EUROPEAN STANDARD EN ISO 14175

NORME EUROPWENNE
EUROPAlSCHE NORM March 2008

ICS 25.160.20; 71.100.20 Supersedes EN 439:1994

English Version

Welding consumables - Gases and gas mixtures for fusion

welding and allied processes (ISO 14175:2008)

Produits consommables pour le soudage - Gaz et SchweiAzusStze - Gase und Mischgase fur das
melanges gazeux pour le soudage par fusion et les LichtbogenschweiAen und verwandte Prozesse (ISO
techniques connexes (ISO 14175:2008) 14175:2008)

This European Standard was approved by CEN on 7 February 2008.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN Management Centre or to any CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the
official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,
Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.

© 2008 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 14175:2008: E
worldwide for CEN national Members.
EN ISO 14175:2008(E)

Foreword
This document (EN ISO 14175:2008) has been prepared by Technical Committee ISO/TC 44 "Welding and
allied processes" in collaboration with Technical Committee CEN/TC 121 “Welding” the secretariat of which is
held by DIN.

This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by September 2008, and conflicting national standards shall be
withdrawn at the latest by September 2008.

Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.

This document supersedes EN 439:1994.

According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech
Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,
Sweden, Switzerland and the United Kingdom.

Endorsement notice

The text of ISO 14175:2008 has been approved by CEN as a EN ISO 14175:2008 without any modification.
 ISO 14175:2008(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.

International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.

The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.

Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.

ISO 14175 was prepared by Technical Committee ISO/TC 44, Welding and allied processes, Subcommittee
SC 3, Welding consumables.

This second edition cancels and replaces the first edition (ISO 14175:1997) which has been technically
revised.

Requests for official interpretations of any aspect of this International Standard should be directed to the
Secretariat of ISO/TC 44/SC 3 via your national standards body, a complete listing of which can be found at
www.iso.org.
 ISO 14175:2008(E)

Welding consumables — Gases and gas mixtures for fusion

welding and allied processes

1 Scope

This International Standard specifies requirements for the classification of gases and gas mixtures used in
fusion welding and allied processes including, but not limited to:

tungsten arc welding (Process 141);

gas-shielded metal arc welding (Process 13);

plasma arc welding (Process 15);

plasma arc cutting (Process 83);

laser welding (Process 52);

laser cutting (Process 84);

arc braze welding (Process 972).

NOTE Process numbers are in accordance with ISO 4063.

The purpose of this International Standard is to classify and designate shielding, backing, process and assist
gases in accordance with their chemical properties and metallurgical behaviour as the basis for correct
selection by the user and to simplify the possible qualification procedures.

Gas purities and mixing tolerances are specified as delivered by the supplier (manufacturer) and not at the
point of use.

Gases or gas mixtures may be supplied in either liquid or gaseous form, but when used for welding and allied
processes, the gases are always used in the gaseous form.

Fuel gases, such as acetylene, natural gas, propane, etc., and resonator gases, as used in gas lasers, are not
covered by this International Standard.

Transportation and handling of gases and containers shall be in accordance with local, national and regional
standards and regulations as required.

2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.

ISO 31-0:1992, Quantities and units — Part 0 : General principles

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ISO 14175:2008(E)

3 Terms and definitions

For the purposes of this document, the following terms and definitions apply.

3.1
base gas
major or only component of a pure or mixed gas

3.2
classification
number of this International Standard, followed by the symbol for the gas or gas mixture (main group and sub-
group)

3.3
component
gaseous substance that is essential to the performance of the gas mixture

EXAMPLE In a mixture containing 11 % of CO 2 in argon, CO2 is considered a component while argon is the base
gas.

3.4
container
vessel used for the shipment and/or storage of pure or mixed gases in a gaseous or liquid state

3.5
designation
classification plus the symbols for all chemical components plus the nominal composition in volume percent

NOTE Symbols for chemical components are given in 5.2.

EXAMPLE A mixture of argon containing 11 % CO 2 is designated as ISO 14175-M20-ArC-11.

3.6
impurity
gaseous substance with chemical composition different from the base gas, component or gas mixture

3.7
mixture
gas consisting of two or more components

3.8
nominal value
percentage value of a component, quoted by the manufacturer or supplier, which corresponds to the general
composition given by the designation

3.9
symbol
main-group and sub-group of a gas mixture

NOTE Symbols are given in Table 2 (see also 5.1).

EXAMPLE The symbol for a mixture of argon containing 11 % CO 2 is M20.

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 ISO 14175:2008(E)

4 Properties of gases

4.1 General

Relevant physical and chemical properties of the gases considered in this International Standard are given in
Table 1.

Table 1 — Properties of gas components

Relative Boiling point

Density a Reactivity
Chemical density a at 0,101 MPa
Type of gas (air = 1,293) during
symbol to air
welding
kg/m3 °C

Argon Ar 1,784 1,380 185,9 Inert

Helium He 0,178 0,138 268,9 Inert

Carbon dioxide CO2 1,977 1,529 78,5 b Oxidizing

Oxygen O2 1,429 1,105 183,0 Oxidizing

Nitrogen N2 1,251 0,968 195,8 Low reactive c

Hydrogen H2 0,090 0,070 252,8 Reducing

a Specified at 0 °C and 0,101 MPa (1,013 bar).
b Sublimation temperature (solid to gas transition temperature).
c The behaviour of nitrogen varies with different materials and applications. Possible influences must be
considered by the user.

4.2 Rounding-off procedure

For purposes of determining compliance with the requirements of this International Standard, the actual test
values obtained shall be subjected to the rounding-off rules of ISO 31-0:1992, Annex B, Rule A. If the
measured values are obtained by equipment calibrated in units other than those of this International Standard,
the measured values shall be converted to the units of this International Standard before rounding off. If an
average value is to be compared to the requirements of this International Standard, rounding off shall be done
only after calculating the average. In the case where the testing standard cited in the normative references of

óóó
this International Standard contains instructions for rounding off that conflict with the instructions of this
International Standard, the rounding-off requirements of the testing standard shall apply. The rounded-off
results shall fulfill the requirements of the appropriate table for the classification under test.

5 Classification and designation

5.1 Classification

5.1.1 General

Gases and gas mixtures shall be classified by the number of this International Standard, followed by the
symbol for the gas in accordance with Table 2.

NOTE The classification is based on the reactivity of the gas or gas mixture.

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ISO 14175:2008(E)

5.1.2 Main group

The letter codes and numbers used for the main groups are:

I: inert gases and inert gas mixtures;

M1, M2 and M3: oxidising mixtures containing oxygen and/or carbon dioxide;

C: highly oxidising gas and highly oxidising mixtures;

R: reducing gas mixtures;

N: low reactive gas or reducing gas mixtures, containing nitrogen;

O: oxygen;

Z: gas mixtures containing components not listed or mixtures outside the composition ranges listed in
Table 2.

5.1.3 Sub-group

The main groups, except Z, are divided into sub-groups based on the presence and level of different
components having an influence on the reactivity (see Table 2). The values indicated in Table 2 are nominal
values.

5.1.4 Classification examples

EXAMPLE 1 For a gas mixture containing 6 % carbon dioxide, 4 % oxygen in argon:

Classification: ISO 14175 – M25

EXAMPLE 2 For a gas mixture containing 30 % helium in argon:

Classification: ISO 14175 – I3

EXAMPLE 3 For a gas mixture containing 5 % hydrogen in argon:

Classification: ISO 14175 – R1

EXAMPLE 4 For a gas mixture containing 0,05 % of oxygen in argon:

Classification: ISO 14175 – Z

5.2 Designation

5.2.1 General

Gases and gas mixtures are designated by the classification (see 5.1) and the symbols of their chemical
components as below, followed by the corresponding nominal composition in volume percent:

Ar: argon

C: carbon dioxide

H: hydrogen

N: nitrogen

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 ISO 14175:2008(E)

O: oxygen

He: helium

The base gas symbol shall be followed by the symbols for the other components in decreasing order of
percent, followed by the nominal composition values, in volume percent, which are separated by a dash.

5.2.2 Designation examples

EXAMPLE 1 For a gas mixture containing 6 % carbon dioxide, 4 % oxygen in argon:

Classification: ISO 14175 – M25

Designation: ISO 14175 – M25 – ArCO – 6/4

EXAMPLE 2 For a gas mixture containing 30 % helium in argon:

Classification: ISO 14175 – I3

Designation: ISO 14175 – I3 – ArHe – 30

EXAMPLE 3 For a gas mixture containing 5 % hydrogen in argon:

Classification: ISO 14175 – R1

Designation: ISO 14175 – R1 – ArH – 5

EXAMPLE 4 For a gas mixture containing 7,5 % argon, 2,5 % carbon dioxide in helium:

Classification: ISO 14175 – M12

Designation: ISO 14175 – M12 – HeArC – 7,5/2,5

For gas mixtures containing components listed, but outside the ranges in Table 2, the letter Z prefixes the
symbol for the base gas and symbols for components as above, followed by the nominal composition values,
in volume percent, which are separated by a dash.

EXAMPLE 5 For a gas mixture containing 0,05 % of oxygen in argon:

Classification: ISO 14175 – Z

Designation: ISO 14175 – Z – ArO – 0,05

For gas mixtures containing components not listed in Table 2, the letter Z prefixes the symbol for the base gas
and symbols for components as above, but with a plus sign preceding the unlisted component, followed by the
nominal composition values, in volume percent, which are separated by a dash.

EXAMPLE 6 For a gas mixture containing 0,05 % of xenon, chemical symbol Xe, in argon:

Classification: ISO 14175 – Z

Designation: ISO 14175 – Z – Ar+Xe – 0,05

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ISO 14175:2008(E)

Table 2 — Classification of process gases for fusion welding and allied processes

Symbol Components in nominal percentage of volume

Main Sub- Oxidizing Inert Reducing Low reactivity

group group CO2 O2 Ar He H2 N2

I 1 100
2 100
3 balance 0,5 u He u 95

M1 1 0,5 u CO2 u 5 balance a 0,5 u H2 u 5

2 0,5 u CO2 u 5 balance a

3 0,5 u O2 u 3 balance a

4 0,5 u CO2 u 5 0,5 u O2 u 3 balance a

M2 0 5 CO2 u 15 balance a

1 15 CO2 u 25 balance a

2 3 O2 u 10 balance a

3 0,5 u CO2 u 5 3 O2 u 10 balance a

4 5 CO2 u 15 0,5 u O2 u 3 balance a

5 5 CO2 u 15 3 O2 u 10 balance a

6 15 CO2 u 25 0,5 u O2 u 3 balance a

7 15 CO2 u 25 3 O2 u 10 balance a

M3 1 25 CO2 u 50 balance a

2 10 O2 u 15 balance a

3 25 CO2 u 50 2 O2 u 10 balance a

4 5 CO2 u 25 10 O2 u 15 balance a

5 25 CO2 u 50 10 O2 u 15 balance a

C 1 100
2 balance 0,5 u O2 u 30

R 1 balance a 0,5 u H2 u 15

2 balance a 15 H2 u 50

N 1 100
2 balance a 0,5 u N2 u 5

3 balance a 5 N2 u 50

4 balance a 0,5 u H2 u 10 0,5 u N2 u 5

5 0,5 u H2 u 50 balance
O 1 100
Z Gas mixtures containing components not listed, or mixtures outside the composition ranges listed. b
a
For the purpose of this classification, argon may be substituted partially or completely by helium.
b Two gas mixtures with the same Z-classification may not be interchangeable.

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 ISO 14175:2008(E)

6 Tolerances of mixtures
Mixture tolerances apply to the volumetric percentage of the components in accordance with Table 3.

Table 3 — Mixture tolerances

Component gas nominal concentration

Allowable tolerance
%
5 10 % of the nominal
1 to 5 0,5 % absolute
1 Not specified in this International Standard

EXAMPLE 1 An addition of 25 % carbon dioxide nominal value shall not vary by more than 2,5 % (from 22,5 % to
27,5 %).

EXAMPLE 2 An addition of 2,5 % oxygen shall not vary by more than 0,5 % (from 2,0 % to 3,0 %).

7 Purities and dew point

The purity and dew point of gas components and gas mixtures shall meet the requirements of Table 4.

Moisture can be expressed as concentration in ppm (parts per million) or as dew points at 0,101 MPa in °C.

Purities and moisture contents for special gas mixtures are not specified in this International Standard.

8 Testing

Testing of gases and gas mixtures for composition and impurity may be carried out by the manufacturer or
supplier using established standards for testing and control (see also Bibliography). The results of the testing
shall fulfil the requirements given in Tables 2 and 3.

Any special or additional testing requirements should be agreed between the purchaser and the manufacturer
or supplier.

Table 4 — Minimum requirements on purities and moisture contents of gases and gas mixtures

Purity Dew point at Moisture

Main groups/gas % by volume 0,101 MPa ppm max.
minimum °C volume
I inert 99,99 50 40
M1 a gas mix 99,9 50 40
M2 a gas mix 99,9 44 80
M3 a gas mix 99,9 40 120
C a carbon dioxide 99,8 40 120
R reducing 99,95 50 40
N nitrogen 99,9 50 40
O oxygen 99,5 50 40
NOTE For certain applications a higher purity and/or lower dew point may be
recommended to avoid possible oxidation and contamination
a Nitrogen: 1 000 ppm maximum.

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ISO 14175:2008(E)

9 Retesting
If any test fails to meet the requirement, that test shall be repeated twice. The results of both retests shall
meet the requirement. Samples for the retest may be taken from the original container or from a new
container. Retests need only be for those specific elements that failed to meet their test requirement. If the
results of one or both retests fail to meet the requirement, the gas under test shall be considered as not
meeting the requirements of this specification for that classification and designation.

In the event that, during preparation or after completion of any test, it is clearly determined that prescribed or
proper procedures were not followed in preparing the sample(s) or in conducting the tests, the test shall be
considered invalid, without regard to whether the test was actually completed, or whether the test results met,
or failed to meet, the requirement. That test shall be repeated following proper prescribed procedures. In this
case, the requirement for doubling the number of test samples does not apply.

10 Marking

The outside of each container (see 3.4) shall be clearly marked with at least the following information:

a) name of manufacturer or supplier;

b) trade name;

c) designation in accordance with this International Standard (see 5.2);

d) health and safety warnings in accordance with local, national and regional standards and regulations as
required.

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 ISO 14175:2008(E)

Bibliography

[1] ASTM E260, Standard Practice for Packed Column Gas Chromatography

[2] JIS Z 3253, Shielding gases for arc welding and plasma arc cutting

[3] ISO 4063, Welding and allied processes — Nomenclature of processes and reference numbers