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SAMPLE PAPER - 2008

Class - XII
SUBJECT - CHEMISTRY

Time allowed: 3 hrs M.Marks: 70

Lessons-P Block elements,D and F Block elements,Coordination Chemistry and

Haloalkanes and Haloarenes

General Instructions:
1. Answer all the questions.
2. Question number 1 to 8 carry 1 mark each. Answer them in one word or one
sentence each.
3. Question number 9to 18 carry 2 marks each. Answer them in 30 words each.
4. Question number 19 to 27 carry 3 marks each. Answer it in about 40 words each.
5. Question number 28 to 30 carry 5 marks each. Answer them in about 70 words
each.
6. Use of calculator not permitted. Use of log table permitted

1. Write the IUPAC name of the compound 1

H3C CH3

H
H Br

CH3
2. Distinguish chemically between chloro benzene and benzyl chloride. 1

3. Which of the following compound react more rapidly by SN1 mechanism? 1

Cl or
Cl

4. Give the structure of the compound Hexaamminecobalt(III)sulphate. 1

5. Which transition metal exhibit only one oxidation state? 1

6. Compare the stability of +2 oxidation state in aqueous solution of the elements whose ground state
Electronic configuration is 3d54s2, 3d34s2 and 3d64s2 1
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7. Give the resonance structures of the molecule N2O4 1

8. Write the equation of the reaction involved in the preparation of XeO3 from XeF6. 1

9 The spin only magnetic moment of the complex[MnBr4]2- is 5.9B.M. Predict the geometry of 2
the complex.(Atomic number of Mn=25)

10. Aqueous copper sulphate gives green precipitate with KF(aq) but bright green solution with
KCl(aq). Explain these results. 2

11. Outer electronic configuration of element X is 5f7 6d0 7s2. Determine the atomic number of
the element. What is the stable oxidation state of this element? Is it an oxidizing or reducing
agent? Why? 2

12. For M2+/M and M3+/M2+ systems E0 values of some metals are given below. 2
Cr2+/Cr - 0.9V Cr3+/Cr2+ - 0.4V
Mn2+/Mn - 1.2V Mn3+/Mn2+ + 1.5V
Fe2+/Fe - 0.4V Fe3+/Fe2+ + 0.8V
Use the data to comment upon:a) Stability of Fe3+ in acid solution when compared to Cr3+
and Mn3+ b) ease with which iron can be oxidized as compared to chromium and manganese.

13. Give two examples to show the anomalous behavior of oxygen. 2

14. Distinguish chemically between a) Chloromethane and Chlorobenzene b) Chloromethane and

Chlorophenyl methane 2

15. Give the structure of the inter halogen compounds a) BrF3 b) IF7 2

16 Draw the structures of geometrical and optical isomers of [CoCl2(en)2]+ 2

17. Give the products and balance the equations:
a) Xe +F2 573K 2
60-70 bar

b) XeF2 +PF5

18. Fluorine has lesser negative value of electron gain enthalpy than chlorine but fluorine is a
stronger oxidizing agent than chlorine. Why? 2
OR
How is ozone estimated quantitatively? Write the equation of the reactions involved. 2

19. Give the structures of a) XeOF4 b) H2S2O7 c) PCl5 3

20. An yellow colored solid A forms its hydride B. B has foul smell and extensively used in 3
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salt analysis. B on oxidation gives C. C further gets oxidized in the presence of a catalyst to
give D. C decolorize acidified potassium permanganate. Identify the compounds. Write the
reaction involved in the conversion of C to D and the reaction of C with acidified potassium
permanganate solution.
21. Account for the following: 3
a) XeF, XeF3 and XeF5 are not known.
b) PCl5 is ionic in solid state.
c) ICl3 is more reactive than I2 or Cl2

22 i) Give the products and balance the following ionic equations: 3

a) MnO4- +H+ + Fe2+
b) Cr2O72-+H++H2S
ii) Name the constituents of misch metal.

23. What is lanthanoid contraction? Mention two consequences of lanthanoid contraction. 3

24. A metal ion M3+ having d6 configuration combine with three Oxalate ligand to form a 3
complex compound. Assuming ∆0>P
i) Draw the diagram showing d orbital splitting during this complex formation.
ii) Write the electronic configuration of the valence electron of the metal Mn+ ion in terms
of t2g and eg.
iii) What type of hybridisation will Mn+ ion have?
iv) Draw the structure of isomers exhibited by this complex.
OR
Account for the following: 3
a) [Ti(H2O)6]3+ become colorless on heating.
b) Tetrahedral complex having two different unidentate ligand do not exhibit geometrical
isomerism.
c) [Fe(CN)6]4- and [Fe(H2O)6]2+ show different colors in aqueous solution..

25. Give one application each of coordination compounds in a) analytical chemistry b) biological
system c) medicine 3

26. Explain the mechanism of the reaction:

(CH3)3CBr +OH- (CH3)3COH+Br- 3

27. Carry out the following conversions: 3

a) Propene to 2,3-Dimethylbutane.
b) Chloro ethane to nitrito ethane.
c) 1-Bromopropane to 2-Bromopropane.

28. Primary alkyl halide A (C4H9Br) react with alcoholic KOH to give B.B reacts with HBr to 5
give C which is an isomer of A. When A is treated with sodium in dry ether it gives a
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compound D C8H18 which is different from the compound when n-butyl bromide is treated
with sodium. Give the structural formula of A and complete the reaction.
OR
i) Give one example each of a) Fittig reaction b) Dehydrohalogenation c) Finkelstein reaction.
ii) Account for the following: 5
a) Haloalkanes are polar in nature but not soluble in water.
b) para dichlorobenzene has higher melting point than its ortho and meta isomers.
29 Account for the following:
a) Among hydrogen halides, HF has the highest boiling point while HCl has the lowest 5
boiling point.
b) Xe forms compounds only with oxygen and fluorine.
c) SF6 is known but SH6 is not known.
d) All the five bonds in PCl5 are not equivalent.
e) PCl5 is more covalent than PCl3.
OR
Account for the following: 5
a) Sulphur has higher negative value of electron gain enthalpy than oxygen.
b) Noble gases have larger atomic size.
c) Flourine shows only -1 oxidation state while other halogens can exhibit positive oxidation
state.
d) Nitrogen can not form pentahalides.
e) Acidity of hydrogen halides is in the order HF<HCl<HBr<HI

30. Account for the following:

a) E0 Mn3+/Mn2+ has higher positive value than E0Fe3+/Fe2+ (Mn=25 Fe=26) 5
b) Transition metal forms complexes easily.
c) Ce4+ is stable and it is an oxidizing agent. (Ce=58)
d) Higher oxides of transition metals are acidic.
e) No regular variation of ionization enthalpy is noticed in transition metals.
OR
i) Write the equations of the reactions involved in the preparation of potassium dichromate
from chromite ore.
ii) Compare the chemistry of lanthanoids and actinoids with respect to
a) Oxidation state b) Magnetic behavior.
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