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Sedimentary Rocks: Weathering

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SEDIMENTARY ROCKS

Weathering
What is weathering

• Disintegration and decomposition of


rocks and minerals at or near the
Earth’s surface

• Occurs in situ

• Does not directly involve the


removal process
What Controls Weathering?
1) Rock properties
– Hardness, composition, solubility, zones of weakness
What Controls Weathering?
2) Climate
– Wide variations in temperature and moisture
accelerate weathering
What Controls Weathering?
3) Relief

4) Biological
aspects

5) Length of exposure
Two Types of Weathering
1. Physical
Only physical changes
Produces smaller particles
from larger ones
Two Types of Weathering
2. Chemical
Involves chemical reactions in which new minerals or
combinations of elements are formed
Two Types of Weathering
2. Chemical
Involves chemical reactions in which new minerals or
combinations of elements are formed
Two Types of Weathering
2. Chemical
Involves chemical reactions in which new minerals or
combinations of elements are formed
Two Types of Weathering
2. Chemical
Involves chemical reactions in which new minerals or
combinations of elements are formed
Theory Versus Reality
In theory they are distinct processes

Theory Versus Reality


In reality they rarely operate separately
Effects of one aids the operation of the
other
Large rock breaks into smaller pieces –
increases total surface area –
accelerates chemical attack
Chemical weathering along
microfractures – weakens rocks –
helps physical processes
Agents of Weathering
1. Gases in the atmosphere
O2 , CO2
Natural and
pollution
Agents of Weathering
1. Gases in the atmosphere
O2 , CO2
Natural and
pollution
Agents of Weathering
2. Plant roots and animal actions
Agents of Weathering
3. Space and chemicals

4.Temperature changes
Affects physical and chemical
weathering

5. Water!
Where Weathering Occurs

Surface of the earth


– Surface rocks altered by weathering to
new materials which are in equilibrium
with surface conditions

Below the surface


– Anywhere where rock is exposed to
weathering agents
– May extend 100’s of meters below
surface
Enter the Weathering Agent
The more openings > the more surface area > the more
exposure to weathering agents > the more weathering
that can occur

Common Types of Openings


• Microscopic
• Joints
• Faults
• Lava vesicles
• Solution cavities
Common Types of Openings
• Joints and fractures
and faults
Common Types of Openings
• lava vesicles

• solution cavities
Weathering Changes Rock
a. Size
Breaks chemical bonds
Separates grain from grain
Fracturing massive solid rock
b. Colour
Oxidation
‘rusting’ iron– red, orange, yellow
Copper – green
c. Texture
Usually looser than underlying rock
Detached with little effort
‘rotten’ rock easily crumbled with finger
pressure
Degree, Rate and Nature of Weathering
Depends On:

1a. Nature (lithology) of rock


Mineral stability varies according to pressure and
temperature conditions during formation
Degree, Rate and Nature of Weathering
Depends On:
1b. Structure of rock
Openings increase surface area

Crystal and grain sizes affect surface area

Cementation in sedimentary rocks

Porosity/permeability
allows agents in or keeps them out
Pumice vs. obsidian
Spheroidal Weathering
Degree, Rate and Nature of Weathering
Depends On:
2. Prevailing climatic conditions
a) Precipitation

Water important weathering agent


E.g. limestone

» Egyptian desert – 4,000 years later tool marks still


visible

» North American grave markers – 300 years later


corroded beyond legibility
Degree, Rate and Nature of Weathering Depends
On:

2. Prevailing climatic conditions

b) Temperature

Chemical reactions take place faster and more


readily in warmer climates

Range of temperatures
Freeze-thaw
Heating-cooling
Temperature as a factor in weathering
Chemical weathering
• Promoted by high temperatures and abundant moisture

• Nearly all chemical reactions require moisture – ions


mobilized and interact vigorously

• High temperatures cause ions to move more rapidly and


collide more frequently

– Rate of many chemical reactions roughly doubles for every


10 C increase in temperature

– Keeps water in liquid form


Temperature as a factor in weathering
Physical weathering:

• Promoted by low temperatures and water deficits

• Freezing – growth of ice crystals – expansive stress

• Dry climates – growth of salt crystals – expansive stress

• Water causes the oscillation in the volumes of substances –


volumetric increase in size (opening or mass)
Degree, Rate and Nature of Weathering
Depends On:
3. Surface configuration (topography)
Flat or sloping
Water runs off
Weathered layer removed to allow
weathering to continue
Exposure of underlying rock

Abundance and size of openings


Surface area
Depth of weathering
General topographic character based on
weathering in various climatic areas:

• Arid
– Angularity and sharp breaks in slope
– Steep cliffs with accumulations of loose debris at
base of slope
– Extensive bedrock exposure

• Humid
– Smooth, rolling hills
– Gently rounded slopes covered with deep
accumulations of weathered material
– Little exposure of bedrock
Degree, Rate and Nature of Weathering
Depends On:

4. Biological impacts on weathering


Biophysical Biochemical
1. Direct
Root pressures Bacterial redox
Growth stresses reactions
Wetting and drying Chelation
Mechanical boring Cation exchange
2. Indirect Solution
– Soil mixing
– Production of organic acids and CO2
– Organic layers protecting a surface
– Vegetal cover protection from raindrop
impact
Micro-organisms and
weathering of surface rocks
Epiliths Euendoliths Chasmoendoliths

Cryptoendoliths
A plant, fungus, or other organism that grows upon
rock
Euendoliths
an organism (archaeon, bacterium, fungus, lichen,
algae or amoeba) that lives inside rock, coral, animal
shells, or in the pores between mineral grains of a rock.

Chasmoendoliths
organisms that inhabit fissures and cracks of the
rock

Cryptoendoliths
Any organism that
colonizes structural cavities within porous rocks
Physical Weathering
• Physical forces break rock into smaller
pieces w/out changing mineral
composition
Physical weathering
Process Force
Frost weathering Crystal growth
Salt weathering Crystal growth
Hydration
Wetting and drying Hydration
Water absorption
Insolation weathering Thermal stress
Fire weathering Thermal stress
Exfoliation, sheeting Unloading or Stress
Release
Compressive weathering Loading
Unloading & Exfoliation
Continued weathering causes
rock slabs to separate & fall

HALF DOME
YOSEMITE NATIONAL PARK (California)
Granodiorite intrusion cut by glacial activity

“exfoliation domes”
Frost Wedging
Chemical Weathering
• Processes that break rock
components and internal structures
of minerals, making new minerals
Chemical weathering
Dissolution May be congruent or
incongruent
Hydration Incorporation of water
molecules into structure of
a compound
Hydrolysis Chemical reaction of water
with rock, involving breaking
of oxygen-hydrogen bonds
Carbonation Reaction of CO2 dissolved in
water with rock
Oxidation and reduction Removal or addition of
(REDOX) electrons from elements
which possess different
oxidation states
Formation of Soil
• Product of both physical and chemical
weathering
“good soil:”
Made of: decomposed rock 45%
+
decayed animal/plant life (“humus”) 5%
+
water 25%
+
air 25%
Important Soil-Forming Factors
• Climate
– Temperature & precipitation

• Time
– Longer time = thicker soil

• Plants/Animals
– Organic matter

• Slope
– If too steep, little/no soil - erosion
Soils and Climate
• Soil formation is directly linked to climate that
soil forms in

Three major groups


• Laterite
– Wet climate
• Pedalfer
– Temperate climate
• Pedocal
– Dry climate
Soil Profile
Laterite

A horizon

C horizon
Pedalfer
Pedocal

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