SDS no. B.

525
Version 2
Revision date 27/Feb/2016
Supersedes date 16/Feb/2016

Safety Data Sheet

Flowback Surfactant B.525

1. Identification
1.1 Product identifier

Product name Flowback Surfactant B.525

Product code B.525

This product may not be distributed or used in Canada.

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Surfactant.

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
Schlumberger Technology Corporation
110 Schlumberger Drive
Sugar Land, Texas 77478, USA
Telephone: 1-281-285-7873

E-mail address [email protected]

Prepared by
Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Gulan Sun

1.4 Emergency Telephone Number

Emergency telephone (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44
(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada
001 613 996 6666

2. Hazards identification
2.1 Classification of the substance or mixture

GHS - Classification

Health hazards
Serious eye damage/eye irritation Category 1

Environmental hazards Not classified

Physical Hazards Not classified

2.2 Label elements

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Signal word
DANGER

Hazard statements
H318 - Causes serious eye damage

Precautionary statements
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/ physician

Unknown acute toxicity 7% of the mixture consists of ingredient(s) of unknown toxicity.

3. Composition/information on Ingredients

3.1 Substances

Not Applicable

3.2 Mixtures

Component CAS-No Weight % - range

Ethoxylated alcohol Proprietary 2.5 - 5
2-[2-(2-Butoxyethoxy)ethoxy]ethanol 143-22-6 2.5 - 5

Comments
The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret

4. First aid measures

4.1 First-Aid Measures

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.

Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious
person. Call a physician or Poison Control Centre immediately. Obtain medical attention.

Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. Get medical attention if irritation persists. Wash contaminated clothing before
re-use.

Eye contact Rinse immediately with plenty of water, also under the eyelids. Hold eye open and rinse
slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the
first five minutes, then continue rinsing eye. Immediate medical attention is required.

4.2 Most important symptoms and effects, both acute and delayed
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Main symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically

5. Fire-fighting measures
5.1 Extinguishing media

Suitable extinguishing media

Water Fog, Alcohol Foam, CO2, Dry Chemical.

Extinguishing media which shall not be used for safety reasons

Do not use a solid water stream as it may scatter and spread fire.

5.2 Special hazards arising from the substance or mixture

Unusual fire and explosion hazards

Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks).
Heating of containers may cause pressure rise, with risk of bursting.

Hazardous combustion products

When heated strongly or burned, oxides of carbon and harmful organic chemical fumes are released.

5.3 Advice for firefighters

Special protective equipment for fire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Special Fire-Fighting Procedures

Cool fire-exposed containers using water spray.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment identified in Section 8. Wash thoroughly after handling. Avoid contact with the skin and the
eyes. Do not breathe vapors or spray mist. Contaminated surfaces will be extremely slippery.

6.2 Environmental precautions

Do not allow material to contaminate ground water system.

Environmental exposure controls

Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and materials for containment and cleaning up

Methods for containment

Prevent further leakage or spillage if safe to do so.

Methods for cleaning up

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and
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place in container for disposal according to local / national regulations (see section 13).

6.4 Reference to other sections

See section 13 for more information.

7. Handling and storage

7.1 Precautions for safe handling

Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wash thoroughly
after handling. Keep away from open flames, hot surfaces and sources of ignition. Prevent splashing and leaking of product. Do not
breathe vapors or spray mist.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Keep airborne concentrations below exposure limits. Ensure adequate ventilation.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Follow safe
warehousing practices regarding palletizing, banding, shrink-wrapping and/or stacking.
Store in original container.

8. Exposure controls/personal protection

8.1 Control parameters
Component Information

Component ACGIH TLV OSHA PEL

Ethoxylated alcohol Not Determined Not Determined
2-[2-(2-Butoxyethoxy)ethoxy]ethanol Not Determined Not Determined

8.2 Exposure controls

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.

Engineering measures to reduce exposure

Ensure adequate ventilation, especially in confined areas.

Personal protective equipment

Eye protection Tightly fitting safety goggles. For spills and emergencies, also wear face shield.
Hand protection Wear chemical resistant gloves such as nitrile or neoprene, Be aware that liquid may
penetrate the gloves. Frequent change is advisable.
Respiratory protection All respiratory protection equipment should be used within a comprehensive respiratory
protection program that meets the requirements of 29 CFR 1910.134 (U.S. OSHA
Respiratory Protection Standard) or local equivalent.

If exposed to airborne mist/aerosol of this product, use at least a NIOSH-approved N95

half-mask disposable or re-usable particulate respirator. In work environments containing
oil mist/aerosol, use at least a NIOSH-approved P95 half-mask disposable or reuseable
particulate respirator. If exposed to vapors from this product use a NIOSH/MSHA-approved
respirator with an Organic Vapor cartridge.
Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available at
the work place.

Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and wash
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contaminated clothing before re-use.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance Transparent
Color Colorless
Odor Slight
Odor threshold Not applicable

Property Values Remarks

pH 6.0 - 9.0
pH @ dilution 5.7 10% aqueous @ 20°C
Melting/freezing point No information available
Boiling point/range > 100 °C / >212 °F
Flash point > 100 °C / > 212 °F PMCC
Evaporation rate (BuAc =1) No information available
Flammability (solid, gas) Not Applicable
Flammability Limits in Air
Upper flammability limit No information available
Lower flammability limit No information available
Vapor pressure No information available
Vapor density No information available
Specific gravity 1.003 @20 °C
Bulk density No information available
Water solubility Soluble
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Log Pow No information available

Explosive properties No information available

Oxidizing properties No information available

9.2 Other information

Pour point -1°C / 30.2°F
Molecular weight No information available
VOC content(%) No information available
Density No information available

10. Stability and reactivity

10.1 Reactivity

No data available.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerization
Hazardous polymerization does not occur.

10.4 Conditions to avoid

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Avoid contact with heat, sparks, open flame, and static discharge. Do not freeze.

10.5 Incompatible materials

Oxidizing agents.

10.6 Hazardous decomposition products

When heated strongly or burned, oxides of carbon and harmful organic chemical fumes are released.

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity
Inhalation May cause irritation.

Eye contact Causes serious eye damage.

Skin contact Prolonged contact may cause redness and irritation.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Toxicology data for the components

Component LD50 Oral LD50 Dermal LC50 Inhalation

Ethoxylated alcohol No data available No data available No data available
2-[2-(2-Butoxyethoxy)ethoxy]ethanol = 5300 mg/kg ( Rat ) = 3480 mg/kg ( Rabbit ) No data available

Component IARC Group 1 or 2 ACGIH - Carcinogens OSHA listed carcinogens NTP

Ethoxylated alcohol No data available No data available No data available No data available
2-[2-(2-Butoxyethoxy)ethoxy]ethanol No data available No data available No data available No data available

Sensitization Not classified.

Mutagenic effects No evidence of mutagenic properties.

Carcinogenicity No evidence of carcinogenic properties.

Reproductive toxicity No evidence of toxicity to reproduction.

Developmental toxicity Not known to cause birth defects or have a deleterious effect on a developing fetus.

Routes of exposure Skin contact. Inhalation. Eye contact.

Routes of entry None known.

Specific target organ toxicity Not classified

(single exposure)
Specific target organ toxicity Not classified.
(repeated exposure)

Aspiration hazard Not classified.

12. Ecological information

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12.1 Toxicity

Toxicity to algae
See component information below.

Toxicity to fish
See component information below.

Toxicity to daphnia and other aquatic invertebrates

See component information below.

Component Toxicity to fish Toxicity to algae Toxicity to daphnia and other

aquatic invertebrates
Ethoxylated alcohol No information available No information available No information available
( 5 - 10 )
2-[2-(2-Butoxyethoxy)ethoxy]ethanol = 2400 mg/L LC50 Pimephales > 500 mg/L EC50 Desmodesmus > 500 mg/L EC50 Daphnia
143-22-6 ( 5 - 10 ) promelas 96 h 2200 - 4600 mg/L subspicatus 72 h magna 48 h
LC50 Leuciscus idus 96 h

12.2 Persistence and degradability

No product level data available.

12.3 Bioaccumulative potential

No product level data available.

12.4 Mobility in soil

No information available.

12.5 Results of PBT and vPvB assessment

This preparation contains no substance considered to be persistent, bioaccumulating nor toxic (PBT)
This preparation contains no substance considered to be very persistent nor very bioaccumulating (vPvB)

12.6 Other adverse effects.

None known.

13. Disposal considerations

13.1 Waste treatment methods

Disposal Method As local regulations may vary; all waste must be disposed/recycled/reclaimed in
accordance with federal, state, and local environmental control regulations.

Contaminated packaging Do not re-use empty containers. Dispose of in accordance with local regulations.

14. Transport information

14.1 UN Number
UN No. (DOT) Not regulated
UN No. (TDG) Not regulated
UN/ID No. (ADR/RID/ADN/ADG) Not regulated
UN No. (IMDG) Not regulated
UN No. (ICAO) Not regulated
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14.2 Proper shipping name

The product is not covered by international regulation on the transport of dangerous goods

14.3 Hazard class(es)

DOT Hazard class Not regulated
TDG Hazard class Not regulated
ADR/RID/ADN/ADG Hazard class Not regulated
IMDG Hazard class Not regulated
ICAO Hazard class/division Not regulated

14.4 Packing group

DOT Packing group Not regulated
TDG Packing group Not regulated
ADR/RID/ADN/ADG Packing group Not regulated
IMDG Packing group Not regulated
ICAO Packing group Not regulated

14.5 Environmental hazard

Marine pollutant No

14.6 Special precautions

Not Applicable

15. Regulatory information

International inventories

USA (TSCA) Complies

Canada (DSL) Complies.
European Union (EINECS and ELINCS) Does not Comply
Philippines (PICCS) Complies
Japan (ENCS) Does not Comply
China (IECSC) Complies
Australia (AICS) Complies
Korean (KECL) Complies
New Zealand (NZIoC) Complies

U.S. Federal and State Regulations

SARA 311/312 Hazard Categories

Immediate (acute) health hazard.

Component SARA 302 / TPQs SARA 313 CERCLA RQ

Ethoxylated alcohol N/A N/A N/A
2-[2-(2-Butoxyethoxy)ethoxy]ethanol N/A 1.0% N/A

State Comments
Proposition 65: This product is not known to contain chemicals considered by the State of California's Safe Drinking Water and
Toxic Enforcement Act of 1986 as causing cancer and/or reproductive toxicity at levels that are expected to pose a significant risk
under anticipated use conditions.
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Canadian Classification

This product may not be distributed or used in Canada.

16. Other information

Supersedes date 16/Feb/2016

Revision date 27/Feb/2016

Version 2

The following sections have been 10, 16.

revised:

HMIS classification

Health 3
Flammability 1
Physical hazard 0
PPE X

N/A - Not Applicable, N/D - Not Determined.

Disclaimer
The information contained herein is considered in good faith as reliable of the date issued and is based upon on
measur ement s,t estsordat ader ivedf rom supplier’
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information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness
of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the
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agreement between the parties.