Amity International School Class: XI
Amity International School Class: XI
Amity International School Class: XI
Class : XI
Annual Examination 2020-2021
CHEMISTRY THEORY (043)
MM:70 Time: 3 Hours
General Instructions. Read the following instructions carefully.
a) There are 33 questions in this question paper. All questions are compulsory.
b) Section A: Q. No. 1 to 2 are case-based questions having four MCQs or Assertion Reason
type based on given passage each carrying 1 mark.
c) Section A: Question 3 to 16 are MCQs and Assertion Reason type questions carrying 1
mark each
d) Section B: Q. No. 17 to 25 are short answer questions and carry 2 marks each.
e) Section C: Q. No. 26 to 30 are short answer questions and carry 3 marks each.
f) Section D: Q. No. 31 to 33 are long answer questions carrying 5 marks each.
g) There is no overall choice. However, internal choices have been provided.
h) Use of calculators and log tables is not permitted.
2. Read the passage given below and answer the following questions: (1x4=4)
Following questions (No. 3 -11) are multiple choice questions carrying 1 mark each:
3.The alkali metals are low melting. Which of the following alkali metals is expected to melt if the
room temperature rises to 30°C?
(a) Na
(b) K
(c) Rb
(d) Cs
(a) 1.5 M
(b) 1.66 M
(c) 0.017 M
(d) 1.59 M
OR
What will be the molarity of a solution, which contains 5.85 g of NaCl(s) per 500 mL?
5 . Metal hydrides are ionic, covalent or molecular in nature. Among LiH, NaH, KH, RbH, CsH, the
correct order of increasing ionic character is
(a) LiH > NaH > CsH > KH > RbH
(b) LiH < NaH < KH < RbH < CsH
(c) RbH > CsH > NaH > KH > LiH
(d) NaH > CsH > RbH > LiH > KH
Hydrogen bonds are formed in many compounds e.g., H2O, HF, NH3 . The
boiling point of such compounds depends to a large extent on the strength
of hydrogen bond and the number of hydrogen bonds. The correct decreasing
order of the boiling points of above compounds is :
a) HF > H2O > NH3
b) H2O > HF > NH3
c) NH3 > HF > H2O
d) NH3 > H2O > HF
9. In NO3 – ion, the number of bond pairs and lone pairs of electrons on nitrogen
atom are
(a) 2, 2
(b) 3, 1
(c) 1, 3
(d) 4, 0
10. Which of the following hydrides is electron-precise hydride?
(a) B2H6
(b) NH3
(c) H20
(d) CH4
11. Hydrogen resembles halogens in many respects for which several factors are
responsible. Of the following factors which one is most important in this respect?
In the following questions (Q. No. 12 - 16) a statement of assertion followed by a statement of
reason is given. Choose the correct answer out of the following choices.
12. Assertion (A): The carbonate of lithium decomposes easily on heating to , form lithium
oxide and C02.
Reason (R): Lithium being very small in size polarizes large carbonate ion leading to the
formation of more stable Li20 and C02.
OR
Assertion (A) : The empirical mass of ethene is half of its molecular mass.
Reason (R) : The empirical formula represents the simplest whole number ratio of various atoms
present in a compound.
(a) Both A and R are the true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) Both A and R are false.
16. Assertion (A): The decomposition of hydrogen peroxide to form water and
oxygen is an example of a disproportionation reaction.
Reason (R): The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation
state in O2 and –2 oxidation state in H2O.
(a) Both A and R are true and R is the correct explanation of A.
(b ) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) Both A and R are false.
SECTION B
The following questions, Q. No 17 – 25 are short answer type and carry 2 marks each.
17. Dinitrogen and dihydrogen react with each other to produce ammonia according to the following
chemical equation:
(i) Calculate the mass of ammonia produced if dinitrogen reacts with 1.00 103 g of
dihydrogen.
(ii) Will any of the two reactants remain unreacted and which one?
OR
Determine the empirical formula of an oxide of iron which has 69.9% iron and 30.1% dioxygen by
mass. ( atomic mass – Fe ₌ 56 u, O ₌16 u)
18. The mass of an electron is kg. If its K.E. is J, calculate its wavelength.
(h ₌ 6.626x 10-34 Js)
19.a. Pressure exerted by saturated water vapour is called aqueous tension. What correction term will
you apply to the total pressure to obtain pressure of dry gas?
b. Compressibility factor, Z, of a gas is given as . What is the value of Z for an ideal gas?
20. In a process, 701 J of heat is absorbed by a system and 394 J ofwork is done by the
system. What is the change in internal energy for the process?
OR
22.i Why are potassium and cesium, rather than lithium used in photoelectric cells?
ii) Beryllium and magnesium do not give colour to flame whereas other alkaline earth
metals do so. Why?
(a)
(b)
24. An alkene 'A' on ozonolysis gives a mixture of ethanal and pentan-3-one. Write structure and
IUPAC name of 'A'?
OR
(i) p-nitrobromobenzene
(ii) m-nitrochlorobenzene
25. Draw the cis and trans structures of hex-2-ene. Which isomer will have higher boiling point and
why?
SECTION C
Q. No 26 -30 are Short Answer Type II carrying 3 mark each.
OR
28. What will be the pressure of the gaseous mixture when 0.5 L of at 0.8 bar and 2.0 L of
dioxygen at 0.7 bar are introduced in a 1L vessel at 27°C?
29. Calculate the standard enthalpy of formation of from the following data:
i.
ii.
iii.
SECTION D
OR
32. a) Addition of HBr to propene yields 2-bromopropane . Give its mechanism.
.
OR
a) Arrange benzene, n-hexane and ethyne in decreasing order of acidic behaviour. Also give reason for
this behaviour.
b) Draw the conformations of Ethane. Which one is more stable and why?
c) Why is benzene extraordinary stable though it has three double bonds? ( 2 ₊2₊ 1)
33. a) What is the equilibrium concentration of each of the substances in the equilibrium when the initial
concentration of ICl was 0.78 M?
2ICl (g) ↔ I2 (g) + Cl2(g); Kc = 0.14
b) Describe the effect of :
i) Addition of H2
ii) Removal of CO
iii) Addition of CH3OH
on the equilibrium of the reaction:
2H2(g) + CO (g) ↔ CH3OH (g) ( 2₊ 3)
OR
a) One mole of H2O and one mole of CO are taken in 10 L vessel and heated to725 K.
At equilibrium 40% of water (by mass) reacts with CO according to the equation,
H2O (g) + CO (g) ↔ H2 (g) + CO2 (g)
Calculate the equilibrium constant for the reaction.
b) Give conjugate acid and base of HSO4 ₋1 .
c) pH of 10 -8 M HCl solution is not 8. Explain. ( 2₊ 1₊ 2)