Current Electricity
Current Electricity
Current:
The rate of flow charge is called an electric current.
Therefore, i = q / t
For the case of time varying charge flow,the current also varies with time.In such
situations, current can be written as
i= dq / dt
It's unit is Ampere.
Current density:
It is defined as the current flowing through the conductor per unit cross-sectional
area .
i.e J = i/ A = vdenA / A = vden
Resistance:
Resistance is defined as the property of the conductor which opposes the flow of
electric current (charge). It is also defined as the ratio of the voltage applied to the electric
current flowing through it.
The following are the main laws of resistance:
(i) Resistance of a conductor is directly proportional to its length, provided temperature
and other physical conditions remain unchanged.
It means that R ∝ L….....................(1)
i.e., if the length increases, the resistance also increases and if length decreases, its
resistance also decreases.
(ii) Resistance of a conductor is inversely proportional to its area of cross section, other
conditions remaining the same.
If A is the area of cross section, then :
R α 1/A …......................(2)
(iii) R depends on the nature of the material of the conductor. It means, if we take equal
lengths of wires of copper, aluminum and iron and all of the same cross-sectional area,
their resistance are different from each other since they are of different materials.
Combining equations (1) and(2) , we get R α L /A
Or, R = ρ L /A …....(3) Where, ρ is resistivity of a
substance.
If L=1 unit and A=1 unit then, R=ρ.
Hence,Resistivity is defined as the resistance offered by the material per unit length for
unit cross-section. The SI unit of resistivity is Ohmmeter. Resistivity increases linearly with
temperature. The resistivity of conductors is low when compared to the resistivity of the
insulators. Therefore, it can be represented as:
Resistivity of conductors < Resistivity of alloys < Resistivity of insulators.
Resistivity is also defined as the ratio of electric field to the current density.
Therefore, ρ= E/J
Conductivity(σ) :
It is defined as the reciprocal of resistivity that is σ=1/ρ.
From equation (3) ρ=RA / L
Therefore, σ=L / RA
Ohm's law:
Ohm’s law states the relationship between electric current and potential difference. The
current that flows through most conductors is directly proportional to the voltage applied
to it. Georg Simon Ohm, a German physicist was the first to verify Ohm’s law
experimentally.
Statement: Ohm’s law states that current passing through a conductor is directly
proportional to the voltage across a conductor, provided all physical conditions and
temperature remain constant.
That is, V ∝ I
V = IR where R is resistance of the conductor
V/ I = R
In the equation, the constant of proportionality, R is Resistance and has units of ohms, with
symbol Ω.
Here a straight line passing through origin is obtained. This graph shows V is
proportions to I which is Ohm’s Law. Hence Verified.
Microscopically ohm's law can be expressed in terms of current density (J) and
electric field (E):
We know, I= V/R
=(E A L)/ρL (E = V/L and R= ρL / A)
Or, I/ A = E/ρ
Or, J = E/ρ = σE (J =I/A and σ = 1/ρ )
Above relation is also known as modified ohm's law and it states that the current
density of a material is proportional to the applied electric field.
Let an electron of mass m and charge e is placed in an electric field E ,The electric force
experienced by electron is F=eE.
Also from Newton's law, F= ma.
Hence, ma = eE
a = eE / m
The average drift speed of electron is, vd=aτ, where τ is average time between collision called
mean free time or relaxation time.
Therefore, v d = eEτ / m........................(1)
The electron mobility is defined as the drift speed per unit applied electric field.
Electron mobility, (μ) = v d / E = eτ / m........................(2)
Since current density, J= vden
= (eEτ / m)ne = (ne2τ / m).E ......................(3)
If vavg is the average thermal velocity of the electrons, which is combination of the thermal
velocity vrms and the drift velocity vd, we may write
τ = L /vavg , L= mean free path(The average distance travelled by the
free electron between two consecutive collisions is called mean free path)
Since, vd<<vrms in most cases, hence contribution of vd can be neglected.
Therefore, τ = L / v rms
Hence, ρ = (mv rms)/ne2L …...................................(8)
The behavior of free electron is similar to the gas molecules and thus,the free electron are
generally called free electron gas. Thus ,we have
(1/2)mv2avg=(3/2)kT...........(9)
Where k is Boltzmann constant ant Tis the absolute temperature of the metallic conductor.
From above, we have ρ = 3kT/ne2Lv...........................(9)
It shows that resistivity of a material of conductor is proportional to the absolute temperature
being other quantities constant.
Semiconductor:
A semiconductor is a material whose electrical conductivity lies between those of
conductors and insulators at the room temperature. That is they are neither
conductor nor insulator. They are tetravalent elements because they have four
electrons in their outermost orbit (They have four valence electrons). Silicon and
germanium are example of semiconductors. They lie in group IV of periodic table. In
semiconductor there is narrow(about 1 eV or less) energy gap. At absolute zero
valence band is completely full and conduction band is completely empty. Thus s/c
are perfectly insulator at zero Kelvin(K). But at room temperature , some of the
valence electrons acquire enough thermal energy and jump to the conduction band.
They leave behind as equal number of empty states(holes) in the valence band. The
electrons in the conduction band and holes valence band contribute the electrical
conductivity. Thus semiconductor behaves as conductor at room temp. At room
temperature valence band and conduction band are partially filled.
The electrons reaching at the conduction band move randomly. The holes created in the
crystal also free to move anywhere. This behaviour of the semiconductor shows that they
have a negative temperature coefficient of resistance.
This means that with the increase in temperature, the resistivity of the material decreases and
the conductivity increases.
Extrinsic Semiconductor
A semiconductor to which an impurity at a controlled rate is added to make it conductive is
known as an extrinsic semiconductor.
An intrinsic semiconductor is capable to conduct a little current even at room temperature,
but it is not useful for the preparation of various electronic devices. Thus, to make it
conducive a small amount of suitable impurity is added to the material.
Doping
The process by which an impurity is added to a semiconductor is known as Doping. The
amount and type of impurity which is to be added to the material have to be closely controlled
during the preparation of extrinsic semiconductor.
Generally, one impurity atom is added to 108 atoms of a semiconductor.
The purpose of adding impurity in the semiconductor crystal is to increase the number of free
electrons or holes to make it conductive. If a Pentavalent impurity, having five valence
electrons is added to a pure semiconductor a large number of free electrons will exist.
If a trivalent impurity having three valence electrons is added, a large number of holes will
exist in the semiconductor.
Depending upon the type of impurity added the extrinsic semiconductor may be classified
as n type semiconductor and p type semiconductor.
N Type Semiconductor
When a small amount of Pentavalent impurity is added to a pure semiconductor providing a
large number of free electrons in it, the extrinsic semiconductor thus formed is known as n-
Type Semiconductor. The conduction in the n-type semiconductor is because of the free
electrons denoted by the pentavalent impurity atoms.
These electrons are the excess free electrons with regards to the number of free electrons
required to fill the covalent bonds in the semiconductors.
The addition of Pentavalent impurities such as arsenic and antimony provides a large
number of free electrons in the semiconductor crystal. Such impurities which produce n-type
semiconductors are known as Donor Impurities.
They are called a donor impurity because each atom of them donates one free electron
crystal.
The Energy level diagram of the n-type semiconductor is shown in the figure below:
A large number of free electrons are available in the conduction band because of the addition
of the Pentavalent impurity. These electrons are free electrons which did not fit in the
covalent bonds of the crystal. However, a minute quantity of free electrons is available in the
conduction band forming hole-electron pairs.
P Type Semiconductor
The extrinsic p-Type Semiconductor is formed when a trivalent impurity is added to a pure semiconductor
in a small amount, and as a result, a large number of holes are created in it. A large number of holes are
provided in the semiconductor material by the addition of trivalent impurities like Gallium and Indium.
Such types of impurities which produce p-type semiconductor are known as an Acceptor
Impurities because each atom of them create one hole which can accept one electron.
A trivalent impurity like gallium, having three valence electrons is added to germanium crystal in a
small amount. Each atom of the impurity fits in the germanium crystal in such a way that its three
valence electrons form covalent bonds with the three surrounding germanium atoms as shown in the
figure below:
The energy band diagram of a p-type Semiconductor is shown below:
In the fourth covalent bonds, only the germanium atom contributes one valence electron,
while gallium atom has no valence bonds.Hence, the fourth covalent bond is incomplete,
having one electron short. This missing electron is known as a Hole. Thus, each gallium
atom provides one hole in the germanium crystal.As an extremely small amount of
Gallium impurity has a large number of atoms, therefore, it provides millions of holes in the
semiconductor.
A large number of holes or vacant space in the covalent bond is created in the crystal with
the addition of the trivalent impurity. A small or minute quantity of free electrons is also
available in the conduction band.They are produced when thermal energy at room
temperature is imparted to the germanium crystal-forming electron-hole pairs. But the holes
are more in number as compared to the electrons in the conduction band. It is because of
the predominance of holes over electrons that the material is called as a p-type
semiconductor.The word “p” stands for positive material.
Some semiconductors are doped with both N and P type impurities which are called
Compensated semiconductors. P and N types semiconductors are basic for fabrication of
Semiconductor devices. P-N junction diode, N-P-N, P-N-P transistors, light emitting diode
(LED), zener diode , photo voltaic cell or solar cell, LASER diode are few examples.
The mobility of semiconductor:
At room temperature, a semiconductor consist of two types of charge carrier, free electrons in the
conduction band and holes in the valence band. When an external electric field is applied to a
semiconductor, there is flow of electrons in the conduction band and holes in the valence band. Thus
both charge carrier contribute to the electric current. The drift velocities of two types of charge carrier
in the electric field are different because of their differing effective masses. Let n and p be the number
of free electrons and holes per unit volume(electron and hole densities) of the semiconductor. Let v e
and vp be the drift velocities of electrons and holes of the given semiconductor at a temperature T
then total current density is given by
J= Je + Jp (J = nev)
= neve + pevp......................(1)
Mobility(μ) can be defined as the drift velocity(vd) per unit external electric field(E).
μ= vd / E
vd = μ x E.............................(2)
Therefore equation (1) becomes J = neμeE + peμpE
= eE(nμe + pμp)
or, J/E = e(nμe + pμp).................(3)
But J/E= σ, the conductivity of material of semiconductor.
Therefore, equation (3) becomes σ = e(nμe + pμp).................(4)
This gives the conductivity of the semicondutor
Also, ρ = 1/σ
ρ = 1 / e(nμe + pμp)....................(5)
This gives the resistivity of the semiconductor
In intrinsic semiconductor, n = p then equation (4) becomes
σ=1 / ρ = en (μe + μp) …..................(6)
Superconductors:
Those material whose resistance(resistivity) goes on decreasing and equals to zero
below certain temperature are called superconductors. This phenomenon in which the
electrical resistivity suddenly drops to zero when the material is cooled to a sufficiently low
temperature is known as superconductivity. And the material that exhibits these properties
are called superconducting materials (superconductors).The current which flows during
superconductivity is famously known as a super current Simply because there is no loss of
energy in any form. The specific temperature at which resistance of the
conductors((materials) become zero is called critical temperature (Tc). At this temperature the
materials undergoes a phase transition from the normal state of a material to the
superconducting state. Superconductivity has been observed in many metals,alloys and
compounds. It is surprising that those metals which are the best conductors like silver,gold
and copper are not super conductors but some chemical compounds which are
semiconductors at ordinary temperatures becomes super conductor at low temperatures.
T
Tc = 4.2K (For mercury)
The electrical resistance of metal and alloys decreases with the decrease of
temperature. The thermal vibration of atoms decreases at lower temperature so due to
decrease in randomness of electrons resistance decreases. The electrical resistance of the
normal conductors like copper,iron,silver etc. decreases with a decrease in temperature and
possesses some finite value even at absolute zero tmperature.There are certain materials for
which resistance decreases with a decrese in temperature and the resistance drops abruptly
to zero when the temperature reaches a certain value.This phenomenon was first observed
by Dutch physicist H.K Onnes. He found that the electrical resistance of mercury drops to
zero at 4.18K. He found that Below 4.18K, the resistance of mercury remained effectively
zero an mercury has passed into a new state is called superconducting state. This
temperature is called critical temperature. Critical temperature is 7.2K for lead, 0.85K for
zinc etc.
scientists are working to obtain high temperature superconductors. Now 164K critical
temperature has obtained ina compound HgBa2Ca2Cu3O (HBCCO) at high pressure. The
highest Tc that has been obtained to date is in a hydrogen based superconductor (hydrogen
sulfide) is 203 K in 2015 at 150 Gpa pressure.
Critical magnetic field:
λL=(ε0mc2/nq2) ½
Where q is charge ,m is the mass, and n is the number density of electrons
Coherence length ξ is another characteristic length in a superconductor, which depends on
the Fermi velocity of material and the band gap associated with the condensation to the
superconducting stage. ξ is a measure of the minimum distance over which number density of
superconducting electron cannot change drastically in a spatially varying magnetic field.
Mathematically,
ξ =2ħvf / πEg
Where ħ(=h/2π) is reduced Planck constant, vf is Fermi-velocity, Eg is the energy gap needed
to destroy the superconductor. It is the intrinsic coherence length of pure superconductor
where coherence length of impure and and alloys is less than of the pure superconductor.
Types of superconductors
Based on the nature of the transition of superconducting state to the normal state under the
application of magnetic field, there are two types of superconductor. They are:
1) Type-I superconductor
2) Type-II superconductor
Type-I superconductor: The superconductor in which the Meissner effect is complete up to
critical field Hc is called type-I superconductor. The magnetic behavior of a typical type-I
superconductor is shown in the figure 1, where magnetization drops suddenly to zero and
there is a direct transition to superconducting state to normal state. These material give
away their superconductivity at lower field strength so these are referred to as soft
superconductors. Pure specimens of various metals exhibits this type of behavior. Surface
energy of a material is a result of magnetic field which is positive for type-I superconductor.
The indium show type-I nature of superconductor, but when some amount of indium is
doped to the lead, the behavior will no longer type-I.
Type-II superconductor:
The superconductor which doesn't exhibit the complete Meissner effect and possess a
mixed state is called type-II superconductor. A plot between the intensity and
magnetization(M) and applied magnetic field(H) for a compound or alloy(impure)
semiconductor is shown in figure 2 where magnetization drops gradually to zero and there is
a gradual transition from superconducting to a normal state. This type of semiconductor is
known as type-II superconductor or hard superconductor.
Decreasing of magnetization starts from the lower magnetic field Hc1 and vanishes
completely at upper higher magnetic field Hc2. The region between the lower and upper
magnetic field is known as vortex state. These superconductors are also called hard or
impure superconductor.
Hard superconductors (Type II) with large magnetic hysteresis are used in making
electromagnets for producing high steady magnetic fields.
● Type-I superconductors strictly follow the Meissner effect. On the other hand, Type II
superconductors do not follow the Meissner effect.
● Type-I superconductors have only one critical field i.e Hc. On the other hand, Type II
superconductors have two critical fields i.e Hc1 and Hc2.
● Last but not least one, Type-I superconductors act as a good conductor at room
temperature. On the other hand, Type II superconductors are not particularly good
conductors at room temperature.
Application of superconductor
● Superconducting magnets are used for accelerating the particles in the Large Hadron Collider.
● SQUIDs (superconducting quantum interference devices) are being used in the production of highly
sensitive magnetometers. They are generally used for the detection of land mines.
● Superconducting magnets are also used in Magnetic Resonance Imaging (MRI) machines.
● As we know due to the electrical resistance, there is a power loss while power transmission. So
nowadays, superconducting cables are used in place of ordinary cable lines to avoid power loss.
● Superconductors are also being used for the development of high-intensity Electro Magnetic
Impulse (EMP). They are used to paralyze all the electronic equipment within the range.
(i) Superconductors form the basis of energy saving power systems, namely the
superconducting generators, which are smaller in size and weight, in comparison with
conventional generators.
(ii) Superconducting magnets have been used to levitate trains above its rails. They can be driven
at high speed with minimal expenditure of energy.
(iii) Superconducting magnetic propulsion systems may be used to launch satellites into orbits
directly from the earth without the use of rockets.
(iv) High efficiency ore-separating machines may be built using superconducting magnets which
can be used to separate tumor cells from healthy cells by high gradient magnetic separation
method.
(v) Since the current in a superconducting wire can flow without any change in magnitude, it can
be used for transmission lines.