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Grade 11 Answer Key Chemistry Revision Sheets

This chemistry revision sheet contains questions to test students' knowledge of key concepts in thermochemistry. It includes multiple choice and written response questions about [1] specific heat capacity, enthalpy, entropy, Gibbs free energy, reaction rates, and factors that influence reaction rates. The document provides definitions and formulas for students to learn thermochemistry concepts and practice applying them to chemical problems and examples.

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0% found this document useful (0 votes)
972 views8 pages

Grade 11 Answer Key Chemistry Revision Sheets

This chemistry revision sheet contains questions to test students' knowledge of key concepts in thermochemistry. It includes multiple choice and written response questions about [1] specific heat capacity, enthalpy, entropy, Gibbs free energy, reaction rates, and factors that influence reaction rates. The document provides definitions and formulas for students to learn thermochemistry concepts and practice applying them to chemical problems and examples.

Uploaded by

kirki p
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Academic Year 2019- 2020

First Term
Chemistry revision sheet

Name: __________________________ Date: _______________

Grade:11 Section: _________

Q1. Circle the correct options

1. What is the specific heat capacity of a substance if 2.41x104 J are needed to


change the temperature of 105.0 g of it from 25.0ºC to 250.0ºC?

A. 1.02 x 10-4 J/gºC C. 9.18 x 10-4 J/gºC


B. 0.918 J/gºC D. 1.02 J/gºC

2. Which statement about enthalpy is true?


A. Heat is given off to the surroundings in endothermic reactions.
B. Some substances have a negative specific heat capacity.
C. Specific heat capacity is the same for all liquids.
D. The sign of ∆H is always negative in exothermic reactions.

3. What happens to the value of ∆H for a thermochemical reaction if the reaction


is reversed?
A. ∆H has the same numerical value, and the sign changes.
B. ∆H has the same numerical value, and the sign remains the same.
C. ∆H is the reciprocal of the original value, and the sign changes.
D. ∆H is the reciprocal of the original value, and the sign remains the same.

4. Which statement correctly describes an endothermic chemical reaction?


A. The products have higher potential energy than the reactants, and the ∆H is
negative.
B. The products have higher potential energy than the reactants, and the ∆H is
positive.
C. The products have lower potential energy than the reactants, and the ∆H is
negative.
D. The products have lower potential energy than the reactants, and the ∆H is
positive.

5. Given the thermochemical equation:


2NO2 (g) → 2NO(g) + O2(g) ∆H = 114 kJ
What is the ∆H for the reaction NO(g) + ½ O2(g) → NO2(g) ?

A. -114 kJ B. -57 kJ C. +57 kJ D. +114 kJ

6. A substance increases in temperature by 255ºC when a 983 g sample of it


absorbs 83 200 J of heat. What is the specific heat capacity of the
substance?

A. 0.332 J/gºC B. 0.450 J/gºC C. 21.6 J/gºC D. 321 J/gºC

7. What is the ∆H value for an exothermic energy change?


A. Always negative
B. Always positive
C. Could be positive or negative
D. Depends on the potential energy of the reactants

8. The presence of a catalyst is thought to increase the rate of a reaction by

a. changing the products that are formed in the reaction


b. decreasing the enthalpy change of the reaction
c. increasing the enthalpy change of the reaction
d. decreasing the activation energy of the reaction
e. increasing the activation energy of the reaction
9. Which of the following statements is true?
A. In an endothermic process heat is transferred from the surroundings to the
system.
B. In an exothermic process heat is transferred from the surroundings to the
system.
C. The surroundings will feel cooler in an exothermic process.
D. The surroundings will feel warmer in an endothermic process.

10. Thermochemistry is study of_____.


A. Transfer of energy as heat
B. Transfer of mass
C. Transfer of sound
D. Transfer of moles of substance

11. The measure of average kinetic energy is called _____.


A. Temperature
B. Pressure
C. Volume
D. Heat
12. Joule is SI unit of _____.
A. Heat
B. Mass
C. Temperature
D. None
13. The measure of degree of randomness is called _____.
A. Entropy
B. Enthalpy
C. Heat
D. None

14. If a solid is converted from liquid to gas, then _____.


A. Entropy will be increased
B. Entropy will be decreased
C. Entropy will remain same
D. None

15. If value of change in free energy is less than zero then the reaction will be
referred as
A. Spontaneous
B. Non spontaneous
C. Can be either spontaneous or non-spontaneous
D. None
16. If the reactants and products have same phase then its means the type of
reaction is .

A. Heterogeneous
B. Exothermic
C. Endothermic
D. Homogeneous

17. The minimum energy required to transform reactants into an activated complex
is called .
A. Activation energy
B. Kinetic energy
C. Potential energy
D. Heat energy
18. If concentration of reactants is increased then the rate of reaction will
be .
A. Increased
B. Decreased
C. Same
D. None
19. An equation that relates reaction rate and concentrations of reactants is
called____________.
A. Rate constant
B. Rate law
C. Rate of reaction
D. None
20. The rate determining step in a reaction is the
A. Slowest step
B. Fastest step
C. Intermediate step

Q2. Write answers to the following questions.

1. What do you mean by thermochemistry?

The branch of chemistry concerned with the quantities of heat evolved or absorbed
during chemical reactions.

2. How would you define SI unit of heat?

as a form of energy, heat has the unit joule (J) in the International System
of Units (SI)

3. What is meant by specific heat?

Specific heat capacity is the amount of heat energy required to raise the temperature
of a substance per unit of mass.

4. Write formula of enthalpy change?

∆H = m x s x ∆T

5. Explain thermochemical equations.

Such an equation in which information about heat change is included is called


a thermochemical equation. It is very important in such a case to indicate the physical
state of the various species involved. Examples are: (i) C(s) + O2(g) →CO2(g) ; ΔH = -
393.5 kJ.
6. Why value of enthalpy of exothermic reactions is negative?

If the enthalpy change of a reaction is negative, the system is losing energy, so the
products have less energy than the reactants, and the products are lower on the
vertical energy scale than the reactants are. Exothermic, then, implies that the
system loses, or gives off, energy.

7. Explain the given graph.

The graph shows that the chemical energy of products is more than that of
reactants
8. State Hess’s law.

Hess's Law) states that regardless of the multiple stages or steps of a reaction, the
total enthalpy change for the reaction is the sum of all changes

9. Calculate ∆H for the following reaction Cgraphite(s)--> Cdiamond(s)

2kj

10. Given : ∆H=91KJ/mol, T=298K, ∆S=6 KJ/K calculate ∆G and state


whether the reaction is spontaneous or not.

11. Discuss signs of entropy if randomness either increase or decreases.


Greater the randomness of particles, greater the value of entropy with
positive sign
In case of less randomness of particles, lesser the value of entropy with
negative sign

12. Define entropy and free energy.

Entropy is the measure of randomness of molecules or particles in a given system


Gibbs free energy is the energy associated with a chemical reaction that can do
useful work. It equals the enthalpy minus the product of the temperature
and entropy of the system.
13. What do you mean by reaction mechanism?

In chemistry, a reaction mechanism is the step by step sequence of


elementary reactions by which overall chemical change occurs.

14. Differentiate between homogeneous and heterogeneous reactions

Homogeneous reactions are chemical reactions in which the reactants and


products are in the same phase, while heterogeneous reactions have reactants in
two or more phases. Reactions that take place on the surface of a catalyst of a
different phase are also heterogeneous

15. Explain collision theory

The collision theory is based on the assumption that for a reaction to occur it is
necessary for the reacting species (atoms or molecules) to come together
or collide with one another.

16. Differentiate between activation energy and activated complex

The activated complex is the structure at the maximum energy point along the
reaction path; the activation energy is the difference between the energies of
the activated complex and the reactants.

17. Explain reaction rate and chemical kinetics


Reaction rate, the speed at which a chemical reaction proceeds. It is often
expressed in terms of either the concentration (amount per unit volume) of a product
that is formed in a unit of time or the concentration of a reactant that is consumed in a
unit of time.

Chemical kinetics is the study of chemical processes and rates of reactions.


18. Which factors can influence the rates of reactions?
Temperature
Concentration
Surface area

19. How does temperature and concentration affect the rate of reaction
Temperature and concentration are directly proportional to the rate reaction
So rate of reaction increases with increase in temperature and concentration

20. Differentiate between catalysis and catalyst

The process by which a substance speeds up a chemical reaction without being


consumed or altered in the process.
catalyst is a substance that speeds up a chemical reaction, but is not consumed by
the reaction

Q3. Write True / False for each statement.


Enthalpy sign in exothermic reaction is positive F

When solid changes into liquid, the entropy sign is negative. F

SI unit of heat is joule. T

Temperature does not affect the rate of reaction. F

CP IS symbol of specific heat capacity. T

In a given reaction if energy goes out of system then it’s called endothermic reaction. F

Entropy is randomness of the particles. T

Homogeneous catalyst has the same phase like reactants and products. T

The minimum energy needed to start a reaction can be referred as activation energy. T

The substance that changes rate of reaction is not called catalyst F

The power to which reactant concentration is raised is not called order of reaction F

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