Safety data sheet

Issue Date 23-Jun-2021 Revision Date 22-Jun-2021 Version 2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product Name Trimethylolpropane Monoallyl Ether

Chemical Name CAS No EC No REACH Registration Number

2-Allyloxymethyl-2-ethylpropanediol 682-11-1 211-662-7 01-2119956667-20-0000

Pure substance/mixture Substance

1.2. Relevant identified uses of the substance or mixture and uses advised against
Industrial Manufacture of substances. Formulation and (re)packing of substances and mixtures.
Distribution and storage. Industrial manufacturing of oligomers and of polymers including
resins.

Professional Laboratory chemicals.

Uses advised against Formation of acrolein (very toxic) can occur in oxidative drying systems catalyzed by
metal salts, for example alkyd paints.

1.3. Details of the supplier of the safety data sheet

Manufacturer

Perstorp Specialty Chemicals AB

SE-284 80 Perstorp, Sweden
Tel. +46 435 380 00
www.perstorp.com

E-mail address [email protected]

1.4. Emergency telephone number

Europe (+)1 760 476 3961 (contract no: 334101)

United Kingdom (+)44 8 08 189 0979 (contract no: 334101)

SECTION 2: Hazards identification

Hazards description
In contact with air/oxygen the product will slowly form peroxides.

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
This substance is not classified as dangerous according to regulation (EC) 1272/2008 [CLP]

2.2. Label elements

This substance is not classified as dangerous according to regulation (EC) 1272/2008 [CLP]

Symbols/Pictograms
Not applicable

Signal word
None

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Hazard statements
Not applicable

Precautionary Statements
Not applicable

2.3. Other hazards

This substance does not meet the criteria for classification as PBT or vPvB

SECTION 3: Composition/information on ingredients

3.1 Substances
Chemical Name EC No CAS No REACH Registration Weight-% Classification according to
Number Regulation (EC) No. 1272/2008
[CLP]
2-Allyloxymethyl-2-ethylpro 211-662-7 682-11-1 01-2119956667-20-0000 90-100 Not classified
panediol

Full text of H- and EUH-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation First aid measures not required, but get fresh air for personal comfort.

Skin contact First aid measures not required, but wash exposed skin with soap and water for hygienic
reasons.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. Use lukewarm water if
possible.

Ingestion Rinse mouth then drink plenty of water. If a large quantity has been ingested or if you
feel unwell, get medical advice/attention.

4.2. Most important symptoms and effects, both acute and delayed
None known.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

High volume water jet.

5.2. Special hazards arising from the substance or mixture

Thermal decomposition can lead to release of irritating and toxic gases and vapours.

Hazardous combustion products

Carbon monoxide (CO), Carbon dioxide (CO2), May emit small amounts of toxic fumes under fire conditions: Allyl alcohol and
acrolein.

5.3. Advice for firefighters

Wear self-contained breathing apparatus and protective suit.

Additional information
Cool containers with flooding quantities of water until well after fire is out.

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SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear safety glasses, gloves, protective clothing and rubber boots for hygienic reasons.

6.2. Environmental precautions

Prevent further leakage or spillage if safe to do so. Minimize the area spreading and cover the drains. Do not allow to enter
sewers/ surface or ground water. See Section 12 for additional ecological information.

6.3. Methods and material for containment and cleaning up

Methods for containment

Small spill Absorb with earth, sand or other non-combustible material and transfer to containers for
later disposal. Take up mechanically, placing in appropriate containers for disposal.
Large spill Pump up the product into a spare container suitably labelled.

Methods for cleaning up

Clean contaminated surface thoroughly. Use: Water (with cleaning agent).

6.4. Reference to other sections

See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Avoid contact with skin, eyes or clothing. Use personal protection recommended in Section 8.

General Hygiene Considerations

Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Keep/store only in original container. Keep tightly closed in a dry and cool place. Hygroscopic. Keep away from heat. Protect
from direct sunlight. In contact with air/oxygen the product will slowly form peroxides. Can form peroxides when stored in
opened, unsealed containers. For additional information regarding peroxide formation, see Perstorp Technical information,
Leaflets TI 1120 and TI 1110.

7.3. Specific end use(s)

This information is supplied in the present Safety Data Sheet.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Exposure Limits
Keep personal exposure levels below Derived No Effect Level (DNEL) and national exposure limit values (if existing).

Derived No Effect Level (DNEL) - worker

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Type Exposure route DNEL Remarks
Chronic effects, systemic Inhalation 7 mg/m3
Chronic effects, systemic Dermal 2 mg/kg bw/d
Acute effects, systemic Inhalation, Dermal - No hazard identified
Acute effects, local: Chronic effects, Inhalation, Dermal - No hazard identified
local
Local health effects Eye - No hazard identified

Derived No Effect Level (DNEL) - Consumer

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Type Exposure route DNEL Remarks

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Chronic effects, systemic Inhalation 1.7 mg/m3

Chronic effects, systemic Dermal 1 mg/kg bw/d
Chronic effects, systemic Oral 1 mg/kg bw/d
Acute effects, systemic Inhalation, Dermal - No hazard identified
Acute effects, local; Chronic effects, Inhalation, Dermal - No hazard identified
local
Local health effects Eye - No hazard identified

Predicted No Effect Concentration

(PNEC)
2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Environmental compartment Predicted No Effect Concentration Remarks
(PNEC)
Freshwater 0.61 mg/l
Marine water 0.061 mg/l
Intermittent 6.1 mg/l
Impact on Sewage Treatment 31.6 mg/l

8.2. Exposure controls

Appropriate engineering controls
No specific measures identified.

Individual protection measures, such as personal protective equipment

Eye/face protection If handled where risk of splashes may occur, use safety goggles.
Hand Protection Recommendation(s): Wear protective gloves. Butyl rubber, Chloroprene rubber, CR,
Nitrile rubber, NBR. Ensure that the breakthrough time of the glove material is not
exceeded. Refer to glove supplier for information on breakthrough time for specific
gloves.

Skin and body protection Normal work clothes for the chemical industry (long legs and sleeves).
Respiratory protection None under normal use conditions.

Environmental exposure controls

Local authorities should be advised if significant spillages cannot be contained. Do not allow into any sewer, on the ground or
into any body of water.

Additional information
Exposure scenarios are not available since not classified as dangerous for health or environment according to CLP Regulation
(EC) No 1272/2008.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
liquid
viscous
colourless
Odour Slight
Odour threshold No data available

Property Value Remarks • Method

pH 6.9 solution (10 %)
Melting point / freezing point < -20 °C / -4 °F
Boiling point / boiling range 272 °C / 522 °F ASTM E 537-02
Flash point 140 °C / 284 °F ASTM D 7094-04
Evaporation rate No information available
Flammability (solid, gas) Not applicable
Explosive limits
Upper explosive limits No information available
Lower explosive limits No information available
Vapour pressure 0.035 Pa Calculation method SPARC, @25°C

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Vapour density No information available

Relative density 1.01 OECD Test No. 109: Density of Liquids and Solids
Water solubility 110 g/L OECD Test No. 105: Water Solubility
Solubility(ies) soluble in: Alcohols, Ketone.
Partition coefficient 1.4 OECD Test No. 117: Partition Coefficient
(n-octanol/water), HPLC Method
Autoignition temperature 285 °C / 545 °F @101.3 kPa, Regulation (EC) No. 440/2008,
Annex, A.15
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity 173 mPa s @ 20 °C OECD Test No. 114: Viscosity of Liquids
Explosive properties Not explosive. May form explosive
peroxides.
Oxidising properties Not oxidising.
Density No information available
Bulk density No information available

9.2. Other information

Hygroscopic.

SECTION 10: Stability and reactivity

10.1. Reactivity
There exists no specific test data for this product. For further information, see the subsequent subsections of this chapter.

10.2. Chemical stability

In contact with air/oxygen the product will slowly form peroxides.

10.3. Possibility of hazardous reactions

In contact with air/oxygen the product will slowly form peroxides. Formation of acrolein (very toxic) can occur in oxidative drying
systems catalyzed by metal salts, for example alkyd paints.

10.4. Conditions to avoid

None under normal use conditions.

10.5. Incompatible materials

Oxidizing substances including air (oxygen).

10.6. Hazardous decomposition products

Thermal decomposition can lead to release of irritating and toxic gases and vapours: Allyl alcohol and acrolein, Carbon
monoxide (CO), Carbon dioxide (CO2).

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure

Inhalation. Dermal.

Symptoms related to the physical, chemical and toxicological characteristics

Most important symptoms and effects, both acute and delayed
None known.

Numerical measures of toxicity

Acute toxicity
May be harmful if swallowed

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Species Exposure route Effective dose Remarks
no guideline Rat Oral 4930 mg/kg LD50 (lethal

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dose)
no guideline rabbit Dermal >15800 mg/kg LD50 (lethal
dose)

Skin corrosion/irritation
Non-irritating to the skin.

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Species Exposure route Results:
OECD Test No. 404: Acute Dermal rabbit Dermal Non-irritating to the skin
Irritation/Corrosion

Serious eye damage/eye irritation

Slightly irritating but not relevant for classification.

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Species Exposure route Results:
OECD Test No. 405: Acute Eye rabbit Eye Slightly irritating but not
Irritation/Corrosion relevant for classification

Respiratory or skin sensitisation

No sensitising effects known.

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Species Exposure route Results:
OECD Test No. 406: Skin Guinea pig Skin Not a skin sensitiser
Sensitisation

Germ cell mutagenicity

Not mutagenic.

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Species Results:
OECD Test No. 471: Bacterial Reverse in vitro Negative
Mutation Test
OECD Test No. 476: In vitro Mammalian Cell in vitro Positive; read-across from supporting
Gene Mutation Test substance (structural analogue)
OECD Test No. 474: Mammalian Erythrocyte Mouse Negative
Micronucleus Test

Carcinogenicity
Not considered to be carcinogen.

Reproductive toxicity
Is not considered hazardous to the reproduction.

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Species Exposure route Effective dose Remarks
OECD Test No. 414: Rat Oral 800 mg/kg bw/d NOEL (No
Pre-natal Development observed effect level)
Toxicity Study No embryotoxic or
teratogenic effects
have been observed.
read-across from
supporting substance
(structural analogue)

STOT - single exposure No information available

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STOT - repeated exposure

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Species Exposure route Effective dose Remarks
OECD Test No. 408: Rat Oral 200 mg/kg bw/d NOAEL;
Repeated Dose 90-Day Oral read-across from
Toxicity Study in Rodents supporting substance
(structural analogue)
OECD Test No. 407: Rat Oral 40 mg/kg bw/d NOAEL
Repeated Dose 28-day Oral
Toxicity Study in Rodents

Aspiration hazard
No hazard identified.

SECTION 12: Ecological information

12.1. Toxicity
Low toxicity to aquatic organisms.

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Species Exposure route Effective dose Exposure time Remarks
OECD Test No. 203: Fish, Brachydanio rerio Freshwater 1200 96h mg/l; LC50 (lethal
Acute Toxicity Test concentration)
OECD Test No. 202: Daphnia magna Freshwater 1530 48h mg/l EC50
Daphnia sp. Acute (effective
Immobilization Test concentration)
OECD Test No. 201: Pseudokirchneriell Freshwater 610 72h mg/l; EC50
Freshwater Algae and a subcapitata (effective
Cyanobacteria, Growth concentration)
Inhibition Test
OECD Test No. 201: Pseudokirchneriell Freshwater 125 72h mg/l NOEC
Freshwater Algae and a subcapitata
Cyanobacteria, Growth
Inhibition Test
OECD Test No. 209: Microorganisms in Freshwater >1000 3h mg/l EC50
Activated Sludge, sewage treatment (effective
Respiration Inhibition Test concentration);
(Carbon and Ammonium read-across from
Oxidation) supporting
substance
(structural
analogue)

12.2. Persistence and degradability

Not readily biodegradable. The substance is inherently biodegradable and therefore has no potential to persist.

2-Allyloxymethyl-2-ethylpropanediol (682-11-1)
Method Value Exposure time Results:
OECD Test No. 302B: Inherent 31% 28d Inherently biodegradable
Biodegradability: Zahn-Wellens/
EVPA Test
OECD Test No. 301A: Ready 4% 14d Not readily biodegradable
Biodegradability: DOC Die-Away
Test (TG 301 A)

12.3. Bioaccumulative potential

No bioaccumulation potential.

Chemical Name Partition coefficient Bioconcentration factor (BCF)

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2-Allyloxymethyl-2-ethylpropanediol 1.4

12.4. Mobility in soil

The substance is not expected to adsorb to a high degree to suspended solids and sediment based upon the log Pow.

12.5. Results of PBT and vPvB assessment

This substance does not meet the criteria for classification as PBT or vPvB

12.6. Other adverse effects

None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste from residues/unused products
The product is not classified as hazardous waste. Incinerate at a licensed installation.

Contaminated packaging
Thoroughly emptied and clean packaging may be recycled. Contaminated packaging materials must be disposed of in the
same manner as the product.

Waste codes / waste designations according to EWC / AVV

Waste codes should be assigned by the user based on the application for which the product was used. Recommended Use: 16
03 06.

SECTION 14: Transport information

ADR Road transport

14.1 UN number Not regulated
14.2 UN proper shipping name Not regulated
14.3 Transport hazard class(es) Not regulated
Subsidiary class -
14.4 Packing Group Not regulated
14.5 Environmental hazard Not applicable
14.6 Special precautions for user None

RID Rail transport

14.1 UN number Not regulated
14.2 UN proper shipping name Not regulated
14.3 Transport hazard class(es) Not regulated
Subsidiary hazard class -
14.4 Packing Group Not regulated
14.5 Environmental hazard Not applicable
14.6 Special precautions for user None

IMDG Sea transport

14.1 UN number Not regulated
14.2 UN proper shipping name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing Group Not regulated
14.5 Marine pollutant Not applicable
14.6 Special precautions for user None
14.7 Transport in bulk according No information available
to Annex II of MARPOL 73/78 and
the IBC Code

IATA Air transport Not regulated

14.1 UN number Not regulated
14.2 UN proper shipping name Not regulated
14.3 Transport hazard class(es) Not regulated
14.4 Packing Group Not regulated

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14.5 Environmental hazard Not applicable

14.6 Special precautions for user None

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
International Regulations
Not applicable.

European Union

Authorisations and/or restrictions on use:

This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV)
This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

France

Occupational Illnesses (R-463-3, France) Not applicable

Germany
Water hazard class (WGK) Water endangering class = 2 (self classification)

15.2. Chemical safety assessment

A Chemical Safety Assessment has been carried out for this substance.

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

Issue Date 23-Jun-2021

Revision Date 22-Jun-2021

Revision Note SDS sections updated: 2: PBT and vPvB assessment, 8, 11.

This safety data sheet complies with the requirements of: Regulation (EC) No. 1907/2006, COMMISSION REGULATION
(EU) No. 830/2015 of 20 May 2015.

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.
The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

EUGB - BE

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