Failure Analysis of Resist Pattern Collapse - Surface Tension ...

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Failure Analysis of Resist Pattern Collapse:

Surface Tension Influences

Cyrus Tabery
May 29, 2000
Problem: Resist Feature Collapse
• Resist features collapse upon formation
at high aspect ratios.
• What are important parameters
controlling this phenomena?
• What is required to design around this
problem?
Shear and Bending Model
• Beam is treated as Pitch P
elastic solid
L
d 4v
EI y 4
= ∆PL
dz

• Young-Laplace R
z Thickness
pressure E
εP/2
y γ
γ
∆P = γ∇ ⋅ n =
R x Substrate
LP3
• Aspect Ratio Iy = Moment of Inertia
96
Thickness z2
ε= M y = ∆PL Bending Moment
HalfPitch 2
Shear and Bending Model Cont.
• Shear Stress is linear x
with ε
2z
τ xy = ∆P(ε − )
P

• Tensile stresses is z
quadratic in ε
My 48∆Pxz 2
σz = x=
Iy P3
γ 2
σ max = 12 ε
P
Perturbation in Spacing
• Stress field in resist
beam causes R
deformation
γ
vmax = 3ε 4
E

• Deformation Elastic Deformation


influences Laplace R
pressure

∆P =
P − vmax
An Illustrative Example
Perturbation in Spacing Cont.
−m
• Updated Laplace 4 γ
i
 4 γ 
pressure gives new
(i )
vmax = 3ε ∑  − 6ε
E m =0 

EP 
elastic problem.
• Several iterations +
reveals a series ∞

convergence for ∑ (− x )−m


= x +1
m =0
deformation and stress
• Note: Rigid Model is
recovered in limit EÆ8 



γ  1 
σ max = 12 ε 2  4 8 2 
P 3ε γ 18ε γ
 1 − − 2 2 
 PE P E 
Feature Collapse Comparison
• Consider the 106
Elas tic Model

system Rigid Model

– E~109 Pa 104

γ~70 mJ/m2 S table Region

Failure Pitch (microns )


102

• High stresses Models Conflict

cause adhesive or 100

plastic deformation
failure, thus critical 10-2
Uns table Region

aspect ratio exists 10-4


for each pitch. 100 101
As pect Ratio
102
Conclusions
• Elastic deformation is important in
considering failure of resist beams
– Rigid model significantly overestimates
stable region

– N = ε γ = Deformation _ scale
4

Ta
PE Feature _ scale

• Length scale for deformation is


γ/Eε4~0.07ε4nm for glassy polymer/H2O
• Supercritical develop would eliminate
interfacial tension induced failure

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