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Chemistry and Aliphatic Hydrocarbons: Questions1 Carry19 Marks and Questions 2, and 3 Carry18.5 Marks Each

1. The document provides information about an exam for an inorganic chemistry course including: 2. The exam has 3 sections with questions worth varying marks and requires answers on separate answer scripts. 3. Section A focuses on inorganic chemistry and requires students to attempt 2 out of 3 questions provided which include topics like atomic structure, molecular orbitals, and ionic character calculations.

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Ingita Deymunshi
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110 views2 pages

Chemistry and Aliphatic Hydrocarbons: Questions1 Carry19 Marks and Questions 2, and 3 Carry18.5 Marks Each

1. The document provides information about an exam for an inorganic chemistry course including: 2. The exam has 3 sections with questions worth varying marks and requires answers on separate answer scripts. 3. Section A focuses on inorganic chemistry and requires students to attempt 2 out of 3 questions provided which include topics like atomic structure, molecular orbitals, and ionic character calculations.

Uploaded by

Ingita Deymunshi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Unique Paper Code : 32175901

Name of the Paper : GE-1 Atomic Structure Bonding, General Organic


Chemistry and Aliphatic Hydrocarbons
Name of the Course : B.Sc., (Hons.)
Semester :I
Duration : 3 hours Maximum marks: 75

Attempt SECTIONS A & B on the DIFFRENT Answer Script.


Questions1 carry19 marks and questions 2,and 3 carry18.5 marks each.

Section A
(Inorganic Chemistry)
Attempt any TWO questions

Gas constant, R= 8.314 JK-1 mol-1 = 0.08206 dm3 atm K-1 mol-1
Avogadro’s number, NA= 6.022x1023 mol-1 nm: 1.6726 x 10-27 kg.
pm: 1.6726 x 10-27 kg. em: 9.1 x 10-31 kg e: 1.6022 x 10-19 Coulomb

1. (a) Why a new approach required to atomic structure?


(b) Show how the LCAO approximation gives rise to bonding and
anti-bonding orbitals. What orbital are formed by the axial
overlap of p orbitals?
(c) (i)What does it meant by anomalous electronic configurations?
Give two examples.
(ii) Write a electronic configurations of following ions: Re2+ and
Gd+
(d) Calculate the percentage of ionic character of HCl? The inter
nuclear distance of HCl is 1.28410−10 m and its actual dipole (5,5,5,4)
moment is 3.68910−30 Cm.

2. (a) (i)Predict the molecular hybridization and geometry for the


following molecules SO42-, H3O+ and XeO2F4 using
VSEPR theory?
(ii) Draw resonating structure: CO32- and N3-.
(b) Calculate the first excited state energy of 31H ion?
(c) Calculate the de Broglie wavelength of an electron travelling at
20% of the speed of light.
(d) Both NBr3 and NF3 are polar but their molecules align
differently in a non-uniform electrostatic field: Why? (5,5,5,3.5)
3. (a) How do you calculate lattice energy from the Born - Landé
equation and What is the limitation of it?
(b) (i) Sketch molecular orbital diagram for NC molecule and
calculate bond order and magnetic properties.
(ii) Based on the M.O diagram arrange the following in
increasing order of their bond length. O2+, O2-, and O22+
(c) For the 6s and 5dx2-y2 hydrogen-like orbitals, sketch the
following:
i) Radial function R
ii) Radial probability distribution 4r2R2
(d) If you wish to locate an electron in an atom within a distance of
0.1Å. What is the uncertainty involved in the measurement of its
velocity? (5,5,5,3.5)

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