Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sri Chaitanya-Jr.Chaina Jee-Main Date: 07-09-19
Time: 3 Hr’s WTM-13 Max.Marks:360
IMPORTANT INSTRUCTIONS:
Mathematics : Question No. 1 to 30 Consists Four (4) marks. Negative (-1)
Physics : Question No. 31 to 60 Consists Four (4) marks. Negative (-1)
Chemistry : Question No. 61 to 90 Consists Four (4) marks. Negative (-1)
SYLLABUS:
Mathematics : Vector Algebra: upto linear combination of vectors, linearly dependent &
independent vectors
Physics : Gravitation: Introduction, Newton’s law of gravitation, gravitational field
due to point mass and distributed mass, Variation of g with different
factors.(EXCLUDE Gravitational Potential)
Chemistry : Chemical Equilibrium

MATHS
    
1. If ABCDEF is a regular hexagon and AD  EB  FC  k  AC  DC  , then k =

1) 1 2) 0 3) 3 4) 2
2. In triangle ABC, A  300 , H is the orthocenter and D is the midpoint of BC. Segment

AT
HD is produced to T such that HD  DT then the value of is
BC
1) 1 2) 2 3) 3 4) 4
3. If D , E , F are midpoints of the sides BC , CA, AB respectively of a triangle ABC and
 2  1 
O is any point then AD  BE  CF 
3 3
  1  
1) AC 2) 2AC 3) AC 4) 0
2
        
4. Position vectors a, b, c and d are coplanar and  sin   a   2sin 2   b   3sin 3  c  d  0 . Then

the least value of sin 2   sin2 2  sin2 3 is

1) 1/14 2) 14 3) 6 4) 1/ 6
Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
  
5. In a quadrilateral PQRS, PQ  a , QR  b , SP  a  b . If E is mid point of QR and F is
4
point on SE such that SF  SE then the points P, F, R
5
1) are collinear 2) form equilateral 
3) form isosceles  4) form right 
6. Let a, b, c be distinct nonnegative numbers. If vectors ai + aj + ck, i + k and ci + cj + bk
lie in a plane, then c is:
1) The AM of a and b 2) the GM of a and b
3) The HM of a and b 4) equal to zero
7. A (1, -1, -3), B (2, 1, -2) & C (-5, 2, -6) are the position vectors of the vertices of a
triangle ABC. The length of the bisector of its internal angle at A is:
10 3 10
1) 2) 3) 10 4) none
4 4
8. Four points A(+1, –1, 1) ; B(1, 3, 1) ; C(4, 3, 1) and D(4, – 1, 1) taken in order are the
vertices of
1) a parallelogram which is neither a rectangle nor a rhombus
2) rhombus
3) an isosceles trapezium
4) a cyclic quadrilateral.
  
9. If the vectors a  3iˆ  ˆj  2kˆ, b  iˆ  3 ˆj  4kˆ & c  4iˆ  2 ˆj  6kˆ constitute the sides of a 

ABC, then the length of the median bisecting the vector c is
1) 2 2) 14 3) 74 4) 6
10. If the three points with position vectors (1, a, b) ; (a, 2, b) and (a, b, 3) are collinear in
space, then the value of a + b is
1) 3 2) 4 3) 5 4) none
11. Four non-zero vectors will always be
1) linearly dependent 2)linearly independent
3)either a or b 4) none of these
Sec: Jr.Chaina Space for Rough Work Page 2
Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
12. Let ABC be a triangle, the position vectors of whose verticals are
respectively iˆ  2 ˆj  4 kˆ,  2iˆ  2 ˆj  kˆ , 2iˆ  4 ˆj  3kˆ . Then ABC is
1) Isosceles 2) equilateral 3) right angled 4)none of these
13. A point O is the centre of a circle circumscribed about a triangle ABC. Then
  
OA sin 2 A  OB sin 2B  OC sin 2C
  
1) (OA  OB  OC ) sin 2 A

2) 3 OG , where G is the centroid of triangle ABC

3) 0
4) none of these
  
14. 'P' is a point inside the triangle ABC , such that BC  PA  + CA  PB  + AB  PC  = O ,

then for the triangle ABC the point P is its :

1) incentre 2) circumcentre 3) centroid 4) orthocentre
 
15. If a and b are non zero, non collinear, and the linear combination
   
 2 x  y  a  4b  5a   x  2 y  b holds for all real x and y then x + y has the value equal to
1) 17 2) 3 3) 1 4) – 3
16. The set of values of m for which the vectors , iˆ  ˆj  mkˆ, iˆ  ˆj  (m  1)kˆ &(iˆ  ˆj  mkˆ) are
non-coplanar :
1) R 2) R - {1} 3) R - {-2} 4) 
17. If r  3 p  4q and 2 r  p  3q then

1) r , q have same direction and r  2 q

2) r , q have opposite direction and r  2 q

3) r , q have opposite direction and r  2 q

4) r , q have same direction and r  2 q

Sec: Jr.Chaina Space for Rough Work Page 3

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
     
18. Let a  iˆ  ˆj , b  ˆj  kˆ & c   a   b . If the vectors, iˆ  2 ˆj  kˆ , 3iˆ  2 ˆj  kˆ & c are coplanar

then is :


1) 1 2) 2 3) 3 4) - 3
19 ABCD is a parallelogram. If L and M be the middle points of BC and CD, respectively
      
express AL and AM in terms of AB and AD . If AL  AM  K . AC then the value of K is
1)1/2 2) 3/2 3) 2 4) 1

20. A vector a has components 2p & 1 with respect to a rectangular cartesian system. The
system is rotated through a certain angle about the origin in the counterclockwise sense.

If with respect to the new system, a has components p + 1 & 1 then ,
1
1) p = 0 2) p = 1 or p  
3
1
3) p = - 1 or p  4) p = 1 or p = - 1
3
    
21 In a trapezium the vector BC   AD . We will then find that p  AC  BD is collinear with
  
AD . If p   AD then which one is true.

1)     2 1)     1 3)     1 4)     1

22 If the points A  a  , B  b , C  c  satisfy the relation 3 a  8 b  5 c  0 then the points are

1) vertices of an equilateral triangle

2) collinear
3) vertices of a right angled triangle
4) vertices of an isosceles triangle
 
23 If the vectors a and b are linearly independent satisfying
 
  
3 tan   1 a  
3 sec   2 b  0 . Then the most general values of  are, where n is an

integer.   n  z 
 11  11
1) n  – 2) 2n  ± 3) n  ± 4) 2n  +
6 6 6 6
Sec: Jr.Chaina Space for Rough Work Page 4
Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
      
24 Given three non – zero, non – coplanar vectors a, b and c , r1  pa  qb  c and
       
r2  a  pb  qc if the vectors r1  2r2 and 2r1  r2 are collinear then (p, q) is

1) (0, 0) 2) (1, –1) 3) (–1, 1) 4) (1, 1)

25 If a + b + c = 0 and | a | = 3, | b | = 5 and | c | = 7, then the angle between a and b is
 2  5
1) 2) 3) 4)
6 3 3 3
26 ABCDEF is a regular hexagon where centre O is the origin. If the position vectors of A
      
and B are i  j  2k and 2i  j  k respectively then BC is equal to
        
1) i  j  2k 2) i  j  2k 3) 3i  3 j  4k 4)none of these
            
27 If a  i  j  k , b  4i  3 j  4k and c  i   j   k are linearly dependent vectors and c  3

then
1)   1,   1 2)   1,   1 3)   1,   1 4)   1,   1
 
28 Let p is the p.v. of the orthocenter & g is the p.v. of the centroid of the triangle ABC
 
where circumcentre is the origin. If p  Kg, then K =
1) 3 2) 5/2 3) 1/3 4) 2/3
  
29 P, Q have position vectors a & b relative to the origin 'O' & X, Y divide PQ internally

and externally respectively in the ratio 2 : 1. Vector = XY
3   4  
5   4  
1)
2

b a  2)
6
ab
b a
3

4) b  a
3
3)    
       
30 A,B,C and D have position vectors a, b, c and d respectively, such that a  b  2( d  c) .
Then
1) AB and CD bisect each other 2) BD and AC bisect each other
3) AB and CD trisect each other 4) BD and AC trisect each other

Sec: Jr.Chaina Space for Rough Work Page 5

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
PHYSICS
31. A uniform solid sphere of mass M and radius R. A spherical portion of the sphere center
at ‘O’ at distance R/2 from the centre C of the sphere and of radius R/2 is cut and
removed. The force of gravity due to the remaining mass of the sphere on unit mass kept
at a point P at a distance 2R from C along CO will be (in magnitude)

R
P
C

O

7GM 7GM 7GM 7GM

1) 2) 3) 4)
32R 2 36R 2 8R 2 16R 2
32. A sphere of mass M and radius R2 has a concentric cavity of radius R1 as shown in
figure. The force F exerted by the sphere on a particle of mass m located at a distance r
from the centre of sphere varies as (0  r  )

1) 2) 3) 4)
33. Two point masses m1 , m2  m1  m2  are fixed on the X-axis at (-a, 0) and (a,0)
respectively. The nature of the graph between resultant gravitational field intensity (ER),
and position distance on X-axis, (The best approximation graph)

Sec: Jr.Chaina Space for Rough Work Page 6

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
ER

Result
field
intensity

x-axis
m1 m2
 a,0  a,0

1)

ER

m1 m2
 a,0 x-axis
  a,0
 0,0

2)

ER

m1 m2
  a, 0  x-axis
 a, 0
 0, 0

3)

ER

m1   a , 0 m2 a, 0
 

4)

Sec: Jr.Chaina Space for Rough Work Page 7

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
34. A uniform circular ring of mass M and radius R. It’s centre at the origin and present in

the Y-Z plane. The nature of graph between gravitational field intensity and position

distance on X-axis is (The best approximation graph is)

R

2
R
 X
2

1)

R
2
R X

2

2)

R R
 
2 2
X

3)

4)

Sec: Jr.Chaina Space for Rough Work Page 8

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
35. Four particles of masses m, m, m 3m are fixed at the four corners A, B, C, D of a square
side length ‘a’ and it’s centre at ‘O’ as shown. Find the resultant Gravitational field
intensity at the point “O”
Am Bm

D a Cm
3m

4Gm
1) 2
along the direction OD 2) Zero
a

12Gm 2Gm
3) along the direction OB along the direction OB
4)
a2 a2
 
36. The position vectors of two particles of masses m1 , and m2 are r1 and r2 respectively.
Find position vector of the point on the line joining of the particles at which resultant
gravitational field intensity is zero
   
m1 r1  m2 r 2 m1 r 2  m2 r1
1) 2)
m1  m2 m1  m2
   
m1 r1  m2 r 2 m2 r1  m1 r 2
3) 4)
m1  m2 m1  m2

37. At what altitude will the acceleration due to gravity be 25% of that at the earth’s surface
(given radius of earth is R, altitude is height above the surface of the earth)
1) R/4 2) R 3) 3R/8 4) R/2
38. At what distance from the centre of the moon is the point at which the strength of the
resultant field of earth's and moon's gravitational field is equal to zero. The earth's mass
is 81 times that of moon and the distance between their centers is 60R where R is the
radius of the earth (Assume Earth and Moon are of uniform density)
1) 6R 2) 4R 3) 3R 4) 5R

Sec: Jr.Chaina Space for Rough Work Page 9

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
39. A man of mass m starts falling towards a planet of mass M and radius R. As he reaches
near to the surface, he realizes that he will pass through a small hole in the planet. As he
enters the hole, he sees that the planet is really made of two pieces a spherical shell of
2M M
negligible thickness of mass and a point mass at the centre. Change in the force
3 3
of gravity experienced by the man when he crosses the surface is
2 GMm 1 GMm 4 GMm
1) 2) 0 3) 4)
3 R2 3 R2 3 R2

40. An infinite number of point masses, each of one kg are fixed on the +ve X axis at 1m,
2m, 4m, 8m and so on from the origin. The magnitude of the gravitational field at origin
due to this distribution of point masses is:
4G 3G
1) 2G 2) 3) 4) G
3 4

41. Two concentric shells of uniform density of mass M1 and M2 are situated as shown in
the figure. The forces experienced by a particle of mass m when placed at positions A, B
and C respectively are (given OA = p, OB = q and OC = r)

M 1m (M + M )m (M 1 + M 2 )m (M + M )m Mm
1) zero, G 2
and G 1 2 2 2) G 2
, G 1 2 2 and G 12
q p p q r
M 1m (M + M )m (M 1 + M 2 )m Mm
3) G 2
,G 1 2 2 and zero 4) G 2
, G 12 and zero
q p p q

42. A uniform solid sphere of mass M and radius R then the gravitational field intensity at
distance R/2 from its centre
4GM GM GM
1) 2) 3) 4) Zero
R2 2R 2 R2

Sec: Jr.Chaina Space for Rough Work Page 10

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
43. A uniform thin rod of mass m and length R is placed normally on surface of earth as
shown. The mass of earth is M and its radius is R. Then the magnitude of gravitational
force exerted by earth on the rod is:

GMm GMm 4GMm GMm

1) 2) 3) 4)
4R2 2R 2 9R2 8R 2
44. The force of attraction on a particle of mass m placed at the centre of curvature of a
semicircular wire of length L and mass M is
GMm 4 GMm 2 GMm 2GMm
1) 2) 3) 4)
L2 L2 L2 L2
45. If the earth stops rotating about its axis, then the magnitude of acceleration due to
gravity
1) increases every where on the surface of earth
2) Will increase only at the poles
3) Will not change at the poles
4) decreases every where on the surface of earth
46. The figure shows a spherical shell of mass M. The point A is not at the centre of the
shell. If a particle of mass m is placed at A, then.

Sec: Jr.Chaina Space for Rough Work Page 11

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
1) It remains at rest
2) It experiences a net force towards the centre
3) It experiences a net force away from the centre
4) None of the above
47. If the mass of the sun were 10 times smaller and gravitational constant G were ten times
larger in magnitude then, incorrect statement is
1) Walking on the ground would become more difficult
2) The ‘g’ value on the earth will not change
3) Rain drops fall much faster
4) Aeroplanes will have to travel much faster.
48. Consider earth to be a homogeneous sphere. Scientist A goes deep down in mine and
scientist B goes high up in a balloon. The value of ‘g’ measured
1) by A decreasing and by B increasing
2) by A increasing and by B decreasing
3) by each decreasing at the same rate
4) by each decreasing at different rate.
49. The density of the core of a planet is 1 and that of outer shell is  2 . That value of ‘g’ on
1
the surface of the planet is same as at a depth ‘R’, then the ration of densities will be,
2

7 5 8 1
1) 2) 3) 4)
3 3 3 3

Sec: Jr.Chaina Space for Rough Work Page 12

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
50. A particle of mass m lies at a distance ‘r’ from centre of earth. The force of attraction
between the particle and earth as a function of distance is F (r )
1 1
1) F (r )  for r  R 2) F (r )  for r  R
r2 r
1
3) F (r )  r for r  R 4) F (r )  for r  R
r
51. At the surface of a certain planet, acceleration due to gravity is one-quarter of that on
earth. If a brass ball is transported to this planet, then which one of the following
statements is not correct?
1) The mass of the brass ball on this planet is a quarter of its mass as measured on earth
2) The weight of the brass ball on this planet is a quarter of the weight as measured on
earth
3) The brass ball has the same mass on the other planet as on earth
4) The brass ball has the same volume on the other planet as on earth.
52. The earth is an approximate sphere. If the interior contained matter which is not of the
same density everywhere, then on the surface of the earth, the acceleration due to gravity
1) will be directed towards the centre but not the same everywhere
2) will have the same value everywhere but not directed towards the centre
3) will be the same everywhere in magnitude directed towards the centre
4) cannot be zero at any point.
53. If the change in the value of ‘g’ at a height h above the surface of the earth is the same as
at a depth x below it, then (both x and h being much smaller than the radius of the earth)
h
1) x  h 2) x  2h 3) x  4) x  h 2
2

Sec: Jr.Chaina Space for Rough Work Page 13

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
54. Inside a uniform sphere of density ‘  ’ there is a cavity. The gravitational field at point
‘P’ is,

4 4
1) G  l along CC ' 2) G  l along C 'C
3 3
3) Zero 4) Non-uniform field inside the cavity.
55. What should be the angular speed of earth, so that body lying on equator may appear
weightlessness…………
( g  10m / sec 2 , R  6400 km )
1 1 1 1
1) rad / sec 2) rad / sec 3) rad / sec 4) rad / sec
600 700 800 900
56. The variation of acceleration due to gravity g with distance d from centre of the earth is
best represented by (R=earth’s radius)

1) 2)

3) 4)

Sec: Jr.Chaina Space for Rough Work Page 14

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
57. If the radius of the earth were to shrink by one per cent, its mass remaining the same, the
acceleration due to gravity on the earth’s surface would
1) decrease 2) remain unchanged
3) increase 4) be zero
58. The magnitude of the gravitational field at distance r1 and r2 from the centre of a uniform
sphere of radius sphere of radius R and mass M are F1 and F2 , respectively. Then

F1 r1 F1 r12
1)  if r1  R and r2  R 2)  if r1  R and r2  R
F2 r2 F2 r2 2

F1 r13 F1 r12
3)  if r1  R and r2  R 4)  if r1  R and r2  R
F2 r23 F2 r2 2

59. The tidal waves in the sea are primarily due to:
1) The gravitational effect of the moon on the earth
2) The gravitational effect of the sun on the earth
3) The gravitational effect of Venus on the earth
4) The atmospheric effect of the earth itself
60. Figure show a hemispherical shell having uniform mass density. The direction of
gravitational field intensity at point P will be along:

1) a 2) b 3) c 4) d

Sec: Jr.Chaina Space for Rough Work Page 15

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
CHEMISTRY
61. For an equilibrium, A  B  C  D , K c  60 ; Starting with 7 moles of A, 8 moles of B
and 14 moles of D, how may moles of C would be present at equilibrium
1) 5 2) 6 3) 4 4) 3
62. Consider the following equilibrium at 300K and 400K with their equilibrium constants
and choose the correct statement
Reactions 300K 400K
I A g   2B  g  K eq  10 K eq  5

II C g   Dg K eq  2 K eq  5

1) I is endothermic, II is exothermic
2) I is exothermic, II is endothermic
3) I and II both are endothermic
4) I & II both are exothermic
63. Calculate the temperature, at which the reaction given below is at equilibrium,
1
Ag 2O  s   2 Ag  s   O2  g  .Given, ∆H = 30.0 kJ/mol and S  0.06 kJK 1mol 1
2
0
1) 500 C 2) 2730 C 3) 3000 C 4) 227 0 C
64. One mole of N 2O4  g  at 300K is left in a closed container under one atm. It is heated to

600K when 20% by mass of N 2O4  g  decomposes to NO 2  g  . The resultant total

pressure is
1) 1.2 atm 2) 2.4 atm 3) 2.0 atm 4) 1.0 atm
65. In an aqueous solution of volume 500 ml, when the reaction of
2
2 Ag aq   Cu  s   Cu ( aq )  2 Ag  s  reached equilibrium the Cu 2  was x M. When 500 ml

of water is further added, at the equilibrium Cu 2  will be

1) 2x M 2) x M
3) Between x M and x /2 M 4) less than x/2 M

Sec: Jr.Chaina Space for Rough Work Page 16

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
0
66. The value of G for a reaction in aqueous phase having K c  1 , would be:
1) –RT 2) -1 3) 0 4) +RT
67. The K p / K c ratio will be highest in case of

1) H 2  g   I 2  g   2HI  g 

1
2) CO  g   O2  g   CO2  g 
2
3) 7H 2  g   2NO2  g   2NH 3  g   4H 2O  g 

4) 2 SO3 g   2SO2 g   O2 g 
68. Equilibrium constant depends on :
1) the actual quantities of reactants and products
2) the presence of a catalyst
3) temperature
4) the presence of inert material
69. When pressure is applied to the equilibrium system Ice  Water
Which of the following phenomena will take place?
1) Water will evaporate
2) more ice is formed
3) More water is formed
4) equilibrium is not disturbed
70. The reaction A  B  C  D is at equilibrium at 27 0C and the value of K = 10 The
value of G and G for the reaction are
1) 0 and -5.74 KJ
2) -5.73 KJ and + 5.73 KJ
3) -2.753 KJ and 0
4) both are zero

Sec: Jr.Chaina Space for Rough Work Page 17

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
71. The decomposition of the compound, represented as

NH 2COONH 4 s  2 NH 3  g   CO2  g 

K P  2.9  10 5 atm3.
If the reaction is started with 1 mole of the reactant, the total pressure at equilibrium
would be:
1) 1.94  10 2 atm 2) 5.82  10 2 atm
3) 7.66  10 2 atm 4) 38.8  10 2 atm
72. Two solids dissociate as follows
A s   B  g   C  g ; K P1  x atm 2

D s   C  g   E  g ; K P2  y atm 2

The total pressure when both the solids dissociate simultaneously is :-

1) x 2  y 2 atm 2)  x  y  atm 3) 2 x  y  atm 4) x  yatm

Kc
73. For the reaction CO  g   Cl2  g  COCl2  g  the value of is equal to
Kp

1
1) RT 2) RT 3) 4) 1 .0
RT

74. Consider the reaction, N 2  g   3H 2  g   2 NH 3  g 

The equilibrium constant of the above reaction is K P and total pressure is P. If pure
ammonia is left to dissociate, the partial pressure of ammonia at equilibrium is given by

 Assumethat P NH3  Ptotal at equilibrium 

3 1 3 1 1 1
2 2 2
2
3 K P 2
P
2
3 K P 2
P K P 2
P K P2
2
P
1) 2) 3) 4)
4 16 16 4

Sec: Jr.Chaina Space for Rough Work Page 18

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
75. 5.1 g NH 4SH is introduced in 3.0 L evacuated flask at 327°C. 30% of the solid NH 4SH
decomposed to NH3 and H2S as gases. The K p of the reaction at 327C is

( R  0.082 L atm mol 1K 1 , Molar mass of S  32 g mol 1 , molar mass

of N  14 g mol 1 )

1) 0.242  104 atm 2 2) 1 104 atm 2

3) 4.9  10 3 atm 2 4) 0.242 atm 2
76. For the chemical reaction X  Y the standard reaction Gibbs energy depends on
temperature T (in K) as :
3
 r G  in kJ mol 1   120  T
8
The major component of the reaction mixture at T is :
1) X if T = 315 K 2) X if T = 350 K
3) Y if T = 300 K 4) Y if T = 280 K

77. In a chemical reaction, A  2 B 
K
 2C  D , the initial concentration of B was 1.5 times
of the concentration of A, but the equilibrium concentrations of A and B were found to
be equal. The equilibrium constant(K) for the above chemical reaction is :
1
1) 16 2) 4 3) 1 4)
4
78. Consider the following reversible chemical reactions:
K1

A2 ( g )  B2 ( g )   2 AB ( g )......(1)
K2

6 AB( g )   3 A2 ( g )  3B2 ( g ).....(2)

The relation between K 1 and K2 is:

2) K2  K13 3) K1K 2  3 1
1) K 2  K13 4) K1K2 
3

Sec: Jr.Chaina Space for Rough Work Page 19

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
79. The values of K p / K c for the following reactions at 300 K are respectively:

(At 300 K, RT = 24.62 dm3 atm mol 1 )

N 2  g   O2  g 
 2 NO  g 



N 2O4  g 
 2 NO2  g 


N 2  g   3 H 2  g  2 NH 3  g 


1) 1, 24.62 dm3atm mol 1 , 606.0 dm6 atm 2 mol 2

2) 1, 24.62 dm3atm mol 1 ,1.65103 dm6 atm2 mol 2
3) 1, 4.1102 dm3atm1 mol , 606 dm 6atm 2 mol 2
4) 606.0 dm6 atm 2 mol 2 ,1.65103 dm6 atm2 mol 2
80. At temperature T, a compound AB2 (g) dissociates according to the reaction
2AB2  g   2AB  g   B2  g  With a degree of dissociation ' x ' which is small
compared with unity. Deduce the expression for x in terms of the equilibrium constant,
K p and total pressure P.
1 1
1
KP K 3 K  2
1) x  2) x   2 K P  3
3) x   P  4) x   P 
4P  P   4P   8P 
81. Consider following reactions in equilibrium with equilibrium concentration 0.01 M of
every species
(I) PCl5  g   PCl3  g   Cl2  g 

(II) 2HI  g   H 2  g   I 2  g 

(III) N 2  g   3H 2  g   2NH 3  g 
Extent of the reaction taking place is
1) I > II > III 2) III < I < II 3) II < III < I 4) I < II < III

Sec: Jr.Chaina Space for Rough Work Page 20

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
82. At constant pressure, addition of helium to the reaction;
N 2  g   3 H 2  g   2 NH 3  g  which of the following is correct
1) Reduces formation of NH 3
2) Favours formation of NH 3
3) Reduces the dissociation of NH 3
4) Does not effect the position of equilibrium
83. In which of the following ,The forward reaction is favored by use of high pressure?
1) H 2  g   I 2  g   2HI  g 

2) N 2  g   O 2  g   2NO  g 

3) 2NH3  g   N 2  g   3 H 2  g 

4) 2 SO2  g   O2  g   2SO3  g 

84. For the reaction A  g   3B  g   2C  g  at 27 0 C , 2 moles of A ,4 moles of B and 6 moles

of C are present in 2 litre vessel . If K c for the reaction is 1.2, the reaction will proceed
in
1) forward direction 2) backward direction
3) neither direction 4) none of these
85. When a bottle of perfume is opened in a room, perfume molecules mix with air and
spread entire the room. The incorrect statement about this phenomenon is
1) H  0 2) S   ve 3) G  ve 4) G  ve
86. In the reversible reaction P  s   2 R  g   3S  g  , if the concentration of S at
equilibrium becomes double, the equilibrium concentration of R becomes
1) Two times the original value
2) One half of the original value
3) 2 2 times the original value
1
4) Times the original value
2 2

Sec: Jr.Chaina Space for Rough Work Page 21

Sri Chaitanya IIT Academy 07-09-19_Sri Chaitanya-Jr.Chaina_Jee-Main_WTM-13_Q.P
87. Which of the factors will not enhance the amount of C2 H 4  g  present at equilibrium in
the following reaction for which the enthalpy change H is negative.
C 2 H 4  g   H 2  g   C2 H 6  g 
1) Decreasing temperature 2) Decreasing pressure
3) Removal of some H 2 (g) 4) adding some C2 H6 (g)
88. The reactions 2SO 2  O 2  2SO3 H  ve
N 2  3H 2  2 NH 3 H  ve
both reactions in forward direction favored by
1) Low temperature and high pressure
2) high temperature and high pressure
3) Low temperature and low pressure
4) high temperature and low pressure
89. K p for the reaction, CaCO3  s   CaO  s   CO2 is 1.16 atm at 8000 C. If 20 g

CaCO3 was kept on 10 L container and heated to 8000 C, what percentage of CaCO3
will remain unreacted at the equilibrium?
1) 34 % 2) 66 % 3) 50 % 4) 25 %
90. The equilibrium constant, K p for the reaction 2SO 2  g   O2  g   2SO3  g  is

4 atm 1 at 1000K. What would be the partial pressure of O 2 if at equilibrium the moles
of SO 2 and SO 3 is the same?
1) 0.25 atm 2) 0.75 atm 3)4 atm 4) 16 atm

Sec: Jr.Chaina Space for Rough Work Page 22