Scribd Logo
Upload

Welcome to Scribd!

  • 35 views

    Topic 19 Test Ms 1. (A) (I) : Paddington Academy

    Uploaded by

    Brianna Douglas
    1) The document is a test covering topics related to organic chemistry and polymers. It contains multiple choice and short answer questions testing understanding of concepts like amino acid structures, peptide bond formation, properties of different polymers. 2) Questions cover topics such as drawing structures of amino acids and identifying functional groups within them. Other questions test understanding of addition polymers versus condensation polymers. 3) The document evaluates knowledge of organic reactions like hydrogenation and hydrolysis, as well as properties of different polymers including hydrogen bonding and hydrolysis reactivity between polyamides versus polyalkenes.

    Copyright:

    © All Rights Reserved
    Download as RTF, PDF, TXT or read online from Scribd

    Topic 19 Test Ms 1. (A) (I) : Paddington Academy

    Uploaded by

    Brianna Douglas
    35 views7 pages
    1) The document is a test covering topics related to organic chemistry and polymers. It contains multiple choice and short answer questions testing understanding of concepts like amino acid structures, peptide bond formation, properties of different polymers. 2) Questions cover topics such as drawing structures of amino acids and identifying functional groups within them. Other questions test understanding of addition polymers versus condensation polymers. 3) The document evaluates knowledge of organic reactions like hydrogenation and hydrolysis, as well as properties of different polymers including hydrogen bonding and hydrolysis reactivity between polyamides versus polyalkenes.

    Original Title

    topic_19_test_ms

    Copyright

    © © All Rights Reserved

    Available Formats

    RTF, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    1) The document is a test covering topics related to organic chemistry and polymers. It contains multiple choice and short answer questions testing understanding of concepts like amino acid structures, peptide bond formation, properties of different polymers. 2) Questions cover topics such as drawing structures of amino acids and identifying functional groups within them. Other questions test understanding of addition polymers versus condensation polymers. 3) The document evaluates knowledge of organic reactions like hydrogenation and hydrolysis, as well as properties of different polymers including hydrogen bonding and hydrolysis reactivity between polyamides versus polyalkenes.

    Copyright:

    © All Rights Reserved
    Download as RTF, PDF, TXT or read online from Scribd
    Download as rtf, pdf, or txt
    35 views7 pages

    Topic 19 Test Ms 1. (A) (I) : Paddington Academy

    Uploaded by

    Brianna Douglas
    1) The document is a test covering topics related to organic chemistry and polymers. It contains multiple choice and short answer questions testing understanding of concepts like amino acid structures, peptide bond formation, properties of different polymers. 2) Questions cover topics such as drawing structures of amino acids and identifying functional groups within them. Other questions test understanding of addition polymers versus condensation polymers. 3) The document evaluates knowledge of organic reactions like hydrogenation and hydrolysis, as well as properties of different polymers including hydrogen bonding and hydrolysis reactivity between polyamides versus polyalkenes.

    Copyright:

    © All Rights Reserved
    Download as RTF, PDF, TXT or read online from Scribd
    Download as rtf, pdf, or txt
    of 7

    Paddington Academy

    TOPIC 19 TEST MS
     

    1.         (a)     (i)      

     
    Allow CO2- and NH2+
    1

    (ii)     NOTE − Two marks for this clip


    M1 for alanine section bonded through N
    M2 for alanine section bonded through C
    But penalise error in proline ring
    1

     
    Allow MAX 1 for correct tripeptide in polymer structure
    1

    (b)     (i)      3-methylpent-2-ene
    Ignore E-Z, commas, spaces or missing hyphens
    1

    (ii)     4-amino-3-methylbutanoic acid
    Ignore commas, spaces or missing hyphens
    1

    (iii)    
    or any polyamide section containing
    8 carbons plus two C=O plus two N-H, such as

    Trailing bonds are required


    1

    (iv)    Non polar OR no polar groups / bonds (for attack by water / acids /


    alkalis / nucleophiles or for hydrolysis)

    C-C bonds are strong


    Page 1
    Paddington Academy
    1
    [7]

    2.           (a)    

    Allow −NH and NH −


    3
    + +
    3

    (b)     

    Allow protonated form, i.e. −NH3+ or NH −


    +
    3

    (c)     

    Allow – CO 2
    –

    (d)     

    Allow zwitterion with any COO −

    Allow use of “wrong” COOH

    1
    [4]

    3.

    Page 2
    Paddington Academy

    4. (a)         (i)

    These four only


    1

    (ii)

    Allow − NH and NH
    3
    + +
    3−

    (iii)    2-amino-3-hydroxybutanoic acid
    Ignore 1 in butan-1-oic acid

    Do not penalise commas or missing hyphens


    Penalise other numbers
    1

    (iv)

    Allow –NH and NH


    3
    + +
    3−

    (b)     (i)      Condensation
    Allow polyester
    1

    (ii)     propane-1,3-diol
    Must have e
    Allow 1,3-propanediol
    1

    Page 3
    Paddington Academy

    Page 4
    Paddington Academy

    (c)     (i)      Addition
    Not additional
    1

    (ii)

    Allow monomers drawn either way round


    Allow bond to F in CF 3

    OR

    1 for each structure within each pair


    1

    (d)     c
    If wrong, CE = 0
    1

    C-C or C-F bonds too strong


    1
    [11]

    Page 5
    Paddington Academy

    4.         (a)     (i)     

    (Ignore n or brackets, but trailing bonds are essential)


    1

    (ii)     Addition or radical


    1

    (b)     (i)      2-aminobutanoic (acid)


    1

    (ii)    

    (c)     (i)      C H O3 4 2

    (ii)    

    (1,4-)butan(e)dioic (acid)
    (allow succinic, but not dibutanoic nor butanedicarboxylic
    acid)
    1

    (iii)     Can be hydrolysed / can react with acid or base or water /


    can react with nucleophiles
    1
    [8]

    5.     (a)     1, 4-diaminobutane or butane -1, 4-diamine (1)


    A: BrCH2CH2Br or ClCH2CH2Cl (1)
    B: NC CH2CH2CN
    Step 1: Br2 or Cl2 (1) (ignore aq)
    Step 2: KCN (1) (NOT HCN)
    Step 3: H2 / Ni or LiAlH or Na / C2H5OH (1) (NOT NaBH4)
    4

    Hydrogenation only for H2 / Ni, or nucleophilic addition only for LiAlH4(1)


    OR reduction or addition
    7

    Page 6
    Paddington Academy

    (b)    

    QL hydrogen bonding (1)

    Polarity of H-bonding shown or discussed (1)


    4

    (c)     Polyamides / peptide link can be hydrolysed (1)


    OR polyalkenes cannot be hydrolysed

              QL OH– attacks peptide link or C (1)


    +

         poly(ethene) non-polar (1)


    3
    [14]

    6. D
    [1]
    7. B
    [1]
    8. B
    [1]
    9. A
    [1]
    10. C
    [1]
    11. C
    [1]

    Page 7

    You might also like