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    13 DPP 03j Goc Excel Mixed (Acid+Base+Dipole - 2)

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    This document contains information about a general organic chemistry exam on mixed GOC topics including acids and bases, dipoles, and other related concepts. The exam contains 17 multiple choice questions to be completed within 30 minutes. It provides the marking scheme and notes that students should only work on the questions during the allowed time. All discussions will take place in scheduled doubt discussion classes.

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    13 DPP 03j Goc Excel Mixed (Acid+Base+Dipole - 2)

    Uploaded by

    klj
    34 views3 pages
    This document contains information about a general organic chemistry exam on mixed GOC topics including acids and bases, dipoles, and other related concepts. The exam contains 17 multiple choice questions to be completed within 30 minutes. It provides the marking scheme and notes that students should only work on the questions during the allowed time. All discussions will take place in scheduled doubt discussion classes.

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    13 Dpp 03j Goc Excel Mixed(Acid+Base+Dipole - 2)

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    This document contains information about a general organic chemistry exam on mixed GOC topics including acids and bases, dipoles, and other related concepts. The exam contains 17 multiple choice questions to be completed within 30 minutes. It provides the marking scheme and notes that students should only work on the questions during the allowed time. All discussions will take place in scheduled doubt discussion classes.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    34 views3 pages

    13 DPP 03j Goc Excel Mixed (Acid+Base+Dipole - 2)

    Uploaded by

    klj
    This document contains information about a general organic chemistry exam on mixed GOC topics including acids and bases, dipoles, and other related concepts. The exam contains 17 multiple choice questions to be completed within 30 minutes. It provides the marking scheme and notes that students should only work on the questions during the allowed time. All discussions will take place in scheduled doubt discussion classes.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 3

    EXCEL 2022

    GENERAL ORGANIC CHEMISTRY


    MIXED GOC, ACID & BASES, DIPOLE 03J

    Marking Scheme : Single Correct (+3,-1) M M: 51 Time : 30 min

    1. What is the pKa of Ethane?


    (a) 4.5 (b) 50 (c) 15.7 (d) 15
    2. Estimate the pKa of the proton indicated
    H

    (a) 50 (b) 35 (c) 25 (d) 5


    3. Which of the following reactions does not occur as shown:
    (a) CH3CC–Na+ + CH3CO2H  CH3CO2–Na+ + CH3CCH
    (b) CH3CC–Na+ + CH3OH  CH3O–Na+ + CH3CCH
    (c) CH3CCH + NaNH2  NH3 + CH3CC–Na+
    (d) CH3CCH + NaOH  H2O + CH3CC–Na+
    4. Of compounds (i) and (ii), ___ is the stronger acid and of compounds (iii) and (iv), ___ is the stronger
    base

    (i) (ii) (iii) (iv)


    N
    H
    (a) (i) and (iii) (b) (i) and (iv) (c) (ii) and (iii) (d) (ii) and (iv)
    5. Which is the following compounds is most acidic:
    OH OH OH
    (a) Cl CH 2 CH 2 OH (b) (c) (d)
    NO2
    6. Which of the following compounds will react with sodium hydroxide solution in water?
    (a) C6H5OH (b) C6H5CH2OH (c) (CH3)3COH (d) C2H5OH
    7. Correct order of acidic strength of given compounds will be?

    (i) (ii) (iii) (iv)

    (a) (iv) > (ii) > (i) > (iii) (b) (iv) > (iii) > (i) > (ii) (c) (iv) > (i) > (ii) > (iii) (d) (iv) > (i) > (iii) > (ii)
    8. Which compound would be most acidic?
    (a) CH3CH2CH3 (b) CH3CH=CH2 (c) Cyclohexane (d) CH3(CO)CH3 (e) Benzene

    26
    9. Chose the order that has the following compounds with respect to decreasing acidity.
    O OH
    OH OH C

    (i) (ii) (iii)

    (a) (ii) > (iii) > (i) (b) (ii) > (i) > (iii) (c) (i) > (ii) > (iii) (d) (i) > (iii) > (ii) (e) (iii) > (i) > (ii)
    10. Which base is strong enough to convert (CH3)3COH into (CH3)3CONa in a reaction that goes to comple-
    tion?
    (a) NaNH2 (b) CH3CH2Na (c) NaOH (d) CH3COONa (e) More than one of the above
    11. Among the following compounds, the one that undergoes deprotonation most readily in the presence of
    base, to form carbonion is-
    O O O O O O O
    (a) (b) (c) (d)
    MeO MeO H
    12. Which hydrocarbon in the following molecule would you expect to be the most acidic (i.e., most easily
    removed as H+)?

    (a) (b) (c) (d)

    13. Based upon a understanding of product stability, predict the product formed when the following dianion
    reacts with one equivalent of acid.
    O O OH O O OH O O O O O O
    H (a) (b) (c) (d) (e)

    14. Rank the following in order of relative acidity (more acidic going to less acidic)
    O
    OH
    (p) COOH (q) (r) H 2SO4 (s) OH
    F
    (a) q > r > p > s (b) r > p > s > q (c) s > r > p > q (d) r > s > p > q (e) q > p > s > r
    15. Arrange the following compounds in order of decreasing acidity.
    OH OH OH OH

    (i) (ii) (iii) (iv)

    Cl
    (a) (ii) > (i) > (iv) > (iii) (b) (i) > (ii) > (iii) > (iv) (c) (i) > (ii) > (iv) > (iii) (d) (ii) > (i) > (iii) > (iv)
    16. Most acidic phenol derivative is:
    OH OH OH OH

    (a) (b) (c) (d)

    17. Among the following compounds, the most acidic is:


    (a) p-nitrophenol (b) p-hydroxybenzoic acid (c) o-hydroxybenzoic acid (d) p-toluic acid

    27
    All students are advised to solve DPPs within allowed time only.
    All discussions are scheduled in every 4th doubt discussion class
    –MKA Sir (Guruji)

    42

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