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Mole & Eqt. Concept (Assignment - 5)

The document contains 9 chemistry questions about equivalent weights and oxidation numbers. Each question is followed by a short solution explaining the concept and calculation used to determine the answer. The questions cover topics such as determining equivalent weights from chemical reactions and formulas, calculating oxidation numbers based on valences, and identifying possible chemical formulas given oxidation numbers of the elements.
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0% found this document useful (0 votes)
58 views19 pages

Mole & Eqt. Concept (Assignment - 5)

The document contains 9 chemistry questions about equivalent weights and oxidation numbers. Each question is followed by a short solution explaining the concept and calculation used to determine the answer. The questions cover topics such as determining equivalent weights from chemical reactions and formulas, calculating oxidation numbers based on valences, and identifying possible chemical formulas given oxidation numbers of the elements.
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Q1: In the reaction 2Na2S2O3 + I2 → Na2S4O6 + 2 NaI, the equivalent weight of Na2S2O3

(mol. wt. = M) is equal to


(A) M

(B) M/2

(C) M/3

(D) M/4
Q1: In the reaction 2Na2S2O3 + I2 → Na2S4O6 + 2 NaI, the equivalent weight of Na2S2O3
(mol. wt. = M) is equal to
(A) M

(B) M/2

(C) M/3

(D) M/4

Solution:

Q2: 74.5 g of a metallic chloride contain 35.5 g of chlorine. The equivalent weight of the
metal is
(A) 19.5

(B) 35.5

(C) 39.0

(D) 78.0
Q2: 74.5 g of a metallic chloride contain 35.5 g of chlorine. The equivalent weight of the
metal is
(A) 19.5

(B) 35.5

(C) 39.0

(D) 78.0

Solution:

wt. of metallic chloride


wt. of chlorine = 35.5
wt. of metal
Equivalent weight of metal

Q3: The equivalent weight of an element is 4. Its chloride has a V.D 59.25. Then the
valency of the element is
(A) 4

(B) 3

(C) 2

(D) 1
Q3: The equivalent weight of an element is 4. Its chloride has a V.D 59.25. Then the
valency of the element is
(A) 4

(B) 3

(C) 2

(D) 1

Solution:

Valency of the element =3.


Q4: The oxide of a metal has 32% oxygen. Its equivalent weight would be
(A) 34

(B) 32

(C) 17

(D) 8
Q4: The oxide of a metal has 32% oxygen. Its equivalent weight would be
(A) 34

(B) 32

(C) 17

(D) 8

Solution:

Let weight of metal oxide = 100gm


Weight of oxygen = 32gm
weight of metal
Equivalent weight of oxide .
Q5: 1.520 g of the hydroxide of a metal on ignition gave 0.995 gm of oxide. The
equivalent weight of metal is
(A) 1.520

(B) 0.995

(C) 19.00

(D) 9.00
Q5: 1.520 g of the hydroxide of a metal on ignition gave 0.995 gm of oxide. The
equivalent weight of metal is
(A) 1.520

(B) 0.995

(C) 19.00

(D) 9.00

Solution:

or

Q6: One gram of hydrogen is found to combine with 80g of bromine one gram of calcium
valency = 2 combines with 4g of bromine the equivalent weight of calcium is
(A) 10

(B) 20

(C) 40

(D) 80
Q6: One gram of hydrogen is found to combine with 80g of bromine one gram of calcium
valency = 2 combines with 4g of bromine the equivalent weight of calcium is
(A) 10

(B) 20

(C) 40

(D) 80

Solution:

One gram of hydrogen combines with 80gm of bromine.


So, equivalent weight of bromine = 80gm
4gm of bromine combines with 1gm of Ca
80gm of bromine combines with = .
Q7: Ca(OH)2 + H3PO4 → CaHPO4 + 2H2O the equivalent weight of H3PO4 in the above
reaction is
(A) 21

(B) 27

(C) 38

(D) 49
Q7: Ca(OH)2 + H3PO4 → CaHPO4 + 2H2O the equivalent weight of H3PO4 in the above
reaction is
(A) 21

(B) 27

(C) 38

(D) 49

Solution:

The equivalent weight of


mole wt of = 3 + 31 + 64 = 98

Q8: A compound contains atoms of three elements in A, B and C. If the oxidation number
of A is +2, B is +5 and that of C is –2, the possible formula of the compound is
(A) A3(BC4)2

(B) A3(B4C)2

(C) ABC2

(D) A2(BC3)2
Q8: A compound contains atoms of three elements in A, B and C. If the oxidation number
of A is +2, B is +5 and that of C is –2, the possible formula of the compound is
(A) A3(BC4)2

(B) A3(B4C)2

(C) ABC2

(D) A2(BC3)2

Solution:

.
Q9: In the following reaction, which choice has value twice that of the equivalent mass of
the oxidising agent
SO2 + H2O → 3S + H2O
(A) 64

(B) 32

(C) 16

(D) 48
Q9: In the following reaction, which choice has value twice that of the equivalent mass of
the oxidising agent
SO2 + H2O → 3S + H2O
(A) 64

(B) 32

(C) 16

(D) 48

Solution:

; Twice

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