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Organic Chemistry Practice Quiz

This document contains 10 multiple choice questions related to organic chemistry. Some questions test understanding of reaction mechanisms and identifying products. Others relate to properties like optical activity, basicity vs nucleophilicity, and identifying functional isomers vs conformers. The questions cover a range of organic chemistry concepts including substitution, elimination, carbocation rearrangements, and identifying major products of reaction sequences.

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Arjun Sabnis
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0% found this document useful (0 votes)
463 views3 pages

Organic Chemistry Practice Quiz

This document contains 10 multiple choice questions related to organic chemistry. Some questions test understanding of reaction mechanisms and identifying products. Others relate to properties like optical activity, basicity vs nucleophilicity, and identifying functional isomers vs conformers. The questions cover a range of organic chemistry concepts including substitution, elimination, carbocation rearrangements, and identifying major products of reaction sequences.

Uploaded by

Arjun Sabnis
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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ORGANIC CHEMISTRY

ENTHUSE
DPP # 16

1. Column-I Column-II
(Reactions) (Statements)
Me
Me
H2SO4
(A) H2O (P) Optically active

Me

Hg(OAc) 2 /H 2O
(B) 
NaBH ,H O
 (Q) One of the major product contains plane of symmetry
4 2

Me

Me

(1) 9  BBN
(C)    (R) Optically active product only
( 2 ) NaOH , H 2O 2

Me
Me B H
2 6
(D)    (S) Only four optically active stereoisomers obtained
NaOH , H 2O 2

2. 1-Methylcyclopentene can be converted into the given compound by the use of :

(A) BD3 followed by HCOOH (B) BH3 followed HCOOD


(C) BD3 followed by HCOOD (D) BH3 followed by CH3COOD

3. Assertion & Reason.


(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
(i) Statement-1 : LDA is a very strong nucleophile but it is not a very good base.
Statement-2 : Nucleophilicity is a kinetic property but basicity is thermodynamic property.
O
||
(ii) Statement-1 : Resonance energy of CH 2  CH  C  NH 2 is very high as compared to

O
||
CH 3CH 2  C  NH 2 .
Statement-2 : Another double bond is introduced in conjugation to C = O.

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, Ph. 0744-2423333 70732-22177 1
www. nucleuseducation.in
ORGANIC CHEMISTRY
ENTHUSE

(iii) Statement-1 : If during a reaction is generated, it quickly rearranges

into by hydride shift.

Statement-2 : Hydride is better migrator than methyl during carbocation rearrangements.


4. Correct order of basic strength of given compound is :

(A) 3>1>2>4 (B) 3<1<2<4 (C) 3<4<1<2 (D) 3>4>1>2


5. Major product 'P' of the following reaction is :


H
 P

(A) (B) (C) (D)

6. Which of the following statement is correct?


CH3
C2H5 CH3 CH3 CH3
CH3 CH3 H C2H5
N N H H
H CH3 N
CH3 CH3 H C2H5
(I) (II) (III)

(A) I & II are conformers while II & III are functional isomers
(B) I & II are functional isomers while II & III are conformers
(C) I & II are functional isomers while I & III are conformers
(D) None of the above
7. Major product (Z) of given reaction is :
( i ) B2 H 6 ,THF conc . H PO 4
   X  3  Y dil
. H
2SO 4
 Z
( ii ) H 2O 2 / OH  

(A) (B) (C) (D)

H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, Ph. 0744-2423333 70732-22177 2
www. nucleuseducation.in
ORGANIC CHEMISTRY
ENTHUSE

8. Reaction-1 H (A)


Reaction-2 H (B)


Reaction-3 H (C)

Total number of -hydrogen present in major product A + B + C is.

9. How many alkenes on reaction with dil. H2SO4 produces 2,3-dimethyl butan-2-ol ?

10. Give major product of following reaction :

H SO Br
(A) 2 
4  (B) 2


H.O. 92, Rajeev Gandhi Nagar, Kota (Raj.) Mob. 97831-97831, Ph. 0744-2423333 70732-22177 3
www. nucleuseducation.in

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