Titration Lab Report Template

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ACID-BASE TITRATION LAB REPORT

PURPOSE
Students will determine the molarity of unknown HCL solutions.

SAFETY
Wear goggles, aprons, and gloves; avoid contact with skin.

PRE-LAB QUESTIONS

1.
2. The equivalence point in a titration is the point at which the amount of titrant added is just
enough to neutralize the solution.
3. Phenolphthalein is colorless in an acid and pink in a base.
4. The molarity of a 25mL HCl solution, neutralized by 30.5 mL of 0.50 M NaOH, is 0.61 mL.

PROCEDURE
1. Pour approximately 20 ml of the unknown HCl solution into a graduated cylinder and record
the exact volume using sig figs.
2. Pour the acid into a large Erlenmeyer flask and add five drops of phenolphthalein indicator.
3. Fill the buret with the standard solution until it’s near where the numbers end at the top.
4. Record the molarity and exact beginning volume of the standard solution using correct sig
figs.
5. Place the flask of acid under the nozzle of the buret and slowly add the standard solution
drop by drop, swirling the flask in order to evenly mix the solution.
6. When a pink color forms, slow the pace of adding the drops.
7. Continue to swirl and after the pink color has lasted for fifteen seconds, record the exact
volume (equivalence point) of the standard solution remaining.
8. Refill the buret, clean the flask, and repeat the process two more times, recording the same
data for each trial.
DATA AND OBSERVATION

TRIAL 1 TRIAL 2 TRIAL 3

Beginning Volume of NaOH 1.35 mL 13.25 mL 25.62 mL

Volume of HCl 20.5 mL 21.3 mL 20.9 mL

Ending Volume of NaOH 13.25 mL 25.62 mL 37.61 mL

CALCULATIONS
1. Trial #1: 13.25 mL - 1.35 mL= 11.9 mL = V2

Trial #2: 25.62 mL - 13.25 mL = 12.37 mL = V2

Trial #3: 37.61 mL - 25.62 mL = 11.99 mL = V2

2. (H3O+)(M1)(20.5mL) = (OH-)(1.0M)(11.9 mL) = .32 M HCl

(H3O+)(M1)(21.3mL) = (OH-)(1.0M)(12.37 mL) = .58 M HCl

(H3O+)(M1)(20.9mL) = (OH-)(1.0M)(11.99 mL) = .57 M HCl

3. (.32 M + .58 M + .57 M) / 3 = .49 M HCl


4. .50 M HCl - .49 M HCl X 100 = 2.00 %
.50 M HCl

POST LAB QUESTIONS


1. HCl(aq) +NaOH(aq) —> NaCl(aq) + H2O(l)
2. Without adding the phenolphthalein solution, the equivalence point would not have been
able to be determined because the solution would have remained clear and lacking the
pinkish color that indicates the end point of the titration.
3. Three trials were conducted in order to provide the most accurate data possible and an
average molarity was determined to account for any slight errors or miscalculations that
took place during the experiments.
CONCLUSION
To determine the molarity of unknown HCl solutions, 5 drops of phenolphthalein is added to the
acid (HCl) solution, which is then placed under the buret containing the standard solution. The
slowly mixed solutions are swirled until a pink color is recognizable, indicating the equivalence
point. The process is repeated two more times to ensure accurate results. In consecutive order by
trial number, the equivalence points are 11.9 mL, 12.37 mL, and 11.99 mL. The molarities for
the hydrochloric acid solutions are .32 M, .58 M, and .57 M. Using the average of the three
molarities, .49 M, a percent error of 2 is determined. Possible explanations for this error include
impure substances or miscalculations. The phenolphthalein indicator used in this experiment is
crucial because without it, the equivalence point wouldn’t have been able to be determined since
both substances are so clear.

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