Atomic Structure Assignment 5
Atomic Structure Assignment 5
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4 2 mr 2 nh 2 mr n
1) 2) 3) 4)
nh 4 2 mr n2 h2 2 mr
11. The shortest wavelength line (in nanometer ) in the Lyman series of the H-
spectrum is
1)81.16 nm 2)91.16 nm 3)31.16 nm 4)32.56 nm
12. The radius of second Bohr’s orbit of hydrogen atom is
1)0.053 nm 2)0.106 nm 3)0.2116 nm4)0.4256 nm
13. Ratio of radii of second and first Bohr’s orbit of H- atom is
1)4:1 2)2:1 3)3:1 4)5:1
14. The frequency of radiation emitted when the electron falls from n = 4 to n=1
in a hydrogen atom will be (Given ionization energy of H= 2.18 10−18 J
atom−1 and h = 6.625 10−34 Js ).
1) 3.08 1015 s −1 2) 2.00 1015 s −1 3) 1.54 1015 s −1 4) 1.03 1015 s −1
15. The radius of which of the following orbit is same as that of the first Bohr’s
orbit of hydrogen atom
1) He+ ( n = 2) 2) Li+2 ( n = 2) 3) Li+2 ( n = 3) 4) Be+3 ( n = 2)
16. The radius of first Bohr’s orbit for hydrogen is 0.53 A0 .The radius of third
Bohr’s orbit would be
1) 0.79A0 2) 1.59A0 3) 3.18A0 4) 4.77 A0
17. The kinetic energy of an electron in the second Bohr orbit of a hydrogen
atom is a0 is Bohr radius
h2 h2 h2 h2
1) 2 2 2) 3) 4)
4 ma0 32 2 ma02 16 2 ma02 64 2 ma02
18. The energy of second Bohr orbit of the hydrogen atom is −328 kJ mol −1 ,hence
the energy of third Bohr orbit would be
1) −41kJ mol −1 2) −1312 kJ mol −1 3) −164kJ mol −1 4) −146 kJ mol −1
19. What is the energy ( in eV) required to excite the electron from n=1 to n=2
state in hydrogen atom?(n= principal quantum number)
1)13.6 2)3.4 3)17.0 4)10.2
20. The energy of hydrogen atom in its ground state is -13.6 eV.The energy of
the level corresponding to the quantum number n= 5 is
1) -5.4 eV 2)-0.54 eV 3)-2.72 eV 4) -0.85 eV
21. Ionisation energy of He+ is 19.6 10−18 J atom −1 .The energy of the first
stationary state (n=1) of Li +2 is
1) 4.4110−16 J atom −1 2) − 4.4110−17 J atom −1
3) −2.2 1015 J atom−1 4) 8.82 10−17 J atom−1
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22. A gas absorbs a photon of 355 nm and emits at two wavelengths. If one of
the emissions is at 680 nm, the other is at
1)1035 nm 2)325 nm 3)743 nm 4)518 nm
23. If the shortest wavelength of H-atom in Lyman series is , then longest
wavelength in Balmer series of He+ ion is:
9 36 5
1) 2) 3) 4)
5 5 4 9
24. The wavelength of electron waves in two orbits is 3;5.The ratio of kinetic
energy of electrons will be
1)25:9 2)5:3 3)9:25 4)3:5
25. A cricket ball of 0.5 kg is moving with a velocity of 100 m/sec. The
wavelength associated with its motion is
1)1/100 cm 2) 6.6 10−34 m 3) 1.32 10−35 m 4) 6.6 10−28 m
KEY
1-10 3 1 3 4 2 4 4 2 1 1
11-20 2 3 1 1 4 4 2 4 4 2
21-30 2 3 1 1 3
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