FIITJEE – (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

QP Code: Test- 14

Time Allotted: 3 Hours Maximum Marks: 198

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examina tion Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
BATCHES – All 2022 Batches

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Three Parts: Part-A, B & Part-C in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.

(i) Part-A (01-06) – Contains seven (06) multiple choice questions which have One or More correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B)
will result in −2 marks, as a wrong option is also darkened.

(ii) Part-B (07-12) contains Six (06) Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer and -1 marks for wrong
answer.

(iii) Part-C (13-18) contains Six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+4 marks for correct answer and there will be no negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

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IT−2022 (PET-14)-(PCM) 2

S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
(Multi Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE OR MORE may be correct.

1. In the given circuit C1 = C, C2 = 2C, V1 = V2 = V & R1 = R2 = R3 = R switch switch

and all switches-are closed at t = 0 then choose the incorrect R1
statement at time t = RC (initially all capacitors are uncharged) C1
V
(A) Current through V1 is less than
2Re
e − 1 V1
R3 C2
2
V
(B) Power delivered by V2 is less than
3 eR V2 R2

V
(C) Current through V1 is greater than
2Re
e − 1
V2
(D) Power delivered by V2 is greater than
3 eR

2. Capacitor C1 of capacitance 1 µF and capacitor C2 of capacitance 2 µF are separately

charged fully by a common battery. The two capacitors are then separately allowed to
discharge through equal resistors at time t = 0.
(A) The current in each of the two discharging circuits is zero at t = 0
(B) The current in two discharging circuits at t = 0 are equal but not zero
(C) The current in two discharging circuits at t = 0 are unequal
(D) Capacitor C1 loses 50% of its initial charge sooner than C2 loses 50% of its initial
charge.

3. As shown in the figure, equivalent resistance. 2

(A) Between 1 and 3 is zero
R R R R
(B) Between O and 1 is
3
R O
(C) Between O and 1, O and 2, O and 3 are equal.
(D) Between 1 and 2, 2 and 3 and 3 and 1 are equal 1 3
R

4. For the circuit as shown, find the correct options: B 40V

(A) The emf of battery E will be 20 V so that ratio of currents
K 4
flowing through 4 resistor in position A to position B of E A
the key K is 2
(B) The emf of battery E will be 32 V so that ratio of currents
flowing through 4 resistor in position A to position B of
the key K is 2

(C) The emf of battery E will be 24 V so that ratio of currents flowing through 4 resistor in
position A to position B of the key K is 2.5
(D) The emf of battery E will be 30 V so that ratio of currents flowing through 4 resistor in
position A to position B of the key K is 4.

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IT−2022 (PET-14)-(PCM) 3

2y
5. A conductor of varying cross-sectional area (as shown) is
made of an isotropic material of resistivity . The length of B
the conductor is L. The battery is connected across the
conductor.
y
2x A
(A) The rate of generation of heat per unit length is maximum at ends A and B.
(B) Drift velocity of conduction electrons is minimum at Middle cross-section.
(C) Electric field intensity is same at ends A and B.
2L
(D) Resistance of the conductor is loge 2 .
5xy

6. Consider the following circuit: R D R

E C
Each resistance is ‘R’. Match the following:
R
R R
R
 13  R
(A) Effective resistance between A & B   R
 21  A B

 10 
(B) Effective resistance between A & C   R
 21 
 10 
(C) Effective resistance between A & D   R
 21 
 13 
(D) Effective resistance between A & E   R
 21 

PART – B
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9.

6V R 2R 3V
7. The diagram shows a part of a circuit. The
capacitor is fully charged. What is the energy (in
C 3R R I
S.I. unit) stored in the capacitor?
 2V 8 
Take I = R & CV = 7 S.I. unit 
2
4V Earth
 
Earth

8. Consider the circuit shown in the

figure. If the potential difference
between points A and B is (22/n)
volts then find the value of n. All the
cells are ideal and emf of each cell is
1 volts.

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IT−2022 (PET-14)-(PCM) 4

4 4
A 4
20 4 8
8
9. Find equivalent resistance between A and B.
4 3 6

B 2

10. Two identical capacitor connected as shown and having initial Q0

charge Q0. Separation between plates of capacitor is d0. v +–
Suddenly the left plate of upper capacitor and right plate of +–
+–
lower capacitor start moving with speed v towards left while
Q v
other plate of capacitor remains fixed. (given 0 =1 amp). Find +–
2d +–
+–
the value of current (in amp) in the circuit.
Q0 v

11. A cell of internal resistance 1 is connected V

across a resistor. A voltmeter having 20V
variable resistance G is used to measure 10V
V R
p.d. across resistor. The plot of voltmeter
5V
reading V against G is shown. What is value
of external resistor R? G()→ 24V 1

12. A galvanometer has an internal resistance of 50  G R1 R2 R3

and current required for full scale deflection is 1
mA. The series resistance R3 required (as shown
in figure) to use it as a voltmeter with given range,
• R1= 950 •
as indicated in figure is 1.4n  10 4  , then n = R2 = 1000 100V

PART – C
(Numerical based)
This section contains 6 questions, numerical based questions, (answer of which maybe positive
or negative numbers or decimals).

13. Eight identical resistances 3 ohm, each are connected along

B C
edges of a pyramid having square base ABCD as shown in
figure. The equivalent resistance between A and D is

A D

0
14. A battery of emf 0 = 12V is connected across a 4m long uniform R=8

wire having resistance 4/m. The cells of small emfs 1 = 2V and

N
2 = 4V having internal resistance 2 and 6 respectively, are A B
connected as shown in the figure. If galvanometer shows no 1 r1 G
deflection at the point N, the distance of point N from the point A (in
m) is equal to: 2 r2

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IT−2022 (PET-14)-(PCM) 5

15. The effective resistance between A & B of the shown A B

network. Where resistance of each resistor is 5 ohm, is K.
Then find the value of K.

16. The figure shows two identical parallel plate capacitors connected to S
a battery with switch S closed. The switch is now opened and the
free space between the plates of the capacitors is filled with a
dielectric of dielectric constant (or relative permittivity) 3. The ratio of V A C B C
the total electrostatic energy stored in both capacitors before and
after the introduction of the dielectric is x. Then find the value of ‘x’.

17. When steady state is reached, switch S is closed.

Then the amount of heat rejected by the resistor is
x KJoule. Then find the value of ‘x’.

18. Four ideal batteries, two capacitors and six

resistors are connected in a circuit as shown. Find
the ratio of current in the branch GD and BC

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IT−2022 (PET-14)-(PCM) 6

S
SEEC
CTTIIO
ONN--2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
(Multi Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE OR MORE may be correct.

1. In which of the following compounds, there will be either loss of optical activity or change
of optical rotation, while keeping in very dilute acidic or basic aqueous solution?
OH H

(A) (B) C H
OH CH3 O

OH
OH
H HO

(C) H3C C CH2 C (D) O

Et O HO
OH

H O+
2 CH2 = C = CH2 ⎯⎯⎯
3
→?
Select the correct statement(s) regarding the (major) product formed in the above reaction.
(A) It decolourises Br2/CCl4 (B) It is oxidized by Tollen’s reagent
(C) It reduces Fehling’s solution (D) It gives iodoform test

3. Glucose do not give positive test with following reagent

(A) 2, 4-DNP test
(B) Schiff’s test
(C) Hydrogen sulphite (NaHSO3)addition test
(D) Bromine water test

4.

Which is correct about major product

(A) major product is

(B) D.O.U is 11

(C) no. of hetero atom is 2 (D) is aromatic

5. Which of the given statement(s) is/are correct?

(A) Rate of ozonolysis of alkene is usually faster than alkyne
(B) Rate of electrophilic addition of alkene is faster than that of alkyne
(C) Rate of catalytic hydrogenation of alkene is faster than that of alkyne
(D) Rate of nucleophilic addition of aldehyde is faster than ketone
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IT−2022 (PET-14)-(PCM) 7

6. Which is/are example involve E1CB as major mechanism?

(A) CH2 - CH 2 - F CH = CH2

OH
(B)
Cl
OH

(C) OH O O

OH

(D) −
CH3CH2Cl + OH ⎯⎯→ CH2 = CH2

PART – B
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9.

O
C
7. When H H reacts with NH3. The difference in no. of carbon and nitrogen in the product
is

8. How many of the given compounds give positive haloform test:

O
OH
C
CH 3OH, CH 3CH 2CH 2OH, CH 3CHCH 2CH 2CH 3 , CH 3CH 2CHCH 2CH 3 , H3C CH3
OH
H
O
O O O O
, CH 3CH 2CH 2 CPh , , CH 3 - C - CH 2 - C - OCH 3, CH 3 - C - NH 2
OH

9.

10. When toluene reacts with CrO2Cl2/CS2 in Etard reaction. The equivalent weight of tolune in
M
Etard reaction is . The value of x is
x
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IT−2022 (PET-14)-(PCM) 8

CH3 − C − H
11. If is treated with dil. OH–, in aldol reaction. Order of given aldol reaction is

12. O
C
CH3
H O+
→ ( A ) ⎯⎯⎯→
CF CO H
⎯⎯⎯⎯⎯
3 3 3
B+C

dil.OH- 

(D)
If compound ‘C’ show effervescence with NaHCO3. The difference in degree of
unsaturation of D and B is

PART – C
(Numerical based)
This section contains 6 questions, numerical based questions, (answer of which maybe positive
or negative numbers or decimals).

13. Cl
O
H SO
CCl3 − C − H + ⎯⎯⎯⎯
2 4
→

M
The mol. Wt of organic product in above reaction is M. Value of is . . . . . gm
8

14. O O
−
CH3 − C − H + CH3CH2 − C − H ⎯⎯⎯⎯
dil.OH
→
How many aldol products are generated?
O

15.
→ ( A ) ⎯⎯⎯⎯ → (B ) ⎯⎯⎯⎯⎯⎯⎯ → ( C ) ⎯⎯⎯→ (D )
HO CH −C −Cl/ AlCl SeO
CaC2 + H2O ⎯⎯⎯
2 Red hot
Fe tube
3 3 2

D
Find the molecular weight of is
6

O OH O

16. CH3 − C − H + NaHSO3 CH3 − C − S − ONa

H O
The formula weight of the actual anionic nucleophile is__________

O
H N
17. Product

Molecular weight
Find the of product of above reaction
6

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IT−2022 (PET-14)-(PCM) 9

18. CH3O

+ CH3 − C − C − Cl ⎯⎯⎯→
3
( A ) Major product
AlCl

CH3
OCH 3
CH3O

+ CH3 − C − C − Cl ⎯⎯⎯→
3
(B ) Major product
AlCl

CH3
B−A
The difference in mol. Wt of major product is
5

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IT−2022 (PET-14)-(PCM) 10

S
SEEC
CTTIIO
ONN--3
3 :: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
(Multi Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE OR MORE may be correct.

1. A function f :R → R satisfies the functional equations

f ( x − y ) = f ( x ) f ( y ) − f ( a − x ) f ( a + y ) where ‘a’ is a given positive constant and
f ( 0 ) = 1 then
(A) f is even (B) f is odd
(C) f is periodic (D) f is one – one

2. Let f :R → R be a continuous function. If there exists M > 0 such that

f ( x ) − f ( y )  M x − y then
(A) f is one – one (B) f is onto
(C) f is monotonic (D) f is bijective

3. Which of the following functions are periodic

 x  x 5x + −1 5x
(A) f ( x ) = 1 + ( −1) (B) g ( x ) = 1 ( )
 x  x  x  x
(C) h ( x ) = 2 − ( −2 ) (D)  ( x ) = 1 − ( −1)

4. Let f :R → R be a function satisfying f ( 2 − x ) = f ( 2 + x ) and f ( 20 − x ) = f ( x )  x  R .

Then which of the following is true
(A) If f ( 0 ) = 5, then minimum possible number of values of x satisfying f ( x ) = 5 for
x  0, 170 is 21.
(B) Graph of y = f ( x ) is symmetrical about x = 18
(C) Graph of y = f ( x ) is symmetrical about x = 8
(D) If f ( 2 )  f ( 6 ) , then period of f ( x ) can’t be 1

5. If f : 0 → , satisfies the functional equation

 1
f ( x ) + f  1 −  = tan−1 x
 x
then
 1
(A) 2f ( x ) = tan−1 x + cot −1 (1 − x ) − tan−1 1 −  for x  ( 0,1)
 x
 1
(B) 2f ( x ) = tan−1 x − cot −1 (1 + x ) + tan−1 1 −  for x  ( 0,1)
 x
1
3
(C)  f ( x ) dx = 8
0
1
3
(D)  f ( x ) dx = 4
0

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IT−2022 (PET-14)-(PCM) 11

  1 
6. If f :R → R is a continuous function satisfying f ( x ) = f ( 4x ) + sin    x  R,
  1 + x2 
where . denote GIF then
(A) f ( x ) is many one (B) f (x) is one – one
(C) f (x) is periodic (D) f ( x ) is onto

PART – B
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9.

7. The number of functions f :R → R satisfying the functional equation

( )
f ( f ( x ) ) + f ( y ) = x f ( x ) + y  x,y  R is _____.
2

The value of ‘a’ for which f ( x ) = x + x + acos x is injective is ______________.

3 2
8.

x 2 − 2x + d
9. Let f :R → a, 6, where f ( x ) = be on ONTO function then
x 2 + 3x + d
7a + d = _________

 1  3
10. Let f be a periodic function satisfying f  x +  + f ( x + 1) = f  x +  + f ( x ) and
 2  2
f ( x )  2  x  R . Then period of f ( x ) is _______________.

min.mf ( t ) :0  t  x ;0  x  1

If f ( x ) = 4x − x − 2x + 1 and g ( x ) = 
3 2
11. then value of
 3−x
 ;1  x  2
 1 3 5
g   + g   + g   = ____________ .
4 4 4

12. Let f ( x ) = 2x ( 2 − x ) ; 0  x  2 . Then number of solutions of the equation

((
f f f (( x )) = )) x
2

PART – C
(Numerical based)
This section contains 6 questions, numerical based questions, (answer of which maybe positive
or negative numbers or decimals).

13. If x  x  x  x   = 2001, then x = ______ (where [.] denotes the Greatest Integer
Function)

 19   20   91 
14. If  x +  + x +  + ..... +  x + = 546 then 100x  = ________ (where [.]
 100   100   100 
denotes the Greatest Integer Function)

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IT−2022 (PET-14)-(PCM) 12

15. If the equation x − 5 − 3 = px + 2, where p  R has only three real and distinct roots then
reciprocal of the sum of possible values of p is

16. Each student of a small school must be a member of at least one of the THREE school
clubs. It is known that each club has 35 members. It is not known that how many students
are members of TWO of the THREE clubs but it is known that 10 students are members of
all the THREE clubs. Let M and m be the largest and least possible number of students in
the school respectively then M+m equals

17. Consider set A = a1,a2 ,a3 ,a4  . Let A  A denote the Cartesian product. The number of
reflexive relations possible on set A is ____________.

18. Consider set A = a1,a2 ,a3 ,a4  . Let A  A denote the Cartesian product. The number of
symmetric relations possible on set A is ____________.

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IT−2022 (PET-14)-(PCM) 13

ANSWERS
S
SEEC
CTTIIO
ONN--1
1 :: P
PHHY
YSSIIC
CSS
PART – A
1. ABD 2. BD 3. ABCD 4. AC
5. ABC 6. ABCD
PART – B
7. 7 8. 9 9. 6 10. 2
11. 5 12. 7
Part – C
13. 1.60 14. 0.25 15. 3.64 16. 0.60
17. 1.60 18. 0.33

S
SEEC
CTTIIO
ONN –– 2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. ABD 2. D 3. ABC 4. ABCD
5. ABD 6. ABC
PART – B
7. 2 8. 3 9. 4 10. 4
11. 3 12. 6
Part – C
13. 44.31 14. 12.00 15. 22.33 16. 80
17. 25.16 18. 13.60

S
SEEC
CTTIIO
ONN –– 3
3:: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. BC 2. ABCD 3. ABD 4. ABD
5. AC 6. AC
PART – B
7. 2 8. 2 9. 6 10. 1
11. 2 12. 8
Part – C
13. 6.99 (range 6.9 to 7) 14. 743 15. –20
16. 133 17. 4096 18. 1024

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