Worksheet 2
Worksheet 2
Worksheet 2
• Choose correct answer from the given options. [Each carries 1 Mark] [78]
1. The derivatives that are not found in nature are .........
(A) Alkanes (B) Carbohydrates (C) Haloalkanes (D) Fats
2. The compounds obtained by the substitution of hydrogen by halogen in alkane series is ......
(A) Aryl halides (B) Alkyl halides (C) Carbon halides (D) All of these
Which of the following drug is used in treatment of typhoid fever ?
RK
3.
(A) Bromopheneramine (B) Chloramphenicol (C) Chloroquine (D) Iodoform
4. Which of the following is present in a hormone thyroxine ?
(A) Fluorine (B) Iodine (C) Bromine (D) Chlorine
5. Which of the following is a primary halide ?
A
(A) Neopentyl bromide (B) Isopropyl bromide
(C) 2-Bromobutane (D) 2-Bromo-2-methyl propane
6.
7.
(A) Covalent RM
The nature of bond of carbon of alkyl group and halogen in alkyl halide is .........
(B) Co-ordinate covalent (C) Metallic
Which of the following is a vicinal dihalides ?
(D) Ionic
Br
|
(A) CH 3 – CH – CH 2 (B) CH 2 – CH2 – CH 2 (C) CH 3 – C – CH 3 (D) All of these
| | |
TE
| |
Br Br Br Br Br
8. Which of the following is a benzylic halide ?
CH2 – Cl CH2 – Br CH3
WA
(A) H 3C – CH = C – CH2 – CH – CH 3
T
| |
Br CH 3
SE
(B) Br – CH2 – CH = CH – CH 2 – CH – CH 3
|
CH3
CH3
|
(C) CH3 – C CH
| |
CH3 Br
(D) Br CH 2 – CH – CH 3
|
CH 3
10. Which of the following is vinylic halide ?
Br
|
(A) H 3C – CH = CH – C – CH 3 (B) Best Br
Wish You - All The
|
CH3
Which of the following is vinylic halide ?
Br
|
(A) H 3C – CH = CH – C – CH 3 (B) Br
|
CH3
CH 3
|
(C) CH 3CH 2 – CH = C – CH 2 – CH 2 – C – CH 3 (D) Cl CH2 – CH = CH – CH2 – Br
| |
Br CH3
11. Which of the following is an aryl halide ?
(A) 1-Chloromethyl-3-(2,2-dimethylpropyl) benzene
(B) 1-Bromo-2-(1-methylpropyl) benzene
(C) 1-Bromo-3,3-dimethyl-1-phenylbutane
(D) 3-Bromo-3-methyl-1-phenylbutane
RK
12. Which of the following is the correct order of dipole moment ?
(A) CH2Cl2 > CHCl3 > CCl4 (B) CHCl3 > CH2Cl2 > CCl4
(C) CCl4 > CH2Cl2 > CCl4 (D) CHCl3 > CH2Cl2 > CCl4
13. Which of the following is the correct order of dipole moment ?
A
(A) CH3F > CH3Cl > CH3Br > CH3I (B) CH3Cl > CH3F > CH3Br > CH3I
(C) CH3F > CH3Cl > CH3I > CH3Br (D) CH3I > CH3Br > CH3F > CH3Cl
14.
(A)
X
(B)
X
RM
The correct structure of o-dihalobenzne is .......
(C)
X
X
(D)
X
X
X X
sp 3
TE
15. In which of the following compounds the halogen is not bonded to carbon ?
(A) Ethylidene dichloride (B) Chloroethyl benzene
(C) 3-chlorocyclohex-1-ene (D) 1-chlorocyclohex-1-ene
16. The isomerism not shown by alkyl halides is....
(A) Chain isomerism (B) Functional isomersim (C) Position isomerism (D) Optical isomerism
WA
CH 3 CH3 Cl
CH3
| | | CH2 – Cl
SE
RK
(A) H (B) CH3 (C) CH3 (D) Br
H Br H3C Br Br
H H H Br H3C
H
H
27. Sym-Tribromobenzene is ..........
Br Br
Br Br Br
A
Br Br
(A) (B) (C) (D)
Br Br Br Br Br
28.
29.
(A) I2 + HIO3 (B) KI + H3PO4
Consider the following reaction :
RM
To prepare alkyl iodides from alcohols, which of following reagent is used ?
(C) NaI + Acetone (D) KI + H2SO4
HCl
R – OH ¾¾¾
® R – Cl + H2O
The above reaction is not true if R is ..........
TE
CH3
|
(A) (B) CH3 – (C) CH3 – CH2 – (D) CH 3 – C –
|
CH 3
30. In the following reaction :
WA
HCl
R – OH ¾¾¾
® R – Cl + H2O the, ZnCl2 is not required if R is ..........
CH3
|
(A) CH3 – (B) CH 3 – C – (C) CH 3 – CH – (D) CH3 – CH2 –
| |
CH 3 C 2 H5
T
I
(B)
+ HI
(C) I
(D)
32. The correct order of reactivity of alcohols with haloacids is ........
(A) 1º > 2º > 3º (B) 1º > 3º > 2º (C) 3º > 2º > 1º (D) 2º > 3º > 1º
33. In the given reaction the total number of products obtained are .........
(A) One
(B) Two + HI
(C) Three
(D) Four Wish You - All The Best
(A) One
(B) Two + HI
(C) Three
(D) Four
34. High purity and more quantity of haloalkanes are obtained by.....
(A) reaction of alcohol with sodium halide and conc. H 2SO4.
(B) reaction of alcohol with phosphorus halide.
(C) reaction of alcohol with HCl in presence of ZnCl2.
(D) reaction of alcohols with SOCl2.
35. Which of the following is not prepared directly from benzene ?
(A) Chlorobenzene (B) Bromobenzene (C) Methylbenzene (D) Fluorobenzene
36. Which of the following reagent is not used to prepare alkyl halides from alcohols ?
(A) Br2 / CCl4 (B) Red P + Br2 (C) NaBr / H2SO4 (D) KI + H3PO4
RK
37. Which of the following have the maximum boiling point ?
CH3
CH 2 – Cl |
(A) (B) CH3 – CH2CH2CH2Cl (C) CH 3 – CH CH 2Cl (D) CH 3 – C – Cl
| |
CH 3 CH 3
The major product in the reaction is .......
A
38.
CH3
(A) H
H Br
CH3
Br RM
CH3 H3C CH3
H Br C=C + Br2
TE
(B) Br + Enantiomer H H
H
CH3
Br – CH 2 CH 2 – Br
(C)
C C
WA
H H
Br – CH2 H
(D) C C
H CH 2 – Br
39. The metallic fluoride used in a Swartz reaction is.......
(A) NaF (B) Cu2F2 (C) Hg2F2 (D) MgF2
T
41. Which of the following cannot be prepared from benzene diazonium halide ?
(A) Chlorobenzene (B) Fluorobenzene (C) Iodobenzene (D) None of these
Acetone
42. CH3CH2 – Br + NaI ¾¾¾¾¾
® X + NaBr
The (X) in above reaction is ...........
(A) Iodomethane (B) Iodoethane (C) Iodopropane (D) Iodobutane
43. Alkyl Fluorides are prepared by......
(A) Finkelstein reaction (B) Hunsdiecker reaction (C) Wurtz reaction (D) Swartz reaction
44. The reaction :
CCl
CH3COOAg + Br2 ¾¾¾®
4 CH3Br + CO2 +AgBr
is known as.....
(A) Finkelstin reaction (B) Hunsdiecker reaction
(C) Birnbaum-Simonini reaction (D) Balz-Schiemann reaction
Wish You - All The Best
is known as.....
(A) Finkelstin reaction (B) Hunsdiecker reaction
(C) Birnbaum-Simonini reaction (D) Balz-Schiemann reaction
45. The reaction :
+ – F
NH2 N2 Cl
NaNO 2 HBF4
0-5ºC D
is known as.....
(A) Sandmeyer’s reaction (B) Balz-schiemann reaction
(C) Birnbaum-Simonini reaction (D) Gatterman reaction
HBr
46. H3C – CH – CH = CH2 ¾¾¾ ®
|
CH3
Br
|
RK
(A) CH 3 – CH – CH – CH 3 (B) CH 3 – C – CH 2 – CH 3
| | |
CH3 Br CH3
Br
|
(C) CH 3 – CH – CH 2CH 2Br (D) CH 3 – C – CH 2CH 2 Br
| |
A
CH3 CH3
47. C2H5Br can be obtained in a laboratory by the action of ethyl alcohol with.....
48.
(A) KBr
Br2
CH3 – CH = CH2 ¾¾¾®
773K
CH 3 – CH – CH 3
(B) KBr + conc.
CH 3 – CH – CH2
(A) | (B) | |
Cl Cl Cl
(C) Cl – CH2 – CH = CH2 (D) CH3 – CH2 – CH2 – Cl
TE
SO Cl
CH3 – CH = CH2 ¾¾¾¾®
2 2
49. light (A). The (A) is....
|
Cl
(C) CH 3 – CH – CH2 (D) Cl – CH2 – CH2 – CH2 – Cl
| |
Cl Cl
NBS
50. In the reaction : (P) The (P) is ..........
light
Br
T
Br Br
(A) (B) (C) (D)
Br Br
SE
Br Br
51. In the reaction :
I
[X]
+ I2
CH3
CH3 CH3 Wish You - All The Best
(A) + (B)
(P)
hv
The product (P) is .........
CH3
CH3 CH3
(A) + (B)
Cl Cl Cl
CH2 – Cl CH2 – Cl
(C) (D)
Cl
53. The product (C) obtained in the following sequence of reaction is :
Br Br
(A)
NO2
NH2
RK
Cl
Br Br (i) HONO
Sn/HCl
(B) (A) (B)
(ii) Cu 2Cl2
Br Br
NO2 (i) HONO
Cl (C)
(ii) H3 PO2
A
(C) Br Br
(D)
Br
Cl
Br RM
Br
54. Which of the following will undergo SN2 most readily ?
TE
(A) CH 3 – C – CH 2 – I (B) CH3CH2I
||
O
(C) CH3 – O – CH2 – I (D) H2C = CH – CH2 – I
55. Arrange the following in decreasing order of their SN2 reactivity :
WA
CH2 – Cl
(i)
Cl Cl
CH2 – Cl
SE
(A) (iii) > (iv) > (ii) > (i) (B) (ii) > (i) > (iii) > (iv)
(C) (iii) > (ii) > (i) > (iv) (D) (iv) > (i) > (ii) > (iii)
57. Identify the correct reactivity order of SN1 reaction :
O NH
(i) (ii) (iii)
Cl Cl Cl
(A) (iii) > (ii) > (i) (B) (i) > (ii) > (iii) (C) (i) > (iii) > (ii) (D) (i) > (ii) > (iii)
58. HO CH2 – Br
+
Ag(aq)
(P)
CH3
H OC2H5
(A) H Br
CH3
CH3 CH3
C2H5O H H Br C2 H5 ONa +
RK
(B) H Br H Br D
CH3 CH3
CH 3 Br
(C) C=C
H CH 3
A
CH 3 CH3
(D) C=C
H Br
60.
ether. This reaction is called.....
(A) Wurtz Fittig reaction
RM
Toluene is obtained by reaction of mixture of chlorobenzene and methyl chloride with Na metal in dry
acetone
(A) CH3Cl + NaI ¾¾¾¾¾ ® CH3I + NaCl
WA
acetone
(B) CH3Br + Nal ¾¾¾¾¾ ® CH3I + NaBr
(C) CH3Br + AgF ¾¾® CH3F + AgBr
Dry ether CH · CH + 2 NaCl
(D) 2CH3Cl + 2Na ¾¾¾¾¾ ¾® 3 3
63. Which one is not a Sandmeyer reagent ?
T
(A) Cu2Cl2 + HCl (B) Cu2Br2 + HBr (C) Cu2(CN)2 + KCN (D) Cu2I2 + KI
64. How many numbers of possible stereoisomers are there of 2, 3, 4-trichloro pentanoic acid ?
SE
H H CH3 OH
RK
(A) When it comes in direct contact of skin, red rashes are formed.
(B) At high temperature on reaction with water forms phosgene.
(C) It is used for extinguishing the fire in substances like oil and petrol
(D) It is insoluble in water and gives fragrance
A
71. Which of the following compound is the most basic ?
NH2 NH2 NH2 NH2
(A)
Cl
(B)
OCH3
RM (C) (D)
NO2
72. Which of the following group of compounds are extinguisher, antiseptic, insecticide and anesthetic
respectively ?
(A) CHCl3, CHI3, DDT, CCl4 (B) DDT, CHCl3, CCl4, CHl3
TE
(C) CCl4, CHI3, DDT, CHCl3 (D) CCl4, CHI3, CHCl3, DDT
73. Polarimeter is used to determine of compounds.
(A) D and L configuration (B) d and l configuration
(C) R and S configuration (D) Both D and L as well as d & l configuration
WA
Roll Number : 0 1 2 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9
A B C D A B C D A B C D A B C D
Marks Identifier :
A B C D A B C D A B C D A B C D
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