4IB IBDP – Chemistry (2020-2021) Revision – 2nd Term Test

Name: __________________ Class: 5IB Class No.: _____ Date: __________

Revision – 2nd Term Test (Answer)

Note 1 (Topic 2) Atomic structure

1. Information is given about four different atoms:

Atom neutrons protons
W 22 18
X 18 20
Y 22 16
Z 20 18
Which two atoms are isotopes?
A. W and Y
B. W and Z
C. X and Z
D. X and Y
B
2. Which statement is correct for the emission spectrum of the hydrogen atom?
A. The lines converge at lower energies.
B. The lines are produced when electrons move from lower to higher energy levels.
C. The lines in the visible region involve electron transitions into the energy level closest
to the nucleus.
D. The line corresponding to the greatest emission of energy is in the ultraviolet region.
D
3. Which species possesses only two unpaired electrons?
A. Zn
B. Mg
C. Ti2+
D. Fe2+
C

1. Calculate the percentage abundance of the two isotopes of rubidium 85Rb and 87Rb. [1]

85 x + 87(100 − x)
Ar(Rb) = 85.47 = ; Accept other valid mathematical alternatives.
100
85
Rb = 76.5 and 87Rb = 23.5%; 1

Prepared by Dr. Lee Ka Ho (April 2021) 1 Printed at 2021/04/19 08:29:41

 4IB IBDP – Chemistry (2020-2021) Revision – 2nd Term Test

Note 2+3 (Topic 4) Chemical bonding and structure (SL)

1. Which compound contains both ionic and covalent bonds?
A. MgCl2
B. HCl
C. H2CO
D. NH4Cl
D

2. How many electrons are used in the carbon-carbon bond in C2H2?

A. 4
B. 6
C. 10
D. 12
B

1. What is the Lewis (electron dot) structure for sulfur dioxide?

A. O S O

B. O S O

C. O S O

D. O S O

D
2. Which species has a trigonal planar shape?
A. CO32–

B. SO32–
C. NF3
D. PCl3
A

3. Which compound has the highest boiling point?

A. CH3CH2CH3
B. CH3CH2OH
C. CH3OCH3
D. CH3CHO
B

4. Which substance is most soluble in water (in mol dm–3) at 298 K?

A. CH3CH3
B. CH3OCH3
C. CH3CH2OH
D. CH3CH2CH2CH2OH C

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4IB IBDP – Chemistry (2020-2021) Revision – 2nd Term Test

1. Predict and explain which of the following compounds consist of molecules:

NaCl, BF3, CaCl2, N2O, P4O6, FeS and CBr4. [2]

BF3, N2O, P4O6 and CBr4; 1

Non-metals only/small difference in electronegativity values of the elements; 1

2. Predict and explain the order of the melting point for propanol, butane and propanone with reference to their
intermolecular forces.
(Hints: propanol is CH3CH2CH2OH, butane is CH3CH2CH2CH3, and propanone is (CH3)2C=O) [4]

butane < propanone < propanol;

butane has van der Waals’ forces;
Accept vdW, dispersion or London forces or attractions between temporary dipoles.
propanone has dipole-dipole attractions;
propanol has (the stronger) H-bonding;

3. By reference to the structure and bonding in NaCl and SiCl4:

State and explain the differences in electrical conductivity in the liquid state. [3]

NaCl conducts and SiCl4 does not; 1

NaCl ionic and SiCl4 covalent; 1

ions can move in liquid (in NaCl); 1

4. Draw a diagram to show hydrogen bonding between two molecules of NH3.The diagram should include any
dipoles and/or lone pairs of electrons [3]

Suitable diagram indicating dipoles;

lone pairs of electrons;
hydrogen bonding;

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 4IB IBDP – Chemistry (2020-2021) Revision – 2nd Term Test

t
Nope 4 (Topic 1) Stoichiometric relationships

yaoi
07
k
1. Which statements about mixtures are correct?
I. The components may be elements or compounds.
II. All components must be in the same phase.

Joycekg
III. The components retain their individual properties
A. I and II only ds
B. I and III only
C. II and III only
D. I, II, and III

2. What is the coefficient for O2(g) when the equation below is balanced?

I 053 4
__C3H8(g) + __O2(g) → __CO2(g) + __H2O(g)
A. 2
B. 3
TY
OC. 5
V
D. 7 10
3. What is the coefficient for H2SO4(aq) when the following equation is balanced, using the smallest
possible integers?

A. 1
ftp.i 0
__Mg3N2(s) + __H2SO4(aq) → __MgSO4(aq) + __(NH4)2SO4(aq)
0
B. 3

OC.D. 4 H
7 p2NHz

Note 5 (Topic 8) Acid and Bases (SL)

O
1. Which is not a strong acid?
o
A. Nitric acid HNO HMS HCl 11
B. Sulfuric acid
Hase C O
H
Hilda
OC. Carbonic acid
to
D. Hydrochloric acid
H4H3P04 It
2. An aqueous solution of which of the following reacts with magnesium metal?
A. Ammonia
NHscaffE
NHaotT MgH H
O
B. Hydrogen chloride
C. Potassium hydroxide
KOH
D. Sodium hydrogencarbonate
Nano M
Prepared by Dr. Lee Ka Ho (April 2021) base 4 Printed at 2021/04/19 08:29:23
 patally ionize

f
4IB IBDP – Chemistry (2020-2021) completely
ionie Revision – 2nd Term Test

g
3. Which methods can distinguish between solutions of a strong monoprotic acid and a weak monoprotic
acid of the same concentration?
conc ol Ht
I. Mg
Add magnesium to each solution and measure the rate of the formation of gas
bubbles.
II.
T NaOH
Add aqueous sodium hydroxide to each solution and measure the temperature
change.
Ht 1 OH Hao OH ve
III. Use each solution in a circuit with a battery and lamp and see how bright the
lamp glows.
A. I and II only r e
conductivity
B. I and III only
C. II and III only conc ol
mohik.int
O
D. I, II and III
Ht A
HA
5. Ammonia can be converted into nitric acid, HNO3(aq), and hydrocyanic acid, HCN(aq).
Distinguish between the terms strong and weak acid and state the equations used to show the dissociation of
each acid in aqueous solution. [3]

1. Calcium carbonate is added to separate solutions of hydrochloric acid and ethanoic acid of the same
concentration. State one similarity and one difference in the observations you could make. [2]

(ii) Write an equation for the reaction between hydrochloric acid and calcium carbonate. [2]

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 40 1440 3 103
4IB IBDP – Chemistry (2020-2021) Xtc D 12 6 Revision – 2nd Term Test te
Note 6 (Topic 9) Redox processes x 14 41
ED ER
14 15
1. What happens to vanadium during the reaction VO2+(aq) → VO3–(aq)?
0 ON B ta
oB.
A. It undergoes oxidation and its oxidation number changes from +4 to +5.
It undergoes oxidation and its oxidation number changes from +2 to +4. I
C. It undergoes reduction and its oxidation number changes from +2 to –1. H H
D. It undergoes reduction and its oxidation number changes from +4 to +2.

2. In which change does oxidation occur?

A. CH3CHO → CH3CH2OH
e ER
B. CrO42–→ Cr2O72–
XEDXER
C. I 42–→ SO
SO 632–
1
Fb 2 ER
D. NO2– → NO3–
O 3 Is 0A
3. Which statement is correct about an oxidizing agent in a chemical reaction?
A
A.
DRA
It reacts with oxygen.
B. It reacts with H+ ions. x
C. It loses electrons.
To R.A X
ME
O Fe
D. It undergoes reduction.
TR oar Fe Fest
SRA wo.tt
1. Which of the following is NOT a redox reaction?
o + Br2(g)
A. 2AgBr(s) → 2Ag(s)
TA.Tw.ae
element
SO2(g) + 2HRA
B.an 2S(g) → 3S(s) + 2H2O(l)
corpond
To an 0 In
C. 4
2KClO3(s) → 2KCl(s) + 3O2(g)
D. Ca(HCO3)2(aq) → CaCO3(s) + H2O(l) + CO2(g)
O o
Hz
4. What is the coefficient for H+ when the redox equation below is balanced?

A't NO 20
3
405 F I NO(g) +
–
Ag(s) + 3 (aq) + H+(aq) → Ag+(aq) + H2O(l)
A. 1 O 15 T2
w
B. 2
C. 3

O
D. 4
O l 13 1 0 130
5. What is the total of all the coefficients in the balanced equation for the reduction of 1 mol of MnO4–?

A. 5
pp
17
085 142 04
__ MnO4– +__H+ + __ e– →__Mn2+ + __H2O
halfequal.ie
B. 9
C. 17 9
O
D. 19 It
Prepared by Dr. Lee Ka Ho (April 2021) 6 Printed at 2021/04/19 08:29:23
 4IB IBDP – Chemistry (2020-2021) Revision – 2nd Term Test

6. Consider the following spontaneous reactions.

Fe(s) + Cu2+(aq) → Fe2+(aq) + Cu(s)

O 0
Cu(s) + 2Ag+(aq) → Cu2+(aq) + 2Ag(s)
Zn(s) + Fe2+ (aq) → Zn2+ (aq) + Fe(s)
Which is the correct combination of strongest oxidizing agent and strongest reducing agent?
Strongest oxidizing agent Strongest reducing agent
Zn Fe Cu
A. Ag(s) Zn(s)
MAO Ag
0
B.
C.
Ag+ (aq)
Zn2+ (aq)
Zn(s)
Ag(s)
w

Agt
D. Zn(s) Ag+(aq)

50A
1. The compounds CH3OH and CH2O contain carbon atoms with different oxidation numbers. Deduce the
oxidation numbers and state the kind of chemical change needed to make CH2O from CH3OH. [3]

2. A part of the reactivity series of metals, in order of decreasing reactivity, is shown below.
magnesium zinc iron lead copper silver
If a piece of copper metal were placed in separate solutions of silver nitrate and zinc nitrate
(i) determine which solution would undergo reaction. [1]

(ii) identify the type of chemical change taking place in the copper and write the half-equation for this
change. [2]

(iii) state, giving a reason, what visible change would take place in the solutions. [2]

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4IB IBDP – Chemistry (2020-2021) Revision – 2nd Term Test

Prepared by Dr. Lee Ka Ho (April 2021) 8 Printed at 2021/04/19 08:29:23