Wave–particle duality

Wave–particle duality is the concept in quantum mechanics that every particle or quantum entity may be
described as either a particle or a wave. It expresses the inability of the classical concepts "particle" or
"wave" to fully describe the behaviour of quantum-scale objects. As Albert Einstein wrote:[1]

It seems as though we must use sometimes the one theory and sometimes the other, while at
times we may use either. We are faced with a new kind of difficulty. We have two
contradictory pictures of reality; separately neither of them fully explains the phenomena of
light, but together they do.

Through the work of Max Planck, Albert Einstein, Louis de Broglie, Arthur Compton, Niels Bohr, Erwin
Schrödinger and many others, current scientific theory holds that all particles exhibit a wave nature and vice
versa.[2] This phenomenon has been verified not only for elementary particles, but also for compound
particles like atoms and even molecules. For macroscopic particles, because of their extremely short
wavelengths, wave properties usually cannot be detected.[3]

Although the use of the wave–particle duality has worked well in physics, the meaning or interpretation has
not been satisfactorily resolved; see Interpretations of quantum mechanics.

Bohr regarded the "duality paradox" as a fundamental or metaphysical fact of nature. A given kind of
quantum object will exhibit sometimes wave, sometimes particle, character, in respectively different
physical settings. He saw such duality as one aspect of the concept of complementarity.[4] Bohr regarded
renunciation of the cause-effect relation, or complementarity, of the space-time picture, as essential to the
quantum mechanical account.[5]

Werner Heisenberg considered the question further. He saw the duality as present for all quantic entities,
but not quite in the usual quantum mechanical account considered by Bohr. He saw it in what is called
second quantization, which generates an entirely new concept of fields that exist in ordinary space-time,
causality still being visualizable. Classical field values (e.g. the electric and magnetic field strengths of
Maxwell) are replaced by an entirely new kind of field value, as considered in quantum field theory.
Turning the reasoning around, ordinary quantum mechanics can be deduced as a specialized consequence
of quantum field theory.[6][7]

Contents
History
Classical particle and wave theories of light
Black-body radiation and Planck's law
Photoelectric effect
Einstein's explanation of photoelectric effect
de Broglie's hypothesis
Heisenberg's uncertainty principle
de Broglie–Bohm theory
Wave nature of large objects
Importance
Visualization
Alternative views
Both-particle-and-wave view
Wave-only view
Particle-only view
Neither-wave-nor-particle view
Uses
See also
References
External links

History

Classical particle and wave theories of light

Democritus (5th century BC) argued that all things in the universe,
including light, are composed of indivisible sub-components.[8] Euclid
(4th–3rd century BC) gives treatises on light propagation, states the
principle of shortest trajectory of light, including multiple reflections
on mirrors, including spherical, while Plutarch (1st–2nd century AD) Thomas Young's sketch of two-
describes multiple reflections on spherical mirrors discussing the slit diffraction of waves, 1803
creation of larger or smaller images, real or imaginary, including the
case of chirality of the images. At the beginning of the 11th century,
the Arabic scientist Ibn al-Haytham wrote the first comprehensive Book of optics describing reflection,
refraction, and the operation of a pinhole lens via rays of light traveling from the point of emission to the
eye. He asserted that these rays were composed of particles of light. In 1630, René Descartes popularized
and accredited the opposing wave description in his treatise on light, The World (Descartes), showing that
the behaviour of light could be re-created by modeling wave-like disturbances in a universal medium i.e.
luminiferous aether. Beginning in 1670 and progressing over three decades, Isaac Newton developed and
championed his corpuscular theory, arguing that the perfectly straight lines of reflection demonstrated light's
particle nature, only particles could travel in such straight lines. He explained refraction by positing that
particles of light accelerated laterally upon entering a denser medium. Around the same time, Newton's
contemporaries Robert Hooke and Christiaan Huygens, and later Augustin-Jean Fresnel, mathematically
refined the wave viewpoint, showing that if light traveled at different speeds in different media, refraction
could be easily explained as the medium-dependent propagation of light waves. The resulting Huygens–
Fresnel principle was extremely successful at reproducing light's behaviour and was subsequently
supported by Thomas Young's discovery of wave interference of light by his double-slit experiment in
1801.[9] The wave view did not immediately displace the ray and particle view, but began to dominate
scientific thinking about light in the mid 19th century, since it could explain polarization phenomena that
the alternatives could not.[10]

James Clerk Maxwell discovered that he could apply his previously discovered Maxwell's equations, along
with a slight modification to describe self-propagating waves of oscillating electric and magnetic fields. It
quickly became apparent that visible light, ultraviolet light, and infrared light were all electromagnetic
waves of differing frequency.

Play media

Particle impacts make visible

Animation showing the wave– the interference pattern of
particle duality with a double-slit waves.
experiment and effect of an
observer. Increase size to see
explanations in the video itself.
See also a quiz based on this
animation.

A quantum particle is Interference of a quantum

represented by a wave packet. particle with itself.

Black-body radiation and Planck's law

In 1901, Max Planck published an analysis that succeeded in reproducing the observed spectrum of light
emitted by a glowing object. To accomplish this, Planck had to make a mathematical assumption of
quantized energy of the oscillators, i.e. atoms of the black body that emit radiation. Einstein later proposed
that electromagnetic radiation itself is quantized, not the energy of radiating atoms.

Black-body radiation, the emission of electromagnetic energy due to an object's heat, could not be
explained from classical arguments alone. The equipartition theorem of classical mechanics, the basis of all
classical thermodynamic theories, stated that an object's energy is partitioned equally among the object's
vibrational modes. But applying the same reasoning to the electromagnetic emission of such a thermal
object was not so successful. That thermal objects emit light had been long known. Since light was known
to be waves of electromagnetism, physicists hoped to describe this emission via classical laws. This became
known as the black body problem. Since the equipartition theorem worked so well in describing the
vibrational modes of the thermal object itself, it was natural to assume that it would perform equally well in
describing the radiative emission of such objects. But a problem quickly arose if each mode received an
equal partition of energy, the short wavelength modes would consume all the energy. This became clear
when plotting the Rayleigh–Jeans law, which, while correctly predicting the intensity of long wavelength
emissions, predicted infinite total energy as the intensity diverges to infinity for short wavelengths. This
became known as the ultraviolet catastrophe.

In 1900, Max Planck hypothesized that the frequency of light emitted by the black body depended on the
frequency of the oscillator that emitted it, and the energy of these oscillators increased linearly with
frequency (according E = hf where h is Planck's constant and f is the frequency). This was not an unsound
proposal considering that macroscopic oscillators operate similarly when studying five simple harmonic
oscillators of equal amplitude but different frequency, the oscillator with the highest frequency possesses the
highest energy (though this relationship is not linear like Planck's). By demanding that high-frequency light
must be emitted by an oscillator of equal frequency, and further requiring that this oscillator occupy higher
energy than one of a lesser frequency, Planck avoided any catastrophe, giving an equal partition to high-
frequency oscillators produced successively fewer oscillators and less emitted light. And as in the
Maxwell–Boltzmann distribution, the low-frequency, low-energy oscillators were suppressed by the
onslaught of thermal jiggling from higher energy oscillators, which necessarily increased their energy and
frequency.

The most revolutionary aspect of Planck's treatment of the black body is that it inherently relies on an
integer number of oscillators in thermal equilibrium with the electromagnetic field. These oscillators give
their entire energy to the electromagnetic field, creating a quantum of light, as often as they are excited by
the electromagnetic field, absorbing a quantum of light and beginning to oscillate at the corresponding
frequency. Planck had intentionally created an atomic theory of the black body, but had unintentionally
generated an atomic theory of light, where the black body never generates quanta of light at a given
frequency with an energy less than hf. However, once realizing that he had quantized the electromagnetic
field, he denounced particles of light as a limitation of his approximation, not a property of reality.

Photoelectric effect

While Planck had solved the ultraviolet catastrophe by using atoms

and a quantized electromagnetic field, most contemporary
physicists agreed that Planck's "light quanta" represented only
flaws in his model. A more-complete derivation of black-body
radiation would yield a fully continuous and "wave-like"
electromagnetic field with no quantization. However, in 1905
Albert Einstein took Planck's black body model to produce his
solution to another outstanding problem of the day: the
photoelectric effect, wherein electrons are emitted from atoms when
they absorb energy from light. Since their existence was theorized
eight years previously, phenomena had been studied with the
electron model in mind in physics laboratories worldwide. The photoelectric effect. Incoming
photons on the left strike a metal
In 1902, Philipp Lenard discovered that the energy of these ejected plate (bottom), and eject electrons,
electrons did not depend on the intensity of the incoming light, but depicted as flying off to the right.
instead on its frequency. So if one shines a little low-frequency light
upon a metal, a few low energy electrons are ejected. If one now
shines a very intense beam of low-frequency light upon the same metal, a whole slew of electrons are
ejected; however they possess the same low energy, there are merely more of them. The more light there is,
the more electrons are ejected. Whereas in order to get high energy electrons, one must illuminate the metal
with high-frequency light. Like blackbody radiation, this was at odds with a theory invoking continuous
transfer of energy between radiation and matter. However, it can still be explained using a fully classical
description of light, as long as matter is quantum mechanical in nature.[11]

If one used Planck's energy quanta, and demanded that electromagnetic radiation at a given frequency
could only transfer energy to matter in integer multiples of an energy quantum hf, then the photoelectric
effect could be explained very simply. Low-frequency light only ejects low-energy electrons because each
electron is excited by the absorption of a single photon. Increasing the intensity of the low-frequency light
(increasing the number of photons) only increases the number of excited electrons, not their energy,
because the energy of each photon remains low. Only by increasing the frequency of the light, and thus
increasing the energy of the photons, can one eject electrons with higher energy. Thus, using Planck's
constant h to determine the energy of the photons based upon their frequency, the energy of ejected
electrons should also increase linearly with frequency, the gradient of the line being Planck's constant.
These results were not confirmed until 1915, when Robert Andrews Millikan produced experimental
results in perfect accord with Einstein's predictions.

While energy of ejected electrons reflected Planck's constant, the existence of photons was not explicitly
proven until the discovery of the photon antibunching effect. This refers to the observation that once a
single emitter (an atom, molecule, solid state emitter, etc.) radiates a detectable light signal, it cannot
immediately release a second signal until after the emitter has been re-excited. This leads to a statistically
quantifiable time delay between light emissions, so detection of multiple signals becomes increasingly
unlikely as the observation time dips under the excited-state lifetime of the emitter.[12] The effect can be
demonstrated in an undergraduate-level lab.[13]

This phenomenon could only be explained via photons. Einstein's "light quanta" would not be called
photons until 1925, but even in 1905 they represented the quintessential example of wave–particle duality.
Electromagnetic radiation propagates following linear wave equations, but can only be emitted or absorbed
as discrete elements, thus acting as a wave and a particle simultaneously.

Einstein's explanation of photoelectric effect

In 1905, Albert Einstein provided an explanation of the photoelectric effect, an experiment that the wave
theory of light failed to explain. He did so by postulating the existence of photons, quanta of light energy
with particulate qualities.

In the photoelectric effect, it was observed that shining a light on certain metals would lead to an electric
current in a circuit. Presumably, the light was knocking electrons out of the metal, causing current to flow.
However, using the case of potassium as an example, it was also observed that while a dim blue light was
enough to cause a current, even the strongest, brightest red light available with the technology of the time
caused no current at all. According to the classical theory of light and matter, the strength or amplitude of a
light wave was in proportion to its brightness: a bright light should have been easily strong enough to create
a large current. Yet, oddly, this was not so.

Einstein explained this enigma by postulating that the electrons can receive energy from electromagnetic
field only in discrete units (quanta or photons): an amount of energy E that was related to the frequency f of
the light by

where h is Planck's constant (6.626 × 10−34 Js). Only photons of a high enough frequency (above a certain
threshold value) could knock an electron free. For example, photons of blue light had sufficient energy to
free an electron from the metal, but photons of red light did not. One photon of light above the threshold
frequency could release only one electron; the higher the frequency of a photon, the higher the kinetic
energy of the emitted electron, but no amount of light below the threshold frequency could release an
electron. To violate this law would require extremely high-intensity lasers that had not yet been invented.
Intensity-dependent phenomena have now been studied in detail with such lasers.[14]

Einstein was awarded the Nobel Prize in Physics in 1921 for his discovery of the law of the photoelectric
effect.

de Broglie's hypothesis

In 1924, Louis-Victor de Broglie formulated the de Broglie hypothesis,

claiming that all matter[15][16] has a wave-like nature, he related
wavelength and momentum:

This is a generalization of Einstein's equation above, since the momentum

of a photon is given by p = and the wavelength (in a vacuum) by λ = ,
where c is the speed of light in vacuum.

De Broglie's formula was confirmed three years later for electrons with the
observation of electron diffraction in two independent experiments. At the
University of Aberdeen, George Paget Thomson passed a beam of
Propagation of de Broglie
electrons through a thin metal film and observed the predicted interference waves in 1d—real part of the
patterns. At Bell Labs, Clinton Joseph Davisson and Lester Halbert Germer complex amplitude is blue,
guided the electron beam through a crystalline grid in their experiment imaginary part is green. The
popularly known as Davisson–Germer experiment. probability (shown as the
colour opacity) of finding the
De Broglie was awarded the Nobel Prize for Physics in 1929 for his
particle at a given point x is
hypothesis. Thomson and Davisson shared the Nobel Prize for Physics in spread out like a waveform;
1937 for their experimental work. there is no definite position
of the particle. As the
amplitude increases above
Heisenberg's uncertainty principle
zero the curvature
decreases, so the amplitude
In his work on formulating quantum mechanics, Werner Heisenberg decreases again, and vice
postulated his uncertainty principle, which states:
versa—the result is an
alternating amplitude: a
wave. Top: Plane wave.
Bottom: Wave packet.
where

here indicates standard deviation, a measure of spread or uncertainty;

x and p are a particle's position and linear momentum respectively.
is the reduced Planck's constant (Planck's constant divided by 2 ).

Heisenberg originally explained this as a consequence of the process of measuring: Measuring position
accurately would disturb momentum and vice versa, offering an example (the "gamma-ray microscope")
that depended crucially on the de Broglie hypothesis. The thought is now, however, that this only partly
explains the phenomenon, but that the uncertainty also exists in the particle itself, even before the
measurement is made.
In fact, the modern explanation of the uncertainty principle, extending the Copenhagen interpretation first
put forward by Bohr and Heisenberg, depends even more centrally on the wave nature of a particle. Just as
it is nonsensical to discuss the precise location of a wave on a string, particles do not have perfectly precise
positions; likewise, just as it is nonsensical to discuss the wavelength of a "pulse" wave traveling down a
string, particles do not have perfectly precise momenta that correspond to the inverse of wavelength.
Moreover, when position is relatively well defined, the wave is pulse-like and has a very ill-defined
wavelength, and thus momentum. And conversely, when momentum, and thus wavelength, is relatively
well defined, the wave looks long and sinusoidal, and therefore it has a very ill-defined position.

de Broglie–Bohm theory

De Broglie himself had proposed a pilot wave construct to explain

the observed wave–particle duality. In this view, each particle has a
well-defined position and momentum, but is guided by a wave
function derived from Schrödinger's equation. The pilot wave
theory was initially rejected because it generated non-local effects
when applied to systems involving more than one particle. Non-
locality, however, soon became established as an integral feature of Couder experiments,[17]
quantum theory and David Bohm extended de Broglie's model to "materializing" the pilot wave model
explicitly include it.

In the resulting representation, also called the de Broglie–Bohm theory or Bohmian mechanics,[18] the
wave–particle duality vanishes, and explains the wave behaviour as a scattering with wave appearance,
because the particle's motion is subject to a guiding equation or quantum potential.

This idea seems to me so natural and simple, to resolve the wave–particle dilemma in such a
clear and ordinary way, that it is a great mystery to me that it was so generally ignored.[19] –
J.S.Bell

The best illustration of the pilot-wave model was given by Couder's 2010 "walking droplets"
experiments,[20] demonstrating the pilot-wave behaviour in a macroscopic mechanical analog.[17]

Wave nature of large objects

Since the demonstrations of wave-like properties in photons and electrons, similar experiments have been
conducted with neutrons and protons. Among the most famous experiments are those of Estermann and
Otto Stern in 1929.[21]
Authors of similar recent experiments with atoms and molecules, described below,
claim that these larger particles also act like waves.

A dramatic series of experiments emphasizing the action of gravity in relation to wave–particle duality was
conducted in the 1970s using the neutron interferometer.[22] Neutrons, one of the components of the atomic
nucleus, provide much of the mass of a nucleus and thus of ordinary matter. In the neutron interferometer,
they act as quantum-mechanical waves directly subject to the force of gravity. While the results were not
surprising since gravity was known to act on everything, including light (see tests of general relativity and
the Pound–Rebka falling photon experiment), the self-interference of the quantum mechanical wave of a
massive fermion in a gravitational field had never been experimentally confirmed before.
In 1999, the diffraction of C60 fullerenes by researchers from the University of Vienna was reported.[23]
Fullerenes are comparatively large and massive objects, having an atomic mass of about 720 u. The de
Broglie wavelength of the incident beam was about 2.5 pm, whereas the diameter of the molecule is about
1  nm, about 400 times larger. In 2012, these far-field diffraction experiments could be extended to
phthalocyanine molecules and their heavier derivatives, which are composed of 58 and 114 atoms
respectively. In these experiments the build-up of such interference patterns could be recorded in real time
and with single molecule sensitivity.[24]

In 2003, the Vienna group also demonstrated the wave nature of tetraphenylporphyrin[25]—a flat biodye
with an extension of about 2 nm and a mass of 614 u. For this demonstration they employed a near-field
Talbot Lau interferometer.[26][27] In the same interferometer they also found interference fringes for
C60 F48 , a fluorinated buckyball with a mass of about 1600 u, composed of 108 atoms.[25] Large molecules
are already so complex that they give experimental access to some aspects of the quantum-classical
interface, i.e., to certain decoherence mechanisms.[28][29] In 2011, the interference of molecules as heavy as
6910 u could be demonstrated in a Kapitza–Dirac–Talbot–Lau interferometer.[30] In 2013, the interference
of molecules beyond 10,000 u has been demonstrated.[31]

Whether objects heavier than the Planck mass (about the weight of a large bacterium) have a de Broglie
wavelength is theoretically unclear and experimentally unreachable; above the Planck mass a particle's
Compton wavelength would be smaller than the Planck length and its own Schwarzschild radius, a scale at
which current theories of physics may break down or need to be replaced by more general ones.[32]

Couder, Fort, et al. showed[33] that macroscopic oil droplets on a vibrating fluid bath can be used as an
analogue model of wave–particle duality; a localized droplet creates periodical wave field around itself.
Resonant interaction between the droplet and its own wave field exhibits behaviour analogous to quantum
particles: interference in double-slit experiment,[34] unpredictable tunneling[35] (depending in complicated
way on practically hidden state of field), orbit quantization[36] (that particle has to 'find a resonance' with
field perturbations it creates—after one orbit, its internal phase has to return to the initial state) and Zeeman
effect.[37] Note that other single and double slit experiments [38][39] have shown that wall-droplet
interactions rather than diffraction or interference of the pilot wave may be responsible for the observed
hydrodynamic patterns, which are different from slit-induced interference patterns exhibited by quantum
particles.

Importance
Wave–particle duality is deeply embedded into the foundations of quantum mechanics. In the formalism of
the theory, all the information about a particle is encoded in its wave function, a complex-valued function
roughly analogous to the amplitude of a wave at each point in space. This function evolves according to
Schrödinger equation. For particles with mass this equation has solutions that follow the form of the wave
equation. Propagation of such waves leads to wave-like phenomena such as interference and diffraction.
Particles without mass, like photons, have no solutions of the Schrödinger equation. Instead of a particle
wave function that localizes mass in space, a photon wave function can be constructed from Einstein
kinematics to localize energy in spatial coordinates.[40]

The particle-like behaviour is most evident due to phenomena associated with measurement in quantum
mechanics. Upon measuring the location of the particle, the particle will be forced into a more localized
state as given by the uncertainty principle. When viewed through this formalism, the measurement of the
wave function will randomly lead to wave function collapse to a sharply peaked function at some location.
For particles with mass, the likelihood of detecting the particle at any particular location is equal to the
squared amplitude of the wave function there. The measurement will return a well-defined position, and is
subject to Heisenberg's uncertainty principle.
Following the development of quantum field theory the ambiguity disappeared. The field permits solutions
that follow the wave equation, which are referred to as the wave functions. The term particle is used to
label the irreducible representations of the Lorentz group that are permitted by the field. An interaction as in
a Feynman diagram is accepted as a calculationally convenient approximation where the outgoing legs are
known to be simplifications of the propagation and the internal lines are for some order in an expansion of
the field interaction. Since the field is non-local and quantized, the phenomena that previously were thought
of as paradoxes are explained. Within the limits of the wave–particle duality the quantum field theory gives
the same results.

Visualization
There are two ways to visualize the wave-particle behaviour: by the standard model and by the de Broglie–
Bohr theory.

Below is an illustration of wave–particle duality as it relates to de Broglie's hypothesis and Heisenberg's

Uncertainty principle, in terms of the position and momentum space wavefunctions for one spinless particle
with mass in one dimension. These wavefunctions are Fourier transforms of each other.

The more localized the position-space wavefunction, the more likely the particle is to be found with the
position coordinates in that region, and correspondingly the momentum-space wavefunction is less
localized so the possible momentum components the particle could have are more widespread.

Conversely, the more localized the momentum-space wavefunction, the more likely the particle is to be
found with those values of momentum components in that region, and correspondingly the less localized
the position-space wavefunction, so the position coordinates the particle could occupy are more
widespread.

Position x and momentum p wavefunctions corresponding to quantum particles. The

colour opacity of the particles corresponds to the probability density of finding the
particle with position x or momentum component p.
Top: If wavelength λ is unknown, so are momentum p, wave-vector k and energy E
(de Broglie relations). As the particle is more localized in position space, Δx is
smaller than for Δpx .
Bottom: If λ is known, so are p, k, and E. As the particle is more localized in
momentum space, Δp is smaller than for Δx.
Alternative views
Wave–particle duality is an ongoing conundrum in modern physics. Most physicists accept wave–particle
duality as the best explanation for a broad range of observed phenomena; however, it is not without
controversy. Alternative views are also presented here. These views are not generally accepted by
mainstream physics, but serve as a basis for valuable discussion within the community.

Both-particle-and-wave view

The pilot wave model, was originally developed by Louis de Broglie and further developed by David
Bohm into the hidden variable theory. The phrase “hidden variable” is misleading since the variable in
question is the positions of the particles.[41] Instead of duality, the pilot wave model proposes that both
wave and particle are present with the wave guiding the particle in a deterministic fashion. The wave in
question is the wavefunction obeying Schrödinger’s equation. Bohm’s formulation is intended to be
classical, but it has to incorporate a distinctly non-classical
feature: a nonlocal force ("quantum potential")
acting on the particles.

Bohm’s original purpose (1952) “was to show that an alternative to the Copenhagen interpretation is at least
logically possible.[42] Soon after he set the project aside and did
not revive it until he met Basil Hiley in
1961 when both were at Birbeck College (University of London). Bohm and Hiley then wrote extensively
on the theory and it gained a wider audience. This idea is held by a significant minority within the physics
community.[43]

The Afshar experiment[44] (2007) may suggest that it is possible to simultaneously observe both wave and
particle properties of photons. This claim is, however, disputed by other scientists.[45][46][47][48]

Wave-only view

The wave-only view was first formulated by Nobel laureate Julian Schwinger in his six papers on “The
theory of quantized fields”.[49] Schwinger’s theory is based on extending the discretization observed in the
Stern-Gerlach experiment to include field strength, so that field strength is described by Hilbert algebra, not
ordinary numbers.[50] This use of Hilbert space leads to the existence of individual units of field called
quanta, that replace the two classical concepts of particles and waves.[51] The concept that quantized fields
are the fundamental constituents of nature has also been stated by Nobel laureate Frank Wilczek.[52]

According to this theory, quanta are separate entities that evolve and interact according to deterministic
equations, except that when a quantum transfers its energy to an absorbing atom, it disappears from all of
space.[53] What we call a particle is actually a holistic unit of field that in its totality behaves as a
particle.[54][55] Even if it is spread out over many kilometers, it must disappear instantaneously, like a
photon collapsing into a photoreceptor cell in the eye. You can’t have just part of a photon.[56]

While instantaneous collapse is hard for many physicists to accept, there is nothing logically inconsistent
about it, nor does it violate the Principle of Relativity.[57] Removing a field before it has had a chance to do
anything does not transmit any causal information.[58] The collapse of a quantum involves only non-local
correlations between events at separated locations, and correlations cannot transmit energy or
information.[59] Besides, it is an experimental fact.[60]

Carver Mead, an American scientist and professor at Caltech, has also proposed that the duality can be
replaced by a "wave-only" view. In his book Collective Electrodynamics: Quantum Foundations of
Electromagnetism (2000), Mead purports to analyze the behaviour of electrons and photons purely in terms
of electron wave functions, and attributes the apparent particle-like behaviour to quantization effects and
eigenstates. According to reviewer David Haddon:[61]

Mead has cut the Gordian knot of quantum complementarity. He claims that atoms, with their
neutrons, protons, and electrons, are not particles at all but pure waves of matter. Mead cites as
the gross evidence of the exclusively wave nature of both light and matter the discovery
between 1933 and 1996 of ten examples of pure wave phenomena, including the ubiquitous
laser of CD players, the self-propagating electrical currents of superconductors, and the Bose–
Einstein condensate of atoms.

Albert Einstein, who, in his search for a Unified Field Theory, did not accept wave–particle duality,
wrote:[62]

This double nature of radiation (and of material corpuscles) ... has been interpreted by
quantum-mechanics in an ingenious and amazingly successful fashion. This interpretation ...
appears to me as only a temporary way out...

The many-worlds interpretation (MWI) is sometimes presented as a waves-only theory, including by its
originator, Hugh Everett who referred to MWI as "the wave interpretation".[63]

The three wave hypothesis of R. Horodecki relates the particle to wave.[64][65] The hypothesis implies that
a massive particle is an intrinsically spatially, as well as temporally extended, wave phenomenon by a
nonlinear law.

The deterministic collapse theory[66] considers collapse and measurement as two independent physical
processes. Collapse occurs when two wavepackets spatially overlap and satisfy a mathematical criterion,
which depends on the parameters of both wavepackets. It is a contraction to the overlap volume. In a
measurement apparatus one of the two wavepackets is one of the atomic clusters, which constitute the
apparatus, and the wavepackets collapse to at most the volume of such a cluster. This mimics the action of a
point particle.

Particle-only view

Still in the days of the old quantum theory, a pre-quantum-mechanical version of wave–particle duality was
pioneered by William Duane,[67] and developed by others including Alfred Landé.[68] Duane explained
diffraction of x-rays by a crystal in terms solely of their particle aspect. The deflection of the trajectory of
each diffracted photon was explained as due to quantized momentum transfer from the spatially regular
structure of the diffracting crystal.[69]

Neither-wave-nor-particle view

It has been argued that there are never exact particles or waves, but only some compromise or intermediate
between them. For this reason, in 1928 Arthur Eddington[70] coined the name "wavicle" to describe the
objects although it is not regularly used today. One consideration
is that zero-dimensional mathematical
points cannot be observed. Another is that the formal representation of such points, the Dirac delta function
is unphysical, because it cannot be normalized. Parallel arguments apply to pure wave states. Roger
Penrose states:[71]
 Such 'position states' are idealized wavefunctions in the opposite sense from the momentum
states. Whereas the momentum states are infinitely spread out, the position states are infinitely
concentrated. Neither is normalizable [...].

Uses
Although it is difficult to draw a line separating wave–particle duality from the rest of quantum mechanics,
it is nevertheless possible to list some applications of this basic idea.

Wave–particle duality is exploited in electron microscopy, where the small wavelengths

associated with the electron can be used to view objects much smaller than what is visible
using visible light.
Similarly, neutron diffraction uses neutrons with a wavelength of about 0.1 nm, the typical
spacing of atoms in a solid, to determine the structure of solids.
Photos are now able to show this dual nature, which may lead to new ways of examining
and recording this behaviour.[72]

See also
Arago spot
Afshar experiment
Basic concepts of quantum mechanics
Complementarity (physics)
Einstein's thought experiments
Englert–Greenberger–Yasin duality relation
EPR paradox
Faraday wave
Hanbury Brown and Twiss effect
Kapitsa–Dirac effect
Photon polarization
Scattering theory
Wavelet
Wheeler's delayed choice experiment

References
1. Albert Einstein, Leopold Infeld (1938). The Evolution of Physics: The Growth of Ideas from
Early Concepts to Relativity and Quanta. Cambridge University Press.
Bibcode:1938epgi.book.....E (https://ui.adsabs.harvard.edu/abs/1938epgi.book.....E).
Quoted
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External links
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quantum phenomena (http://www.toutestquantique.fr/#dualite) (Université Paris Sud)
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