ORGANIC CHEMISTRY
ENTHUSE
DPP # 16
1. Column-I Column-II
(Reactions) (Statements)
Me
Me
H2SO4
(A) H2O (P) Optically active
Me
Hg(OAc) 2 /H 2O
(B)
NaBH ,H O
(Q) One of the major product contains plane of symmetry
4 2
Me
Me
(1) 9 BBN
(C) (R) Optically active product only
( 2 ) NaOH , H 2O 2
Me
Me B H
2 6
(D) (S) Only four optically active stereoisomers obtained
NaOH , H 2O 2
2. 1-Methylcyclopentene can be converted into the given compound by the use of :
(A) BD3 followed by HCOOH (B) BH3 followed HCOOD
(C) BD3 followed by HCOOD (D) BH3 followed by CH3COOD
3. Assertion & Reason.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
(i) Statement-1 : LDA is a very strong nucleophile but it is not a very good base.
Statement-2 : Nucleophilicity is a kinetic property but basicity is thermodynamic property.
O
||
(ii) Statement-1 : Resonance energy of CH 2 CH C NH 2 is very high as compared to
O
||
CH 3CH 2 C NH 2 .
Statement-2 : Another double bond is introduced in conjugation to C = O.
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, Ph. 0744-2423333 70732-22177 1
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ORGANIC CHEMISTRY
ENTHUSE
(iii) Statement-1 : If during a reaction is generated, it quickly rearranges
into by hydride shift.
Statement-2 : Hydride is better migrator than methyl during carbocation rearrangements.
4. Correct order of basic strength of given compound is :
(A) 3>1>2>4 (B) 3<1<2<4 (C) 3<4<1<2 (D) 3>4>1>2
5. Major product 'P' of the following reaction is :
H
P
(A) (B) (C) (D)
6. Which of the following statement is correct?
CH3
C2H5 CH3 CH3 CH3
CH3 CH3 H C2H5
N N H H
H CH3 N
CH3 CH3 H C2H5
(I) (II) (III)
(A) I & II are conformers while II & III are functional isomers
(B) I & II are functional isomers while II & III are conformers
(C) I & II are functional isomers while I & III are conformers
(D) None of the above
7. Major product (Z) of given reaction is :
( i ) B2 H 6 ,THF conc . H PO 4
X 3 Y dil
. H
2SO 4
Z
( ii ) H 2O 2 / OH
(A) (B) (C) (D)
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, Ph. 0744-2423333 70732-22177 2
www. nucleuseducation.in
ORGANIC CHEMISTRY
ENTHUSE
8. Reaction-1 H (A)
Reaction-2 H (B)
Reaction-3 H (C)
Total number of -hydrogen present in major product A + B + C is.
9. How many alkenes on reaction with dil. H2SO4 produces 2,3-dimethyl butan-2-ol ?
10. Give major product of following reaction :
H SO Br
(A) 2
4 (B) 2
H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, Ph. 0744-2423333 70732-22177 3
www. nucleuseducation.in