Ii Puc Chemistry: Passing Capsule 2021
Ii Puc Chemistry: Passing Capsule 2021
S.NIJALINGAPPPA/INDEPENDENT PU
COLLEGE
Rajajinagar,
Bengaluru – 560010
II PUC CHEMISTRY
PASSING CAPSULE
2021
Prepared by: Anojya Tandon
Lecturer in Chemistry
KLE PU College, Rajajinagar,
Bengaluru-560010.
= 8 corner atoms X contribution of each atom+ 6 face centred atoms X ½ atom per unit cell
1 1
= [8 X ]+6X = 1+3=4
8 2
8. Give the difference between Schottky and Frenkel defects in ionic solids.
Ans:-
Schottky defect Frenkel defect
1. Equal number of cations and anions are 1. The smaller ion gets dislocated from its
missing from their lattice points . lattice point
2. Density decreases 2. Density remains same
3. Cations and anions have similar size 3. Cations and anions differ in their size
Eg:NaCl,KCl,etc. Eg: AgCl,ZnS,etc
5. Define boiling point elevation constant [OR] molal elevation constant [OR] Ebullioscopic
constant. Mention its SI unit.
Ans:- The elevation in boiling point when the molality of the solution is unity.
K kg mol-1
7. Define :-
a. molality: Molality is defined as “the number of moles of solute present in 1kg of solvent”.
c. mole fraction:”It is the ratio of number of moles of one component to the total number of moles
of solute and solvent present in solution”
e. Azeotropic mixture:-“The solutions (liquid mixture) of binary mixture having the same
composition in the liquid and vapour phase and boil at constant temperature.”
2. Derive an integrated rate equation for rate constant of a zero order reaction.
Ans:- Consider a zero order reaction R P
− d[R] = k[R]0
dt
d[R] = − k dt (∴ [R]0 = 1)
On integration we get,
𝑅 𝑜 − [𝑅]
𝑘=
𝑡
6. Explain Peptization.
Ans:- The process of converting a freshly prepared precipitate into a colloidal solution by adding a
suitable electrolyte having common ion. For example:- A freshly prepared precipitate of ferric hydroxide
is treated with ferric chloride solution and stirred well ferric hydroxide sol is formed.
9. Explain dialysis
Ans:- The process of removing the particles of true solutions from colloidal solutions by using
parchment paper or animal membrane is called dialysis. The sol to be purified is taken in a parchment
bag. The bag is suspended in a tank ,in which water is circulated. Particles of true solution diffuse out
from the bag. Water flowing in the tank carries away these particles. The sol gets purified and stabilized.
1. Draw the flow chart of manufacture of ammonia and explain the process with equation.
Ans:-On a large scale, ammonia is manufactured by Haber‟s process.
In accordance with Le Chatelier‟s principle, high pressure would favour the formation of ammonia. The
optimum conditions for the production of ammonia are a pressure of 200 × 10 5 Pa (about 200 atm), a
temperature of ~ 700 K and the use of a catalyst such as iron oxide with small amounts of promoter K2O
and Al2O3 to increase the rate of attainment of equilibrium.
4. Give reason transition metals and their compounds acts as a good catalyst .
Ans:-
Due to presence of large surface area.
They exhibit variable oxidation state.
Transition state
3. Explain Swarts reaction .
Ans:- Fluoroalkanes are prepared by heating an alkyl chloride or bromide in the presence of metallic
fluoride such as AgF or Hg2F2 . This is known as Swarts reaction.
For eg.
Step 2:- Formation of carbocation: It is the slowest step and hence, the rate determining step of
the reaction
Step 2:- The nucleophile [CN-] attacks planar carbonyl group of aldehyde or ketones to form
Tetrahedral intermediate.
[OR]
8. Explain the acidic strength of formic acid, acetic acid and benzoic acid
Ans:-The acid strength of formic acid, acetic acid and benzoic acid are in the following decreasing order,
Formic acid > benzoic acid > acetic acid
(pKa = 3.75) (pKa =4.19) (pKa = 4.75)
5. What is Hinsberg’s reagent?How it is used to distinguish between primary and secondary amine?
Ans:- It is benzene sulphonyl chloride (C6H5SO2Cl)
3. What is nucleoside?
Ans:- Nucleoside is a compound containing nitrogen base and pentose sugar.
16. How do you show that six carbon atoms in a straight line ?
Ans:- Glucose on heating with HI and red phosphorus gives n-hexane
In globular proteins polypeptide chains are coiled around, giving a spherical shape.
Ex : Insulin
Anojya Tandon Lecturer in Chemistry Page 22
19. What are nucleotides?
Ans:- Nucleotides is a compound containing nitrogen base ,pentose sugar and phosphate.
21. How many peptide bond present in dipeptide, tripeptide and tetrapeptide.
Ans:- Dipeptide- 1
Tripeptide- 2
Tetrapeptide-3
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