Safety Data Sheet: 1. Identification

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SAFETY DATA SHEET

1. Identification
Product identifier DEVCON® Plastic Steel® Putty (A) Resin
Other means of identification
SKU# 0100
Recommended use Not available.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name ITW Performance Polymers
Address 30 Endicott Street
Danvers, MA 01923
United States
Telephone Customer Service 978-777-1100
Website www.itwperformancepolymers.com
E-mail Not available.
Contact person EHS Department
Emergency phone number Chemtrec 800-424-9300
International 703-527-3887

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Sensitization, skin Category 1
Specific target organ toxicity, single exposure Category 3 narcotic effects
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Warning


Hazard statement Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May
cause drowsiness or dizziness.
Precautionary statement
Prevention Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Use only
outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the
workplace. Wear eye protection/face protection. Wear protective gloves.
Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable
for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin
irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Take off contaminated clothing and wash it before reuse.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 1/7


3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Ferrosilicon, [with >= 30% But <= 8049-17-0 60 - 80
70% Silicon]
Epoxy Resin:--reaction Product Of EPOXY RESIN 25068-38-6 10 - 30
Bisphenol A And Epichlorohydrin
(refer To Epichlorohydrin)
Fiberglass Fibers 65997-17-3 0.1 - 1
Other components below reportable levels 2.5 - 10

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of
eczema or other skin disorders: Seek medical attention and take along these instructions. Wash
contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
symptoms/effects, acute and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
delayed cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Move containers from fire area if you can do so without risk.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
containment and cleaning up possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 2/7


7. Handling and storage
Precautions for safe handling Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing.
Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good
industrial hygiene practices.
Conditions for safe storage, Store locked up. Store in tightly closed container. Store away from incompatible materials (see
including any incompatibilities Section 10 of the SDS).

8. Exposure controls/personal protection


Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form

Fiberglass Fibers (CAS TWA 3 fibers/cm3 Fiber.


65997-17-3)
3 fibers/cm3 Fibrous dust.
5 mg/m3 Fiber, total
5 mg/m3 fibers, total dust
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Occupational Exposure Limits are not relevant to the current physical form of the product.
Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Provide eyewash station and safety
shower.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Contaminated work clothing should not be allowed out of the
workplace.

9. Physical and chemical properties


Appearance Paste.
Physical state Not available.
Form Paste.
Color Dark grey
Odor Slight.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 608 °F (320 °C) estimated
range
Flash point > 399.2 °F (> 204.0 °C) Pensky-Martens Closed Cup
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 3/7


Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 2.80 g/cm3
Explosive properties Not explosive.
Flammability class Combustible IIIB estimated
Oxidizing properties Not oxidizing.
Specific gravity 2.8

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye irritation.
Ingestion Knowledge about health hazard is incomplete.
Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
physical, chemical and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
toxicological characteristics cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity Not known.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Due to partial or complete lack of data the classification is not possible.
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity Due to partial or complete lack of data the classification is not possible.
Carcinogenicity Due to partial or complete lack of data the classification is not possible.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 4/7


OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity Due to partial or complete lack of data the classification is not possible.
Specific target organ toxicity - May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity - Due to partial or complete lack of data the classification is not possible.
repeated exposure
Aspiration hazard Due to partial or complete lack of data the classification is not possible.

12. Ecological information


Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data is available on the degradability of any ingredients in the mixture.
Bioaccumulative potential
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information


DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not established. Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Toxic Substances Control Act (TSCA)
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 5/7


Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Skin corrosion or irritation
categories Serious eye damage or eye irritation
Respiratory or skin sensitization
Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations


Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
California Proposition 65
WARNING: This product can expose you to chemicals including Benzene, which is known to the State of
California to cause cancer and birth defects or other reproductive harm. For more information go
to www.P65Warnings.ca.gov.
California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2) Listed: February 27, 1987
California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
Toluene (CAS 108-88-3) Listed: January 1, 1991
California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Fiberglass Fibers (CAS 65997-17-3)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 04-01-2019
Revision date 05-01-2020

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 6/7


Version # 02
HMIS® ratings Health: 2
Flammability: 1
Physical hazard: 0
NFPA ratings Health: 2
Flammability: 1
Instability: 0
Disclaimer ITW Performance Polymers cannot anticipate all conditions under which this information and its
product, or the products of other manufacturers in combination with its product, may be used. It is
the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use. The
information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or
in any process, unless specified in the text. The information given is designed only as a guidance
for safe handling, use, processing, storage, transportation, disposal and release.
Revision information This document has undergone significant changes and should be reviewed in its entirety.

Material name: DEVCON® Plastic Steel® Putty (A) Resin SDS US

0100 Version #: 02 Revision date: 05-01-2020 Issue date: 04-01-2019 7/7


SAFETY DATA SHEET

1. Identification
Product identifier Putty Hardener
Other means of identification
SKU# 0200C
Recommended use Not available.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name ITW Performance Polymers
Address 30 Endicott Street
Danvers, MA 01923
United States
Telephone Customer Service 978-777-1100
Website www.itwperformancepolymers.com
E-mail Not available.
Contact person EHS Department
Emergency phone number Chemtrec 800-424-9300
International 703-527-3887

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Acute toxicity, oral Category 4
Acute toxicity, dermal Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Sensitization, skin Category 1
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Danger


Hazard statement Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic
skin reaction. Causes serious eye damage.
Precautionary statement
Prevention Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do not eat,
drink or smoke when using this product. Contaminated work clothing must not be allowed out of
the workplace. Wear eye protection/face protection. Wear protective gloves/protective clothing.
Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with
plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If skin
irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it
before reuse.
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
Material name: Putty Hardener SDS US
0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 1/8
3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Aliphatic Amines N/A 40 - 60
Benzyl Alcohol 100-51-6 20 - 40
TRIETHYLENETETRAMINE TETA 112-24-3 20 - 40
Silicon Dioxide Silica, amorphous, fumed, cryst.-free 112945-52-5 2.5 - 10
Titanium Dioxide TITANIUM DIOXIDE 13463-67-7 0.1 - 1
Other components below reportable levels 0.1 - 1

4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical
advice/attention if you feel unwell. In case of eczema or other skin disorders: Seek medical
attention and take along these instructions. Wash contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Get medical advice/attention if you feel unwell.
Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
symptoms/effects, acute and vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness
delayed and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
medical attention and special under observation. Symptoms may be delayed.
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated
clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Water spray. Alcohol resistant foam. Powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting Use water spray to cool unopened containers.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Following product recovery, flush area
containment and cleaning up with water.

Small Spills: Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 2/8
7. Handling and storage
Precautions for safe handling Do not get this material in contact with eyes. Do not taste or swallow. Avoid breathing
dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. When using, do not
eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Wash contaminated clothing before reuse.
Observe good industrial hygiene practices.
Conditions for safe storage, Store in tightly closed container. Store away from incompatible materials (see Section 10 of the
including any incompatibilities SDS).

8. Exposure controls/personal protection


Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form

Titanium Dioxide (CAS PEL 15 mg/m3 Total dust.


13463-67-7)
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components Type Value Form

Silicon Dioxide (CAS TWA 0.8 mg/m3


112945-52-5)
20 mppcf
Titanium Dioxide (CAS TWA 5 mg/m3 Respirable fraction.
13463-67-7)
15 mg/m3 Total dust.
50 mppcf Total dust.
15 mppcf Respirable fraction.

US. ACGIH Threshold Limit Values


Components Type Value
Titanium Dioxide (CAS TWA 10 mg/m3
13463-67-7)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Silicon Dioxide (CAS TWA 6 mg/m3
112945-52-5)
US. Workplace Environmental Exposure Level (WEEL) Guides
Components Type Value
Benzyl Alcohol (CAS TWA 44.2 mg/m3
100-51-6)
10 ppm
TRIETHYLENETETRAMIN TWA 6 mg/m3
E (CAS 112-24-3)
1 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Occupational Exposure Limits are not relevant to the current physical form of the product.
US WEEL Guides: Skin designation
TRIETHYLENETETRAMINE (CAS 112-24-3) Can be absorbed through the skin.
Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If
controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Provide eyewash station and safety
shower.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Face shield is
recommended.
Material name: Putty Hardener SDS US
0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 3/8
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene Keep away from food and drink. Always observe good personal hygiene measures, such as
considerations washing after handling the material and before eating, drinking, and/or smoking. Routinely wash
work clothing and protective equipment to remove contaminants. Contaminated work clothing
should not be allowed out of the workplace.

9. Physical and chemical properties


Appearance Paste.
Physical state Solid.
Form Paste.
Color White
Odor Ammoniacal.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 4.64 °F (-15.2 °C) estimated
Initial boiling point and boiling 420.8 °F (216 °C) estimated
range
Flash point > 199.9 °F (> 93.3 °C)
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 5.73 hPa estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature 640 °F (337.78 °C) estimated
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 1.00 g/cm3 estimated
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
Specific gravity 1 estimated

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 4/8
Conditions to avoid Avoid temperatures exceeding the decomposition temperature. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Peroxides. Phenols.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation No adverse effects due to inhalation are expected.
Skin contact Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction.
Eye contact Causes serious eye damage.
Ingestion Harmful if swallowed.
Symptoms related to the Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
physical, chemical and vision. Permanent eye damage including blindness could result. Skin irritation. May cause
toxicological characteristics redness and pain. May cause an allergic skin reaction. Dermatitis. Rash.
Information on toxicological effects
Acute toxicity Harmful in contact with skin. Harmful if swallowed.
Components Species Test Results
Benzyl Alcohol (CAS 100-51-6)
Acute
Dermal
LD50 Rabbit 2000 mg/kg
Inhalation
LC50 Rat 1000 mg/l, 8 Hours
Oral
LD50 Rat 1230 - 3100 mg/kg
Silicon Dioxide (CAS 112945-52-5)
Acute
Oral
LD50 Rat > 22500 mg/kg
TRIETHYLENETETRAMINE (CAS 112-24-3)
Acute
Dermal
Liquid
LD50 Rat 1465 mg/kg
Oral
Liquid
LD50 Rat 1716 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Not classifiable as to carcinogenicity to humans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Silicon Dioxide (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.
Titanium Dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 5/8
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard.

12. Ecological information


Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data is available on the degradability of any ingredients in the mixture.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Benzyl Alcohol 1.1
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Dispose of contents/container in
accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information


DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Toxic Substances Control Act (TSCA)
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Material name: Putty Hardener SDS US
0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 6/8
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Acute toxicity (any route of exposure)
categories Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitization
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations


Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
California Proposition 65
WARNING: This product can expose you to Titanium Dioxide, which is known to the State of California to
cause cancer. For more information go to www.P65Warnings.ca.gov.

California Proposition 65 - CRT: Listed date/Carcinogenic substance


Titanium Dioxide (CAS 13463-67-7) Listed: September 2, 2011
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Titanium Dioxide (CAS 13463-67-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 07-03-2019
Revision date 01-12-2021
Version # 05
HMIS® ratings Health: 3
Flammability: 1
Physical hazard: 0

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 7/8
NFPA ratings Health: 3
Flammability: 1
Instability: 0
Disclaimer ITW Performance Polymers cannot anticipate all conditions under which this information and its
product, or the products of other manufacturers in combination with its product, may be used. It is
the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use. The
information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or
in any process, unless specified in the text. The information given is designed only as a guidance
for safe handling, use, processing, storage, transportation, disposal and release.
Revision information This document has undergone significant changes and should be reviewed in its entirety.

Material name: Putty Hardener SDS US


0200C Version #: 05 Revision date: 01-12-2021 Issue date: 07-03-2019 8/8

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