Scribd Logo
Upload

Welcome to Scribd!

  • 117 views

    Volumetric Analysis - 1

    Uploaded by

    Aaliyah Batool
    This experiment involves determining the molarity and strength of a potassium manganate (VII) solution (KMnO4) using a standard solution of ferrous ammonium sulfate (Mohr's salt). A 0.05M solution of Mohr's salt is prepared and 20mL is titrated against the KMnO4 solution until a light pink color persists. The titration is repeated for accuracy. Calculations show the KMnO4 solution has a molarity of 0.009M and strength of 1.422 g/L.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Volumetric Analysis - 1

    Uploaded by

    Aaliyah Batool
    117 views3 pages
    This experiment involves determining the molarity and strength of a potassium manganate (VII) solution (KMnO4) using a standard solution of ferrous ammonium sulfate (Mohr's salt). A 0.05M solution of Mohr's salt is prepared and 20mL is titrated against the KMnO4 solution until a light pink color persists. The titration is repeated for accuracy. Calculations show the KMnO4 solution has a molarity of 0.009M and strength of 1.422 g/L.

    Original Title

    Volumetric Analysis- 1.Docx

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This experiment involves determining the molarity and strength of a potassium manganate (VII) solution (KMnO4) using a standard solution of ferrous ammonium sulfate (Mohr's salt). A 0.05M solution of Mohr's salt is prepared and 20mL is titrated against the KMnO4 solution until a light pink color persists. The titration is repeated for accuracy. Calculations show the KMnO4 solution has a molarity of 0.009M and strength of 1.422 g/L.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    117 views3 pages

    Volumetric Analysis - 1

    Uploaded by

    Aaliyah Batool
    This experiment involves determining the molarity and strength of a potassium manganate (VII) solution (KMnO4) using a standard solution of ferrous ammonium sulfate (Mohr's salt). A 0.05M solution of Mohr's salt is prepared and 20mL is titrated against the KMnO4 solution until a light pink color persists. The titration is repeated for accuracy. Calculations show the KMnO4 solution has a molarity of 0.009M and strength of 1.422 g/L.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 3

    EXPERIMENT 7(Ruled page)

    Prepare 0.05M solution of Ferrous ammonium sulphate (Mohr’s salt). Using this solution
    find out the molarity and strength of the given KMnO4 solution.

    Aim:
    To Prepare 0.05M solution of ferrous ammonium sulphate (Mohr’s salt). Using this
    solution find out the molarity and strength of the given KMnO4 solution.

    Chemical Equations: ( Blank page)

    2KMnO4 + 3H2SO4 K2SO4 + 2MnSO4 + 3H2O + 5[O]


    [2FeSO4 (NH4)2.6H2O + H2SO4 + [O] Fe2(SO4)3 + 2(NH4)2SO4 + 13H2O] x 5

    2KMnO4 + 8H2SO4 + 10FeSO4 (NH4)2.6H2O K2SO4 + 2MnSO4 + 5Fe2(SO4)3 +


    + 10(NH4)2SO4 + 68H2O

    Ionic equations:

    MnO4- + 8H+ + 5e- Mn2+ +


    4H2O [Fe2+ Fe + e-] x 5
    3+

    MnO4- + 8H++ 5Fe2+ 5Fe3++ Mn2+ + 4H2O


    Procedure:
    (Ruled page)

    1. Prepare 250ml of 0.05M of Mohr’s salt solutions by dissolving 4.9g of Mohr’s salt in
    water as described in experiment. Rinse the pipette with the 0.05M Mohr’s salt
    solution and pipette out 20.0ml of it in a washed titration flask
    2. Rinse and fill the burette with the given KMnO4 solution.
    3. Add one test tube (20ml) full of dilute sulphuric acid (4N) to the solution in titration
    flask.
    4. Note the initial reading of the burette.
    5. Now add KMnO4 solution from the burette till a permanent light pink colour is
    imparted to the solution in the titration flask on addition of least single drop of
    KMnO4 solution.
    6. Note the final reading of the burette.
    7. Repeat the above steps 4-5 times to get a set of two concordant readings

    Observation:
    Weight of watch glass = 16.734 g
    Weight of watch glass + Mohr’s salt = 16.734g +4.9g = 21.634 g
    Weight of Mohr’s salt = 4.9g
    Volume of Mohr’s salt solution prepared = 250ml
    Molarity of Mohr’s salt solution = 0.05M
    ( Blank page)

    S.No TITRATION
    1 Burette solution Unknown solution of KMnO4
    2 Pipette solution 20mL of standard solution of Mohr’s salt
    3 H2SO4 Solution One TT of 4N of H2SO4
    4 Temperature Room temperature
    5 Indicator Self-indicator (KMnO4)
    6 End point Colourless to permanent pink colour

    Titration Table: ( Blank page)

    S.No Volume of Volume of Concordant


    Mohr’s salt Burette Readings (mL) KMnO4 Value
    solution Initial Final solution (mL)
    (mL)
    1 20 mL 0 mL 20.4mL 20.4mL
    2 20 mL 0 mL 20.2mL 20.2mL 20.2mL
    3 20 mL 0 mL 20.2mL 20.2mL

    Calculations: ( Blank page)

    a)
    Molarity of the KMnO4 solution.
    From the overall balanced chemical equation, it is clear that 2 moles of KMnO4 react
    with 10 moles of Mohr’s salt

    𝑴𝑲𝑴𝒏𝑶𝟒 𝑿 𝑽𝑲𝑴𝒏𝑶𝟒
    𝟐
    𝑴𝑴𝒐𝒉𝒓𝘍𝒔 𝒔𝒂𝒍𝒕 𝑿 𝑽𝑴𝒐𝒉𝒓𝘍𝒔 𝒔𝒂𝒍𝒕 = 𝟏𝟎

    M KMnO4 = Molarity of KMnO4 solution =


    M
    V KMnO4 = Volume of KMnO4 solution = 20.2mL
    M Mohr’s salt = Molarity of Mohrs salt solution =
    0.05M
    V Mohr’s salt = Volume of Mohr’s salt solution
    𝑴𝑲𝑴𝒏𝑶𝟒 𝑿 2 0 . 2
    𝟐
    𝟎.𝟎𝟓 𝑿 𝟐𝟎 𝟐 = 𝟏𝟎

    M KMnO4 = 0.009 M

    b) Strength of the KMnO4 solution


    Strength (in g/L) = Molarity x Molar mass = 0.009 M x 158 = 1.422 g/L
    Result: (Ruled page)

    Molarity of the KMnO4 solution =0.009 M

    Strength of the KMnO4 solution =1.422 g/L


    --------------------------------------------------------------------------------------------------------------------------------

    You might also like