Module 1 - Lesson 2
Module 1 - Lesson 2
Bislig Campus
Maharlika, Bislig City
Thermodynamics
1
Adam C. Macapili
Instructor
Thermodynamics 1, Surigao del Sur State University Page | 1
Module 1
Module Overview
In this Module
• Introduction to thermodynamics
• Basic principles and concepts
Objectives:
• Discuss the different types of thermodynamics properties;
• Discuss about fluid pressure;
• Apply the principle of fluid pressure in manometry;
• Familiarize the temperature equations; and
Introduction
You have learned in the previous lesson that there are three properties
of a substance namely: intensive, extensive, and specific properties. In this
lesson, you will learn what are these intensive and extensive properties of a
substance and by applying these properties you can solve some sample
problems pertaining to the basic principles, and concept of thermodynamics.
ACTIVITY
Task 1: Word Search
T L J M V S S M A S S
TEMPERATURE
H E B S Q S
B B O L F
PRESSURE
T N M B W U
N H K L V DENSITY
F T C P D L Y U V P B VOLUME
W H W L E M T W M R S ENTHALPY
E A X O N R G S C E T ENERGY
MASS
I L A P S N A X L S A
SUBSTANCE
G P W W I B H T K S N WEIGHT
H Y E Q T O J V U U C
T U R A Y P K H Y R E
E N E R G Y I U H E E
ABSTRACTION
Newton’s Law
Newton’s law states that “the acceleration of a particular
body is directly proportional to the resultant force acting on it
and inversely proportional to its mass.”
𝑘𝐹 𝑚𝑎 𝑚𝑎
𝑎= 𝐹= , 𝑘= ,
𝑚 𝑘 𝐹
where k is proportionality constant.
𝑘𝑔𝑚 . 𝑚 𝑘𝑔𝑚 . 𝑚
Therefore, 1 = 9.8066
𝑁 . 𝑠2 𝑘𝑔𝑓 . 𝑠 2
𝑠𝑙𝑢𝑔 . 𝑓𝑡 𝑙𝑏𝑚 . 𝑓𝑡
𝑘=1 , 𝑘 = 32.174
𝑙𝑏𝑓 . 𝑠 2 𝑙𝑏𝑓 . 𝑠 2
𝑠𝑙𝑢𝑔 . 𝑓𝑡 𝑙𝑏𝑚 . 𝑓𝑡
Therefore, 1 = 32.174
𝑙𝑏𝑓 . 𝑠 2 𝑙𝑏𝑓 . 𝑠 2
1 𝑠𝑙𝑢𝑔 = 32.174 𝑙𝑏𝑚
Sample Problem 3:
What is the weight of a 66 − 𝑘𝑔𝑚 at standard condition?
Solution:
𝑚𝑔 (66 𝑘𝑔𝑚 )(9.80066 𝑚⁄𝑠 2 )
𝐹=𝑊= = = 66 𝑘𝑔𝑓
𝑘 𝑘𝑔𝑚 . 𝑚
9.8066 𝑘𝑔 2
𝑓. 𝑠
Sample Problem 4:
The weight of an object is 50 lb. What is its mass at standard
condition?
Solution:
𝑙𝑏𝑚 . 𝑓𝑡
(50 𝑙𝑏𝑓 )(32.174
𝐹𝑘 𝑙𝑏𝑓 . 𝑠 2
𝑚= = = 50𝑙𝑏𝑚
𝑔 𝑓𝑡
32.174 2
𝑠
Density
The density (ρ) of a substance is defined as the mass of a substance per
unit volume. In symbols,
𝑚
𝜌 = 𝑉, [𝑘𝑔𝑚 ⁄𝑉 3 , 𝑙𝑏𝑚 ⁄𝑉 3]
Specific Volume
Specific Volume (v) is defined as the volume per unit mass. The specific
volume of a substance is therefore the reciprocal of its density.
Sample Problem 5:
Determine the specific weight of water at standard condition, in 𝑘𝑔𝑓 ⁄𝑚3 .
Solution: At standard condition, 𝑔 = 9.8066 𝑚/𝑠 2 and 𝜌 = 1000 𝑘𝑔𝑚 /𝑚3
𝜌𝑔 (1000 𝑘𝑔𝑚 /𝑚3 )(9.8066 𝑚/𝑠2 )
𝜸= = 𝑘𝑔𝑚 . 𝑚 = 1000 𝑘𝑔𝑓 /𝑚3
𝑘 9.8066
𝑘𝑔𝑓 . 𝑠2
Sample Problem 6:
Two liquids of different densities (𝜌1 = 1500 𝑘𝑔/𝑚3 , 𝜌2 = 500 𝑘𝑔/𝑚3 )
are poured together into a 100-L tank, filling it. If the resulting density of the
mixture is 800 kg/m3, find the respective quantities of liquids used.
𝑉1 + 𝑉2 = 0.100 (2)
Solving equations (1) and (2) simultaneously
𝑉1 = 0.03 𝑚3
𝑉2 = 0.07 𝑚3
` Then, 𝑚1 = 45 𝑘𝑔
Specific Gravity
Specific gravity (SG) is defined as the ratio of the specific weight of a
substance to the specific weight of water.
𝛾 (𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒) 𝜌 (𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒)
SG = =
𝛾 (𝑤𝑎𝑡𝑒𝑟) 𝜌 (𝑤𝑎𝑡𝑒𝑟)
Pressure
Pressure (𝑝) is defined as a normal force per unit area. Such force is
acting on the surface of a system.
𝒑 = 𝑭/𝑨, [kPa, kg/cm2, psi]
2. By using manometers
The height (h) of a fluid column can also be used for pressure
measurement. A pressure gauge which uses this principle is called a
manometer. A manometer that is used to measure the pressure of
the atmosphere is called a barometer.
𝑝 = 𝛾ℎ = 𝜌𝑔ℎ
a. Open-type Manometer
Source: https://www.thinglink.com/scene/853908429259931648
Source: https://opentextbc.ca/chemistry/chapter/9-1-gas-pressure/
b. Differential-type Manometer
Atmospheric Pressure
A barometer is used to measure atmospheric pressure.
𝑝𝑜 = 𝛾𝑜 ℎ𝑜
where: ℎ𝑜 = the height of column of liquid supported by atmospheric
pressure 𝑝𝑜 .
Standard atmospheric pressure:
1 atm = 14.7 psia
= 101,325 Pa
= 101.325 kPa
= 29.92 in. Hg
Absolute Pressure
Absolute Pressure is the actual pressure at a given position in a system.
Most pressure-measuring instruments measure the difference between the
pressure of a fluid and the pressure of the atmosphere and give readings with
the atmospheric pressure as the reference point. Such a pressure reading is
called the gauge pressure of the fluid. The absolute pressure 𝑝𝑎𝑏𝑠 is related to
the gauge pressure 𝑝𝑔𝑎𝑔𝑒 and the atmospheric pressure 𝑝𝑎𝑡𝑚 as:
Sample Problem 8:
A 30-m vertical column of fluid, 𝜌 = 1878 𝑘𝑔/𝑚3 is located where 𝑔 =
9.65 𝑚/𝑠 2 . Find the pressure at the base of the column, in kPag.
Sample Problem 9:
A 20-m vertical column of fluid (density 1678 kg/m3) is located where g
= 9.81 m/s2. Find the pressure at the base of the column.
Solution:
𝑝 = 𝜌𝑔ℎ = 1678 𝑘𝑔⁄𝑚3 × 9.81 𝑚⁄𝑠 2 × 30 𝑚
𝑝 = 493,835.4 Pa
Temperature
Temperature is defined as the measure of coldness and hotness of a
body. It is an intensive thermodynamic property used to indicate the amount of
energy within the molecules of the substance.
Two arbitrary scales are commonly used for measuring temperature,
namely: Fahrenheit scale (named after Gabriel Fahrenheit, 1686-1736), and
the Celsius scale (named after Anders Celsius, 1701-1744).
Fahrenheit scale is scale is based on the freezing point of water as 0°F
and the boiling point of water as 212°F at 1 standard atmospheric pressure.
This scale is used for English system of measurement.
Celsius scale is based on the freezing point of water as 100°C at 1
standard atmospheric pressure. This scale is used in the Metric and SI systems
of measurement.
Absolute temperature is the temperature of a body or system in
reference to absolute zero. Rankine is the unit used in the English system while
Kelvin is used in the Metric or SI system of units.
Temperature Equations
▪ Conversion of °F to °C
5
𝑡𝐶 = (𝑡𝐹 − 32)
9
▪ Conversion of °C to °F
9
𝑡𝐹 = 𝑡𝐶 + 32
5
▪ Absolute temperature in K
𝑇𝐾 = 𝑡𝑐 + 273
5
𝑡𝐶 = (𝑡𝐹 − 32)
9
5
𝐶 = (𝐶 − 32)
9
9𝐶 = 5𝐶 − 160
𝐶 = −40 = 𝐹
Conservation of Mass
The law of conservation of mass states that mass can neither be created
nor destroyed, it just transforms into components.
For any system, conservation of mass is expressed in the following
relation or equation.
𝑚𝑎𝑠𝑠 𝑒𝑛𝑡𝑒𝑟𝑖𝑛𝑔 𝑚𝑎𝑠𝑠 𝑙𝑒𝑎𝑣𝑖𝑛𝑔 𝑐ℎ𝑎𝑛𝑔𝑒 𝑜𝑓 𝑚𝑎𝑠𝑠
[ ]−[ ]=[ ]
𝑡ℎ𝑒 𝑠𝑦𝑠𝑡𝑒𝑚 𝑡ℎ𝑒 𝑠𝑦𝑠𝑡𝑒𝑚 𝑠𝑡𝑜𝑟𝑒𝑑 𝑖𝑛 𝑡ℎ𝑒 𝑠𝑦𝑡𝑒𝑚
𝑑𝑚𝑖𝑛 − 𝑑𝑚𝑜𝑢𝑡 = 𝑑 (∆𝑚𝑠 )
𝑚𝑖𝑛 − 𝑚𝑜𝑢𝑡 = ∆𝑚𝑠
The equation for mass flow rate is expressed by the following equation:
𝑚1 − 𝑚2 = 0
𝑚1 − 𝑚2 = 𝜌1 𝐴1 𝑉1 = 𝜌2 𝐴2 𝑉2
where:
𝑚1 = mass entering the system, kg/s, lb/min
𝑚2 = mass leaving the system, kg/s, lb/min
𝜌1 = density of fluid entering the system, kg/m3, lb/ft3
𝜌2 = density of fluid leaving the system, kg/m3, lb/ft3
𝑉1 = velocity of fluid entering the system, m/s. ft/min
𝑉2 = velocity of fluid leaving the system, m/s. ft/min
Continuity equation is in the form of mass flow rate and volume flow rate
of the fluid into or from the system. It is expressed by the following relations and
is good only for one-dimensional, steady-flow open system.
▪ Mass Flow Rate Equation
𝑚̇ = 𝜌𝐴𝑉
▪ Volume Flow Rate Equation
𝑉̇ = 𝐴𝑉
where:
𝑚̇ = mass flow rate, kg/s, lb/min
𝑉̇ = volume flow rate, m3/s, ft3/min
𝐴 = cross sectional area, m2, ft2
𝑉 = velocity of fluid, m/s, ft/min
ρ = density of fluid, kg/m3, lb/ft3
Directions: Solve the following problems and write your answer in a separate
sheet of paper.
1. What is the mass in grams and the weight of 12 ounces (oz.) of salt?
Local gravity is 9.65 m/s2 and 1 lbm=16 oz.
2. The metal has a specific gravity of 22.5. (a) What is the weight of 4 in 3
of this metal? (b) What is the volume of 400 pounds of this metal?
3. How large a volume of Uranium which has a specific gravity of 18.7 a
man can carry if he can lift a load of 400 pounds?
4. A 200-pound man floats with all his body below the surface of the water.
What is his volume?
5. A block weighs 10 N and has a volume of 400 cm3. What is its density?
6. What is the equivalent pressure of a 100 cm column of water, in kPag.
7. At the beach, atmospheric pressure is 101.325 kPa. You dive 40 ft. down
in the ocean and you later climb a hill to 315 ft. elevation. Assume the
density of water 1020 kg/m3 and the density of air is 1.21 kg/m3. What
pressure do you feel at each place?
8. A piston/cylinder with a cross-sectional area of 0.02
m2 has a piston mass of 120 kg resting on the stops
as shown in the figure. With an outside atmospheric
pressure of 101 kPa, what should the water pressure
be to lift the piston?
CONGRATULATIONS!
You have just finished this module.