11 L of CO,. Find
combustion at 25° Cproduces
complete on burning 1
L of the gas
B C, AG-? of heat evolved
out the amount and methane
combustion of ethylene
From the calculated value of AG and AG°indicate the mixture. The heat of
5M)
order of stability of (A), (B) and (C). Write a reasonable are -1423 and 891 kJ molat 25°C.m f
1991,

reaction mechanism showing all intermediates leading to 100 g of glucose (C%H120%) of energy
76. An athlete is given
(A), (B) and (C). oe (2001, 10M)
equivalent to 1560 kJ.
He utilizes 50 per cent of this gained
avoid storage of energy in
the
event. In order to
energy in the
73. Show that the reaction, CO(g)+ 0,(g) CO,(g) at body, calculate the weight
of water he would need
to
44 kJ/mol.
300 K, is spontaneous and exothermic, when the standard of evaporation of water is
perspire. The enthalpy (1989, 2M)
entropy change is -0.094 kJ K. The standard
mol
Gibbs' free energies of formation for CO and CO are statement is true only under some specific
77. Following in than
-394.4 and-137.2 kJ mol", respectively. for that not more
(2000, 3M) conditions. Write the conditions
74. A sample of argon gas at 1 atm pressure and 27°Cexpands two sentences
"The heat energy q, absorbed by a gas is AH" (1984, 1M)
reversibly and adiabatically from 1.25 dm' to 2.50 dm'

Topic 2 Thermochemistry (OrO

Objective Questions I (Only one correct option) (ii) CO(g)+0,(g) C0,(g; A,H° = z kJ mol
1. Lattice enthalpy and enthalpy of solution of NaClare 788 kJ
Based the above thermochemical equations, find out
on
mol and 4 kJ mol , respectively. The hydration enthalpy
which one of the following algebraic relationships is correct?
of NaCl is (2020 Main, 5 Sep 1) (2019 Main, 12 Jan 1)D
(a) -780 kJ mol b) 780 kJ mol (b) x =y-z
(a) y=2z - x o
(c)-784kJ mol (d) 784 kJ mol (C) z =X +y (d) x=y+ z
2. The variation of equilibrium constant with temperature is
(2020 Main, 6 Sep I)
5. Given, C(graphite)+O2(g) CO(g);
given below: ot io eg A,H°-393.5 kJ mol
Temperature Equilibrium constant
Halg)+0,g) H,O); A,H° = - 285.8 kJ mol-
T 25°C K =10
T =100°C K2 =100
Co,(g)+2 H,OU) CH,(g) +20,(g);
The values of AH°, AG° at 7 and AG° at A,H° =+ 890.3 kJ moll
T (in kJ mol) respectively, are close to
Based on the above thermochemical equations, the value of
[use R = 8314 JK mol] A,H° at 298 K for the reaction, (2017 Main)
(a) 28.4, -7.14 and -5.71 C(graphite)+2 H(g) CH(g) will be
to et en FS
(6) 0.64, -7.14 and -5.71
(C) 28.4, -5.71 and -14.29o fy orb (a)+78.8kJmol (b)+144.0kJmol
(d) 0.64, -5.71 and 14.29 (c)-74.8kJ mol (d) -144.0kJ mol
3. Enthalpy of sublimation of iodine is 24 cal g at 200°C. If
6. The heats of combustion of carbon and carbon monoxide are
specific heat ofI, (s) and I,(vap.) are 0.055 and 0.031 cal g K
-393.5 and 283.5 kJ
250°C mol, respectively.
The heat of
respectively, then enthalpy of sublimation of iodine at formation (in kJ) of carbon monoxide
in cal g is (2019 Main, 12 April 1) per mole is
(2016 Main)
(a) 2.85 (b) 5.7 (c) 22.8 (d) 11.4 (a) 676.5 (b) -676.5
4. Given (c)-110.5 (d) 110.5
kJ mol 7. For the complete combustion of ethanol,
0Cgraphite)+ 0, (g) -> C0, (gx A,H° =x

CH,OH)+30, (g) 2c0,(g)+3H,OU),the

(i) C(graphite)+0,(g) CO(gK amount of heat
produced as measured in bomb
ne A,H° =
y kJ mol calorimeter, is 1364.47 kJ molrl at 25°C. Assuming
AV 13 6h'h7
T16 Thermodynamics and Thermochemistry
1deality the enthalpy of combustion, AcH, for the reaction 16. The thermal dissociation of
will be (R- 8.314 JK mol) equilibrium of CaCO,(ai:
(0) is
23. The polyr

(2014 Main) studied under different conditions. represente

(a) -1366.95 kJ mol (b) -1361.95 kJ mol CaCO,() CaO(s)+ cO, (8) (2013 Ad)
()-1460.50 k mol (d) 1350.50 kJ mol
-
For this equilibrium, the correct
(a) AH is dependent on T
statement(s) is/are where, 7

8. The standard enthalpies offormation

ofCO,
(g ) H,O(/) and (6) Kis independent of the initial amount of
e n t h a l p i e

glucose(s) at 25°C are - 400 kJ/mol, - 300 kJ/mol and

(c) Kis dependent on the pressure CaCO 298 K are

1300 kJ/mol, respectively. The standard

enthalpy of of CO, at a given T
(d) AH is independent of the catalyst, if any enthalpy
combustion per gram of glucose at 25°C is (2013 Adv.)
(a)+2900kJ (b)-2900kJ Subjective Questions order i
(c) -16.11kJ (d) +16.11kJ 24.
In
17. In a constant volume havean
9. Using the data provided, calculate the multiple bond energy calorimeter, 3.5
g of a gas with
molecular weight 28 was burnt in excess to 3 time

The temperature of the calorimeter was oxygen 298.0 K

at
(k mol ) of a C=C bond CH,. That energy is (take the for compl
found to
bond energy of a C- Hbond as 350 kJ from 298.0 K to 298.45 K due to the increases
mol') (2012) combustion process, adjusted
Given that the heat
2C(s)+H(s) CH,(g): AH =
225 kJ mol capacity of calorimeter is 2.5 kJK-1
the numerical value for the the
ox litre/hC

2C(s) 2C(g); AH =1410 kJ mol enthalpy of combustion of the In order te

gas in kJ mol is
rate of suE
H,(g) 2H(g); AH 330 kJ mol 18. Diborane is a (2009)
(a) 1165 (b) 837 (c) 865
potential rocket fuel which undergoes to incomE
(d) 815 combustion according to the reaction and that t
10. The species which
by definition has
enthalpy of formation at 298 K is
zero standard molar B,H,(g)+30,(g)
From the
B,0, (5)+ 3H,0 (g) CH,-8
(a) Br,(g) (b) ClL(g) (2010) following data, calculate the enthalpy change for
()H,O(g) (d) CH,(g) the combustion of diborane. 25. Determin
11. The bond (2000, 2M)
energy (in kcal mol) of C-C single bond is C,H,(g)
2B
approximately (2010)
()+0,
2 (g)>B,0, (s); AH = -

1273 kJ mol given hea

(a) 1 (6) 10 (c) 100 (d) 1000 Compour
12. AHap 30 kJ/mol and H,(g)+ 0,(g) H,o ();
=

AS van =75 Jmol K". Find the AH =-286 kJ mol AH° (kJ/
temperature of vapour, at one atmosphere H,O () The stanc
(a) 400 K (b) 350 K (2004, 1M) H,O (g); AH =
44 kJ mol
(c) 298 K (d) 250 K 2B
13. Which
(s)+3H, (g) B,H, (g ); AH =36 kJ mol
of the following reactions defines 19. Estimate the 26. Using the
AH,? average S-F bond in
(a) standard enthalpy of formationenergy SF5. The values of given bel
C(diamond)+O, (g) CO, (g) (2003, 1M)
are-1100, 275 and 80 of SF,(g), S(g) and F(g)
kJ
bonds.
mol respectively. (1999, 3M)
)He)+E (g)HFg) 20. From the
following data, calculate the enthalpy
)N, (g)+ 3H, (g) the combustion of change for
cyclopropane at 298 K. The enthalpy
2NH, (g) formation of CO2 (g), of
H,O (1) and propane (g) are -393.5,
(d) co (g)+0, (g) -285.8 and 20.42 kJ H (g
Co,(8) mol
isomerisation of cyclopropanerespectively.
to
The
enthalpy of
14. The propene is-33.0 kJ mol.
AH for
CO,(g),CO(g )and H,O (g) are Heat of c
(1998, 5M)
-393.5,-110.5 and -241.8 kJ mol respectively. The 21. Compute the heat of formation of
liquid methyl alcohol in Heat of c-
standard enthalpy
change (in kJ mol) for the reaction
kJ mol, using the following data. Heat 27. The stanc
CO, (g) + H, liquid methyl alcohol =38 kJ/mol. Heatofofvaporisation of
(a) 524.1
(g)>CO(g) H,O(g) is
+
(2000, 1M) gaseous atoms from the elements in their formation of cyclohex
(b)+41.2 H=218 kJ/mol, C =715 kJ/mol, O =249 standard states -3800 a
(c)-262.5 kJ/mol
(d)-41.2 Average bond energies
Objective Question II C-H 415 kJ/mol, C-0 356 (1997, 5M)
hydrogen
28. An intima
kJ/mol,
0-H 463 kJ/mol Al, is use
(One or more than one correct option)
22. The standard molar gram an
15. The following is/are endothermic reaction(s) enthalpies of fomation of
(a) Combustion of methane
(1999, 3M) cyclohexane () and benzene () at 25°C are -156
+49 kJ mol
respectively. The standard
and formatio
(b) Decomposition of water
hydrogenation of cyclohexene () at 25°C is enthalpy of H,(A
H(F
(c) Dehydrogenation of ethane to ethylene Use these data to -119 kJ
estimate the magnitude of the mol
(d) Conversion of graphite to diamond energy of benzene.
resonance
(1996, 2M)
Density